CN1377637A - Herbal pigment and perfume for cosmetics - Google Patents

Herbal pigment and perfume for cosmetics Download PDF

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Publication number
CN1377637A
CN1377637A CN 01112466 CN01112466A CN1377637A CN 1377637 A CN1377637 A CN 1377637A CN 01112466 CN01112466 CN 01112466 CN 01112466 A CN01112466 A CN 01112466A CN 1377637 A CN1377637 A CN 1377637A
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oil
compositions
colorant
acid
essential oil
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帕尔普·普什潘格丹
尚塔·梅罗特拉
阿贾·库马尔·辛格·罗瓦特
塞亚达·哈通
拉加万·戈文达罗简
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Lektratek Instrumentation Pty Ltd
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Lektratek Instrumentation Pty Ltd
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Abstract

The present invention relates to a kind of safe herbal composite with health function, no harm to ecological environment and beautifying function. The composite may be used in various cosmetics, such as lipstick, eye-shadow, flashing agent and rouge. The composite has pigment separate from borage family plant material. The present invention also provides the preparation process of the composite and also relates to the use of the lipstick as fragrant treating medium.

Description

The herbal pigment of used for cosmetic and spice
The present invention relates to a kind of safety, ECO-friendly, protect the health and cosmetic compositions, it can be used as lip pomade or is used for other cosmetics, as eye shadow cream, protective skin cream, glitter and kermes.
Because synthetic colorant may cause some side effect, so for the use of natural earth pigment, particularly the interest of using in cosmetics and medicine has been recovered in worldwide.Holding this viewpoint, the present invention gets down to the pure natural herbal pigment that exploitation is used for cosmetic composition.One aspect of the present invention relates to exploitation as the draft compositions of lip pomade, and it has the functional characteristic that changes emotion, comprises the creative thinking of the user that promotes to use it for lip.These characteristics of this compositions are owing to the selectivity mixed preparing of natural earth pigment and essential oil/fragrant mono-isolate wherein.
Lip is the sensitive portions of skin, and it can produce Transdermal absorption fast, and very the lip near nose is easy to continue to suck the essential oil/flavor chemistry material that is mixed in the slow evaporation in the compositions.Therefore, can cause the neurochemical that emotion changes stimulates and spiritual perception changes, the double effects that acts on the specific center of brain is provided by discharging.Essential oil/fragrant mono-isolate/natural perfume material chemical substance that selectivity is mixed in the lip pomade is carried out different mixing, produce antidepressant, rouse oneself the effect of emotion/raising emotion and cause creationary thinking.
When develop for the Ms different color and lusters be mixed with the lip pomade of essence the time, also be man's exploitation other compositionss as lip pomade.These compositionss do not contain colorant, and produce moistening transparent effect, and they have the function that changes emotion and are designed to change spiritual perception, and it acts on lip composition similar and for Ms's exploitation.By preventing the lip blackening and for lip provides moistening effect, two groups of lip pomades have the characteristic of additional promotion/protect the health and beautify equally.These compositionss also make lip produce tempting gloss and texture.The band color lip pomade of developing for the Ms has antibacterium, antifungal and anti-infective effect.The lip of touching upon beautifies local articles for use, and the lip pomade of different color and lusters is well-known.Equally, the sprinkling of aromatic oil or freshener also is well-known.There are many researchs to be conceived to the influence of fragrance to spiritual perception; For example, good fragrance stays beautiful impression and our life is produced multiple active influence to the people, they be not only for have therapeutic efficiency and mysterious product joyful and that attract also be the creator of active mood.
Be published in Phytochemisry with reference to Y.N.Shukla etc., 1971, Vol.10, the publication that is entitled as " Naphthaquinones of Arnebia Nobilis " of pp.1909-1915.Wherein report the 4-naphthoquinone of being appointed as A-1, A-2, A-3, A-4, also reported the use of Arnebia nobilis extract.Sayyada Khatoon and Shanta Mehrotra are being published in NaturalProduct Sciences, reported that some are derived from the naphthoquinone of comfrey, have also reported the various characteristics of these chemical compounds in 1,996 2 (2) pp.75-85 " Naphthaquinones from someBoraginaceous Texa-A Chemical Review ".
V.P.Papageorgiou is published in Planta Medica at him, 1980, Vol.38, reported some lipotropy red pigments available from each kind of plant in the publication that is entitled as " Naturally occurring Isohexenylnaphthazarin Pigments:A newClass of Drugs " of No.3, wherein plant comprises Radix Arnebiae (Radix Lithospermi), Echium, radix onosmae, Folium Fumicis Dentati, Fructus Lithospermi Zollingeri.
United States Patent (USP) 4996044 is described a kind of lip pomade formulation that contains organic brilliant idea color dyestuff, and described formulation has white shape, glossy, soft precipitation and uses permanent characteristic.This formulation does not use any extract available from any plant.
With reference to United States Patent (USP) 5593662, a kind of moistening lip pomade is described wherein.In this invention, use the compositions that contains the 30-80% lipophilic materials.Because the existence of humidity, it may have than short retention period and may promote microbial growth.As if they use about 0-35% to synthesize colorant, and this is too high for cosmetic composition.Synthetic colorant produces deleterious side effect usually, as tarnish, skin darkening, and also may shown in website (http://www.orst.edu/foodresource/color/colorants/.html), have carcinogenesis.
Another list of references is a patent 5665778, wherein describes a kind of N fatty acyl sphingosine, its preparation process and the application in cosmetics and dermal drug thereof.These chemical compounds are red-and complex mixtures of forming of Soviet Union-diastereomer.They synthesize these chemical compounds through complicated and expensive approach.They are used for lip pomade with organic pigment, and do not use herbal pigment.
Can be with reference to the recent PCT application PCT/EP00/02217 on March 13rd, 2000.Wherein the inventor with zinc salt particularly zinc citrate be used for lip pomade, to produce antimicrobial characteristic.Use the shortcoming of zinc or zinc salt to be: they have side effect usually, promptly cause vomiting and cause conjunctivitis.
In essential oil, aromatic and spice international conference (in November, 1989), a bit not mentioned description of in lip pomade, using spice.The lip pomade that can obtain in the international market is only as pure and fresh refiner.
And United States Patent (USP) 5665778 has been described the another kind of cosmetic formulations thing that contains N fatty acyl sphingosine and other chemical compound.The compositions of this patent is complete synthesis compositions.
United States Patent (USP) 5676957 has been described a kind of external preparation for skin medicament, and described medicament is the extract of Euonymus gene plants such as Euonymus alata.This extract of the present invention can be accepted base material in cosmetics and prepare.
With reference to United States Patent (USP) 5,85,8348, wherein,, only the single mono-isolate of the essential oil of a kind of similar ROSE OXIDE is used for synthetic lip pomade and other cosmetics for producing pure and fresh sensation.A kind of so single mono-isolate of essential oil will not have the multiple effect of expectation, rouse oneself, will feel joyful and induce the effect of spiritual thinking as emotion.
Known to the applicant, there be not cosmetics (as eye shadow cream, glitter and kermes), the men's same lip pomade that does not contain colorant and have utilitarian function of any lip pomade that contains herbal pigment and have functional characteristic, use herbal pigment.
Main purpose of the present invention provides safety, ECO-friendly, protects the health and cosmetic compositions, and it contains natural earth pigment and the spice/essential oil that can be used for various cosmetics.
Another object of the present invention is that herbal pigment is used for lip pomade.
Another object of the present invention provides transparent cosmetic composition, and it can be used as lip pomade and contains essential oil and fragrant mono-isolate.
Another purpose of the present invention is that herbal pigment is used for other cosmetic composition, as eye shadow cream, protective skin cream, glitter and kermes.
Another purpose of the present invention is that functional lip pomade is used to cover up vitiligo skin, particularly lip.
Another purpose of the present invention provides a kind of preparation method of cosmetic composition, and this compositions contains herbal pigment and can be used in other the cosmetics.
The invention provides a kind of safety, ECO-friendly, protect the health and beautify the draft compositions of usefulness, it contains colorant and spice, and can be used for various cosmetics.The present invention also provides the preparation approach of this draft cosmetic composition, comprises from natural resources such as plant extracting colorant and other base materials of colorant, spice and cosmetics being mixed.
The present invention relates to a kind of draft cosmetic composition that contains colorant, it is used for local application and external.Specifically, the present invention provides a kind of new cosmetic composition especially, and it can be particularly useful as lip pomade.When as lip pomade, said composition contains herbal pigment, and this colorant mixes with the blend of selected quintessence oil or fragrant mono-isolate, and said composition can change the emotion and the spiritual perception of user.
The present invention relates to a kind of safety, ECO-friendly, protect the health and beautify the draft cosmetic composition of usefulness, but it contains one or more additives that particular characteristics is provided and the acceptable base material of cosmetics of herbal pigment, cosmetics receiving amount.
