CN102210300A - Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system - Google Patents
Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system Download PDFInfo
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Abstract
The invention relates to a multifunctional atomizing agent for preventing and controlling pests of an inspection and quarantine system. A composition comprising a sterilizing composition, an insecticidal composition, a novel rodenticide, a surfactant, an atomizing agent and a cosolvent serves as preparation and application of the multifunctional atomizing agent. The multifunctional atomizing agent comprises the following ingredients in percentage by mass: 0.01 to 10 percent of the sterilizing composition, 0.1 to 15 percent of the insecticidal composition, 0.1 to 15 percent of the novel rodenticide, 1 to 40 percent of the surfactant, 0 to 40 percent of the atomizing agent, 1 to 10 percent of the cosolvent and the balance of water. The invention aims to provide preparation of the multifunctional atomizing agent. The preparation of the multifunctional atomizing agent comprises the following steps of: mixing and stirring the insecticidal composition, the novel rodenticide, the surfactant and the cosolvent according to the mass percentage for 1 hour to prepare a mixed substance A; mixing and stirring the mixed substance A and one half of the water for 1 hour to prepare a mixed substance B; mixing and stirring the sterilizing composition, the atomizing agent and on half of the rest of the water according to the mass percentage for 1 hour to prepare a mixed substance C; mixing and stirring the mixed substance B and the mixed substance C for 1 hour; standing for 1 hour; measuring the content of the mixture; and packaging the qualified mixture to prepare the qualified product.
Description
Technical field
PCO product scope such as the invention belongs to disinfection, desinsection and kill mouse, relate to the preparation and the application of inspection and quarantine system control pest multipotency Alevaire, wherein contain of preparation and the application of the composition of disinfection composition, Pesticidal combination, novel rat-bane, surfactant, Alevaire, cosolvent as inspection and quarantine system control pest multipotency Alevaire.
Background technology
In the present common infectious disease of WHO report, there is 1/3rd infectious disease to cause by pests such as insects which are carriers of diseases, as the plague, cholera, dengue fever, bird flu, Hemorrhagic fever, Japanese Type-B encephalitis, kala-azar, malaria, schistosomiasis, influenza etc., but in the inspection and quarantine system, be used for the PCO field PCO medicament is divided into disinfectant, insecticide and rat-bane, disinfectant belongs to the Ministry of Public Health and examines management in administrative permission, insecticide and rat-bane belong to the Ministry of Agriculture and examine management, two big classes have been divided into from system and management, but sterilization is with desinsection and to kill mouse be inseparable when the health and epidemic prevention of Public Health Emergencies and PCO, so put into different categories and can cause the back disinfestation and deratization of in actual application, sterilizing earlier, not only waste of manpower, material resources, increase use cost, can cause the secondary pollution environment simultaneously, also can exist sterilization and problems such as the disinfestation and deratization effect is undesirable to occur.
For a long time, the disinfectant that is used for always extensively adopting in the PCO field in the inspection and quarantine system is: chlorine-containing disinfectant, brominated disinfectant etc., the disinfestation and deratization agent is: contact insecticide, fumigant and anticoagulation rodenticide etc.
The disinfection principle of chlorine-containing disinfectant is based on its hypochlorous sterilizing mechanisms by generating behind the hydrolysis in water.But in long-term use, find following shortcoming:
1, the pH value narrow range of its effective killing microorganisms, its minimum dissociation reaction occurs in the pH7.0 place, and when the pH value continued to raise, hypochlorous acid was dissociated into the hypochlorite ion of the power extreme difference of killing livestock easily in a large number.Because hypochlorite ion has negative electrical charge, when its when the microorganism, be subjected to the anion exclusion of load on the microorganism wall, be difficult to permeate through cell membranes, therefore just lost the vigor of killing microorganisms;
2, can generate carcinogenic substance (as: chloroform) with the organic matter in the water;
3, the smelly pungent taste of unpleasant chlorine is arranged, skin is had excitant;
4, metal is corrosive, fabric is had damage etc.
The disinfection principle of bromine-containing disinfectant is based on its sterilizing mechanisms by the hypobromous acid that generates behind the hydrolysis in water.But in use, find following shortcoming:
1, its solvability in water is little, and dissolution velocity is slow, has influenced it greatly as the application of disinfectant in the sterilization field;
2, unpleasant bromine pungent taste is arranged, skin is had excitant;
3, metal is corrosive etc.
Contact insecticide mostly is the pyrethroid medicament, as Permanone, tetramethrin, decis, flucythrinate, cypermethrin etc.
Permanone has stronger tagging and stomach poison function, has that the power of knocking down is strong, the fireballing characteristics of desinsection.More stable to light, also slower to the pest resistance development under equal service condition, efficient to lepidopterous larvae.Can be used for various pests such as crop control cabbage caterpillar, aphid, cotton bollworm, pink bollworm, cotten aphid, green plant bug, striped flea-beetle, peach fruit borer, phyllocnistis citrella stainton, potato ladybug, tea geometrid, tea caterpillar, the thin moth of tea such as vegetables, tealeaves, fruit tree, cotton, sanitary insect pests such as mosquito, fly, flea, cockroach, louse are also had good effect.
Tetramethrin is a kind of powerful synthetic pesticide, and sanitary insect pests such as mosquito, fly are had quick down effect, but the poor performance that causes death has anabiosis, and use therefore will be mixed with the medicament of other good disinsection effect.This medicine has certain effect of driveing to blattaria, perch is run out under the effect of blattaria at tetramethrin at dark place and is subjected to the poisoning of other insecticides and causes death.This medicine is that world health organisation recommendations is used for one of sanitarian main insecticide, but result of use is not obvious separately.
