CN1192855A - Insecticide containing light diesel oil for plant protection - Google Patents
Insecticide containing light diesel oil for plant protection Download PDFInfo
- Publication number
- CN1192855A CN1192855A CN98101715A CN98101715A CN1192855A CN 1192855 A CN1192855 A CN 1192855A CN 98101715 A CN98101715 A CN 98101715A CN 98101715 A CN98101715 A CN 98101715A CN 1192855 A CN1192855 A CN 1192855A
- Authority
- CN
- China
- Prior art keywords
- diesel oil
- agricultural chemicals
- insecticide
- solvent
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 35
- 239000002917 insecticide Substances 0.000 title claims abstract description 14
- 239000003905 agrochemical Substances 0.000 claims abstract description 18
- 239000000575 pesticide Substances 0.000 claims abstract description 11
- 239000005660 Abamectin Substances 0.000 claims abstract description 10
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 9
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims abstract description 8
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 5
- 239000002728 pyrethroid Substances 0.000 claims abstract description 5
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims abstract description 4
- 230000000895 acaricidal effect Effects 0.000 claims abstract description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 24
- 239000002904 solvent Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- BUHNCQOJJZAOMJ-UHFFFAOYSA-N ZXI 8901 Chemical compound C=1C=C(OC(F)F)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=C(Br)C=C1 BUHNCQOJJZAOMJ-UHFFFAOYSA-N 0.000 claims description 7
- 230000000740 bleeding effect Effects 0.000 claims description 7
- 239000003120 macrolide antibiotic agent Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 3
- 241000894006 Bacteria Species 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229960002587 amitraz Drugs 0.000 claims description 3
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 claims description 3
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- XJFIKRXIJXAJGH-UHFFFAOYSA-N 5-chloro-1,3-dihydroimidazo[4,5-b]pyridin-2-one Chemical group ClC1=CC=C2NC(=O)NC2=N1 XJFIKRXIJXAJGH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005945 Chlorpyrifos-methyl Substances 0.000 claims description 2
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005916 Methomyl Substances 0.000 claims description 2
- YBOFEONRFJMHND-UHFFFAOYSA-N [Br].N#CC#N Chemical compound [Br].N#CC#N YBOFEONRFJMHND-UHFFFAOYSA-N 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- YFVOXLJXJBQDEF-UHFFFAOYSA-N isocarbophos Chemical compound COP(N)(=S)OC1=CC=CC=C1C(=O)OC(C)C YFVOXLJXJBQDEF-UHFFFAOYSA-N 0.000 claims description 2
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 claims description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- 238000009472 formulation Methods 0.000 claims 2
- 241000238631 Hexapoda Species 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- -1 Liuyang mycin Substances 0.000 abstract description 2
- 239000003986 organophosphate insecticide Substances 0.000 abstract description 2
- 230000035515 penetration Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000007721 medicinal effect Effects 0.000 abstract 2
- 238000011109 contamination Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 230000000241 respiratory effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 23
- 239000003814 drug Substances 0.000 description 15
- 239000008096 xylene Substances 0.000 description 8
- 239000006071 cream Substances 0.000 description 4
- 230000000857 drug effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000005906 Imidacloprid Substances 0.000 description 3
- 229940056881 imidacloprid Drugs 0.000 description 3
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 2
- 239000005944 Chlorpyrifos Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 229950008167 abamectin Drugs 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 1
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CTZNINKRTKCWGU-UHFFFAOYSA-N Dinactin Natural products CC1C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 CTZNINKRTKCWGU-UHFFFAOYSA-N 0.000 description 1
- YPUPRVWRYDPGCW-UHFFFAOYSA-N Monactin Natural products CC1C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 YPUPRVWRYDPGCW-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- RMIXHJPMNBXMBU-QIIXEHPYSA-N Nonactin Chemical group C[C@H]([C@H]1CC[C@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](C)OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](C)OC(=O)[C@H]1C)C)C(=O)O[C@H](C)C[C@H]2CC[C@@H]1O2 RMIXHJPMNBXMBU-QIIXEHPYSA-N 0.000 description 1