Therefore, the invention provides a kind of compositions that contains the additive that particular characteristics is provided, wherein additive is selected from the essential oil/fragrant mono-isolate that obtains from the plant species of Lignum Aquilariae Resinatum genus, Cinnamomum, Cymbopogon, Elettaria, Eucalyptus genus, Geranium, jasminum, Ocimum, Pelargonium, Rosa, Rosmarinus, Lignum Santali Albi genus and Vetiveria.
In one embodiment of the invention, essential oil/fragrant mono-isolate as emotion improving agent, antidepressant, antipsychotic, feel joyful generation agent, creative thinking derivant, uneasy alleviant, freshener, analeptic, console agent, antioxidant, fixastive, spice and antimicrobial.
The applicant finds herbal pigment each kind of plant available from Boraginaceae.The applicant finds and can obtain the broad-spectrum colorant from described plant by the specific solvent that uses special ratios.For example, the petroleum ether of different proportion and chloroform can successfully be used for extracting coloring matter from described plant, to obtain the wide spectrum colorant, as soft redness, reddish violet, cerise, ruby, DarkMagenta, beet root purple, three-coloured amaranth redness, mulberry, dark violet rowland color, DarkVoilet, navy blue, black and blue color etc.It should be noted that above-named every kind of plant can produce above-mentioned color spectrum.
The applicant finds, produces a kind of draft compositions available from the herbal pigment of each kind of plant with essential oil and conventional additive, and it is applicable to cosmetics such as lip pomade.This draft compositions does not have toxic action.The applicant also believes, essential oil and fragrant mono-isolate can have the characteristic that emotion strengthens, feels joyful, antidepressant, creative thinking derivant.And essential oil and fragrant mono-isolate are as the supplier of functional characteristic and be used for transparent lip pomade.
Those skilled in the art can determine the mixed proportion of band color substance/band color chemical compound and essential oil and additive at an easy rate.But, preferred 0.0005% band color substance and 10 -6% essential oil, 1% Flos Carthami wet goods luminous agent mix.Base material and other material of adding can supply 100%.
The colorant of draft lipophilic, safety can extract the plant in Lithospermum, Bixa, Puerarta genus, Flos Carthami genus, Hibisci Mutabilis genus, Jatropha, Lithospermum, Radix Arnebiae genus, Maharanga, Nyctanthes, radix onosmae genus, Cuculus polioephalus genus and Tagetes, known it is nontoxic and without any side effects to human body, during in particular for local application.Extraction is bright and glossy from the colorants of these plants, and it is said antibacterium and anti-infective activity.For example a kind of well bright colorant--red-andora colorant, its color and luster is colour table 8.4L (the Maerz and Paul of colorant dictionary, 1950), after being applied to lip, [garnet is to vernonia purple (the colour table 6.3L-6.5A of same dictionary)] provides different practical functions, as emotion rouse oneself, concentration power improves, CNS loosens, work efficiency is quickened, and improved ability to work.It should be noted that each plant of enumerating at this can both produce the broad-spectrum colorant.
Therefore; the invention provides safety, ECO-friendly, the herbal pigment that protects the health and spice; it can be used for cosmetic product; wherein contain the organic compound that extracts from natural resources such as plant, the described organic compound that extracts is used for cosmetic product as the colorant with fragrance in the base material.
One embodiment of the invention are: the herbal pigment of safety is separable from being under the jurisdiction of the different plant species of Boraginaceae, and it is nontoxic and can be without any side effects.
Another embodiment of the invention is: fragrant mono-isolate/essential oil is optional to be belonged to and the Vetiveria plant from Lignum Aquilariae Resinatum genus, Cinnamomum, Cymbopogon, Elettaria, Eucalyptus genus, Geranium, Pelargonium, Rosa, Rosmarinus, Lignum Santali Albi.
In another embodiment, herbal pigment can be used in lip pomade, eye shadow cream, glitter and the kermes.
In yet another embodiment, the lip pomade that contains the combination of essential oil and fragrant mono-isolate can discharge neurochemical by the receptor in mouth and the nose in brain, and it also can have following characteristic: rouse oneself emotion, feel joyful, antidepressant and induce creative thinking.In another embodiment of the present invention, the essential oil that gives the antidepressant characteristic is selected from:
Essential oil preferred proportion 1. basils oil: jasminum vegetable oil: fragrant (1: 2: 1) thatch platymiscium oil 2. basils oil: mint oil: fan (2: 1: 1) the fragrant platymiscium oil 3. jasminum vegetable oil that change: mint oil: fan (1: 1: 1) the fragrant platymiscium oil 4. Cymbopogon plants oil that changes: basil oil: thin (1: 2: 1) lotus platymiscium oil 5. basils oil: Cymbopogon plants oil (2: 1) is mint oil 6.: Rosmarinus vegetable oil (1: 1) is basil oil 8. Rosmarinus vegetable oil 7.
In another embodiment of the present invention, induce the essential oil of creative thinking characteristic to be selected from:
Essential oil preferred proportion 1. Lignum Santali Albi platymisciums oil 2. Lignum Santali Albi platymiscium oil: gul oil (1: 2)
In another embodiment of the present invention, the essential oil that gives the antitonic characteristic is selected from:
Essential oil preferred proportion 1. santal platymiscium oil: lavender platymiscium oil (2: 1) is lavender platymiscium oil 2.: eucalyptus oil: gul oil (1: 1: 1) is eucalyptus oil 3.: gul oil (1: 2) is eaglewood oil 4.: Elettaria oil: Rosmarinus vegetable oil (1: 1: 1) is jasminum vegetable oil 6. santal platymisciums oil 7. lavender platymiscium oil 5.
In another embodiment of the invention, reach pure and fresh effect by essential oil, described essential oil is selected from
Essential oil preferred proportion 1. santal platymiscium oil: gul oil: Rosmarinus vegetable oil (1: 1: 1) is santal platymiscium oil 2.: storksbill oil (1: 2) is the jasminum vegetable oil 3.: lavender platymiscium oil (1: 2) is lavender platymiscium oil 5. santal platymiscium oil 4.: gul oil 6. santal platymiscium oil
In another embodiment of the invention, reach the joyful effect of sense organ by essential oil, described essential oil is selected from
Essential oil preferred proportion 1. jasminum vegetable oil: lavender platymiscium oil: storksbill oil (1: 2) is basil oil 2.: the jasminum vegetable oil: Cymbopogon plants oil (1: 2: 1) is jasminum vegetable oil 4. jasminum vegetable oil 3.: lavender platymiscium oil (2: 1)
In another embodiment of the invention, reach the effect that rouses oneself emotion by essential oil, described essential oil is selected from
Essential oil preferred proportion 1. jasminum vegetable oil: gul oil oil: India (1: 2) certain herbaceous plants with big flowers platymiscium oil 2. Rosmarinus vegetable oil (1: 2) are Cymbopogon plants oil 3.: gul oil (2: 1) is gul oil 5. jasminum vegetable oil 4.: gul oil
In another embodiment of the invention, reach the effect that reduces anxiety by essential oil, described essential oil is selected from
Essential oil preferred proportion 1. guls: cinnamon oil (1: 2)
In another embodiment of the invention, essential oil and fragrant mono-isolate are used for transparent lip pomade as the functional characteristic supplier.
Another embodiment of the invention relates to compositions, and wherein, tocopherol also can be used as fixative as antioxidant, and it exists to ppm with trace.
An embodiment is such as the method for extracting organic compound the plant from natural material, this method comprises carries out drying to plant parts, pulverize with conventional means, described dry powder is used to extract herbal pigment, at random adopt the acid or the alkali of different proportion that described colourity is handled, change to produce various colourities.
In another embodiment, described plant parts can be root, stem, leaf, and depends on from wherein extracting the plant parts of essential oil, and the quantity that is used to prepare the essential oil of compositions changes.
In another embodiment of the invention, described plant parts is 30-45 ℃ place, cool place drying in temperature.
It is the 30-60 order that dried plant position in another embodiment can be crushed to grain graininess.
Further, the red colorant of draft in the embodiment can be by extracting in the plant, and described plant is the plant in Lithospermum, Bixa, Puerarta genus, Flos Carthami genus, Hibisci Mutabilis genus, Jatropha, Lithospermum, Radix Arnebiae genus, Maharanga, Nyctanthes, radix onosmae genus, Cuculus polioephalus genus and the Tagetes.Described plant or their portion are positioned over Soxhlet equipment when being arranged in 20-80 ℃.The selected solvent that is used to extract can be nonpolar hexane, petroleum ether, toluene and cyclohexane extraction, and wherein said polar solvent is selected from chloroform, acetone, ethanol and methanol.Nonpolar and polar solvent can reclaim under 50-100psi low pressure and 40-80 ℃ of temperature.Described herbal pigment obtains after described solvent recovery.Concentrate produces the colorant of various colourities, and such as aubergine, cerise, ruby, beet root purple, dark violet rowland color, avy blue and black-and-blue colorant, it derives from natural herb, does not have the organic solvent of trace in final concentrate.
