CN1357462A - Scagliola - Google Patents
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- CN1357462A CN1357462A CN 00134990 CN00134990A CN1357462A CN 1357462 A CN1357462 A CN 1357462A CN 00134990 CN00134990 CN 00134990 CN 00134990 A CN00134990 A CN 00134990A CN 1357462 A CN1357462 A CN 1357462A
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Abstract
The present invention discloses a kind of scagliolas and its making process. The said scagliola is a marble imitating layer attached to some substrate. The material for the scagliola includes unsaturated resin, curing agent, promoter and stone grain. The curing agent is methyl ethyl ketone or cyclohexanone peroxide, the promoter is cobalt naphthenate solution or T-8A promoter, and the stone grain is 20 mesh below natural or artificial stone grain. It has excellent marble texture and service life in the open air as long as 50 years.
Description
The present invention relates to the manufacture method of a kind of Scagliola and Scagliola.
The marble major part of building trade and construction decoration industry use at present is a natural marble, exploits natural marble in a large number, can destroy natural landscape, brings harmful effect to environmental protection.The needs that the natural marble that construction decoration uses has are through Carving Machining, yield rate is lower in the engraving process, cause the wasting of resources, and the engraving process of natural marble is generally carried out by hand, can not realize the mechanization batch process, the labour intensity of sculpting operation is big, and operator's technical merit is had relatively high expectations.Therefore, costing an arm and a leg of natural marble is difficult to popularization and application.In order to address the above problem, someone attempts to make imitating natural marble, this imitating natural marble forms matrix after mainly adopting mixing casting formings such as magnesia, magnesium chloride, stone and sand, and then at surface lacquer, the colored paint of abutment surface is copied the color of natural marble.The emulation degree of this imitating natural marble is relatively poor, does not have the appearance tactile impression and the smoothness of natural marble, and surperficial colored paint comes off easily, and service life is shorter.Because there is above-mentioned shortcoming in imitating natural marble, there be limited evidence currently of has the people to adopt.
One of purpose of the present invention is, the Scagliola that provides a kind of surface to have the texture of natural marble, and the manufacturing cost of this Scagliola is lower, the life-span is longer.
Two of purpose of the present invention is, a kind of manufacture method that can produce Scagliola in batches is provided, and it can reduce labor intensity.
One of purpose of the present invention is achieved in that Scagliola, comprises matrix, and its special character is to be attached with simulation layer on the surface of matrix; The raw material of making simulation layer contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain.
The unsaturated-resin gel coat is than unsaturated-resin glue price height, and the curing agent that both adopt is identical with promoter, but the simulation layer that adopts the unsaturated-resin gel coat to make is better than the texture of the simulation layer that adopts unsaturated-resin glue to make.
Raw material such as unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and Shi Li solidify after mixing very soon, and the stone grain is bonded in together, thereby form simulation layer.
The raw material manufacturing that matrix adopting is cheap is to reduce manufacturing cost.Matrix is mainly used in the support simulation layer, and it has enough intensity.Matrix can adopt different scheme manufacturings, as long as have enough intensity, can play a supporting role to simulation layer, and low cost of manufacture just can.Simulation layer is mainly used in the texture of performance natural marble, and the texture of natural marble is by the particle diameter of stone grain and color representation.The outer surface of matrix can be attached directly on the inner surface of simulation layer, also can be by intermediate course indirectly on the inner surface attached to simulation layer.The stone grain both can adopt the natural stone grain, also can adopt the artificial stone grain, can also adopt quartz sand, cullet etc.The natural stone grain generally uses the barren rock material manufacturing that produces in the exploitation stone material process.The size of the particle diameter of stone grain can specifically be selected according to different requirements.Unsaturated-resin gel coat or unsaturated-resin glue are mainly used in the stone grain are bonded together.Curing agent is mainly used in and makes unsaturated-resin gel coat or unsaturated-resin adhesive curing, promoter being mainly used in make curing agent accelerate to solidify.It is bonding to the invention is not restricted to adopt unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter that the stone grain is carried out, as long as adopt other adhesive can the stone grain is bonding firmly, and bonding speed be fast, and is anti-aging just all in protection scope of the present invention.Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain that the present invention makes simulation layer are stocks, can add other satisfactory material on the basis of these stocks.For example, fade, can in the above-mentioned raw material of making simulation layer, add the ultraviolet radiation resisting agent for preventing simulation layer.
The raw material curing agent that the present invention makes simulation layer adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter, and it is the following natural or artificial stone grains of 20 orders that the stone grain adopts fineness.