- RMIXHJPMNBXMBU-UHFFFAOYSA-N Nonactin Natural products CC1C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 RMIXHJPMNBXMBU-UHFFFAOYSA-N 0.000 description 1
- 241000488581 Panonychus citri Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000187747 Streptomyces Species 0.000 description 1
- 241001468227 Streptomyces avermitilis Species 0.000 description 1
- 241000187392 Streptomyces griseus Species 0.000 description 1
- 241001655322 Streptomycetales Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- NKNPHSJWQZXWIX-DCVDGXQQSA-N Tetranactin Chemical compound C[C@H]([C@H]1CC[C@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](CC)OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](CC)OC(=O)[C@H]1C)CC)C(=O)O[C@H](CC)C[C@H]2CC[C@@H]1O2 NKNPHSJWQZXWIX-DCVDGXQQSA-N 0.000 description 1
- NKNPHSJWQZXWIX-UHFFFAOYSA-N Tetranactin Natural products CC1C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC2CCC1O2 NKNPHSJWQZXWIX-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 229960000074 biopharmaceutical Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- ZBDGIMZKOJALMU-MVWQHRGOSA-N dinactin Chemical compound C[C@@H]([C@@H]1CC[C@@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@H]1CC[C@H](O1)C[C@@H](C)OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@H](CC)OC(=O)[C@H]1C)CC)C(=O)O[C@H](C)C[C@@H]2CC[C@H]1O2 ZBDGIMZKOJALMU-MVWQHRGOSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000001339 epidermal cell Anatomy 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229960002418 ivermectin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YPUPRVWRYDPGCW-GGOMOPATSA-N monactin Chemical compound C[C@H]([C@H]1CC[C@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](C)OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](C)OC(=O)[C@H]1C)CC)C(=O)O[C@H](C)C[C@H]2CC[C@@H]1O2 YPUPRVWRYDPGCW-GGOMOPATSA-N 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- DFQMKYUSAALDDY-MQEBUAKTSA-N trinactin Chemical compound C[C@@H]([C@@H]1CC[C@@H](O1)C[C@H](OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](CC)OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](CC)OC(=O)[C@@H]1C)CC)C(=O)O[C@@H](C)C[C@@H]2CC[C@H]1O2 DFQMKYUSAALDDY-MQEBUAKTSA-N 0.000 description 1
- DFQMKYUSAALDDY-UHFFFAOYSA-N trinactin Natural products CC1C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 DFQMKYUSAALDDY-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a compound insecticidal and acaricidal preparation containing diesel oil for plant protection. Said compound preparation is made up by using diesel oil and other agricultural chemicals, emulsifying agent and penetrant according to a certain proportion. Said other agricultural chemicals include avermectin, Liuyang mycin, organophosphorus insecticide, carbamates, synthetic pyrethroid insecticide and related chemical pesticides. Said invention uses the functions of diesel oil which can close the respiratory pores of insect and promote the penetration of the chemical pesticide into the epidermic cells of crops and insects to make pesticide give full play to medicinal effect. It can raise medicinal effect by 0.5-2.5 times, reduce the contamination of chemical pesticide to environment, and reduce production cost.
Description
The present invention relates to the insecticide of the hydrocarbon-containifirst that plant protection uses, more particularly, is a kind of Insecticidal and acaricidal agent by light diesel fuel and other agriculture chemical compounding.
Itself has certain insecticidal activity diesel oil, it is strong to insect epidermis penetration, can react with pest body inner cell matter, can also on polypide, form oil film, sealing insect body surface is used to exhale the getter hole, insect is suffocated, can impel the epidermal cell infiltration of other agricultural chemicals in composite dose again, thereby the drug effect of giving full play to and prolong drug effect improves the effective rate of utilization of Recompounded pesticide to crop and insect, save the consumption of agricultural chemicals, reduce residually, reduce environmental pollution (" newly organized agricultural chemicals handbook sequel ", Chinese agriculture publishing house, 1998, P202-206).