Further, the invention provides a kind of method and be used to prepare herbal pigment, its comprise the steps: dried plant raw material, pulverizing and under 20-48 ℃ of temperature with ethanol or methanol lixiviate.The extract that is dissolved in alcohols concentrates under 50-100psi low pressure and 40-60 ℃ of temperature.Described concentrate wherein adopts the mixture of non-polar solven-petroleum ether, hexane, cyclohexane extraction, toluene and nonpolar and polar solvent with silicon gel chromatographic columns eluting.Described polar solvent can be chloroform, acetone, ethyl acetate and methanol.The ratio of non-polar solven and polar solvent is 20: 1 to 4: 1.The post fraction concentrates and can carry out under 80-100psi low pressure and 30-60 ℃ of temperature.The colourity of concentrate can be soft redness (pastel red), aubergine, rose, cerise, ruby, peony, beet root purple, three-coloured amaranth redness, mulberry, dark violet rowland color, darkviolet, avy blue, and black and blue color.
In another embodiment, herbal pigment can be antibacterial, anti-infective and can be used for vitiligo, in particular for lip.
In embodiment of the present invention, described herbal pigment can be the mixture of naphthazarin, and can be the unsaturated diketone of ring-type, and wherein the two keys and the ketone group of diketone can be conjugation.
In another embodiment of the invention, described herbal pigment can be changed into different colourity with organic acid or mineral acid.Can adopt organic acid to increase the colourity of color, weaken the colourity of color with mineral acid.The concentration range of acid can be 0.1-10%.
In another embodiment of the invention, described herbal pigment can change by organic base or inorganic base.
In another embodiment of the invention, alkali concn can be 0.1-20%.
In another embodiment of the invention, described herbal pigment can be lipophilic, and its hydrophilic very a little less than.
In another embodiment of the invention, described herbal pigment dissolves in organic solvent, and such as hexane, petroleum ether, benzene, ether, ethyl acetate, chloroform, acetone and alcohol, its value is 30-100%.
In embodiments, the pH value of the herbal pigment of extraction can be 5-6.
Herbal pigment that can be used for cosmetic product and spice that the present invention will provide safety, ECO-friendly, protect the health; it comprises the organic compound that extracts from natural material, the organic compound of described extraction is used as the colorant of band fragrance in the cosmetic product base material.
Described safe herbal pigment can be separated from different floristics, and it belongs to Boraginaceae, and is nontoxic and have no side effect.
In the present invention, fragrant mono-isolate/essential oil can be selected from plant-Lignum Aquilariae Resinatum genus, Cinnamomum, Cymbopogon, Elettaria, Eucalyptus genus, Geranium, Pelargonium, Rosa, Rosmarinus, Lignum Santali Albi genus and Vetiveria.Described herbal pigment can be used for lip pomade, eye shadow cream, glitter and kermes.
But the receptor of described lip pomade through port that contains essential oil and fragrant mono-isolate compositions and nose discharges the chemical substance of system that affects the nerves to brain, and has the effect of improving emotion, improving the joyful degree of sense organ, antidepressant and induce creative thinking.
Essential oil of the present invention and fragrant mono-isolate are used for transparent lip pomade as the supplier of functional characteristic.
Another aspect of the present invention relates to from plant the method for extracting organic toner, described method comprise the preparation plant parts, with organic solvent extraction, by conventional method except that desolvate, under low pressure concentrated extract and randomly with acid or alkali treatment to produce various colourities.
Another aspect of the present invention relates to the organic toner extracting method, and described method comprises step:
A) dried plant position,
B) described dried plant position is pulverized,
C) Soxhlet leaching is carried out at the dried plant position that obtains in step (b) under 40-80 ℃ of temperature, or under 20-45 ℃ of temperature with the cold diafiltration of organic solvent.
D) in 50-100psi low pressure be no more than under 50 ℃ the temperature, with conventional method the mixture in the step (c) is concentrated,
E) concentrate in the step (d) and silicon gel are obtained slurry with 1: 3 to 2: 7 mixed,
F) obtain various fractions with the described slurry of organic solvent eluting,
G) under the pressure of 50-100psi, concentrate described fraction and obtain herbal pigment, and randomly with acid or alkali treatment producing various colourities, and
H) by with acid or the described fraction of alkali treatment producing the colorant of various colourities, thereby obtain various colorants.
The invention still further relates to the other method of from comfrey, extracting herbal pigment, described method comprises: the dried plant position at room temperature obtains being dissolved in the draft raw material of alcohol with pure diafiltration, described draft raw material is concentrated under the temperature of 50-100psi low pressure and 40-60 ℃ with conventional method, described concentrate and silicon gel obtain slurry with 1: 3 to 2: 7 mixed, adopt the described slurry of organic solvent eluting to obtain various fractions with known method, under the pressure of 50-100psi, further concentrate described fraction and obtain herbal pigment with known method, and randomly with acid or alkali treatment to produce various colourities.
Described herbal pigment can be from three kinds of positions of plant arbitrary extracting section, i.e. root, stem or leaf or all these positions.These positions can be dry by conventional methods then, and it is included in heat treatment under the 30-45 ℃ of temperature.Though drying means also can be realized the change of colourity, required time is oversize.After this, the grain graininess that the dried plant raw material obtains suiting after pulverizing and sieve screening is preferably 30-60 purpose powder.
Dried powder can extract by Soxhlet equipment under 40-80 ℃ of temperature.
The dried powder plant material also can extract under 20-45 ℃ of temperature in cold diafiltration.
The non-polar solven that the available selection of described extraction is used to extract and the mixture of non-polar solven and polar solvent carry out.Non-polar solven can select oneself alkane, petroleum ether, toluene and cyclohexane extraction, and polar solvent can be selected from chloroform, acetone, ethanol and methanol.Herbal pigment can prepare by concentrate described extract under 50-100psi low pressure and 40-60 ℃ of temperature.Can obtain aubergine, cerise, ruby, beet root purple, dark violet rowland color, avy blue behind the concentration step, and the black and blue color colorant, it derives from natural herb, and does not have trace organic solvents in final concentrate.
In another approach, described dried powder plant material can be with ethanol or methanol diafiltration under 20-48 ℃ of temperature.The material that is dissolved in alcohol can concentrate under 50-100psi low pressure and 40-60 ℃ of temperature.So described concentrate can the silicon gel chromatographic columns, adopt the non-polar solven eluting, non-polar solven is the mixture of petroleum ether, hexane, cyclohexane extraction, toluene and described non-polar solven and polar solvent.Available polar solvent such as chloroform, acetone, ethyl acetate and methanol.The ratio of non-polar solven and polar solvent can be 20: 1 to 4: 1.Concentrating of post fraction can be carried out under 80-100psi low pressure and 30-60 ℃ of temperature.The color of concentrate can be soft redness (pastel), pale red, aubergine, rose, cerise, ruby, peony, beet root purple, three-coloured amaranth redness, mulberry, dark violet rowland color, DarkVoilet, avy blue, and black and blue color.
These new colorants can use when being with or without fragrant mono-isolate/essential oil.The suitable mixture of fragrance mono-isolate/essential oil can obtain rousing oneself emotion, improve that sense organ is joyful, antidepressant and bring out creationary ideal effect.In order to obtain this type of ideal effect in cosmetics such as lip pomade, described herbal pigment can mix and be applied to described base reason material with the aromatics of selecting.These herbal pigments also can be used for eye shadow cream, glitter, kermes and skin conditioning agent.
These colorants can be the naphthazarin mixture, and can be the unsaturated diketone of ring-type, but wherein two keys of diketone and ketone group conjugation.These herbal pigments can be handled to obtain different colourities by organic acid or mineral acid.Can strengthen colourity and weaken colourity by organic acid with mineral acid.Acid concentration can be 0.1-10%.Add organic acid and mineral acid, the color of herbal pigment can be by red stain indigo plant.The concentration of alkali can be 0.1-20%.
Described herbal pigment has excellent lipotropy and extremely low hydrophilic.These colorants dissolve in organic solvent such as hexane, petroleum ether, benzene, ether, ethyl acetate, chloroform, acetone and alcohol, and its value is 30-100%.The pH value of the colorant that is extracted is 5-6.These characteristics utmost points of described herbal pigment are suitable for cosmetics.Method of the present invention can prepare various colorants, arrives as shown in the table 6 as table 3.
Be used to prepare following the showing of key parameter of various colorants:
A) be used for the solvent composition of chromatographic column.
B) polar solvent also is to produce the key parameter of different colorants with the ratio of non-polar solven.
C) be used for the temperature of Rotavapours of extract method for concentration also for key parameter.
D) temperature of the air oven that adopts in the lip pomade preparation process also is key parameter.
E) acid or the described colorant of alkali treatment with specific concentrations produces various colourities.