The fineness that the present invention makes the raw material stone grain of simulation layer is preferably 5～20 orders.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain that the present invention makes simulation layer mix according to following weight ratio: unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05 0.02～0.08 0.5～1.5
In order to make the present invention have antiultraviolet, aging-resistant function, perhaps in order to regulate the color on surface, the raw material of making simulation layer can also contain mica powder and mill base except containing unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain.
Raw material such as unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone grain, mica powder and mill base solidify after mixing very soon, and stone grain and mica powder are bonded in together, thereby form simulation layer.
Mica powder can shine by antiultraviolet, and ageing resistace of the present invention is improved.Mica powder is a kind of of ultraviolet radiation resisting agent, and mica powder can replace with other ultraviolet radiation resisting agent.In addition, glittering when mica powder is subjected to the light irradiation, make the aesthetic feeling multiplication of simulation layer.Mill base is used for artificially regulating the color on simulation layer surface, and the color of mill base can be selected according to different needs.After adding mica powder and mill base, the emulation degree of simulation layer weakens.Therefore, generally just add mica powder and mill base under the situation of specific (special) requirements having.
The fineness that the present invention makes the raw material mica powder of simulation layer is preferably below 1000 orders.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone grain, mica powder and mill base that the present invention makes simulation layer mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain mica powder mill base
1 0.01～0.05 0.02～0.08 0.5～1.5 0.1～0.5 is an amount of
Mill base can add as one feels fit according to concrete needs.
Has back-up coat between simulation layer of the present invention and the matrix, on the inner surface of the outer surface of back-up coat attached to simulation layer, on the inner surface of the outer surface of matrix attached to back-up coat.
Matrix is mainly used in the inner chamber of filling back-up coat, because it has enough intensity, with back-up coat simulation layer is played a supportive role.On the inner surface that back-up coat should be firm, prevent that simulation layer from breaking, simulation layer is played better supporting role, to improve the intensity of simulation layer attached to simulation layer.
The raw material of manufacturing back-up coat of the present invention contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and glass fabric; Glass fabric bonds together by the inner surface of unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter and simulation layer.
After unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter are mixed, before solidifying, rapidly it is brushed on the inner surface of simulation layer, and rapidly glass fabric is layered on the inner surface of simulation layer.After the mixture of unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter solidified, glass fabric was bonded on the inner surface of simulation layer, thereby formed back-up coat.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and glass fabric that the present invention makes back-up coat are stocks, can add other satisfactory material on the basis of these stocks.
Unsaturated-resin gel coat or the unsaturated-resin glue of making back-up coat are used for glass fabric and simulation layer are bonded together, and glass fabric can improve the intensity of simulation layer, and it can lay one deck, also which floor can be laid.The curing agent of manufacturing back-up coat is identical with the effect of the curing agent of making simulation layer and promoter with the effect of promoter.
The curing agent that the present invention makes in the raw material of back-up coat adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter.
The present invention makes raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent and the promoter of back-up coat and mixes according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter
1 0.01～0.05 0.02～0.08
The raw material of manufacturing back-up coat of the present invention are except that containing unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and glass fabric, and can also contain fineness is the above stone flours of 20 orders.Stone flour bonds together by unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter and glass fabric and simulation layer.
After unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone flour mix, before solidifying, rapidly it is brushed on the inner surface of simulation layer, and rapidly glass fabric is layered on the inner surface of simulation layer.After the mixture of unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone flour solidifies, stone flour be bonded on the glass fabric and the inner surface of simulation layer on, glass fabric is bonded on the inner surface of simulation layer together with stone flour, thereby forms back-up coat.
Adopt the packing material of an amount of stone flour, can reduce manufacturing cost of the present invention as back-up coat.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone flour that the present invention makes back-up coat mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone flour
1 0.01～0.05 0.02～0.08 0.5～1.5
One of scheme of matrix of the present invention is that the raw material of making matrix contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone or stone flour.
Unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone or stone flour were cast to it in inner chamber of back-up coat rapidly before solidifying after mixing.The mixture solidification forming of unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone or stone flour, thus matrix formed.
It is stock that the present invention makes the raw material unsaturated-resin gel coat of matrix or unsaturated-resin glue, curing agent, promoter and stone or stone flour, can add other satisfactory raw material on these raw-material bases.
The size of the particle diameter of the stone of manufacturing matrix is generally unrestricted.The unsaturated-resin gel coat of manufacturing matrix or the effect of unsaturated-resin glue, curing agent and promoter are identical with the effect of the unsaturated-resin gel coat of making simulation layer or unsaturated-resin glue, curing agent and promoter.