The objective of the invention is the characteristic of utilizing diesel oil to have, make that a kind of cost is low, the agricultural insecticidal that contains diesel oil of good drug efficacy, kill the mite mixed emulsifiable solution.
The objective of the invention is to realize: diesel oil, other agricultural chemicals, emulsifier, bleeding agent, solvent are prepared into missible oil by following technical proposals.
Missible oil of the present invention is concrete to be formed and content (percetage by weight):
Diesel oil 3-70%, other agricultural chemicals 0.05-40%, emulsifier 3-50%, bleeding agent 0-5%, other is a solvent.
Diesel oil of the present invention is that boiling range that PETROLEUM PROCESSING obtains is 200-380 ℃ a light diesel fuel, comprises commercially available 0-10 diesel oil.
Other agricultural chemicals of the present invention comprise bromine cyanogen bacterium ester in A Wei chrysanthemum element, macro tetrolide, organic phosphates, carbamates, the pyrethroid class, beta-cypermethrin, brofluthrinate, cyfluthrin bacterium ester, sumicidin with and comprise other chemical pesticide of Imidacloprid, Amitraz, azacyclotin.
Described Avermectin is the tunning of A Foman streptomycete (Streptomyces avermitilis), is AvermectinA by the mixture of forming of the quite similar homology of eight structures
1a, A
1b, A
2a, A
2b, B
1a, B
1b, B
2a, B
2b, generally use B more
1a, B
1bMixture, it can adopt existing technology extract and separate (William C.Campbell. " Ivermectin and Abamectin ", Springer-Verlag, New York Inc, 1989, P1-3).
Described macro tetrolide is the mite farm antibiotics extremely that is produced by streptomyces griseus Liuyang mutation Streptomyces griseusvar liuyanggensis fermentation, by five components is tetranactin, trinactin, dinactin, monactin, nonactin forms (" newly organized agricultural chemicals handbook sequel ", Chinese agriculture publishing house, 1988, P87-89).
Described organophosphorus insecticide comprises that chlopyrifos, chlorpyrifos-methyl, isocarbophos, fenthion, carbamate comprise carbosulfan, Methomyl, pyrethroid class (comprising decis, beta-cypermethrin, brofluthrinate, cyfloxylate, sumicidin) and other chemical pesticide that comprises Imidacloprid, Amitraz, azacyclotin.
Emulsifier of the present invention comprises Tween-80,0203B and comprises OP-10 and the OP series of OP-21.
Bleeding agent of the present invention comprises JFC, is the commercially available prod.
Solvent of the present invention comprises dimethylbenzene, ethanol, acetone, isopropyl alcohol.
Method for producing insecticide of the present invention: at first dissolve other agricultural chemicals with partial solvent, add emulsifier again, stir evenly the solvent that the back adds diesel oil and surplus, mixing promptly obtains required cream pesticide.
Missible oil of the present invention is taked the using method used always: carry out constant, low volume or direct ultra low volume spray behind the dilute with water; Also spray behind the dilutable water or brush.
The major advantage of insecticide of the present invention:
Insecticide of the present invention is exhaled getter hole and the insect cuticle Premeabilisation of cells effect that promotes agricultural chemicals to crop owing to utilize diesel oil to have the sealing insect, therefore less agricultural chemicals dosage obtains the better effect of common using dosage, during equal pesticide concentration, preventive effect can improve 0.5-2.5 doubly, so just can reduce the usage amount of agricultural chemicals, thereby reduced production cost, reduced the pollution of chemical pesticide environment.Insecticide of the present invention can be used for preventing and treating insect and the evil mite on the crops such as vegetables, fruit tree, cotton, flowers, tobacco.
Further describe characteristics of the present invention below by example.