New technical feature of the present invention:
1. from nontoxic and highly lipophilic plant material, extract herbal pigment.
2. novelty of the present invention is, adopts herbal pigment to be used for the production of cosmetics such as lip pomade, eye shadow cream, glitter and kermes.
3. by basic herbal pigment being carried out simple process, be in harmonious proportion colourity with organic acid or mineral acid or alkali.
The accompanying drawing summary
Therefore, method of the present invention can obtain different colorants.Some prepared colorants are shown in the drawings.In the accompanying drawings:
Fig. 1 is redness-purple group colorant (60C)
Fig. 2 is redness-purple group colorant (61A)
Fig. 3 is redness-purple group colorant (58A)
Fig. 4 is redness-purple group colorant (46A)
Fig. 5 is redness-purple group colorant (53A)
Fig. 6 is blue group colorant (103A)
Fig. 7 is blue group colorant (99A)
Fig. 8 is an orange group of colorant (25B)
Fig. 9 is an orange red colour cell colorant (31C)
Figure 10 is an orange red colour cell colorant (34C)
Figure 11 is an orange red colour cell colorant (32C)
Figure 12 is an orange red colour cell colorant (33B)
Figure 13 is red group colorant (46A)
Figure 14 is red group colorant (44A)
Figure 15 is red group colorant (46B)
Figure 16 is red group colorant (59A)
Figure 17 is blue group colorant (103B)
Figure 18 is blue group colorant (103A)
Figure 19 is a blueness-green group colorant (114A)
Figure 20 is Lycoperdon polymorphum Vitt-purple group colorant (187B)
Figure 21 is Lycoperdon polymorphum Vitt-purple group colorant (187A)
Figure 22 is a purple group colorant (79A)
Figure 23 is a brown group colorant (200A)
Figure 24 obtains the lip pomade of several different colourities according to the present invention.The form summary
What table 1 was listed is the preferred spice that functional characteristic is provided for cosmetics, i.e. essential oil.
What table 2 was listed is the preferred fragrant mono-isolate that functional characteristic is provided for cosmetics.
Table 3 is depicted as the variation of the colorant that is obtained by direct extraction (method 1)-change color with alkali.
Table 4 is depicted as the variation of the colorant that is obtained by direct extraction (method 1)-change color with acid.
Table 5 is depicted as the variation of the colorant that is obtained by chromatographic column (method 2)-change color with acid.
Table 6 is depicted as the variation of the colorant that is obtained by chromatographic column (method 2)-change color with alkali.
Table 7 is the corresponding color standard table based on Flower Council of Holland (Flower Council of Holland).
Shown shades of colour is to be numbered with the RHS colourity that the The Royal Horticultural Society that is positioned at the London formulates according to Flower Council of Holland.
The following example is to be used for illustrating of the present invention, can not regard them as limitation of the scope of the invention.The preparation of herbal pigment and lip pomade
The present invention is described further with the following example, yet the present invention is not limited to these embodiment.Method
With the mixture of non-polar solven (as hexane, petroleum ether, toluene and cyclohexane extraction) and non-polar solven and polar solvent (as described in polar solvent be chloroform, acetone, ethyl acetate, methanol, ethanol) dusty material is extracted.
The proportion of non-polar solven and polar solvent is 99: 1～0: 100.
Colorant is handled as the acetic acid below 0.1% with the food acids of trace and obtained the change of color.
Alkali with trace is handled the change that obtains color as the alkali below 0.1%.Embodiment 1
100 grams are crossed 40 mesh sieves through the corase meal of the root of air dried radix onosmae platymiscium, extracted 12-18 hour down at 50 ℃ with hexane in the Soxhlet instrument then, the result obtains the extracting solution of hexane solubility draft material.This extracting solution at 70psi and 35 ℃ of following concentrating under reduced pressure, is obtained mauve material 6.0 grams (colour table No 12 A7 of Methuen color handbook, version in 1978).Embodiment 2
Is that 1: 4 corase meal is crossed 40 mesh sieves with 100 grams through the ratio of the stem of air dried radix onosmae platymiscium and root, extracts 18-24 hour down at 60 ℃ with chloroform in the Soxhlet instrument then, and the result obtains the extracting solution of chloroform soluble draft material.This extracting solution at 80psi and 40 ℃ of following concentrating under reduced pressure, is obtained material 8.5 grams (colour table No:13 D8) of beet root purple.Embodiment 3
With chloroform and hexane being mixed in 5: 95 ratio mixture be that 1: 1: 3 corase meal at room temperature carries out diafiltration and extracts 4 hours (3 times) to 100 grams through the ratio of stem, root and the leaf of air dried Radix Arnebiae species, merge all extracting solution and, obtain cerise colorant 3.5 grams (colour table No:12 C8) at 70psi and 50 ℃ of following concentrating under reduced pressure.Embodiment 4
100 grams are crossed 40 mesh sieves through the corase meal of the root of air dried radix onosmae platymiscium, extracted 12-18 hour down at 50 ℃ with hexane in the Soxhlet instrument then, the result obtains the extracting solution of hexane solubility draft material.This extracting solution at 70psi and 35 ℃ of following concentrating under reduced pressure, is obtained mauve material 6.0 grams (colour table No 12 A7).This mauve material becomes rose after 1% formic acid is handled.Embodiment 5
Is that 1: 4 corase meal is crossed 40 mesh sieves with 100 grams through the ratio of the stem of air dried radix onosmae platymiscium and root, extracts 18-24 hour down at 60 ℃ with chloroform in the Soxhlet instrument then, and the result obtains the extracting solution of chloroform soluble draft material.This extracting solution at 80psi and 40 ℃ of following concentrating under reduced pressure, is obtained material 8.5 grams (colour table No:13 D8) of beet root purple.This purple material becomes the such redness of ruby (colour table No:12 D8) after 0.1%HCl handles.Embodiment 6
With chloroform and hexane being mixed in 5: 95 ratio mixture be that 1: 1: 3 corase meal at room temperature carries out diafiltration and extracts 4 hours (3 times) to 100 grams through the ratio of stem, root and the leaf of air dried Radix Arnebiae platymiscium, merge all extracting solution and, obtain cerise colorant 3.5 grams (colour table No:12 C8) at 70psi and 50 ℃ of following concentrating under reduced pressure.Gradually become bright-coloured blue color (colour table No:21 A8) after in this colorant, adding 0.1%NaO.Embodiment 7
With ethanol 100 grams are at room temperature carried out diafiltration extraction 24 hours (4 times) through the corase meal of the root of air dried radix onosmae platymiscium.The ethanol soluble part of stem and root at 70psi and 50 ℃ of following concentrating under reduced pressure, is obtained the ethanol solubility and concentrates thing 18 grams.This concentrate and 54 gram silica gel are mixed preparing slurry, under the assistance of vacuum pump with the slurry drying of gained.Adopt hexane: chloroform (95: 5) is implemented column chromatography analysis to exsiccant slurry.The fraction that obtains with described solvent at 90psi and 40 ℃ of following concentrating under reduced pressure, is obtained the soft red material (colour table No:9 A5) of 0.3 gram thus.After having added 0.%NaOH, this material becomes bright-coloured blueness (colour table No:21A8).The preparation of cosmetic composition
The herbal pigment that is made by the method for embodiment 1-7 can be used to develop various cosmetic compositions as lip pomade, eyeliner, eye shadow cream, glitter and kermes according to the present invention.These preparation of compositions can be carried out according to making the used general procedure of cosmetic composition.Specifically, the herbal pigment that will make from the each several part of plant mixes with base material by proper proportion.Can be at first with described base material liquefaction and then add selected colorant and stir.Perhaps, base material and colorant added mix, the mixture of gained is heated, stir each constituent to obtain uniform mixture.In this mixture, adding essential oil, softening agent, emotion rouse oneself agent and may be other necessary additives concerning said composition.For example, what prepare is the glitter compositions, can provide the additive of brightness effect then need join in the binder composition.When prepared composition cools just be can be used as cosmetic composition after room temperature.
Above just to the summary description of cosmetic composition preparation method, the object lesson that preparation is used for the different cosmetic composition of various uses then is described in embodiment 10-17 hereinafter.These concrete examples provided below only are the description of this invention, can not regard them as limitation of the scope of the invention by any way.Embodiment 8
0.5 milligram herbal pigment and 1 milliliter of safflower oil and 1 milliliter of Oleum Ricini fully mix.In described mixture, sneak into the fused Cera Flava of 1.5 grams at 70 ℃ again.After this, in the gained mixture, add 5 microlitre tocopherols and 1 microlitre essential oil--Rosmarinus vegetable oil.Then with the mixture cool to room temperature.So far, this chilled mixture just can use.