Decis has another name called " decis ", is the highest a kind of of virulence in the present chrysanthemum ester insecticide.Insecticidal spectrum is wide, effective to various pests such as Lepidoptera, orthoptera, thrips, Semiptera, diptera, coleopteras, but very low or invalid substantially to preventive effects such as mite class, scale insect, mirid pentatomids, also can stimulate the breeding of mite class, when the worm mite is concurrent, use with specialized acaricide.Decis belongs to the malicious class of poisoning.The skin contact can cause irritation, red papule occurs.During acute poisoning, the lighter has headache, dizziness, feels sick, vomiting, poor appetite, weak, and weight person muscle bundle also can occur and tremble and twitch, and the WHO hazard rating is the II level, medium harmfulness.
Flucythrinate claims flucythrinate again, belongs to pyrethrin pesticide, is the moderate toxicity insecticide, the mode of action based on tag, stomach toxicity, do not have stifling and systemic action, insecticidal spectrum is wide, drug effect is rapid.Can use with general insecticide, bactericide, its biologically active is lower than by Temperature Influence and kills chrysanthemum ester and chlorobenzene chrysanthemum ester, and the WHO hazard rating is the II level, medium harmfulness.
Cypermethrin claims struggle again, belongs to the chrysanthemum esters medicine, is the moderate toxicity insecticide, and insecticidal spectrum is wide, and drug effect is rapid, and the WHO hazard rating is the II level, medium harmfulness.
The long-term use of above-mentioned pyrethroid medicament makes sanitary insect pest such as insects such as cockroach, mosquitos and flies improve greatly the pesticide resistance of this type of medicament, has occurred the problem that control efficiency generally reduces in recent years.
Fumigant mostly is Celfume and vikane.
Celfume is a kind of liquid of colorless and odorless, it has strong fumigation action, can be efficient, kill various pests wide spectrum, soil is had very strong penetration capacity, can be penetrated in the organism that rots to decompose, thereby reach the purpose of deinsectization, diseases prevention, weeding.Along with closing on of World Earth Day, this methyl bromide fumigation agent that is widely used has caused global concern.Since the forties in 20th century, just be extensive use of by various countries always.Because it has plurality of advantages, thereby very popular; Caused many environment and soil issues because of it again, thus controversial.Rise the nineties in 20th century, countries in the world government all is tending towards stopping using this fumigant for security consideration, also halted for the previous period by United Nations Environment Programme, it is a kind of material of ozone layer depletion, according to " Montreal Protocol Copenhagen amendment ", developed country eliminated in 2005, and developing country also will eliminate in 2015.
Vikane is no color or smell gas at normal temperatures and pressures, have that diffusion permeability is strong, broad spectrum disinfestation, dosage are economized, residual quantity is low, desinsection speed fast, the gas time of loosing is short, low temperature is easy to use, to germination rate characteristics such as influence and toxicity is not lower, be applied to the survive the winter control of insect, the tree moth dryness insect that lives of warehouse, freighter, container and building, reservoir dam, termite control and gardens more and more widely.China has just begun to manufacture experimently vikane the beginning of the eighties.But U.S.'s scientist's current research shows, can become a kind of potent greenhouse gases after being dispersed into air, and it endangers greater than the previous judgement of scientist, and its acute toxic action mainly damages central nervous system, causes convulsions.Environment there is harm, can pollutes, must not be used for lived plant, fruit, vegetables and all food according to " SN/T 1281-2003 " vikane to water body.It is reported that it is 4800 times of one kilogram of carbonic acid gas that one kilogram of vikane is discharged in the atmosphere effect to global warming, but it is increasing with annual 5% speed.
Summary of the invention
The objective of the invention is to provides the preparation and the application of inspection and quarantine system control pest multipotency Alevaire at the various drawbacks of existing inspection and quarantine system control pest product with for solving the technical problem that exists in the known technology, especially with preparation and the application as inspection and quarantine system control pest multipotency Alevaire of the composition of disinfection composition, Pesticidal combination, novel rat-bane, surfactant, Alevaire, cosolvent, it has characteristics such as safety, efficient, wide spectrum, convenient, low toxicity, environmental protection.
One of purpose of the present invention provides inspection and quarantine system control pest multipotency Alevaire, especially a kind of preparation that prevents and treats pest multipotency Alevaire with the composition of disinfection composition, Pesticidal combination, novel rat-bane, surfactant, Alevaire, cosolvent as the inspection and quarantine system.
Inspection and quarantine of the present invention system control pest multipotency Alevaire contains following component by mass percent:
| Component | Mass percent % |
| The disinfection composition | 0.01~10 |
| Pesticidal combination | 0.1~15 |
| Novel rat-bane | 0.1~15 |
| Surfactant | 10~40 |
| Alevaire | 1~40 |
| Cosolvent | 1~10 |
| Water | Surplus |
Disinfection composition described in the component is selected from: quaternary ammonium compound, the mixture of one or more of guanidine compound, quaternary ammonium compound comprises benzalkonium bromide, benzalkonium chloride, the n-zephiran, the mixture of one or more of n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides, guanidine compound comprises polyhexamethylene guanide, poly hexamethylene biguanide, poly-ring is guanidine, the mixture of one or more in poly-[2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
Wherein the n in the n-zephiran is 8 ~ 18, as cetalkonium chloride, and molecular formula: C
25H
46NCl is white or light yellow solid.Soluble in water, ethanol are insoluble to benzene, ether.The fusing point of pure product is 68 ℃, has cleaning, bactericidal action.Character with typical cationic surfactants can produce a large amount of foams during its aqueous solution brute force vibration.Good dispersion is arranged, peel off the foundry loam effect.Stable in properties, fast light, heat-resisting, non-volatility, but long term storage.
N in wherein two n-zephirans is 8 ~ 14.Two n-alkyl-dimethyl ammonium chlorides are two long chain quaternaries.Product type has multiple combining forms such as two octyl groups, two certain herbaceous plants with big flowers base, two dodecyl, octyl group certain herbaceous plants with big flowers base, and its bactericidal effect obviously strengthens.As: two octyldimethyl ammonium bromides, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride etc.