Example 1
This example is that preparation contains Avermectin 0.25%, the missible oil of diesel oil 30%.
The oily liquid 2.5kg (containing Avermectin 0.25kg) that will contain Avermectin 10% with the 10kg xylene soluble after, add 15kgOP-10, mix the back thoroughly and add 30kg10 diesel oil, 2kgJFC adds 100 liters of dimethylbenzene promptly behind the mixing.
Example 2
This example is that preparation contains macro tetrolide 15%, the compounded cream of diesel oil 50%.
With the former powder of macro tetrolide (purity 90%) 83.3kg, with adding the 25kg Tween-80 after 50 liters of xylene soluble, stir evenly the back and add 250kg0 diesel oil, add dimethylbenzene to 500 behind the mixing liter promptly.
Example 3
This example is that preparation contains Le Siben (chlopyrifos) 40%, the compounded cream of diesel oil 15%.
To find pleasure in this basis powder (purity 90%) 222kg, and, stir evenly the back and add 75kg0 diesel oil, add dimethylbenzene to 500 behind the mixing liter promptly with adding the 150kg Tween-80 after 80 liters of xylene soluble.
Example 4
This example is that preparation contains carbosulfan 1%, the missible oil of diesel oil 70%,
1.25kg fourth sulphur crude oil (purity 80%) is used xylene soluble, add 5 liters of xylene soluble after, add 10kgOP-10, add 70kg0 diesel oil then, 5kgJFC adds to 100 liters promptly with dimethylbenzene.
Example 5
This example is that preparation contains brofluthrinate 5%, the missible oil of diesel oil 5%.
The former powder of 31.25kg brofluthrinate (purity 80%) is used xylene soluble, add 50 liters of xylene soluble after, add 50kgOP-21, add 25kg10 diesel oil then, 5kgJFC adds to 500 liters promptly with dimethylbenzene.
Example 6
This example is that preparation contains Imidacloprid 1%, the missible oil of diesel oil 30%.
With 1.25kg than the former powder of worm quinoline (purity 80%) with adding 10kgOP-10 after the 12kg xylene soluble, 2kgOP-21,2kgJFC adds 30kg0 diesel oil behind the mixing, add to 100 liters with dimethylbenzene.
Example 7
This example is that compounded cream and the commercially available missible oil among the present invention compares, and the results are shown in Table 1 and table 2.
With several missible oil at one time, the place carries out field control effectiveness test, the equal dilute with water spraying of various missible oil, and respectively at observing and calculated preventive effect behind the medicine in 1 day, 3 days, 7 days, 14 days.
1.8% avermectin missible oil is the abamectin emulsifiable concentrate that New Tech. Development General Co., Beijing Agriculture Univ. produces in the table 1, and 40.7% chlorpyrifos ec all is the commercially available prod for Dow Chemical company produces; 10% macro tetrolide missible oil is the commercially available prod that Hunan Factory of Biologicals produces in the table 2, the commercially available prod that 10% brofluthrinate missible oil produces for Shanghai Westen and Chinese Tranditional Medicine Pharamacentic Co., Ltd's saliva.
Data by table 1 and table 2 find out, the present invention uses less with the composite agricultural chemicals of diesel oil and dosage can obtain the same effect of common agricultural using dosage or better effect.
