CN101133741A - Vermins-expelling vermins-proof disinfection preparations for fabric - Google Patents
Vermins-expelling vermins-proof disinfection preparations for fabric Download PDFInfo
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- CN101133741A CN101133741A CNA200710044075XA CN200710044075A CN101133741A CN 101133741 A CN101133741 A CN 101133741A CN A200710044075X A CNA200710044075X A CN A200710044075XA CN 200710044075 A CN200710044075 A CN 200710044075A CN 101133741 A CN101133741 A CN 101133741A
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Abstract
The present invention relates to a mosquito-repellent insect-proofing bactericidal preparation for fabric. It is characterized by that it is made up by using raw material and water according to a certain mass percentage through a certain preparation process. The described raw material includes effective component, solvent and surfactant, in which the effective component is permethrin, its content is 35.2-45.8 wt%, the surfactant is nonylphenol polyoxyethylene ether, its content is 11.3-33.1 wt% and the solvent content is 31.7-53.5 wt%. Said invention also provides its concrete application method.
Description
Technical field
The present invention relates to a kind of Vermins-expelling vermins-proof disinfection preparations, particularly a kind of Vermins-expelling vermins-proof disinfection preparations for fabric.
Background technology
In the human puzzlement that always is in the virus infections that insect bites and bring thus, although the highly developed modern people of science have grasped the means of a lot of replies, annual still have a large amount of people to suffer biting and attacking of mosquito, fly, Lian, attagenus piceus, flea, mite and ant etc., particularly the people who lives or work in arduous area.
Permethrin is a kind of insect to be had repulsion, and knocks down and kill active synthetic pyrethroid.Permethrin is to plant, food, most of animal, human harmless, and can not generate other harmful material under daily condition.Although permethrin has so many beneficial features, because therefore its short relatively effective insecticidal activity, is difficult to be extensive use of in the mankind's daily life always.This be because oxygen and ultraviolet in the presence of, permethrin can resolve into inactive, the product of no pesticidal.
Summary of the invention
The object of the present invention is to provide the long Vermins-expelling vermins-proof disinfection preparations for fabric of a kind of safe, efficient, term of validity, it can be sprayed on the fabric, plays the effect of longer-term mosquito repellent.
The present invention solves the problems of the technologies described above by the following technical programs, reaches goal of the invention of the present invention.
Fabric insect protected biocide preparation is characterized in that: formulated by certain quality percentage by raw material and water; Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 35.2～45.8wt%, and surfactant is a polyoxyethylene nonylphenol ether, and content is 11.3～33.1wt%, and the content of solvent is 31.7～53.5wt%.
In the present invention, the content of active component permethrin is preferably 36～40%wt.
In the present invention, solvent is a medicinal alcohol, but is not limited thereto, so long as all kinds of solvents that can dissolve permethrin all can, choice of Solvent is accomplished for the person of ordinary skill of the art very easily.
In the present invention, the mass percent of raw material and water is generally 1: 55～80, but is not limited to this.
Permethrin of the present invention, English name is: permethrin; Another name Permanone, permethrin, 3-phenoxy benzyl-2,2-dimethyl-3-(2, the 2-dichloroethylene)-1-cyclopropanecarboxylcompound; Molecular formula is: C
21H
20Cl
2O
3Formal name used at school: (3-benzyloxy phenoxy base) cis, trans-(±)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester; The Latin chemical name is: (3-phenoxyphenyl) methyl (±) cis-trans-3-(2,2dichloroethenyl)-2,2-dimethyl-cyclopropanecarboxylatecis/trans isomers ratio:min35% (±) cis and max65% (±) trans; Structural formula is as follows:
Its outward appearance is faint yellow to little brown viscous liquid, and postpone for a long time can be formed solid.
Vermins-expelling vermins-proof disinfection preparations for fabric of the present invention, as long as raw material is mixed with water, stirring gets final product, can hot a little hydrotropy during preparation.
Vermins-expelling vermins-proof disinfection preparations for fabric of the present invention, its major function has:
1, prevents biting of insects such as mosquito, fly, mite, Lian, attagenus piceus, flea, flat lice and ant
2, anti-intensive ultraviolet (30+UV).
Thereby 3, make people avoid the generation of diseases such as invasion and attack, Lyme arthritis, encephalitis, dengue fever, yellow fever, typhoid fever as West Nile Virus owing to prevent biting of above insect
Its key property is:
1, effective: as to compare with similar pest repellant in the market and to have lasting effectiveness.
2, convenient: as, just again to need not to smear other culicifuge and insect protected articles for use as long as put on the clothing of handling by preparation of the present invention.