Amount of material percentage composition colorant 0.5mg 0.5% safflower oil 1.0ml 1.0% castor oil 1.0ml 1.0% tocopherol 5 μ l 0.005% Rosmarinus vegetable oil (essential oil) 1.0 μ l 0.001% beeswax 1.5g supplies 100%
Embodiment 9
0.5 milligram herbal pigment and 1 milliliter of safflower oil and 1 milliliter of Oleum Ricini fully mix.In described mixture, sneak into the fused Cera Flava of 1.5 grams at 70 ℃ again.After this, in the gained mixture, add tocopherol 5 microlitres and jasminum and each 1 microlitre of Lignum Santali Albi platymiscium essential oil.Then with the mixture cool to room temperature.So far, this chilled mixture just can use.
Amount of material percentage composition colorant 0.1mg 0.5% safflower oil 1.0ml 1.0% castor oil 1.0ml, 1.0% tocopherol 5.0 μ l, 0.005% jasminum and santal platymiscium oil (essential oil) 1.0 μ l 0.001% beeswax 1.5g supply 100%
Embodiment 10
0.5 milligram herbal pigment and 1 milliliter of safflower oil and 1 milliliter of Oleum Ricini fully mix.In described mixture, sneak into the fused Cera Flava of 1.5 grams at 70 ℃ again.After this, in the gained mixture, add 5 microlitre tocopherols and 1 microlitre sandalwood oil.Then with the mixture cool to room temperature.So far, this chilled mixture just can be used as eye shadow cream.
Amount of material percentage composition colorant 0.5mg 0.5% safflower oil 1.0ml 1.0% castor oil 1.0ml 1.0% tocopherol 5.0 μ l, 0.005% sandalwood oils (essential oil) 1.0 μ l 0.001% beeswax 0.5g supplies 100%
Embodiment 11
1.0 milligram herbal pigment and 1 milliliter of safflower oil and 1 milliliter of Oleum Ricini fully mix.In described mixture, sneak into the fused Cera Flava of 0.2 gram at 70 ℃ again.After this, in the gained mixture, add 10 microlitre tocopherols and 2 microlitre Oleum Rosae Rugosae.Then with the mixture cool to room temperature.So far, this chilled mixture just can be used as glitter.
Amount of material percentage composition colorant 1.0mg 1.0% safflower oil 1.0ml 1.0% castor oil 1.0ml 1.0% tocopherol 10 μ l 0.001% Rosmarinus vegetable oil (essential oil) 2.0 μ l 0.002% beeswax 0.2g supplies 100%
Embodiment 12
The rose-red colorant of 0.25 gram is mixed in ball milling with 10 gram Talcums.In the gained mixture, add 1 microlitre jasminum essence oil from plant and abundant mixing again.So far, the colorant of mixing gained just can be used as kermes.
Amount of material percentage composition colorant 0.25mg 0.25% jasmin essence oil 1.0 μ l 0.001% Talcum 10.0g supplies 100%
Embodiment 13 (antidepressant activity)
0.5 milligram herbal pigment and 1 milliliter of safflower oil and 1 milliliter of Oleum Ricini fully mix.In described mixture, sneak into the fused Cera Flava of 1.5 grams at 70 ℃ again.After this, essential oil blend 1 microlitre that in the gained mixture, adds 5 liters of tocopherols and sweet basil platymiscium oil (having linalool and linalyl acetate), jasmine and lemonweed oil/citral.Then with the mixture cool to room temperature.So far, this chilled mixture just can use.
Amount of material percentage composition colorant 1.5mg 1.0% safflower oil 1.0ml 1.0% Oleum Ricini 1.0ml 1.0% tocopherol 10 μ l 0.01%
Sweet basil platymiscium oil, jasmine and lemonweed 2.0 μ l 0.002% oily Cera Flava 1.5g supply 100%
Embodiment 14 (emotion rouses oneself effect)
1.5 milligram herbal pigment and 1 milliliter of safflower oil and 1 milliliter of Oleum Ricini fully mix.In described mixture, sneak into the fused Cera Flava of 1.5 grams at 70 ℃ again.After this, essential oil blend 1 microlitre that in the gained mixture, adds 5 liters of tocopherols and jasminum plant, Moschus plant and lavandula angustifolia platymiscium oil.Then with the mixture cool to room temperature.So far, this chilled mixture just can use.
Amount of material percentage composition colorant 1.5mg 1.0% safflower oil 1.0ml 1.0% castor oil 1.0ml 1.0% tocopherol 10 μ l 0.01% jasminum, Moschus plant and lavender platymiscium 2.0 μ l, 0.002% oil (essential oil) beeswax 1.5g supply 100%
Embodiment 15 (lip pomade that the man uses)
1 milliliter of safflower oil and 1 milliliter of Oleum Ricini are fully mixed.In described mixture, sneak into the fused Cera Flava of 1.5 grams at 70 ℃ again.After this, blend 1 microlitre that in the gained mixture, adds 5 liters of tocopherols and sandalwood oil and basil oil.Then with the mixture cool to room temperature.So far, this chilled mixture just can use.
Amount of material percentage composition safflower oil 1.0ml 1.0% castor oil 1.0ml, 1.0% tocopherol 10 μ l, 0.01% sandalwood or basil oil (essential oil) 2.0 μ l 0.002% beeswax 1.5g supply 100%
The preferred spice (that is, giving the essential oil of the functional characteristic of cosmetics) of table 1
Functional characteristic Essential oil Preferred proportion
1. antidepressant 1. basil oil: jasminum vegetable oil: Cymbopogon plants oil 2. basil oil: mint oil: Rosmarinus vegetable oil 3. jasminum vegetable oil: mint oil: Rosmarinus vegetable oil 4. Cymbopogon plants oil: basil oil: mint oil 5. basil oil: Cymbopogon plants oil 6. mint oil: Rosmarinus vegetable oil 7. basils oil 8. Rosmarinus vegetable oil (1∶2∶1) ? (2∶1∶1) ? (1∶1∶1) ? (1∶2∶1) ? (2∶1) (1∶1) ? ?
2. antitonic 1. santal platymiscium oil: lavender platymiscium oil 2. lavender platymiscium oil: eucalyptus oil: gul oil 3. eucalyptus oil: gul oil 4. eaglewood oil: Elettaria oil: Rosmarinus vegetable oil 5. jasminum vegetable oil 6. santal platymisciums oil 7. lavender platymiscium oil (2∶1) (1∶1∶1) ? (1∶2) (1∶1∶1) ? ? ? ?
3. bring pure and fresh sense 1. santal platymiscium oil: gul oil: Rosmarinus vegetable oil 2. santal platymiscium oil: storksbill oil 3. jasminum vegetable oil: lavender platymiscium oil 4. lavender platymisciums oil 5. santal platymiscium oil: gul oil 6. santal platymiscium oil (1∶1∶1) ? (1∶2) (1∶2) ? (1∶2) ?
4. sense organ is joyful 1. jasminum vegetable oil: lavandula angustifolia platymiscium oil: storksbill oil 2. basil oil: jasminum vegetable oil: Cymbopogon vegetable oil 3. jasminum vegetable oil 4. jasminum vegetable oil: lavandula angustifolia platymiscium oil (1∶2∶1) (1∶2∶1) ? (2∶1)
5. excite creative thinking 1. Lignum Santali Albi platymiscium oil 2. Lignum Santali Albi platymiscium oil: gul oil (1∶2)
6. rouse oneself emotion 1. jasminum vegetable oil: gul oil: storksbill oil 2. Rosmarinus vegetable oil 3. Cymbopogon vegetable oil: gul oil 4. guls oil 5. jasminum vegetable oil: gul oil (1∶2) ? (2∶1) ? ?
7. minimizing anxiety 1. gul oil: cinnamon oil (1∶2)
The preferred fragrant mono-isolate of table 2 (that is, giving the essential oil of the functional characteristic of cosmetics)
Functional characteristic The fragrance mono-isolate Preferred proportion
1. antitonic Citral
2. bring pure and fresh sense 1. linalool 2. benzylalcohols 3. terpenols 4. terpenols: linalool (1∶2)
3. sense organ is joyful Butanoic acid
4. excite creative thinking 1. isopropylformic acid.: butanoic acid: linalool 2. isopropylformic acid .s: benzylalcohol: linalool 3. isopropylformic acid .s 4. linalools: isopropylformic acid. (1∶2∶1) (1∶2∶1) (1∶2)
5. rouse oneself emotion 1. jasmone 2. citrals 1. acetaminol 4. citrals 5. acetaminol: citral ? ? ? ? (1∶2)
When above-mentioned colorant was used acid or alkali treatment, change in color took place in them.For example, the color of colorant changes when colorant being handled as the acetic acid below 0.1% with the food acids of trace.In addition, when colorant being handled as the alkali below 0.1% with the alkali of trace, the color of colorant also changes.