Stone, stone grain and stone flour alleged among the present invention are to divide from the size of particle diameter, and the particle diameter of stone is bigger, and the particle diameter of stone flour is less, and the stone grain is between stone and stone flour, and the three does not have strict boundary.One of raw material " stone or stone flour " of making matrix among the present invention are meant can adopting of from the stone to the stone flour various particle diameters, comprise stone grain and sand.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone or stone flour that the present invention makes matrix mix according to following weight ratio: unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone or stone flour
1 0.01～0.05 0.02～0.08 2～5
Two of the scheme of matrix of the present invention is, the raw material of making matrix contain magnesia, magnesium chloride and stone or stone flour, and magnesium chloride is 20～30 Baume degrees.
Magnesia, magnesium chloride and stone or stone flour were cast to it in inner chamber of back-up coat rapidly before solidifying after mixing.The mixture solidification forming of magnesia, magnesium chloride and stone or stone flour, thus matrix formed.
Raw material magnesia, magnesium chloride and stone or stone flour that the present invention makes matrix are stocks, can add other satisfactory raw material on these raw-material bases.
The implication of " stone or stone flour " in the implication of here " stone or stone flour " and one of scheme of making matrix is identical.Magnesia, magnesium chloride and stone or stone flour mix the back and form magnesia cement.
Raw material magnesia, magnesium chloride and stone or stone flour that the present invention makes matrix mix according to following weight ratio:
Magnesia magnesium chloride stone or stone flour
40～50 40～50 50～100
The present invention makes the raw material of matrix except that containing magnesia, magnesium chloride and stone or stone flour, can also contain talcum powder and hydrochloric acid.
Talcum powder is a kind of additive, and it can reduce manufacturing cost of the present invention.Hydrochloric acid is used to regulate the acid-base value of matrix.
Raw material magnesia, magnesium chloride, stone or stone flour, talcum powder and hydrochloric acid that the present invention makes matrix mix according to following weight ratio:
Magnesia magnesium chloride stone or stone flour talcum powder hydrochloric acid
40～50 40～50 50～100 2～5 1～5 wherein: the concentration of hydrochloric acid is 20～36 Baume degrees.
Three of the scheme of matrix of the present invention is that the raw material of making matrix contain white cement, stone and water.
White cement, stone and water were cast to it in inner chamber of back-up coat rapidly before solidifying after mixing.The mixture solidification forming of white cement, stone and water, thus matrix formed.
Raw material white cement, stone and water that the present invention makes matrix are stocks, can add other satisfactory raw material on these raw-material bases.
Raw material white cement, stone and water that the present invention makes matrix mix according to following weight ratio:
White cement stone water
50 10～40 20～40
The raw material of making matrix can also contain gluewater in use for construction and pigment except that containing white cement, stone and water.
Gluewater in use for construction can adopt 107 glue, resin glue etc., and it can improve the intensity of matrix.Pigment is used to regulate the color of matrix.
Raw material white cement, stone, water, gluewater in use for construction and pigment that the present invention makes matrix mix according to following weight ratio:
White cement stone water gluewater in use for construction pigment
50 10～40 20～40 1～3 is an amount of
Pigment can add as one feels fit according to concrete needs.
Two of purpose of the present invention is achieved in that a kind of manufacture method of above-mentioned Scagliola, and its special character is to operate by following step:
1. unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05 0.02～0.08 0.5～1.5
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, these raw material that mix solidify the back and form simulation layer;
3. matched moulds;
4. the raw material with matrix mix;
5. before the raw material that step mixes in 4. solidify, be cast to rapidly in the inner chamber of the back-up coat in the model, make these raw material be full of the inner chamber of back-up coat with these raw material that mix, and closely knit in the inner chamber of back-up coat, even;
6. after making the 5. middle raw material solidification forming of casting of step, form matrix;
7. the product that is shaped is taken out in die sinking.
The shape of model should be according to the shape manufacturing of the Scagliola of specific requirement, guarantees the shape of the Scagliola product produced with the shape of model.Unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and the stone grain of step in 1. is basic raw material, can add other satisfactory raw material on the basis of these basic raw materials.The curing agent of step in 1. adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter, and it is the following natural or artificial stone grains of 20 orders that the stone grain adopts fineness.The raw material of making matrix can adopt different prescriptions, and are as long as raw material can be cast in the model after mixing within a certain period of time, can very fast solidification forming after the casting just passable.In addition, behind the raw material solidification forming of matrix, have enough intensity, the inner chamber of back-up coat is played filling effect.