3, reliable: as to be not made of salt, to expose to the weather, sweat, laundry and flatiron.
4, continue: on clothing, use once, still effective after washing 50 times.
5, tasteless: without any peculiar smell.
6, colourless: as, to be applied in the sensation that can not give people's difference on the clothing without any color.
7, harmless: without any side effect and harm, more safer than present pest repellant to human body.
8, environmental protection: can not produce any pollution and harm to environment.
9, sterilization: the present invention has the effect of sterilization.
This fabric only is about 0.5% with the permethrin content that the insect protected biocide preparation finally is applied to clothes, and promptly the content on cloth is 0.12mg/cm
2About.It is than present any all safety and effectively lasting of pest repellant that skin smears that is applied to.Safety message is: the oral and Skin-test data on rat and the rabbit: skin LD50〉2000mg/kg (rabbit), oral LD50〉5000mg/kg (rat), proved that it is one of former medicine of safe class in the world.
This fabric is with the steel drum that adopts liner PE or PVF of packing of insect protected biocide preparation, net weight 25 or 50 kilograms.
This fabric is a cream preparation with insect protected biocide preparation finished product, behind the thin up, used up in two hours during use, diluted concentration is: the 17.5g medicament adds water 987.5g, directly spray on the heavy clothes of 1kg after making the liquid of 1kg, specifically have two kinds of spraying methods as follows:
1, uses the aerosol spray spraying method
At first sprayer is thoroughly cleaned up with clear water, the preparation after will diluting is then filled sprayer and is stirred and be forced into 0.55Mpa.Fine in the ventilation every suit is divided on the ground, every is evenly sprayed with above-mentioned 0.55Mpa pressure, and the time is preferably 50s, and turn-over carries out same processing then.Hang up after double treatment finishes and dry, and on every clothes, stamp marks for treatment and processing time.
2, special purpose machinery facture
By the operation of streamline, batch process on a large scale.
Below, provide concrete laboratory report and further specify major function characteristic of the present invention and beneficial effect.
One, the mosquito repellent evaluating drug effect of preparation of the present invention
1, examination criteria: detect by State Standard of the People's Republic of China GB/T 17322.10-1998 " agriculture chemical registration hygienic insecticide indoor harmacological effect is estimated repellant " regulation;
2, testing conditions and sample
1) laboratory temperature: 26 ± 1 ℃, relative moisture: 65 ± 5%
2) mosquito kind: aedes albopictus (Aedes albopictus), the back 4～5 days (the standard examination worm that Prevention ﹠ Control Station of Parasitic Disease, China Diseases Prevention ﹠ C raises) of sprouting wings
3) mosquito number: 300 female insect/cages of not sucking blood (35 * 35 * 35cm)
4) test pre-treatment: before test with the jejunitas 18h of mosquito
5) test sample: the clothing (calling the insect protected clothing in the following text) that has sprayed preparation of the present invention by preceding method
6) control sample: the clothing of handling by preceding method of the same race (calling the contrast clothing in the following text) not
3, experimenter
5 volunteers participate in test
4, detect step
1) mosquito attack test: the experimenter stretches into left hand in the mosquito cage before the test, and it is qualified for attack to stop to fall to biting 30 above persons in the 2min, and this person and this cage mosquito can be used for repellency test
2) the insect protected clothing is inserted in the experimenter on hand, stretches in the mosquito cage, observe 2min, record the back of the hand mosquito stops falling and biting number
3) will contrast clothing and be inserted in the experimenter on hand, and stretch in the mosquito cage, and observe 2min, record the back of the hand mosquito stops falling and biting number
5, testing result
As following table
| Detect sequence number | Insect protected clothing mosquito stops the number (only) that falls | Contrast clothing mosquito stops the number (only) that falls | Repellent number (only) | Scattering ratio (%) |
| 1 2 3 4 5 | 25 24 28 26 12 | 92 81 91 97 84 | 67 57 63 71 72 | 72.83 70.37 69.23 73.96 85.74 |
| ∑ | 115 | 445 | 330 | 74.16 |
6, conclusion
With reference to State Standard of the People's Republic of China GB/T 17322.10-1998 " agriculture chemical registration hygienic insecticide indoor harmacological effect is estimated repellant " relevant regulations, the clothing that has sprayed preparation of the present invention is 74.16% to the scattering ratio of aedes albopictus, and the clothing that has sprayed preparation of the present invention has repellent action to aedes albopictus.