Several missible oil of table 1. compare sub-district, the field drug effect of diamond-back moth
| Medicament | Effective ingredient consumption | Preventive effect % behind the medicine | |||
| Behind the medicine 1 day | Behind the medicine 3 days | Behind the medicine 7 days | Behind the medicine 14 days | ||
| Example 1 missible oil | 0.31g/ mu | 84.3 | 88.2 | 95.1 | 97.3 |
| 1.8% avermectin missible oil | 0.14g/ mu | 82.5 | 85.8 | 92.1 | 93.2 |
| Example 3 missible oil | 38g/ mu | 82.3 | 84.9 | 90.4 | 93.6 |
| 40.7% chlorpyrifos ec | 50g/ mu | 78.1 | 80.3 | 85.2 | 86.9 |
Several missible oil of table 2. to sub-district, citrus red mite field drug effect relatively
| Medicament | Effective ingredient consumption (g/ mu) | Preventive effect behind the medicine, % | |||
| Behind the medicine 1 day | Behind the medicine 3 days | Behind the medicine 7 days | Behind the medicine 14 days | ||
| Example 2 missible oil | 15 | 90.2 | 92.5 | 96.4 | 97.3 |
| 10% macro tetrolide missible oil | 25 | 88.3 | 92.1 | 93.8 | 96.5 |
| Example 5 missible oil | 18 | 88.1 | 90.7 | 92.6 | 94.5 |
| 10% brofluthrinate missible oil | 25 | 86.2 | 89.4 | 90.3 | 92.8 |
Claims (7)
1. plant protection Insecticidal and acaricidal agent that contains diesel oil; it is characterized in that it being a kind of missible oil formulation that contains diesel oil, other agricultural chemicals, emulsifier, bleeding agent and solvent; the concrete content (by weight percentage) of forming: diesel oil 3-7%, other agricultural chemicals 0.05-4%, emulsifier 3-50%, bleeding agent 0-5%, other is a solvent.
2. according to the described insecticide of claim 1, it is characterized in that described diesel oil is boiling range 200-380 ℃ light diesel fuel.
3. according to the described insecticide of claim 1, it is characterized in that described other agricultural chemicals comprises Avermectin, macro tetrolide, organic phosphates, carbamates, pyrethroid class and the chemical pesticide that comprises the pouring of pyrrole worm, Amitraz, azacyclotin, described organic phosphates comprises chlopyrifos, chlorpyrifos-methyl, isocarbophos, fenthion, described pyrethroid class comprises bromine cyanogen bacterium ester, beta-cypermethrin, brofluthrinate, cyfloxylate, sumicidin, and described carbamates comprises carbosulfan, Methomyl.
4. according to the described insecticide of claim 1, it is characterized in that described emulsifier comprises OP-10, OP-21,0203B, Tween-80.
5. according to the described insecticide of claim 1, it is characterized in that described bleeding agent comprises JFC.
6. according to the described insecticide of claim 1, it is characterized in that described solvent comprises dimethylbenzene, ethanol, isopropyl alcohol, acetone.
7. the described insecticide preparation method of claim 1 is characterized in that dissolving other agricultural chemicals earlier with partial solvent, adds emulsifier again, stirs evenly the solvent that the back adds diesel oil, bleeding agent and surplus, promptly obtains the missible oil formulation through stirring and evenly mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98101715A CN1192855A (en) | 1998-04-23 | 1998-04-23 | Insecticide containing light diesel oil for plant protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98101715A CN1192855A (en) | 1998-04-23 | 1998-04-23 | Insecticide containing light diesel oil for plant protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1192855A true CN1192855A (en) | 1998-09-16 |
Family
ID=5216886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98101715A Pending CN1192855A (en) | 1998-04-23 | 1998-04-23 | Insecticide containing light diesel oil for plant protection |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1192855A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1115964C (en) * | 1998-12-24 | 2003-07-30 | 章阿恩 | Composition for agricultural chemicals and preparation thereof |
| WO2006094371A3 (en) * | 2005-03-09 | 2007-06-28 | Fmc Quimica Do Brasil Ltda | Carbosulfane-based pesticidal compositions, process for preparing same, process for controlling insects/mites/nematodes, and use of said compositions |