Between simulation layer and matrix, increase the manufacture method of the Scagliola of back-up coat, can operate according to following step:
1. unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05 0.02～0.08 0.5～1.5
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, these raw material that mix solidify the back and form simulation layer;
3. with unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter according to following weight
Than mixing:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter
1 0.01～0.05 0.02～0.08
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer that 2. forms in step rapidly with these raw material that mix, after these raw material that mix solidify, glass fabric is bonded on the inner surface of simulation layer and forms back-up coat;
5. matched moulds;
6. the raw material with matrix mix;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly in the inner chamber of the back-up coat in the model, make these raw material be full of the inner chamber of back-up coat with these raw material that mix, and closely knit in the inner chamber of back-up coat, even;
8. behind the raw material solidification forming of step in 7., form matrix;
9. the product that is shaped is taken out in die sinking.
The shape of model should be according to the shape manufacturing of the Scagliola of specific requirement, guarantees the shape of the Scagliola product produced with the shape of model.Unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and the stone grain of step in 1. is the basic raw material of making simulation layer, can add other satisfactory raw material on the basis of these basic raw materials.The curing agent of step in 1. adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter, and it is the following natural or artificial stone grains of 20 orders that the stone grain adopts fineness.Step 3. and the unsaturated-resin gel coat 4. or unsaturated-resin glue, curing agent, promoter and glass fabric be the basic raw material of making back-up coat, on the basis of these basic raw materials, can add other satisfactory raw material.The raw material of making matrix can adopt different prescriptions, and are as long as raw material can be cast in the model after mixing within a certain period of time, can very fast solidification forming after the casting just passable.In addition, behind the raw material solidification forming of matrix, have enough intensity, the inner chamber of back-up coat is played filling effect.
In the method for above-mentioned manufacturing Scagliola of the present invention, one of raw-material prescription of matrix is to contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone or stone flour; Unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone or stone flour are mixed according to following weight ratio: unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone or stone flour
1 0.01～0.05 0.02～0.08 0.5～1.5
In the method for above-mentioned manufacturing Scagliola of the present invention, two of the raw-material prescription of matrix is, contains magnesia, magnesium chloride and stone, and magnesium chloride is 20～30 Baume degrees; Magnesia, magnesium chloride and stone are mixed according to following weight ratio:
Magnesia magnesium chloride stone
40～50 40～50 50～100
In the method for above-mentioned manufacturing Scagliola of the present invention, three of the raw-material prescription of matrix is to contain white cement, stone and water; White cement, stone and water are mixed according to following weight ratio:
White cement stone water
50 10～40 20～40
Scagliola of the present invention has good marmorean texture, and its surface can access as required than natural marble abundant colors more.It surperficial firm, acid and alkali-resistance, anti-aging, its life-span can reach 50 years under the service condition in the open.Because the present invention adopts cheap raw material manufacturing, and manufacturing process is simple, so manufacturing cost is lower.Compare with similar natural marble goods, manufacturing cost of the present invention has only 20% of natural marble goods.Adopt the present invention can save a large amount of lithotomes, avoid the exhaustive exploitation of lithotome, help protecting environment.
The present invention makes the method for Scagliola and can produce in batches Scagliola, helps realizing mechanization, reduces the manufacturing cost of Scagliola.The present invention can produce various difform Scagliolas according to concrete needs owing to adopt model to guarantee the profile of Scagliola.The method that the present invention makes Scagliola improves effect more than 200 times than hand engraving natural marble, and greatly reduces operator's labour intensity.
Embodiments of the present invention is described in detail below in conjunction with accompanying drawing.
Fig. 1 is the outline drawing of embodiments of the invention 1.
Fig. 2 is the profile of embodiments of the invention 1.
Fig. 3 is the outline drawing of embodiments of the invention 2.
Fig. 4 is the A-A view among Fig. 3.
Fig. 5 is the outline drawing of embodiments of the invention 3.
Fig. 6 is the cutaway view of embodiments of the invention 3.