Two, the insect protected of preparation of the present invention, mosquito repellent evaluating drug effect
1, detects foundation: State Standard of the People's Republic of China GB13917.1-92 " the indoor harmacological effect assay method of agriculture chemical registration hygienic insecticide indoor harmacological effect detection method propellant " and GB/T17322.10-1998 " agriculture chemical registration hygienic insecticide indoor harmacological effect is estimated repellant "
2, test sample: the clothes, the trousers (calling insect protected clothing, insect protected trousers in the following text) that have sprayed preparation of the present invention by preceding method; Control sample: the clothing of handling by preceding method of the same race (calling the contrast clothing in the following text) not
3, testing conditions: laboratory temperature is 26 ± 1 ℃, relative moisture 65 ± 5%
4, for the examination insect: the standard examination worm that Prevention ﹠ Control Station of Parasitic Disease, China Diseases Prevention ﹠ C raises
Culex pipiens pallens (Culexpipiens pallens), the 2nd～3 day female adult worm of not sucking blood in back of sprouting wings
Aedes albopictus (Aedes albopictus), emergence back 4～5 days
Housefly (Musca doestica), the 3rd～5 day adult in back that sprout wings, male and female half and half
Groton bug (Blatte germanica), two all adults, male and female half and half
Method is had a liking for skin mite (Dermatophagoidesfarinae), female male imago
Attagenus piceus (Attagenus unicolorjaponicus), the 10-11 instar larvae
Xanthopsyllacheopis (Xenopsylla cheopis), back the 1st～2 all adults sprout wings
Monomorium pharaonis (Monomrium pharaonis), worker ant becomes ant
5, detection method
1) forces contact method
Evaluation of pesticide effectiveness step by the 2.4.2 residual spray among the State Standard of the People's Republic of China GB13917.1-92 " the indoor harmacological effect assay method of agriculture chemical registration hygienic insecticide indoor harmacological effect detection method propellant " detects.
Respectively each examination worm is placed and force in the contactor (GB13917.1-92 2.3 defineds force contactor), force to be contacted with insect protected clothing contact-making surface 30min.To try then to feed with feed and immersion cotton balls in the dependent insect cage (ware) that worm all is transferred to cleaning.Dead examination borer population when flight property examination worm is checked 24h.Dead examination borer population when creeping inspection 24,48 of examination worm and 72h.Detect triplicate, calculate average dead examination borer population.
2) anthelminthic effect detects
After the insect protected clothing is inserted in experimenter's hand, stretch in the mosquito cage, observe 2min, record the back of the hand mosquito stops the number that falls.Parallel control: the hand that is inserted in the contrast clothing is observed mosquito and is stopped the number that falls in contrast.
6, testing result
Insect protected clothing insect protected drug effect testing result is as following table
| The examination worm | Examination borer population (only) | 30min knocks down number (only) | 30min rate of knockdown (%) | 24h lethality (%) | 48h lethality (%) | 72h lethality (%) |
| Mosquitos and flies Lian | 20 20 20 | 20 20 20 | 100 100 100 | 100 190 90 | - - 90 | - - 90 |
| Attagenus piceus | 20 | 20 | 100 | 90 | 90 | 90 |
| Flea | 20 | 18 | 90 | 80 | 80 | 80 |
| Mite | 153 | 137 | 89.54 | 71.24 | 71.89 | 72.54 |
| Ant | 105 | 98 | 93.33 | 79.05 | 80.95 | 81.90 |
The insect protected clothing is to aedes albopictus repellent effect testing result such as following table
| Detect sequence number | Insect protected clothing mosquito stops the number (only) that falls | Contrast clothing mosquito stops the number (only) that falls | Repellent number (only) | Scattering ratio (%) |
| 1 2 3 4 5 6 | 41 29 52 47 32 38 | 84 76 96 92 74 88 | 43 47 44 45 42 50 | 51.19％ 61.84％ 45.83％ 48.91％ 76.76％ 56.82％ |
| ∑ | 239 | 510 | 271 | 53.14％ |
7, conclusion
Estimate according to 3.2.2 among the State Standard of the People's Republic of China GB/T 17322.1-1998 " indoor harmacological effect of agriculture chemical registration hygienic insecticide is estimated propellant ".Insect protected clothing insect protected drug effect testing result is as follows:
The insect protected clothing is 100% to mosquito, fly, Lian and attagenus piceus 30min rate of knockdown, and the 24h lethality is respectively 100%, 90.0%, 90.0% and 90.0%, and Lian and attagenus piceus 72h lethality are respectively 90.0% and 90.0%; The insect protected clothing is respectively 90.0%, 89.54% and 93.33% to flea, mite and ant 30min rate of knockdown, and the 72h lethality is respectively 80.0%, 72.54% and 81.90%.
The insect protected clothing is 53.14% to the scattering ratio of aedes albopictus.