Wherein the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, molecular formula: N-C
23H
42Cl, molecular weight: 368.0393, can be used as hospital, nursing home, the disinfectant in public place and the industry, and the Biocidal algae-killing agent in swimming pool and the Treatment of Industrial Water, wood preservation, and the sterilization of medicine equipment can be used as deodorant simultaneously, product is: alkyl (50%C12,30%C14,17%C16,3%C18) dimethyl ethyl benzyl ammonium chloride, alkyl (60%C14,30%C16,5%C12,5%C18) dimethyl ethyl benzyl ammonium chloride, as the dodecyl dimethyl ethylbenzylammonium chloride, myristyl dimethyl ethyl benzyl ammonium chloride etc., the structural formula of n-alkyl dimethyl ethylbenzylammonium chloride is as follows:
Wherein benzalkonium bromide claims dodecyl dimethyl benzyl ammonium bromide again, molecular formula: C
21H
38BrN, be white waxy solid or yellow colloid, the aqueous solution shows neutrality or faintly alkaline reaction, soluble in water, be slightly soluble in ethanol, be one of surfactant of using always, have cleaning, sterilizing and algae removal effect, being widely used in aspects such as sterilization, sterilization, anticorrosion, emulsification, de-sludging, solubilising, is industrial cycle water treatment non-oxidizable Biocidal algae-killing agent commonly used, glutinous mud remover and cleaning agent, also can be used for the control of microorganisms and the cleaning of circulation.
Wherein benzalkonium chloride claims the dimethyl benzyl alkyl ammomium chloride again, molecular formula: C
17H
30ClN, belong to cationic surfactant, belong to non-oxidizable bactericide, have wide spectrum, sterilization algae removal ability efficiently, can control bacterium algae propagation and foundry loam growth in the water effectively, and have the effect of peeling off of good foundry loam and certain dispersion, osmosis, have simultaneously certain deoil, deodorizing capability and corrosion inhibition.
Wherein the hydrochloride in the polyhexamethylene guanide is a kind of white amorphous powder, and no special odor is soluble in water, and the aqueous solution is colourless to faint yellow, tasteless, does not fire not quick-friedly, and metal material is not had corrosion substantially, and decomposition temperature is greater than 400 ℃, and molecular formula is (C
7H
16N
3Cl)
n, to the handle no discoloration in surface, undergoing no deterioration in 2 years, the aqueous solution of 0.1 % concentration has the taste of little hardship.Very extensive in the every field application, can be used as the candida albicans disinfectant of various body surfaces, and can make daily mould inhibitor; Can be widely used in beverage and food-processing industry, drinking water and swimming pool, lake water, pool, cooling tower, fountain, remove algae, oil exploitation, construction material mildewproof additive, plant's sterilization, and be used for textile industry, paper-making industry, wood-processing industry, rubber industry, agricultural etc., also can be used as the flocculant of waste water treatment.
Hexamethylene wherein, its colorless and odorless, water-soluble fully, stable in properties, its bactericidal mechanism is different with chlorine-containing disinfectant, strong oxidation reaction does not take place in the sterilization process, produce precipitation in the cell, the quantity of endocellular phosphorus rises simultaneously, thereby block cell wall and nucleic acid is synthetic; Reduce the cell permeability of the membrane, stop phosphorus to cell exocrine, and the energy bind protein, this disinfectant is widely used in pharmaceuticals industry, has when reporting it as mouthwash, and is very strong to the Gram-negative bacteria property killed.
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Es-EXTHIN wherein, chemical name: dextrorotation-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid-(R, S)-2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be the former medicine of a kind of wide spectrum pyrethroid, for upsetting the contact killing type never poison of aixs cylinder conduction, act on insect and cause the violent paralysis effect of ordering, reclining falls, until death, very strong tagging and repellent action arranged, and the power of knocking down is stronger, and it is strong 2 times that its insecticidal toxicity is executed allethrin than the right side, and knock down the active tetramethrin that surpasses, be mainly used to prevent and treat flying pests such as mosquito, fly, mosquito, fly, wasp, cockroach, flea, ant are had special effect, structural formula is as follows:
S-bioallethrin wherein, chemical name: (1R)-trans-chrysanthemate-(S)-and 2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be a kind of wide spectrum pyrethroid insecticides, very strong tagging and repellent action arranged, the power of knocking down is stronger, and insecticidal toxicity is 4.9 times of allethrin, and structural formula is as follows:
The trans phenothrin of wherein rich dextrorotation claims d-phenothrin again, chemical name: (1R)-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid-3-phenoxy benzyl ester, molecular formula: C
23H
26O
3, molecular weight: 350.45, be unique nontoxic product in the pyrethroid, be the unique allowance of the U.S. is used for the insecticide that civil aviaton uses, be one of insecticide of world health organisation recommendations.These product have for insect tags and stomach poison function, and insecticidal spectrum is wide, high 8.5 ~ 20 times than the Dalmatian chrysanthemum class to the deadly power of insect, can be widely used in the control of household, warehousing, public health, industrial area insect.
Tetrafluoro methothrin wherein, chemical name: 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid 2,3,5,6-tetrafluoro-4-(methoxy) benzyl ester, molecular formula: C
19H
22F
4O
3, molecular weight: the 374.37th, suck and the contact killing type insecticide agent, knock down and kill activity to what sanitary insect pests such as mosquito, fly had a brilliance.In the experimental concentration scope, the acute toxicity and chronic toxicity of tetrafluoro methothrin is extremely low, no teratogenesis, carcinogenicity, to Aedes aegypti, housefly, Groton bug, that a curtain casemaking clothes moth is knocked down speed is fast, consumption is little, be suitable for the hygienic biocide goods, belong to broad spectrum pesticide, energy effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Transfluthrin wherein, chemical name: 2,3,5, the 6-ptfe benzyl (1R, 3S)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
15H
12Cl
2F
4O
2, molecular weight: 371.16, this product desinsection wide spectrum, energy effectively preventing sanitary insect pest and storage insect have quick knockdown effect to dipteral insect such as mosquito class, and cockroach, bedbug are had good residual effect.
Seven fluorobenzene chrysanthemum esters wherein.Chemical name: 2,3,5,6-tetrafluoro-4-methyl-benzyl (Z)-(1RS, 3RS)-3-(2-chloro-2,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
14ClF
7O
2, molecular weight: 418.73, this product belongs to pyrethroid insecticides, is soil insecticide, can prevent and treat coleoptera and Lepidoptera and some Diptera pest of perching in soil well, than transfluthrin stronger killing action is arranged.
Novel rat-bane described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, inclined to one side seven fluorine methoxy chrysanthemum esters, seven fluorine to go first chrysanthemum ester, inclined to one side seven fluorine to remove first chrysanthemum ester, the mixture of one or more in the tefluthrin etc. partially.
Seven fluorine methothrins wherein, chemical name: 2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
15ClF
7O
3Molecular weight: the 448.6th, a kind of novel dissipation class agricultural chemicals, be mainly used in hygienic insecticides such as preparation aerosol and propellant, with pests such as control cockroach, mosquito, ant, flea, dirt mite, silverfish, cricket, spider, mouse, have the very strong suction and the ability of tagging, have the stronger ability of killing than tetrafluoro methothrin, be better than seven fluorobenzene chrysanthemum esters, structural formula is as follows:
。
Wherein seven fluorine methyl ethers remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy ester, molecular formula: C
18H
17F
7O
3, molecular weight: 414.1, belong to novel dissipation class agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is as follows:
。
Wherein inclined to one side seven fluorine methoxy chrysanthemum esters, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15F
7O
3, molecular weight: 400.1, belong to novel dissipation class agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is as follows:
。
Wherein inclined to one side tefluthrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
17H
15F
7O
2, molecular weight: 384.1, belong to novel dissipation class agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is as follows:
Wherein inclined to one side seven fluorine remove first chrysanthemum ester, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-ptfe benzyl, molecular formula: C
16H
13F
7O
2, molecular weight: 370.1, belong to novel dissipation class agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is as follows:
Seven fluorine methoxy chrysanthemum esters wherein, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15ClF
7O
3, molecular weight: 434.6, belong to novel dissipation class agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is as follows:
Wherein seven fluorine remove first chrysanthemum ester, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
16H
13ClF
7O
2, molecular weight: 434.6, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is as follows:
Surfactant described in the component is selected from: (TX/NP)-and one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc.
(TX/NP)-n wherein, chemical name: polyoxyethylene nonylphenol ether, have been widely used at washing agent, printing and dyeing, chemical industry, good penetration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance are arranged, (TX/NP)-n among the n is 3,4,6,7,10,15..
OP-10 wherein, chemical name: alkylphenol polyoxyethylene, main with the emulsifier on the used as pesticides, also be the good finishing agent of textile industry, defoamer, washing agent, dispersant, emulsifier, softening agent, dyeing assistant, fibre finishing, crude oil demulsifier etc.
AEO-n wherein, chemical name: fatty alcohol-polyoxyethylene ether, chemical composition: natural fatty alcohol and oxirane synthetic, wherein the n among the AEO-n is 3 or 9, AEO-3 can make water-in-oil emulsifier, and AEO-9 is mainly used in Wool detergent, woolen industry degreasing agent, general industry emulsifier.
Isomery alcohol APEO wherein, chemical composition: isomery alcohol and polymers of ethylene oxide, belong to nonionic surface active agent, the general R of structural formula: RO-(C2H4O) n H:(is C8, C11, C13), performance: this product is colourless or weak yellow liquid, and emulsifying capacity is strong, the surface-active height, anti-hard water, the washing performance is strong, and chemical stability and Environmental compatibility are good in the pH value scope of broad.Can be used as dispersant, wetting agent, bleeding agent, washing agent, be widely used in family expenses and industrial washing field, leather is had tangible degreasing; Be specially adapted to do emulsifier, better performances.
Wherein isomery alcohol polyoxyethylene poly-oxygen propylene aether is to react in proportion with oxirane, expoxy propane with isomery alcohol to form, and is one and has 100% biodegradable novel, low bubble, efficient, environment-friendly type non-ionic surface active agent.Good, acidproof, alkaline-resisting, anti-oxidant with various surfactants, auxiliary agent, additive, solvent compatibility.Characteristics: have excellent emulsification, dispersibility; Have excellent permeation and alkali tolerance; Have excellent washing, dirt-removing power; Extremely low foam belongs to ultralow bubble interfacial agent, does not use defoamer, does not therefore have silicon spot problem; Nontoxic, non-stimulated, free from extraneous odour, nonflammable explosive, safe in utilization.
Alevaire described in the component is: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.;
Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.It has passed through the U.S. FDA authentication, meets American Pharmacopeia (USP), NF (NF), and Food Chemistry code (FCC) standard is widely used in the production of industries such as food, pharmacy, feed, personal care articles, chemistry.It is the water white transparency thick liquid, and it is sweet to distinguish the flavor of, and has hygroscopicity, and is miscible with water, lower aliphatic alcohols, glycerine, acetic acid, acetone, can be used as solvent, dispersant, lubricant, emulsifier etc. and is used for cosmetics, agricultural chemicals, food, medicine and other fields.
Wherein 1, the 2-dihydroxypropane is the stable water imbibition liquid of colourless thickness, almost tasteless odorless, with water, ethanol and multiple immiscible organic solvent, as gas-chromatography fixer, solvent, antifreeze, plasticizer, dehydrating agent, carrier solvent, wetting agent, humectant, anticaking agent, antioxidant, surface-active, stabilizing agent, thickener, emulsifier, processing aid, it classifies food processing aid as among the GB 2760-96, its aqueous solution is effective antifreeze, can be used as humectant in the cosmetics, softening agent, solvent etc.
Wherein trihydroxy propane outward appearance is the water white transparency thick liquid, odorless, tasteless, have hygroscopicity, humectation, a property of softening, it is neutral that the aqueous solution is, can mix arbitrarily with water, ethanol, methyl alcohol, have good freeze-proof, be widely used in industries such as weaving, printing and dyeing, papermaking, printing, washing agent, daily use chemicals, system wine, food, cigarette, glassine paper, enamel, oil, electronics, rubber, plastics, process hides, chemistry, chemical fibre.Main as humectant, humectant, hygroscopic agent, lubricant, softening agent, softening agent, thickener, plasticizer, thinner, antifreezing agent etc.
Wherein the triethylene-glycol outward appearance is that no color or smell has the hygroscopicity thick liquid, can be miscible with water, ethanol, benzene, toluene, be insoluble in ethers, and be insoluble to benzinum, have hygroscopicity, have the character of pure and mild ether.As solvent, extractant, desiccant, air disinfection agent etc.The toxicity data are little poison, LD
50(rat oral) 16.8ml/kg. is to eyes and skin nonirritant.
Cosolvent described in the component is selected from: 95% ethanol.
Water described in the component is deionized water.
Each component is role in the present invention:
Disinfection composition described in the component is the environmental protection and safety type disinfectant, has the quick sterilization effect, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, is not subjected to organic substance influence, good stability;
Pesticidal combination described in the component for sucking and the contact killing type insecticide agent, has and knocks down fast and the quick-acting lethal effects of killing, and to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, is not subjected to organic substance influence, good stability;
Novel rat-bane described in the component for sucking and the contact killing type rat-bane, has and knocks down fast and the quick-acting lethal effects of killing, to mucocutaneous nonirritant, good stability;
Surfactant described in the component plays emulsification, the dissolving insecticide component;
Alevaire described in the component plays good dispersion, atomizing and synergistic effect, to mucocutaneous non-stimulated, good stability is harmless to article, to metal and fabric non-corrosiveness.
Cosolvent described in the component plays dissolution and antifreeze effect.
Inspection and quarantine of the present invention system control pest multipotency Alevaire is the proportioning of following mass percent most preferably:
| Component | Mass percent % |
| The disinfection composition | 0.1~7 |
| Pesticidal combination | 1~10 |
| Novel rat-bane | 1~10 |
| Surfactant | 15~35 |
| Alevaire | 5~35 |
| Cosolvent | 2~8 |
| Water | Surplus |
Disinfection composition described in the component is selected from: quaternary ammonium compound, guanidine compound, quaternary ammonium compound comprises benzalkonium bromide, benzalkonium chloride, the n-zephiran, the mixture of one or more of n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides, wherein the n in the n-zephiran is 8 ~ 18, n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, n in two n-alkyl-dimethyl ammonium chlorides is 8 ~ 14, guanidine compound comprises polyhexamethylene guanide, hexamethylene, poly-ring is guanidine, the mixture of one or more in poly-[2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.;
Novel rat-bane described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, inclined to one side seven fluorine methoxy chrysanthemum esters, seven fluorine to go first chrysanthemum ester, inclined to one side seven fluorine to remove first chrysanthemum ester, the mixture of one or more in the tefluthrin etc. partially;
Surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4,6,7,10,15.; N among the AEO-n is 3 or 9.
Alevaire described in the component is: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
Cosolvent described in the component is selected from: 95% ethanol;
Water described in the component is: deionized water.
Another object of the present invention is, the compound method of inspection and quarantine system control pest multipotency Alevaire is provided, and it mainly is to adopt disinfection composition, Pesticidal combination, novel rat-bane, surfactant, Alevaire, cosolvent and water formulated through mixing, reacting, stir, leave standstill.
The compound method that the above-mentioned inspection and quarantine system that contains the mass percent component prevents and treats pest multipotency Alevaire is as follows:
1, Pesticidal combination, novel rat-bane, surfactant and cosolvent are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, disinfection composition and Alevaire are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Purpose of the present invention also comprises the application that above-mentioned inspection and quarantine system control pest multipotency Alevaire is provided:
1, by the multi-functional atomizer (patent No.: 201020662097.X) and the Portable atomizer (patent No.: 201020682031.7) be applied to disinfection, desinsection and the PCO such as kill mouse in the sealed container space of inspection and quarantine system, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse;
2, by the multi-functional atomizer (patent No.: 201020662097.X) and the Portable atomizer (patent No.: 201020682031.7) be applied to entry and exit cargo hold, the main cabin of inspection and quarantine system, automotive interior, railway car, the disinfection in aircraft hold, main cabin, desinsection and PCO such as kill mouse can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse;
3, by the multi-functional atomizer (patent No.: 201020662097.X) and the Portable atomizer (patent No.: 201020682031.7) be applied to the immigration junk of inspection and quarantine system, disinfection, the desinsection of immigration bulk goods and PCO such as kill mouse, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse;
4, by the multi-functional atomizer (patent No.: 201020662097.X) and the Portable atomizer (patent No.: 201020682031.7) be applied to disinfection, the desinsection of the environment of import and export food processing enterprise, indoor and air and PCO such as kill mouse, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse.
Combination matching between each component of inspection and quarantine of the present invention system control pest multipotency Alevaire has the effect of Synergistic, and has following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric are not had corrosivity;
3, have no irritating odor, colourless, be not subjected to the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
The experimental study that inspection and quarantine of the present invention system control pest multipotency Alevaire product is carried out:
The disinfectant of experimental example 1 described component and the sterilization experiment of one-component thimerosal contrast (cooperative synergism effect experiment):
1, the prescription of one-component thimerosal and component disinfection composition is formed:
| Component | Prescription |
| A | Be dodecyl benzyl dimethyl ammonium chloride |
| B | Be polyhexamethylene guanide |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, experimental result:
| Component | Content | 1min kills logarithm value to Escherichia coli |
| The A(quaternary ammonium compound) | 100ppm | ＞1.2 |
| The B(guanidine compound) | 100ppm | ＞1.0 |
| A+B | ? | ＞3.0 |
Investigate by above-mentioned experimental technique, when quaternary ammonium compound wherein is selected from: (wherein the n in the n-zephiran is 8-18 to the mixture of one or more in benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and the two n-alkyl-dimethyl ammonium chloride, n in two n-alkyl-dimethyl ammonium chlorides is 8-14, and the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18); Guanidine compound is selected from: polyhexamethylene guanide, hexamethylene, poly-ring is guanidine, the mixture of one or more in poly-[2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or when being selected from the mixture of above-mentioned guanidine compound and polyhexamethylene guanide, also obtained as experimental example 1(cooperative synergism effect experiment) effect of same Synergistic, promptly ideal with the sterilization effect of A+B, simultaneously, the combining form of the A+B of described product is being investigated bacterial propagule, mycobacterium, virus, killing in the process of fungi etc., the Disinfection Effect that has equally also shown the good Synergistic of A+B combination, be that special feature of the present invention is, after sanitizing composition in the component is made up by quarternary ammonium salt compound and guanidine compound, it has outstanding disinfection activity, and this activity is to be predicted out by the bactericidal action of known single component.
The Pesticidal combination of experimental example 2 described components and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, the prescription of one-component insecticide described in the component and component Pesticidal combination is formed:
| Component | Prescription |
| A | Be the Es-EXTHIN |
| B | Be the trans phenothrin of rich dextrorotation |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, result of the test:
| Component | To American cockroach 24H lethality rate |
| A | ＞70% |
| B | ＞70% |
| A+B | ＞95% |
Investigate by above-mentioned experimental technique, when Pesticidal combination wherein is selected from: the Es-EXTHIN, the S-bioallethrin, the trans phenothrin of rich dextrorotation, the tetrafluoro methothrin, transfluthrin, during the mixture of one or more in the seven fluorobenzene chrysanthemum esters etc., also obtained as experimental example 1(cooperative synergism effect experiment) effect of same Synergistic, promptly ideal with the desinsection of A+B, simultaneously, the combining form of the A+B of described product is being investigated American cockroach, killing in the process of mosquitos and flies etc., the killing effect that has equally also shown the good Synergistic of A+B combination, be that special feature of the present invention is, Pesticidal combination in the component is by the Es-EXTHIN, the S-bioallethrin, the trans phenothrin of rich dextrorotation, the tetrafluoro methothrin, transfluthrin, after the mixture combination of one or more in the seven fluorobenzene chrysanthemum esters etc., it has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The effect experiment of experimental example 3 inspection and quarantine of the present invention system control pest multipotency Alevaire:
The killing effect of 1 pair of American cockroach of example, culex, housefly, mouse:
The killing effect of 2 pairs of staphylococcus aureuses of example (ATCC 6538), Escherichia coli (8099), Candida albicans (ATCC10231):
The killing effect of 3 pairs of verdigris vacations of example unicellular (ATCC15542):
The field experiment of experimental example 4 inspection and quarantine of the present invention system control pest multipotency Alevaire:
The air that example 1 is done in certain hospital and the field trial of body surface:
Example 2 certain port sealed container (volume: 33.2m3) to the on-the-spot killing effect of American cockroach, culex, housefly:
Embodiment
Embodiment 1
| Component | Mass percent % |
| Dodecyl benzyl dimethyl ammonium chloride | 0.1~3 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~3 |
| Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides | 0.1~3 |
| Two octyldimethyl ammonium chlorides | 0.1~3 |
| Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride | 0.1~3 |
| The Es-EXTHIN | 0.1~3 |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine methothrins | 1~5 |
| TX-10 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation, seven fluorine methothrins, TX-10 and 95% ethanol are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride, two octyldimethyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 2
| Component | Mass percent % |
| Cetalkonium chloride | 0.1~3 |
| Benzalkonium bromide | 0.1~3 |
| Myristyl dimethyl ethyl benzyl ammonium chloride | 0.1~3 |
| Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride | 0.1~3 |
| The tetrafluoro methothrin | 1~5 |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine methothrins | 1~5 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| OP-10 | 15~30 |
| Ethylene glycol APEO 200 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, tetrafluoro methothrin, seven fluorobenzene chrysanthemum esters, seven fluorine methothrins, seven fluorine methyl ethers are gone permethrin, OP-10 and 95% ethanol mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, cetalkonium chloride, benzalkonium bromide, myristyl dimethyl ethyl benzyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and ethylene glycol APEO 200, triethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 3
| Component | Mass percent % |
| Dodecyl benzyl dimethyl ammonium chloride | 0.1~5 |
| Polyhexamethylene guanide | 0.1~5 |
| The S-EXTHIN | 1~5 |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine methothrins | 1~5 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| AEO-3 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, S-EXTHIN, the trans phenothrin of rich dextrorotation, seven fluorine methothrins, seven fluorine methyl ethers are gone permethrin, AEO-3 and 95% ethanol mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl benzyl dimethyl ammonium chloride, polyhexamethylene guanide and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 4
| Component | Mass percent % |
| Polyhexamethylene guanide | 0.1~5 |
| Hexamethylene | 0.1~5 |
| The tetrafluoro phenothrin | 1~5 |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine remove first chrysanthemum ester | 1~5 |
| Inclined to one side seven fluorine remove first chrysanthemum ester | 1~5 |
| NP-15 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, tetrafluoro phenothrin, seven fluorobenzene chrysanthemum esters, seven fluorine are gone first chrysanthemum ester, inclined to one side seven fluorine go first chrysanthemum ester, NP-15 and 95% ethanol to mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with polyhexamethylene guanide, hexamethylene and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 5
| Component | Mass percent % |
| Benzalkonium bromide | 0.1~5 |
| Benzalkonium chloride | 0.1~5 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~5 |
| The tetrafluoro phenothrin | 0~2 |
| Transfluthrin | 0~2 |
| Seven fluorobenzene chrysanthemum esters | 0~2 |
| Inclined to one side tefluthrin | 0~3 |
| Seven fluorine remove first chrysanthemum ester | 0~3 |
| Inclined to one side seven fluorine remove first chrysanthemum ester | 0~3 |
| Isomery alcohol APEO | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, tetrafluoro phenothrin, transfluthrin, seven fluorobenzene chrysanthemum esters, inclined to one side tefluthrin, seven fluorine are gone first chrysanthemum ester, inclined to one side seven fluorine go first chrysanthemum ester, isomery alcohol APEO and 95% ethanol to mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with benzalkonium bromide, benzalkonium chloride, dodecyl dimethyl ethylbenzylammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 6
| Component | Mass percent % |
| Benzalkonium bromide | 0.1~5 |
| Benzalkonium chloride | 0.1~5 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~5 |
| The myristyl dimethyl benzyl ammonium chloride | 0.1~5 |
| The tetrafluoro phenothrin | 0~2 |
| Transfluthrin | 0~2 |
| Seven fluorobenzene chrysanthemum esters | 0~2 |
| The S-bioallethrin | 0~2 |
| Inclined to one side tefluthrin | 0~3 |
| Seven fluorine remove first chrysanthemum ester | 0~3 |
| Inclined to one side seven fluorine remove first chrysanthemum ester | 0~3 |
| Seven fluorine methoxy chrysanthemum esters | 0~3 |
| TX-7 | 15~30 |
| Ethylene glycol APEO 400 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, tetrafluoro phenothrin, transfluthrin, seven fluorobenzene chrysanthemum esters, S-bioallethrin, inclined to one side tefluthrin, seven fluorine are gone first chrysanthemum ester, inclined to one side seven fluorine go first chrysanthemum ester, inclined to one side seven fluorine methoxy chrysanthemum esters, TX-7 and 95% ethanol to mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, benzalkonium bromide, benzalkonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, myristyl dimethyl benzyl ammonium chloride and ethylene glycol APEO 400, triethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 7
| Component | Mass percent % |
| Benzalkonium bromide | 0.1~5 |
| Benzalkonium chloride | 0.1~5 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~5 |
| The myristyl dimethyl benzyl ammonium chloride | 0.1~5 |
| Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride | 0.1~5 |
| The tetrafluoro phenothrin | 0~2 |
| Transfluthrin | 0~2 |
| Seven fluorobenzene chrysanthemum esters | 0~2 |
| The S-bioallethrin | 0~2 |
| The Es-EXTHIN | 0~2 |
| Inclined to one side tefluthrin | 0~3 |
| Seven fluorine remove first chrysanthemum ester | 0~3 |
| Inclined to one side seven fluorine remove first chrysanthemum ester | 0~3 |
| Seven fluorine methoxy chrysanthemum esters | 0~3 |
| Seven fluorine methothrins | 0~3 |
| OP-10 | 5-15 |
| TX-10 | 5-15 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 5~25 |
| Tetraethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, tetrafluoro phenothrin, transfluthrin, seven fluorobenzene chrysanthemum esters, S-bioallethrin, Es-EXTHIN, inclined to one side tefluthrin, seven fluorine are gone first chrysanthemum ester, inclined to one side seven fluorine go first chrysanthemum ester, inclined to one side seven fluorine methoxy chrysanthemum esters, seven fluorine methothrins, OP-10, TX-10 and 95% ethanol to mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, benzalkonium bromide, benzalkonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, myristyl dimethyl benzyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and 2-ethyl-2-(methylol)-1,3 propane diols, tetraethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 8
| Component | Mass percent % |
| The dodecyl dimethyl ethylbenzylammonium chloride | 1~6 |
| Seven fluorobenzene chrysanthemum esters | 1~8 |
| Seven fluorine methoxy chrysanthemum esters | 1~8 |
| AEO-9 | 15~30 |
| Tetraethylene-glycol | 15~35 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, seven fluorine methoxy chrysanthemum esters, AEO-9 and 95% ethanol are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, dodecyl dimethyl ethylbenzylammonium chloride and tetraethylene-glycol are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 9
| Component | Mass percent % |
| Hexamethylene | 1~6 |
| Seven fluorobenzene chrysanthemum esters | 1~8 |
| Seven fluorine methoxy chrysanthemum esters | 1~8 |
| TX-15 | 15~30 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 15~35 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, seven fluorine methoxy chrysanthemum esters, TX-15 and 95% ethanol are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, hexamethylene and 2-ethyl-2-(methylol)-1,3 propane diols are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 10
| Component | Mass percent % |
| Hexamethylene | 1~6 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 1~6 |
| The trans phenothrin of rich dextrorotation | 0.5~8 |
| Seven fluorobenzene chrysanthemum esters | 0.5~8 |
| Seven fluorine methyl ethers remove permethrin | 0.5~6 |
| Seven fluorine methoxy chrysanthemum esters | 0.5~6 |
| AEO-3 | 5~15 |
| TX-15 | 5~15 |
| 1, the 2-dihydroxypropane | 10~20 |
| Trihydroxy propane | 10~20 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, seven fluorine methoxy chrysanthemum esters, seven fluorine methyl ethers are gone permethrin, the trans phenothrin of rich dextrorotation, TX-15, AEO-9 and 95% ethanol mix to stir and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with hexamethylene, dodecyl dimethyl ethylbenzylammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The present invention is further elaborated by above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.