Change in color when table 3 directly extracts (method 1) with alkali treatment
Numbering Color Sodium hydroxide Potassium hydroxide Sodium acetate
??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％
????1. ??58C ??95A ??98B ??98B ??98B ??99C ??100B ??80D ??97B ??97C
????2. ??55A ??101A ??100D ??100B ??105D ??94B ??93D ??82A ??97C ??97D
????3. ??58B ??101B ??100B ??100D ??101D ??93B ??93C ??80C ??97B ??97D
????4. ??55B ??95B ??97D ??100C ??107A ??99C ??100B ??80D ??97C ??97D
????5. ??55C ??98A ??98C ??98D ??101B ??92B ??92D ??80B ??97D ??97D
????6. ??115B ??115B ??114B ??94C ??115A ??114B ??95D ??201B ??97D ??114D
????7. ??115A ??115A ??113C ??113C ??114D ??113C ??115B ??116B ??111B ??113C
????8. ??122A ??122A ??187B ??187C ??122B ??187C ??200D ??201A ??183C ??182A
Table 4 directly extracts (method 1)
Change in color during with acid treatment
Numbering Color Acetic acid Citric acid Oxalic acid
??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％
????1. ??58C ??46C ??73B ??65B ??46B ??55B ??56A ??47D ??48D ??49A
????2. ??55A ??55C ??68C ??69A ??51A ??55C ??56A ??51B ??52C ??52D
????3. ??58B ??73D ??75D ??75D ??73C ??38A ??39C ??73A ??69A ??69A
????4. ??55B ??73B ??73D ??73D ??73C ??73D ??69A ??73A ??69B ??69B
????5. ??55C ??70D ??68D ??69A ??73D ??69A ??69B ??68D ??38A ??38B
????6. ??115B ??95C ??94B ??94C ??96B ??95C ??95D ??97B ??97D ??97D
????7. ??115A ??115B ??113C ??133C ??116C ??115A ??115B ??113A ??111B ??111B
????8. ??122A ??200A ??200C ??200C ??200B ??200C ??200D ??183D ??183C ??182A
Table 5 carries out column chromatography and separates (method 2)
Change in color during with acid treatment
Numbering Color Acetic acid Citric acid Oxalic acid
??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％
??C 1 ??25B ??25C ??24A ??24A ??24A ??24C ??24C ??24A ??24C ??24A
??C 2 ??31C ??29B ??29C ??29C ??27A ??27B ??27B ??29B ??29C ??27B
??C 3 ??34C ??33A ??33C ??33C ??33A ??33C ??33D ??33A ??33C ??33C
??C 4 ??32C ??29A ??28C ??28D ??29A ??28D ??28D ??29A ??28C ??28D
??C 5 ??33B ??40C ??39C ??39D ??31B ??30C ??30D ??31C ??31D ??31D
??C 6 ??46A ??46A ??45C ??45D ??32A ??31B ??30C ??33B ??32A ??32B
??C 7 ??44A ??43A ??40B ??40C ??45D ??42A ??42B ??45C ??44B ??44C
??C 8 ??46B ??47B ??47D ??47D ??47B ??48A ??48B ??46C ??46A ??46D
??C 9 ??59A ??60A ??59D ??57D ??59B ??59D ??59D ??60B ??60C ??59C
??C 10 ??95A ??95C ??94B ??94C ??96B ??95C ??95D ??97B ??97D ??97D
??C 11 ??103A ??200A ??200C ??200C ??187A ??187C ??187D ??187A ??187C ??187C
??C 12 ??114A ??115B ??113C ??113C ??116C ??115A ??115B ??113A ??111B ??111B
??C 13 ??187B ??182A ??180C ??180D ??182C ??181D ??181D ??180B ??181C ??181D
??C 14 ??187A ??59A ??60B ??60C ??59B ??58A ??58C ??59D ??58D ??58C
??C 15 ??79A ??187A ??183A ??183C ??187B ??187B ??185C ??182C ??181D ??181D
??C 16 ??200A ??200A ??200C ??200C ??200B ??200C ??200D ??183D ??183C ??182A
Table 6 carries out column chromatography and separates (method 2)
Change in color during with alkali treatment
Numbering Color ????????????NaOH ?????????????KOH ???????????CH 3COONa
??2％ ??0.1％ ??0.05％ ??2％ ??0.1％ ??0.05％ ??2％ ?0.1％ ?0.05％
??C 1 ??25B ??90A ??89A ??24A ??92A ??89C ??24C ??181B ?24C ?89D
??C 2 ??31C ??106B ??106D ??29C ??98B ??105D ??27B ??58C ?29C ?105D
??C 3 ??34C ??86C ??33C ??33C ??83B ??83C ??33D ??171C ?33C ?83D
??C 4 ??32C ??93B ??93D ??28D ??102A ??99C ??28D ??169C ?38C ?93C
??C 5 ??33B ??98B ??98C ??39D ??105C ??98C ??30D ??169B ?31D ?99C
??C 6 ??46A ??103C ??102C ??45D ??98B ??102D ??30C ??34B ?32A ?101C
??C 7 ??44A ??102B ??102C ??40C ??116A ??102D ??42B ??40A ?44B ?102D
??C 8 ??46B ??116B ??116D ??47D ??116A ??116D ??48B ??46A ?46A ?116C
??C 9 ??59A ??116C ??116D ??57D ??115B ??116D ??59D ??53A ?60C ?116D
??C 10 ??95A ??115B ??114B ??94C ??115A ??114B ??95D ??201B ?97D ?114D
??C 11 ??103A ??188A ??200C ??200C ??116B ??200C ??187D ??83B ?187C ?200C
??C 12 ??114A ??115A ??113C ??113C ??114D ??113C ??115B ??116B ?111B ?113C
??C 13 ??187B ??122B ??121C ??180D ??114B ??121C ??181D ??199C ?181C ?119C
??C 14 ??187A ??120C ??120D ??60C ??114C ??120D ??58C ??201B ?58D ?119D
??C 15 ??79A ??119B ??119C ??183C ??114A ??187B ??185C ??201C ?181D ?181D
??C 16 ??200A ??122A ??187B ??187C ??187B ??187C ??200D ??201A ?183C ?182A
The corresponding meaning of the color code that table 7 Flower Council of Holland formulates
Code Colour cell
?1-13 ?14-23 ?24-29 ?30-35 ?36-56 ?57-74 ?75-79 ?80-82 ?83-88 ?89-98 ?99-110 ?111-124 ?125-143 ?144-154 ?155 ?156-157 ?158-159 ?160-162 ?163-177 ?178-182 ?183-187 ?188-198 ?199-200 ?201 ?202 Grey-white group orange-white that orange group of orange of the yellow set Huang-orange group-red group of redness group red-purple group purple group purple-violet colour cell pansy group violet-blueness is organized the green group Huang of blue group blue-green group-green group white group is organized ash-yellow set ash-orange group ash-redness group ash-purple group ash-green group brown group ash colour cell black group
Shades of colour shown in the last table is to encode according to the RHS color diagram that Flower Council of Holland and RHS work out.
Main advantage of the present invention is:
1. have need not relevant department such as the approval of FAO, WHO and cosmetics administrative department and the advantage that can add and use for herbal pigment.
2. described herbal pigment safety, ECO-friendly also can protect the health.
3. described herbal pigment can be used for a plurality of sensitivities of health and delicate position, such as lip, cheek and eyelid.
4. described herbal pigment can be used in particular for Bai Dianfeng patient's lip district.
5. described herbal pigment has 100% lipophilicity.
6. described herbal pigment can be antibiotic and anti-infective.
Described herbal pigment without any strong as the user being produced the side effect of carcinogenic effect.
8. described herbal pigment can the effective mode of cost be used for various overcovers.
9. the adding of various essential oil and their mono-isolate has promoted the generation of creative thinking, has strengthened the sense organ impression, brings out healthy emotion, and the state and the help that keep good overcome depressed emotion (antidepression).
Therefore, the invention provides a kind of safety, ECO-friendly, protect the health and strengthen beautiful draft functional composition, it only contains natural products. Natural safe colorant can obtain in the different plant varieties by Lithospermum, Bixa, palas genus, safflower genus, lotus genus, Jatropha, Lithospermum, radix macrotomiae genus, Maharanga, Nyctanthes, radix onosmae genus, Genus Rhododendron and Tagetes. The colorant of various colourities extracts respectively according to some extracting methods of having described. The present invention also seeks to use lipstick as the media of spices treatment. Essential oil separates acquisition from the different plant varieties of agalloch eaglewood genus, Cinnamomum, Cymbopogon, Elettaria, eucalyptus genus, Geranium, jasminum, Ocimum, Pelargonium, Rosa, Rosmarinus, santal genus and Vetiveria. The multiple mixture of these essential oil components has been used for obtaining effect such as antidepression and the creative thinking of hope.

Claims (70)

  1. A safety, ECO-friendly, protect the health and increase beautiful draft cosmetic composition; but said composition contains one or more additives of herbal pigment, cosmetics receiving amount and can be used for the base material of cosmetics, and described additive provides special performances for cosmetics.
  2. 2. according to the compositions of claim 1, the wherein said additive that property is provided be selected from by Lignum Aquilariae Resinatum genus, Cinnamomum, Cymbopogon, Elettaria, Eucalyptus genus, Geranium, jasminum, Ocimum, Pelargonium, Rosa, Rosmarinus, Lignum Santali Albi belong to and the different plant varieties of Vetiveria in essential oil/fragrant mono-isolate of obtaining.
  3. 3. according to the compositions of claim 1, wherein said essential oil/fragrant mono-isolate plays the effect that emotion rouses oneself agent, antidepressant, antipsychotic, joyful dose of sense organ, creative thinking inducing agent, anxiety palliative, freshener, analeptic, consoles agent, antioxidant, fixative, aromatic and antibacterial.
  4. 4. according to the compositions of claim 1, wherein said essential oil/fragrant mono-isolate discharge the neurochemical in the brain by the receptor in mouth and the nose and provide in high spirits, sense organ is joyful, antidepressant and bring out the creative thinking performance.
  5. 5. according to the compositions of claim 1, wherein said colorant separates from the plant of Boraginaceae, and it is nontoxic and without any side effect.
  6. 6. according to the compositions of claim 1, wherein said colorant obtains from the plant of Lithospermum, Bixa, Puerarta genus, Flos Carthami genus, Hibisci Mutabilis genus, Jatropha, Lithospermum, Radix Arnebiae genus, Maharanga, Nyctanthes, radix onosmae genus, Cuculus polioephalus genus and Tagetes.
  7. 7. according to the compositions of claim 1, wherein from root, stem or the leaf of described plant, extract described colorant, and the use amount of described essential oil is decided based on the position of extracting essential oil.
  8. 8. according to the compositions of claim 1, wherein said colorant can be dissolved in the scope of 30-100% in the organic solvent that is selected from hexane, petroleum ether, benzene, ether, ethyl acetate, chloroform, acetone and alcohol.
  9. 9. according to the compositions of claim 1, the pH value of wherein said colorant is between the 5-6.
  10. 10. according to the compositions of claim 1, the content of wherein said colorant is 0.1-10%.
  11. 11. according to the compositions of claim 1, wherein said colorant is antibacterial, anti-infective and the lip that is specially adapted to Bai Dianfeng patient.
  12. 12. according to the compositions of claim 1, wherein said colorant has lipotropy.
  13. 13. according to the compositions of claim 1, wherein said colorant is the mixture of the unsaturated diketone of naphthazarin and/or cyclisation, two keys in the unsaturated diketone of described cyclisation and ketone group can be conjugated.
  14. 14. compositions according to claim 1, wherein said colorant has the colourity of different colours, and described color is selected from aubergine, cerise, ruby, beet root purple, dark violet rowland color, navy blue, black and blue color, soft redness, light red, aubergine, rose, cerise, ruby, DarkMagenta, beet root purple, three-coloured amaranth redness, mulberry, dark violet rowland color, DarkVoilet, navy blue and black and blue color.
  15. 15. according to the compositions of claim 1, the redness of wherein said colorant can become different colourity with mineral acid with organic.
  16. 16. according to the compositions of claim 15, the red intensity of wherein said herbal pigment can increase and reduce with mineral acid with organic acid.
  17. 17. according to the compositions of claim 15, the concentration of wherein said acid is 1-20%.
  18. 18. according to the compositions of claim 1, the redness of wherein said herbal pigment can become different colourity with inorganic base with organic.
  19. 19. according to the compositions of claim 18, the red intensity of wherein said herbal pigment can increase and reduce with inorganic base with organic base.
  20. 20. according to the compositions of claim 18, the concentration of wherein said alkali is 1-20%.
  21. 21. according to the compositions of claim 1, said composition is used as lip pomade in the aroma-therapeutic to the people.
  22. 22. according to the compositions of claim 1, said composition is as eye shadow cream.
  23. 23. according to the compositions of claim 1, said composition is as glitter.
  24. 24. according to the compositions of claim 1, said composition is as rose.
  25. 25. according to the compositions of claim 1, the use amount of wherein said essential oil is that trace is to ppm.
  26. 26. according to the compositions of claim 1, the use amount of wherein said softening agent is the 0.5%-2% of composition total weight.
  27. 27. according to the compositions of claim 1, wherein the use amount of third contact of a total solar or lunar eclipse agent is 0.5%-2%.
  28. 28. according to the compositions of claim 1, wherein the use amount of Derma-Guard is 0.0001%-0.09%.
  29. 29. according to the compositions of claim 1, wherein being used to provide the use amount of the essential oil of functional characteristic is 0.0001%-0.009%.
  30. 30. according to the compositions of claim 1, wherein Cera Flava uses as base material and is the aequum of described compositions.
  31. 31. according to the compositions of claim 1, wherein said armaticity is provided by the essential oil that obtains in the plant variety that is selected from Lignum Aquilariae Resinatum genus, Cinnamomum, Cymbopogon, Elettaria, Eucalyptus genus, Geranium, jasminum, Ocimum, Pelargonium, Rosa, Rosmarinus, Lignum Santali Albi genus and Vetiveria.
  32. 32. according to the compositions of claim 1, wherein be used for making up pharmaceutical applications and lip pomade, eye shadow cream, glitter, kermes and skin conditioning agent use the organic compound that is extracted.
  33. 33. according to the compositions of claim 1, wherein said compositions is to have the lip pomade that improves wettability effect.
  34. 34. compositions according to claim 1, wherein said additive is an essential oil mixture, plays emotion and rouses oneself agent, antipsychotic, anxiety palliative, joyful dose of sense organ, antidepressant, creative thinking inducing agent, freshener, antioxidant, fixative and anti-depressant effect.
  35. 35. according to the compositions of claim 1, wherein said antidepressant performance provides by being selected from following essential oil: Essential oil Preferred proportion ??1 Basil oil: jasminum vegetable oil: Cymbopogon vegetable oil ????1∶2∶1 ??2 Basil oil: mint oil: Rosmarinus vegetable oil ????2∶1∶1 ??3 Jasminum vegetable oil: mint oil: Rosmarinus vegetable oil ????1∶1∶1 ??4 Cymbopogon vegetable oil: basil oil: mint oil ????1∶2∶1 ??5 Basil oil: Cymbopogon vegetable oil ????2∶1
    ?6 Mint oil: Rosmarinus vegetable oil ????1∶1 ?7 Basil oil ?8 The Rosmarinus vegetable oil
  36. 36. according to the compositions of claim 1, the wherein said creation performance thinking performance of bringing out provides by being selected from following essential oil: Essential oil Preferred proportion ????1 Lignum Santali Albi platymiscium oil ????2 Lignum Santali Albi platymiscium oil: gul oil ????1∶2
  37. 37. according to the compositions of claim 1, wherein said antitonic performance provides by being selected from following essential oil: Essential oil Preferred proportion ????1 Lignum Santali Albi platymiscium oil: lavandula angustifolia platymiscium oil ????2∶1 ????2 Lavandula angustifolia platymiscium oil: eucalyptus oil: gul oil ????1∶1∶1 ????3 Eucalyptus oil: gul oil ????1∶2 ????4 Eaglewood oil: Elettaria oil: Rosmarinus vegetable oil ????1∶1∶1 ????5 The jasminum vegetable oil ????1∶2 ????6 Lignum Santali Albi platymiscium oil ????7 Lavandula angustifolia platymiscium oil
  38. 38. according to the compositions of claim 1, wherein said pure and fresh performance provides by being selected from following essential oil: Essential oil Preferred proportion ????1 Lignum Santali Albi platymiscium oil: gul oil: Rosmarinus vegetable oil ????1∶1∶1 ????2 Lignum Santali Albi platymiscium oil: storksbill oil ????1∶2 ????3 Jasminum vegetable oil: lavandula angustifolia platymiscium oil ????1∶2 ????4 Lignum Santali Albi platymiscium oil: gul oil ????1∶1 ????5 Lavandula angustifolia platymiscium oil ????6 Lignum Santali Albi platymiscium oil
  39. 39. according to the compositions of claim 1, the joyful performance of wherein said sense organ provides by being selected from following essential oil: Essential oil Preferred proportion ????1 Jasminum vegetable oil: lavandula angustifolia platymiscium oil: storksbill oil ????1∶2 ????6 Basil oil: jasminum vegetable oil: Cymbopogon vegetable oil ????1∶2∶1 ????7 The jasminum vegetable oil ????8 Jasminum vegetable oil: lavandula angustifolia platymiscium oil ????2∶1
  40. 40. according to the compositions of claim 1, wherein said performance in high spirits provides by being selected from following essential oil: Essential oil Preferred proportion ????1 Jasminum vegetable oil: gul oil: storksbill oil ????1∶1∶1 ????2 The Rosmarinus vegetable oil ????3 Cymbopogon vegetable oil: gul oil ????2∶1 ????4 Gul oil ????5 Jasminum vegetable oil: gul oil
  41. 41. according to the compositions of claim 1, wherein said anxiety alleviates performance to be provided by being selected from following essential oil: Essential oil Preferred proportion ????1 Gul oil: cinnamon oil ????1∶2
  42. 42. according to the compositions of claim 1, wherein said antitonic performance is provided by fragrant mono-isolate citral.