The insect protected clothing has the Vermins-expelling vermins-proof effect.
Three, the mosquito repellent evaluating drug effect of preparation of the present invention
1, detects foundation: State Standard of the People's Republic of China GB/T 17322.10-1998 " agriculture chemical registration hygienic insecticide indoor harmacological effect is estimated repellant "
2, test sample: the clothes (calling insect protected clothing 1# in the following text) that has sprayed preparation of the present invention by preceding method; Sprayed the clothes (calling insect protected clothing 2# in the following text) of preparation of the present invention by preceding method; Control sample: the clothing of handling by preceding method of the same race (calling the contrast clothing in the following text) not
3, for the examination insect: the standard examination worm that Prevention ﹠ Control Station of Parasitic Disease, China Diseases Prevention ﹠ C raises
Aedes albopictus (Aedes albopictus), emergence back 4～5 days
4, detection method
1) examination criteria: detect by State Standard of the People's Republic of China GB/T 17322.10-1998 " agriculture chemical registration hygienic insecticide indoor harmacological effect is estimated repellant " regulation
2) testing conditions:
1. laboratory temp. and humidity: 26 ± 1 ℃, RH65 ± 5%
2. mosquito kind: aedes albopictus (Aedes albopictus), the back 4～5 days of sprouting wings
3. mosquito number: 300 female insect/cages of not sucking blood (35 * 35 * 35cm)
4. test pre-treatment: before test with the jejunitas 18h of mosquito
3) study subject
3 volunteers participate in test.
4) testing procedure
1. mosquito attack: the experimenter stretches into left hand in the mosquito cage before the test, and it is qualified for attack to stop to fall to biting 30 above persons in the 2min, and this person and this cage mosquito can be used for repellency test.
2. method of testing: respectively insect protected clothing and contrast clothing are inserted in the experimenter on hand
3. measure of merit: after the insect protected clothing is inserted in experimenter's hand, stretch in the mosquito cage, observe 2min, record the back of the hand mosquito stops falling and biting number.
4. parallel control: the hand that is inserted in the contrast clothing is observed mosquito and is stopped falling and biting number in contrast
5, testing result:
The insect protected clothing is to aedes albopictus repellent effect testing result such as following table
| Test sample | Insect protected clothing mosquito stops the number (only) that falls | Contrast clothing mosquito stops the number (only) that falls | Repellent number (only) | Scattering ratio |
| Insect protected clothing 1# | 32 | 154 | 122 | 77.71 |
| Insect protected clothing 2# | 57 | 154 | 97 | 62.99 |
Effect detection such as following table that the anti-aedes albopictus of insect protected clothing is bitten
| Test sample | Insect protected clothing bite by mosquitos number (only) | Contrast clothing mosquito stops the number (only) that falls | Repellent number (only) | Scattering ratio |
| Insect protected clothing 1# | 0 | 7 | 7 | 100 |
| Insect protected clothing 2# | 0 | 7 | 7 | 100 |
6, conclusion
With reference to State Standard of the People's Republic of China GB/T 17322.10-1998 " agriculture chemical registration hygienic insecticide indoor harmacological effect is estimated repellant ".
Insect protected clothing 1# is 77.11% to the scattering ratio of aedes albopictus, prevents that biting rate is 100%.Insect protected clothing 2# is 62.99% to the scattering ratio of aedes albopictus, prevents that biting rate is 100%.
Insect protected clothing 1# is better than insect protected clothing 2# to the repellent effect of aedes albopictus.
Insect protected clothing 1# and insect protected clothing 2# have repellent effect to aedes albopictus, and it is obvious to prevent biting effect.
Embodiment
For technological means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with embodiment, further set forth the present invention.
Embodiment 1
Vermins-expelling vermins-proof disinfection preparations for fabric is that 1: 55 ratio is formulated by raw material and water by mass ratio.Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 35.2wt%, and surfactant is a polyoxyethylene nonylphenol ether, and content is 11.3wt%, and solvent is a medicinal alcohol, and content is 53.5wt%.
Embodiment 2
Vermins-expelling vermins-proof disinfection preparations for fabric is that 1: 80 ratio is formulated by raw material and water by mass ratio.Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 45wt%, and surfactant is a polyoxyethylene nonylphenol ether, and content is 15wt%, and solvent is a medicinal alcohol, and content is 40wt%.
Embodiment 3
Vermins-expelling vermins-proof disinfection preparations for fabric, formulated by raw material and water by 1: 70 ratio.Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 36wt%, and surfactant is a polyoxyethylene nonylphenol ether, and content is 14wt%, and solvent is a medicinal alcohol, and content is 50wt%.