Claims (10)
1. an inspection and quarantine system prevents and treats pest multipotency Alevaire, it is characterized in that containing following component by mass percent:
。
2. inspection and quarantine as claimed in claim 1 system control pest multipotency Alevaire, disinfection composition described in the component is selected from: quaternary ammonium compound, guanidine compound, quaternary ammonium compound comprises benzalkonium bromide, benzalkonium chloride, the n-zephiran, the mixture of one or more of n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides, wherein the n in the n-zephiran is 8 ~ 18, n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, n in two n-alkyl-dimethyl ammonium chlorides is 8 ~ 14, guanidine compound comprises polyhexamethylene guanide, hexamethylene, poly-ring is guanidine, the mixture of one or more in poly-[2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
3. inspection and quarantine as claimed in claim 1 system control pest multipotency Alevaire is characterized in that described insecticide is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
4. the control pest multipotency Alevaire of inspection and quarantine as claimed in claim 1 system is characterized in that described novel rat-bane is selected from: seven fluorine methothrins, inclined to one side seven fluorine methothrins, seven fluorine methoxy chrysanthemum esters, inclined to one side seven fluorine methoxy chrysanthemum esters, seven fluorine go first chrysanthemum ester, inclined to one side seven fluorine to remove first chrysanthemum ester, the mixture of one or more in the tefluthrin etc. partially.
5. inspection and quarantine as claimed in claim 1 system control pest multipotency Alevaire, it is characterized in that described surfactant agent is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4,6,7,10,15.; N among the AEO-n is 3 or 9.
6. inspection and quarantine as claimed in claim 1 system control pest multipotency Alevaire, it is characterized in that described Alevaire is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
7. inspection and quarantine as claimed in claim 1 system control pest multipotency Alevaire is characterized in that described cosolvent is selected from: 95% ethanol.
8. the control pest multipotency Alevaire that is used for the inspection and quarantine system as claimed in claim 1 is characterized in that described water is: deionized water.
9. as the preparation of the described arbitrary inspection and quarantine of claim 1-8 system control pest multipotency Alevaire, it is characterized in that: insecticide, novel rat-bane, surfactant and cosolvent are mixed to stir being mixed with compounding substances A in 1 hour by above-mentioned mass percent; Said mixture matter A is mixed stirring be mixed with compounding substances B in 1 hour with the water of above-mentioned mass percent 50%; Disinfectant and Alevaire mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour; Said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
10. as the application of the described arbitrary inspection and quarantine of claim 1-8 system control pest multipotency Alevaire, it is characterized in that: be applied to disinfection, desinsection and the PCO such as kill mouse in the sealed container space of inspection and quarantine system by multi-functional atomizer and my Portable atomizer, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse; Be applied to entry and exit cargo hold, the main cabin of inspection and quarantine system by multi-functional atomizer and my Portable atomizer, automotive interior, railway car, the disinfection in aircraft hold, main cabin, desinsection and PCO such as kill mouse can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse; Be applied to disinfection, desinsection and the PCO such as kill mouse of immigration junk, the immigration bulk goods of inspection and quarantine system by multi-functional atomizer and my Portable atomizer, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse; Be applied to disinfection, the desinsection of the environment of import and export food processing enterprise, indoor and air and PCO such as kill mouse by multi-functional atomizer and my Portable atomizer, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011101240583A CN102210300A (en) | 2011-05-15 | 2011-05-15 | Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system |
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| CN2011101240583A CN102210300A (en) | 2011-05-15 | 2011-05-15 | Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system |
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| CN102210300A true CN102210300A (en) | 2011-10-12 |
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| CN2011101240583A Pending CN102210300A (en) | 2011-05-15 | 2011-05-15 | Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102334501A (en) * | 2011-05-17 | 2012-02-01 | 覃终 | Preparation and application of multifunctional atomization agent for controlling pests |
| CN102334502A (en) * | 2011-05-18 | 2012-02-01 | 覃终 | Preparation and application of multifunctional atomization agent for controlling pests in sealed container |
| CN103210950A (en) * | 2013-04-26 | 2013-07-24 | 王福建 | Disinfection and pest-killing mixture |
| CN115067313A (en) * | 2022-06-29 | 2022-09-20 | 广西壮族自治区农业科学院 | Method for fumigating and killing soil-dwelling termites by smoke |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069855A (en) * | 1991-09-02 | 1993-03-17 | 天津畜产进出口公司皮毛加工厂 | High efficient pesticide and anti-mould atomizing agent |
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
| CN101933521A (en) * | 2009-07-01 | 2011-01-05 | 李新建 | Preparation and application thereof of sterilization composition |
-
2011
- 2011-05-15 CN CN2011101240583A patent/CN102210300A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069855A (en) * | 1991-09-02 | 1993-03-17 | 天津畜产进出口公司皮毛加工厂 | High efficient pesticide and anti-mould atomizing agent |
| CN101933521A (en) * | 2009-07-01 | 2011-01-05 | 李新建 | Preparation and application thereof of sterilization composition |
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102334501A (en) * | 2011-05-17 | 2012-02-01 | 覃终 | Preparation and application of multifunctional atomization agent for controlling pests |
| CN102334502A (en) * | 2011-05-18 | 2012-02-01 | 覃终 | Preparation and application of multifunctional atomization agent for controlling pests in sealed container |
| CN103210950A (en) * | 2013-04-26 | 2013-07-24 | 王福建 | Disinfection and pest-killing mixture |
| CN103210950B (en) * | 2013-04-26 | 2014-03-26 | 王福建 | Disinfection and pest-killing mixture |
| CN115067313A (en) * | 2022-06-29 | 2022-09-20 | 广西壮族自治区农业科学院 | Method for fumigating and killing soil-dwelling termites by smoke |
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Application publication date: 20111012 |