Embodiment 1:
As depicted in figs. 1 and 2, present embodiment is a kind of Scagliola ornamental blocks, and it has simulation layer 1, back-up coat 2 and matrix 3.On the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.The raw material of making simulation layer 1 adopt unsaturated-resin gel coat, curing agent, promoter and stone grain.It is the natural or artificial stone grains of 5～20 purposes that the stone grain adopts fineness.Unsaturated-resin gel coat, curing agent, promoter and stone grain mix according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain
1 0.02 0.03 1
After above-mentioned raw material mix, solidify very soon, the stone grain is bonded in together, thereby forms simulation layer 1.The raw material of making back-up coat 2 adopt unsaturated-resin glue, curing agent, promoter and glass fabric.Glass fabric adopts 0.1～0.4 purpose glass fabric.Unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
Inner surface with glass fabric and simulation layer 1 after the mixture of 1 0.02 0.03 unsaturated-resin glue, curing agent and promoter solidifies bonds together.The raw material of making matrix 3 adopt unsaturated-resin glue, curing agent, promoter and stone.Unsaturated-resin glue, curing agent, promoter, stone mix according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone
The mixture of 1 0.03 0.04 3 unsaturated-resin glue, curing agent, promoter and stone solidifies the back and forms matrix 3, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
Curing agent in the raw material of above-mentioned manufacturing simulation layer 1, back-up coat 2 and matrix 3 adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter,
This Scagliola ornamental blocks is to adopt model to make, be ready to model after, concrete manufacture method is operated according to following step:
1. unsaturated-resin gel coat, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain
1 0.02 0.03 1
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, brush 2～3 times after treating to solidify a little again, these raw material that mix solidify the back and form simulation layer 1;
3. unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
1 0.02 0.03
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer 1 that 2. forms in step rapidly with these raw material that mix, brush is spread 2～3 layers of glass fabric altogether, after these raw material that mix solidify, glass fabric is bonded in forms back-up coat 2 on the inner surface of simulation layer;
5. matched moulds;
6. unsaturated-resin glue, curing agent, promoter, stone are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone
1 0.03 0.04 3 these mixtures stir with mixer;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly with these raw material that mix in the inner chamber of the back-up coat 2 in the model, make these raw material be full of the inner chamber of back-up coat 2 through vibration, and closely knit in the inner chamber of back-up coat 2, even;
8. behind the raw material solidification forming of step in 7., form matrix 3;
9. the product that is shaped is taken out in die sinking.
Embodiment 2:
As shown in Figure 3 and Figure 4, present embodiment is the Scagliola decorative railing, and it has simulation layer 1, back-up coat 2 and matrix 3.On the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.The raw material of making simulation layer 1 adopt unsaturated-resin gel coat, curing agent, promoter, stone grain, mica powder and mill base, and it is the natural or artificial stone grains of 5～20 purposes that the stone grain adopts fineness, and the fineness of mica powder is below 20 orders.Unsaturated-resin gel coat, curing agent, promoter, stone grain, mica powder and mill base mix according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain mica powder mill base
1 0.02 0.03 1 0.1 is an amount of
Mill base adds as one feels fit according to concrete needs.After above-mentioned raw material mix, solidify very soon, stone grain and mica powder are bonded in together, thereby form simulation layer 1.The raw material of making back-up coat 2 adopt unsaturated-resin glue, curing agent, promoter, stone flour and glass fabric.The fineness of stone flour is more than 20 orders, and glass fabric adopts 0.1～0.4 purpose glass fabric.Unsaturated-resin glue, curing agent, promoter and stone flour mix according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone flour
1 0.02 0.03 1
Inner surface with glass fabric and simulation layer 1 after the mixture of unsaturated-resin glue, curing agent, promoter and stone flour solidifies bonds together.The raw material of making matrix 3 adopt magnesia, magnesium chloride and stone, and magnesium chloride is 20～30 Baume degrees.Magnesia, magnesium chloride and stone mix according to following weight ratio:
Magnesia magnesium chloride stone
45 50 60
The raw material of making matrix 3 can also adopt magnesia, magnesium chloride, stone, talcum powder and hydrochloric acid, and magnesium chloride is 26 Baume degrees, and hydrochloric acid is 36 Baume degrees.Magnesia, magnesium chloride, stone, talcum powder and hydrochloric acid mix according to following weight ratio:
Magnesia magnesium chloride stone talcum powder hydrochloric acid
45 50 60 2 1
Raw-material two kinds of mixtures of above-mentioned manufacturing matrix 3 solidify the back and form matrix 3, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
Curing agent in the raw material of above-mentioned manufacturing simulation layer 1 and back-up coat 2 adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter,
This Scagliola decorative railing is to adopt model to make, be ready to model after, concrete manufacture method is operated according to following step:
1. unsaturated-resin gel coat, curing agent, promoter, stone grain, mica powder and mill base are mixed according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain mica powder mill base
1 0.02 0.03 1 0.1 an amount of mill bases add as one feels fit according to concrete needs.
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, brush 2～3 times after treating to solidify a little again, these raw material that mix solidify the back and form simulation layer 1;
3. unsaturated-resin glue, curing agent, promoter and stone flour are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone flour
1 0.02 0.03 1
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer 1 that 2. forms in step rapidly with these raw material that mix, brush is spread 2～3 layers of glass fabric altogether, after these raw material that mix solidify, glass fabric is bonded in forms back-up coat 2 on the inner surface of simulation layer;
5. matched moulds;
6. magnesia, magnesium chloride and stone are mixed according to following weight ratio:
Magnesia magnesium chloride stone
45 50 60 magnesium chlorides are 20～30 Baume degrees.This mixture stirs with mixer;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly with these raw material that mix in the inner chamber of the back-up coat 2 in the model, make these raw material be full of the inner chamber of back-up coat 2 through vibration, and closely knit in the inner chamber of back-up coat 2, even;
8. behind the raw material solidification forming of step in 7., form matrix 3;
9. the product that is shaped is taken out in die sinking.
Embodiment 3:
As shown in Figure 5 and Figure 6, present embodiment is a kind of Scagliola door lion, and it has simulation layer 1, back-up coat 2 and matrix 3.On the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.The raw-material component that present embodiment is made simulation layer 1 and manufacturing back-up coat 2 and proportioning are identical with embodiment's 1.The raw material of making matrix 3 adopt white cement, stone and water.White cement, stone and water mix according to following weight ratio:
White cement stone water
50 30 30
The raw material of making matrix 3 can also adopt white cement, stone, water, gluewater in use for construction and pigment.White cement, stone, water, gluewater in use for construction and pigment mix according to following weight ratio:
White cement stone water gluewater in use for construction pigment
50 30 30 1.5 an amount of pigment can add as one feels fit according to concrete needs.
Raw-material two kinds of mixtures of above-mentioned manufacturing matrix 3 solidify the back and form matrix 3, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
This Scagliola door lion is to adopt model to make, be ready to model after, concrete manufacture method is operated according to following step:
1. unsaturated-resin gel coat, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain
1 0.02 0.03 1
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, brush 2～3 times after treating to solidify a little again, these raw material that mix solidify the back and form simulation layer 1;
3. unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
1 0.02 0.03
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer 1 that 2. forms in step rapidly with these raw material that mix, brush is spread 2～3 layers of glass fabric altogether, after these raw material that mix solidify, glass fabric is bonded in forms back-up coat 2 on the inner surface of simulation layer;
5. matched moulds:
6. white cement, stone and water are mixed according to following weight ratio:
White cement stone water
50 30 30 these mixtures stir with mixer;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly with these raw material that mix in the inner chamber of the back-up coat 2 in the model, make these raw material be full of the inner chamber of back-up coat 2 through vibration, and closely knit in the inner chamber of back-up coat 2, even;
8. behind the raw material solidification forming of step in 7., form matrix 3;
9. the product that is shaped is taken out in die sinking.
Claims (28)
1. Scagliola comprises matrix, it is characterized in that, is attached with simulation layer on the surface of matrix; The raw material of making simulation layer contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain.
2. Scagliola according to claim 1 is characterized in that, curing agent adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter, and it is the following natural or artificial stone grains of 20 orders that the stone grain adopts fineness.
3. Scagliola according to claim 2 is characterized in that, the fineness of stone grain is 5～20 orders.
4. Scagliola according to claim 1 is characterized in that, unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05?0.02～0.08?0.5～1.5
5. Scagliola according to claim 1 is characterized in that, the raw material of making simulation layer also contain mica powder and mill base.
6. Scagliola according to claim 5 is characterized in that, the fineness of mica powder is below 1000 orders.
7. Scagliola according to claim 6 is characterized in that, unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone grain, mica powder and mill base mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain mica powder mill base
1 0.01～0.05 0.02～0.08 0.5～1.5 0.1～0.5 is an amount of
8. Scagliola according to claim 1 is characterized in that, has back-up coat between simulation layer and the matrix, on the inner surface of the outer surface of back-up coat attached to simulation layer, on the inner surface of the outer surface of matrix attached to back-up coat.
9. Scagliola according to claim 8 is characterized in that, the raw material of making back-up coat contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and glass fabric; Glass fabric bonds together by the inner surface of unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter and simulation layer.
10. Scagliola according to claim 9 is characterized in that, curing agent adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter.
11. Scagliola according to claim 9 is characterized in that, unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter
1 0.01～0.05 0.02～0.08
12. Scagliola according to claim 9, it is characterized in that, it is the above stone flours of 20 orders that the raw material of making back-up coat also contain fineness, and it bonds together by unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter and glass fabric and simulation layer.
13. Scagliola according to claim 12 is characterized in that, unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone flour mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone flour
1 0.01～0.05?0.02～0.08 0.5～1.5
14. according to claim 1,2,3,4,5,6,7,8,9,10,11,12 or 13 described Scagliolas, it is characterized in that the raw material of making matrix contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone or stone flour.
15. Scagliola according to claim 14, it is characterized in that unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone or stone flour mix according to following weight ratio: unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone or stone flour
1 0.01～0.05?0.02～0.08 2～5
16., it is characterized in that the raw material of making matrix contain magnesia, magnesium chloride and stone or stone flour according to claim 1,2,3,4,5,6,7,8,9,10,11,12 or 13 described Scagliolas, magnesium chloride is 20～30 Baume degrees.
17. Scagliola according to claim 16 is characterized in that, magnesia, magnesium chloride and stone or stone flour mix according to following weight ratio:
Magnesia magnesium chloride stone or stone flour
40～50 40～50 50～100
18. Scagliola according to claim 16 is characterized in that, the raw material of making matrix also contain talcum powder and hydrochloric acid.
19. Scagliola according to claim 18 is characterized in that, magnesia, magnesium chloride, stone or stone flour, talcum powder and hydrochloric acid mix according to following weight ratio:
Magnesia magnesium chloride stone or stone flour talcum powder hydrochloric acid
40～50 40～50 50～100 2～5 1～5 wherein: the concentration of hydrochloric acid is 20～36 Baume degrees.
20., it is characterized in that the raw material of making matrix contain white cement, stone and water according to claim 1,2,3,4,5,6,7,8,9,10,11,12 or 13 described Scagliolas.
21. Scagliola according to claim 20 is characterized in that, white cement, stone and water mix according to following weight ratio:
White cement stone water
50 10～40 20～40
22. Scagliola according to claim 20 is characterized in that, the raw material of making matrix also contain gluewater in use for construction and pigment.
23. Scagliola according to claim 22 is characterized in that, white cement, stone, water, gluewater in use for construction and pigment mix according to following weight ratio:
White cement stone water gluewater in use for construction pigment
50 10～40 20～40 1～3 is an amount of
24. make the method for the described Scagliola of claim 1, it is characterized in that, operate by following step:
1. unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05 0.02～0.08 0.5～1.5
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, these raw material that mix solidify the back and form simulation layer;
3. matched moulds;
4. the raw material with matrix mix;
5. before the raw material that step mixes in 4. solidify, be cast to rapidly in the inner chamber of the back-up coat in the model, make these raw material be full of the inner chamber of back-up coat with these raw material that mix, and closely knit in the inner chamber of back-up coat, even;
6. after making the 5. middle raw material solidification forming of casting of step, form matrix;
7. the product that is shaped is taken out in die sinking.
25. make the method for the described Scagliola of claim 8, it is characterized in that, operate by following step:
1. unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05 0.02～0.08 0.5～1.5
Wherein: curing agent adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter, and it is the following natural or artificial stone grains of 20 orders that the stone grain adopts fineness;
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, these raw material that mix solidify the back and form simulation layer;
3. unsaturated-resin gel coat or unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter
1 0.01～0.05 0.02～0.08
Wherein: curing agent adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter;
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer that 2. forms in step rapidly with these raw material that mix, after these raw material that mix solidify, glass fabric is bonded on the inner surface of simulation layer and forms back-up coat;
5. matched moulds;
6. the raw material with matrix mix;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly in the inner chamber of the back-up coat in the model, make these raw material be full of the inner chamber of back-up coat with these raw material that mix, and closely knit in the inner chamber of back-up coat, even;
8. after making the 7. middle raw material solidification forming of casting of step, form matrix;
9. the product that is shaped is taken out in die sinking.
26. the manufacture method of Scagliola according to claim 25 is characterized in that, the raw material of the matrix of step in 6. contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone or stone flour; Unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone or stone flour are mixed according to following weight ratio: unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone or stone flour
1 0.01～0.05 0.02～0.08?0.5～1.5
27. the manufacture method of Scagliola according to claim 25 is characterized in that, the raw material of the matrix of step in 6. contain magnesia, magnesium chloride and stone, and magnesium chloride is 20～30 Baume degrees; Magnesia, magnesium chloride and stone are mixed according to following weight ratio:
Magnesia magnesium chloride stone
40～50 40～50 50～100
28. the manufacture method of Scagliola according to claim 25 is characterized in that, the raw material of the matrix of step in 6. contain white cement, stone and water; White cement, stone and water are mixed according to following weight ratio:
White cement stone water
50 10～40 20～40
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00134990 CN1357462A (en) | 2000-12-14 | 2000-12-14 | Scagliola |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00134990 CN1357462A (en) | 2000-12-14 | 2000-12-14 | Scagliola |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1357462A true CN1357462A (en) | 2002-07-10 |
Family
ID=4596511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00134990 Pending CN1357462A (en) | 2000-12-14 | 2000-12-14 | Scagliola |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1357462A (en) |
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|---|---|---|---|---|
| CN1301199C (en) * | 2003-12-31 | 2007-02-21 | 杨德宁 | Coloured resin three dimensional pattern artificial stone slab material |
| CN101830139A (en) * | 2010-06-12 | 2010-09-15 | 刘锋 | Manufacturing method of puffing paint decorative surface |
| CN102276967A (en) * | 2010-06-08 | 2011-12-14 | 深圳奔迅汽车玻璃有限公司 | Formula of die casting material |
| CN104957879A (en) * | 2015-05-29 | 2015-10-07 | 泉州市嘉利来石材工艺有限公司 | Manufacturing process of stone-like light outdoor furniture desktop and material for stone-like light outdoor furniture desktop |
| CN104961382A (en) * | 2015-01-10 | 2015-10-07 | 谢秋鸿 | Production process for novel artificial stone |
| CN105218965A (en) * | 2014-08-04 | 2016-01-06 | 陕西金泰氯碱化工有限公司 | Resin/building stones particle manually imitates preparation method and resin/building stones particle manually imitative stone of stone |
| CN106220039A (en) * | 2016-07-08 | 2016-12-14 | 哈尔滨展大科技有限责任公司 | A kind of light body, the preparation method of insulation artificial stone |
| CN107056136A (en) * | 2017-04-28 | 2017-08-18 | 重庆卓林塑料制品有限公司 | A kind of Dali spar making method |
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| CN108058407A (en) * | 2017-11-29 | 2018-05-22 | 武威霖沐科技发展有限公司 | A kind of processing method for emulating Art Stone |
| CN108503274A (en) * | 2018-03-21 | 2018-09-07 | 广州市楚汉园林雕塑有限公司 | Imitative stone carving modeling |
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2000
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301199C (en) * | 2003-12-31 | 2007-02-21 | 杨德宁 | Coloured resin three dimensional pattern artificial stone slab material |
| CN102276967A (en) * | 2010-06-08 | 2011-12-14 | 深圳奔迅汽车玻璃有限公司 | Formula of die casting material |
| CN102276967B (en) * | 2010-06-08 | 2014-03-05 | 深圳奔迅汽车玻璃有限公司 | Formula of die casting material |
| CN101830139A (en) * | 2010-06-12 | 2010-09-15 | 刘锋 | Manufacturing method of puffing paint decorative surface |
| CN105218965A (en) * | 2014-08-04 | 2016-01-06 | 陕西金泰氯碱化工有限公司 | Resin/building stones particle manually imitates preparation method and resin/building stones particle manually imitative stone of stone |
| CN104961382A (en) * | 2015-01-10 | 2015-10-07 | 谢秋鸿 | Production process for novel artificial stone |
| CN104957879A (en) * | 2015-05-29 | 2015-10-07 | 泉州市嘉利来石材工艺有限公司 | Manufacturing process of stone-like light outdoor furniture desktop and material for stone-like light outdoor furniture desktop |
| CN106220039A (en) * | 2016-07-08 | 2016-12-14 | 哈尔滨展大科技有限责任公司 | A kind of light body, the preparation method of insulation artificial stone |
| CN107056136A (en) * | 2017-04-28 | 2017-08-18 | 重庆卓林塑料制品有限公司 | A kind of Dali spar making method |
| CN107056136B (en) * | 2017-04-28 | 2019-08-02 | 重庆卓林塑料制品有限公司 | A kind of Dali spar making method |
| CN107382147A (en) * | 2017-08-18 | 2017-11-24 | 漳平市美利达装饰材料有限公司 | A kind of imitative ceramic tile high molecular density construction material |
| CN108058407A (en) * | 2017-11-29 | 2018-05-22 | 武威霖沐科技发展有限公司 | A kind of processing method for emulating Art Stone |
| CN108503274A (en) * | 2018-03-21 | 2018-09-07 | 广州市楚汉园林雕塑有限公司 | Imitative stone carving modeling |
| CN108503274B (en) * | 2018-03-21 | 2021-03-26 | 广州市楚汉园林雕塑有限公司 | Stone-imitating sculpture |
| CN110304861A (en) * | 2019-07-18 | 2019-10-08 | 佛山市高明金石建材有限公司 | A kind of quartz of high compactness and preparation method thereof |
| CN110304861B (en) * | 2019-07-18 | 2021-09-21 | 佛山市高明金石建材有限公司 | High-compactness quartz stone and preparation method thereof |
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