Embodiment 4
Vermins-expelling vermins-proof disinfection preparations for fabric, formulated by raw material and water by 1: 70 ratio.Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 45%wt, and surfactant is a polyoxyethylene nonylphenol ether, and content is 15%wt, and solvent is a medicinal alcohol, and content is 40%wt.
Embodiment 5
Vermins-expelling vermins-proof disinfection preparations for fabric, formulated by raw material and water by 1: 70 ratio.Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 40%wt, and surfactant is a polyoxyethylene nonylphenol ether, and content is 20%wt, and solvent is a medicinal alcohol, and content is 40%wt.
More than show and described basic principle of the present invention, principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; that describes in the foregoing description and the specification just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (4)
1. Vermins-expelling vermins-proof disinfection preparations for fabric is characterized in that: formulated by certain quality percentage by raw material and water; Raw material comprises active component, solvent, surfactant, and active component is a permethrin, and content is 35.2%～45.8wt%, and surfactant is a polyoxyethylene nonylphenol ether, and content is 11.3～33.1wt%, and the content of solvent is 31.7%～53.5wt%.
2. Vermins-expelling vermins-proof disinfection preparations for fabric according to claim 1 is characterized in that: the content of active component permethrin is 36～40%wt.
3. Vermins-expelling vermins-proof disinfection preparations for fabric according to claim 1 is characterized in that: solvent is a medicinal alcohol.
4. Vermins-expelling vermins-proof disinfection preparations for fabric according to claim 1 is characterized in that: preparing the raw material of described Vermins-expelling vermins-proof disinfection preparations and the mass percent of water is 1: 55～80.
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| CN200710044075A CN101133741B (en) | 2007-07-20 | 2007-07-20 | Vermins-expelling vermins-proof disinfection preparations for fabric |
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|---|---|---|---|
| CN200710044075A CN101133741B (en) | 2007-07-20 | 2007-07-20 | Vermins-expelling vermins-proof disinfection preparations for fabric |
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| CN101133741A true CN101133741A (en) | 2008-03-05 |
| CN101133741B CN101133741B (en) | 2010-05-19 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102517910A (en) * | 2011-12-06 | 2012-06-27 | 福建锦江科技有限公司 | Anti-mite polyamide fiber and preparation method thereof |
| CN103397520A (en) * | 2013-08-27 | 2013-11-20 | 董海燕 | Vermin-killing mosquito-repellent anti-static biological preparation for fabrics |
| CN104213403A (en) * | 2014-08-28 | 2014-12-17 | 无锡市奇盛针织手套厂 | Insect-proof and antibacterial finishing agent for fabrics and preparation method thereof |
| CN110234806A (en) * | 2017-06-12 | 2019-09-13 | 柏桥生物科技有限公司 | Multi-functional expelling parasite agent addition agent |
| CN116122044A (en) * | 2023-01-17 | 2023-05-16 | 上海洁宜康化工科技有限公司 | Mite-proof finishing method for mattress cloth |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101173485A (en) * | 2006-11-02 | 2008-05-07 | 上海鼎中保鲜科技有限公司 | Vermins-proof preparations for fabric |
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2007
- 2007-07-20 CN CN200710044075A patent/CN101133741B/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102517910A (en) * | 2011-12-06 | 2012-06-27 | 福建锦江科技有限公司 | Anti-mite polyamide fiber and preparation method thereof |
| CN103397520A (en) * | 2013-08-27 | 2013-11-20 | 董海燕 | Vermin-killing mosquito-repellent anti-static biological preparation for fabrics |
| CN103397520B (en) * | 2013-08-27 | 2015-07-29 | 董海燕 | Fabric desinsection mosquito-repellent anti-static biologic product |
| CN104213403A (en) * | 2014-08-28 | 2014-12-17 | 无锡市奇盛针织手套厂 | Insect-proof and antibacterial finishing agent for fabrics and preparation method thereof |
| CN104213403B (en) * | 2014-08-28 | 2016-05-18 | 无锡市奇盛针织手套厂 | A kind of fabric insect protected antibacterial finishing agent and preparation method thereof |
| CN110234806A (en) * | 2017-06-12 | 2019-09-13 | 柏桥生物科技有限公司 | Multi-functional expelling parasite agent addition agent |
| CN116122044A (en) * | 2023-01-17 | 2023-05-16 | 上海洁宜康化工科技有限公司 | Mite-proof finishing method for mattress cloth |
| CN116122044B (en) * | 2023-01-17 | 2024-03-08 | 上海洁宜康化工科技有限公司 | Mite-proof finishing method for mattress cloth |
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| CN101133741B (en) | 2010-05-19 |
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