  43. 43. according to the compositions of claim 1, wherein said pure and fresh performance is provided by fragrant mono-isolate, described fragrant mono-isolate is selected from linalool, benzyl alcohol, terpenol, and the preferred ratio of terpenol and linalool is 1: 2.
  44. 44. according to the compositions of claim 1, the joyful performance of wherein said sense organ is provided by fragrant mono-isolate butanoic acid.
  45. 45. according to the compositions of claim 1, the wherein said creative thinking performance of bringing out provides by being selected from following fragrant mono-isolate: The fragrance mono-isolate Preferred proportion ????1 Isopropylformic acid.: butanoic acid: linalool ????1∶2∶1 ????2 Isopropylformic acid.: benzyl alcohol: linalool ????1∶2∶1 ????3 Isopropylformic acid. ????4 Linalool: isopropylformic acid. ????1∶2
  46. 46. according to the compositions of claim 1, wherein said performance in high spirits is provided by fragrant mono-isolate, described fragrant mono-isolate is selected from jasmone, citral and acetaminol, and acetaminol and citral are preferably than being 1: 2.
  47. 47. according to the compositions of claim 1, wherein said fixative is tocopherol and Lignum Santali Albi platymiscium oil, tocopherol is also as fixative, and it exists to ppm with trace.
  48. 48. extract the method for organic toner from plant, this method comprises the following steps:
    Obtain the position of plant, use organic solvent extraction, remove solvent with conventional method, the concentrating under reduced pressure extract, and randomly handle with acid or alkali, to obtain various colourities.
  49. 49. extract the method for organic toner, this method comprises the following steps:
    A) dried plant position;
    B) with exsiccant plant parts powdered;
    C) the exsiccant powder that step (b) is obtained carries out the Soxhlet extracting or is saturating with the organic solvent merceration between 20-45 ℃ in temperature in temperature is 40-80 ℃ scope;
    D) with the low pressure of conventional method in pressure is the 50-100psi scope and the mixture that is no more than concentration step (c) under 50 ℃ of temperature;
    E) concentrate of step (d) and silica gel are obtained slurry with 1: 3 to 2: 7 mixed;
    F) obtain different fractions with this slurry of organic solvent eluting;
    G) in pressure is the 50-100psi scope, concentrate described fraction and obtain herbal pigment, randomly produce various color degree with acid or the said colorant of alkali treatment; With
    H) by produce the colorant of various colourities with acid or the said fraction of alkali treatment, obtain shades of colour.
  50. 50. according to the method for claim 49, wherein said organic solvent is selected from polar solvent, nonpolar flux or their mixture.
  51. 51. according to the method for claim 49, wherein said polar solvent is selected from acetone, chloroform, ethyl acetate, methanol and ethanol.
  52. 52. according to the method for claim 49, wherein said non-polar solven is selected from petroleum ether, hexane, toluene and cyclohexane extraction.
  53. 53. from comfrey, extract the method for herbal pigment, this method comprises: at room temperature soak into the draft material that the plant parts powder obtains being dissolved in alcohol with alcohol, said draft material is 40-60 ℃ with temperature with known method in pressure is the 50-100psi scope concentrate down, said concentrate and silica gel are made slurry with 1: 3 to 2: 7 mixed, obtain fraction by known method with the said slurry of organic solvent eluting, in pressure is the 50-100psi scope, concentrate described fraction again and obtain herbal pigment, randomly produce various colourities with acid or the said colorant of alkali treatment by known method.
  54. 54. according to the method for claim 53, wherein said plant is selected from the plant of Boraginaceae.
  55. 55. according to the method for claim 49 and 53, wherein said plant parts is selected from root, stem or the leaf of plant, and the use amount of described essential oil is decided based on the position of extracting essential oil.
  56. 56. according to the method for claim 49 and 53, wherein said plant parts is in 30-45 ℃ temperature range, in the shady place drying.
  57. 57. according to the method for claim 49 and 53, the wherein said plant parts that has been dried by powdered to 30-60 purpose granular size.
  58. 58. according to the method for claim 53, wherein employed alcohol is selected from methanol and ethanol.
  59. 59. according to the method for claim 53, wherein said organic polar solvent is selected from acetone, chloroform, ethyl acetate, methanol and ethanol.
  60. 60. according to the method for claim 53, wherein said non-polar solven is selected from petroleum ether, hexane, toluene and cyclohexane extraction.
  61. 61. according to the method for claim 49 and 53, the ratio of wherein said polar solvent and non-polar solven is according to the character decision of solvent for use.
  62. 62., wherein prepare the mixture of non-polar solven and chloroform with 99: 1 to 0: 100 ratio according to the method for claim 49 and 53.
  63. 63. according to the method for claim 49 and 53, wherein said color gamut is aubergine, cerise, ruby, beet root purple, dark violet rowland color, navy blue, black and blue color, soft redness, light red, aubergine, rose, cerise, ruby, DarkMagenta, beet root purple, three-coloured amaranth redness, mulberry, dark violet rowland color, DarkVoilet, navy blue and black and blue color.
  64. 64. according to the method for claim 49 and 53, wherein employed acid is selected from the organic acid such as formic acid and acetic acid, such as HCl, HNO 3And H 2SO 4Mineral acid
  65. 65. according to the method for claim 49 and 53, wherein the concentration of employed acid is 0.1%-10%.
  66. 66. according to the method for claim 49 and 53, the change of the color in the wherein said colorant realizes with 0.1% amount processing colorant by food-grade acid such as acetic acid with trace.
  67. 67. according to the method for claim 49 and 53, the change of the color in the wherein said colorant realizes by handling colorant with the alkali of trace with 0.1% amount.
  68. 68. according to the method for claim 49 and 53, wherein employed alkali is selected from the organic base such as sodium acetate, potassium acetate and diethylamide, such as NaOH, KOH, Na 2CO 3Inorganic base with NaCl.
  69. 69. according to the method for claim 49 and 53, wherein the concentration of employed alkali is 0.1%-20%.
  70. 70. according to the method for claim 49 and 53, wherein said herbal pigment is antibacterial, anti-infective and the lip that is specially adapted to Bai Dianfeng patient.
CN 01112466 2001-03-30 2001-03-30 Herbal pigment and perfume for cosmetics Pending CN1377637A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103432037A (en) * 2013-08-24 2013-12-11 上海艳紫化工科技有限公司 Clove basil oil skin cream
CN104188885A (en) * 2014-09-12 2014-12-10 皖南医学院 Moistening and moisturizing type lithospermum erythrorhizon lip balm and preparation method thereof
CN104771351A (en) * 2015-03-19 2015-07-15 苏州谷力生物科技有限公司 Edible lipstick and preparation method thereof
CN107595751A (en) * 2017-08-21 2018-01-19 澳宝化妆品（惠州）有限公司 A kind of lip skin care composition containing agalloch eaglewood anthophorids honey
CN112057384A (en) * 2020-09-27 2020-12-11 南京绿瞬电子科技有限公司 Man perfume and preparation method thereof
CN113521125A (en) * 2020-04-14 2021-10-22 青岛森度生物科技有限公司 Feilomeng composition for cats and preparation method thereof
CN114191507A (en) * 2020-09-17 2022-03-18 广东工业大学 Anti-depression traditional Chinese medicine formula and anti-depression essential oil

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103432037A (en) * 2013-08-24 2013-12-11 上海艳紫化工科技有限公司 Clove basil oil skin cream
CN103432037B (en) * 2013-08-24 2015-08-19 上海艳紫化工科技有限公司 Clove basil oil skin cream
CN104188885A (en) * 2014-09-12 2014-12-10 皖南医学院 Moistening and moisturizing type lithospermum erythrorhizon lip balm and preparation method thereof
CN104188885B (en) * 2014-09-12 2018-04-03 皖南医学院 A kind of moist humidity-preserving type Asian puccoon lip gloss and preparation method thereof
CN104771351A (en) * 2015-03-19 2015-07-15 苏州谷力生物科技有限公司 Edible lipstick and preparation method thereof
CN107595751A (en) * 2017-08-21 2018-01-19 澳宝化妆品（惠州）有限公司 A kind of lip skin care composition containing agalloch eaglewood anthophorids honey
CN113521125A (en) * 2020-04-14 2021-10-22 青岛森度生物科技有限公司 Feilomeng composition for cats and preparation method thereof
CN114191507A (en) * 2020-09-17 2022-03-18 广东工业大学 Anti-depression traditional Chinese medicine formula and anti-depression essential oil
CN112057384A (en) * 2020-09-27 2020-12-11 南京绿瞬电子科技有限公司 Man perfume and preparation method thereof

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