| CN102613210A (en) * | 2012-01-05 | 2012-08-01 | 安徽迪邦药业有限公司 | 1.8% avermectin |
| CN104304283A (en) * | 2014-10-15 | 2015-01-28 | 济南新起点医药科技有限公司 | Water dispersible granules containing amitraz and application |
| CN104397012A (en) * | 2014-11-14 | 2015-03-11 | 济南新起点医药科技有限公司 | Wettable pulvis containing beta-cypermethrin and application |
-
1998
- 1998-04-23 CN CN98101715A patent/CN1192855A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1115964C (en) * | 1998-12-24 | 2003-07-30 | 章阿恩 | Composition for agricultural chemicals and preparation thereof |
| WO2006094371A3 (en) * | 2005-03-09 | 2007-06-28 | Fmc Quimica Do Brasil Ltda | Carbosulfane-based pesticidal compositions, process for preparing same, process for controlling insects/mites/nematodes, and use of said compositions |
| CN102613210A (en) * | 2012-01-05 | 2012-08-01 | 安徽迪邦药业有限公司 | 1.8% avermectin |
| CN104304283A (en) * | 2014-10-15 | 2015-01-28 | 济南新起点医药科技有限公司 | Water dispersible granules containing amitraz and application |
| CN104304283B (en) * | 2014-10-15 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of water dispersible granules containing Amitraz and application |
| CN104397012A (en) * | 2014-11-14 | 2015-03-11 | 济南新起点医药科技有限公司 | Wettable pulvis containing beta-cypermethrin and application |
| CN104397012B (en) * | 2014-11-14 | 2016-04-20 | 济南新起点医药科技有限公司 | A kind of wetting powder and application containing beta-cypermethrin |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102283254A (en) | Plant source environmentally-friendly pesticide preparation | |
| CN101642117A (en) | Pesticidal composition with synergistic effect | |
| CN101911955B (en) | Biogenic acaricidal water suspension composition and preparation method thereof | |
| CN1954673A (en) | Powder for crawling pest control | |
| CN1267451A (en) | Mineral oil-containing pesticide for protecting plant | |
| CN103081939A (en) | Methylamino abamectin benzoate/indoxacarb oil suspension and preparation method thereof | |
| CN1192855A (en) | Insecticide containing light diesel oil for plant protection | |
| CN102228044B (en) | Insecticidal composition containing sufluoxime | |
| CN110623002A (en) | Preparation method of sweet wormwood wax oil insect repellent | |
| CN112772671B (en) | Dinotefuran-containing compound insecticidal composition and application thereof | |
| CN109757498A (en) | A kind of bactericidal composition of plant source finish | |
| CN103875703A (en) | Pesticide paste for controlling longicorn beetles | |
| CN102239875A (en) | Insecticidal composition containing 1-(3-fluoro-4-chlorphenyl)-2-methylthioethanone-O-(2-hydroxymethyl-3-methyl)aether and partial nicotine compounds | |
| CN1165236C (en) | Insecticide compounded with nimbin and nereistoxin | |
| CN1033356C (en) | Acaricidal composition | |
| CN101715782B (en) | Blended pesticide preparation of cygon and antibiotic insecticides | |
| CN101124906A (en) | Nimbin-containing injection formulation for tree trunk and application of nimbin in field of injection for tree trunk | |
| US7833996B2 (en) | Composition and method for controlling rice water weevils | |
| CN105941423B (en) | A kind of Pesticidal combination containing capillary and cyromazine | |
| CN108849914A (en) | Agricultural chemical composition for disinsection and its preparation method and application | |
| CN1593126A (en) | Selaginella moellendorfii essential oil alcohol-based aerosol and preparation method thereof | |
| CN103109846B (en) | Dichlorovos kadethrine compounded pesticide | |
| CN115399316B (en) | A pesticide tank-mix adjuvant composition and its preparation method and application | |
| CN119096992A (en) | Insecticide composition and its application | |
| CN101406186A (en) | Composition for killing insects and mites with synergism and uses thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Applicant after: China Agricultural University Applicant before: Wang Yuwan Applicant before: Pan Zhende Applicant before: Dai Xiaoxi Applicant before: You Cunhua |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: WANG YUWAN; PAN ZHENDE; DAI XIAOXI; YOU CUNHUA TO: CHINA AGRICULTURAL UNIVERSITY |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |