CN1084120A - Artificial grantie decoration plate and manufacture method thereof - Google Patents
Artificial grantie decoration plate and manufacture method thereof Download PDFInfo
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- CN1084120A CN1084120A CN 93111877 CN93111877A CN1084120A CN 1084120 A CN1084120 A CN 1084120A CN 93111877 CN93111877 CN 93111877 CN 93111877 A CN93111877 A CN 93111877A CN 1084120 A CN1084120 A CN 1084120A
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Abstract
The present invention relates to a kind of artificial grantie decoration plate and manufacture method thereof, with the cullet is that primary raw material is processed into the composite construction board that contains superficial layer, intermediate layer and bottom through pulverizing, base, roasting, grinding, polishing etc., superficial layer is a compacted zone, make by cullet, quartz filler and useless stained glass, the intermediate layer is a time compacted zone, add quartz filler by cullet and make, bottom is that porous layer is that the main body filling contains SiO with the cullet
2Slag or sand, add an amount of blowing agent and make.
Description
The present invention relates to a kind of artificial grantie decoration plate of cullet manufacturing and manufacture method of artificial grantie decoration plate of adopting.
The natural granite decorative panel has good ornamental and resistance to weathering, is a kind of good construction material, but costs an arm and a leg that resource is also limited.The decoration of building indoor and outdoor adopts ceramic tile, mosaic, natural marble more at present, artificial marble and stonite, and the chemical analysis of natural marble mainly is CaCO
3Therefore, not acid and alkali-resistance, easy loss of gloss, eclipsed.Artificial marble and person's granite are divided into two classes substantially, one is made the bonding agent and the painted bed of material (adding organic or inorganic dyestuff) with white cement or refractory cement, bottom is that bonding agent adds marble, sandstone or granite waste material and makes the inserts laminated pouring with the Portland cement, a vibration moulding, the maintenance demoulding forms, the very easily variable color of this product, loss of gloss, not acid and alkali-resistance; It two is organic stonite or artificial marble, adds filler (Dali stone or granite etc.) with unsaturated-resin and carries out manually syntheticly, and this product hardness is low, easy warpage, and easy loss of gloss, variable color, easily aging.This two class stonite's chemical analysis, physical and chemical index are all poor than natural granite.That China CN87104465A discloses the is a kind of " artificial grantie decoration plate of firing with cullet; though some physical and chemical index of decorative panel and natural granite decorative panel is close; because prescription and binding agent are limit; the color decorative pattern is not naturally; no third dimension; glossiness is low, the superficial layer decorative pattern is similar to terrazzo.
The object of the present invention is to provide a kind of artificial grantie decoration plate of cullet manufacturing and manufacture method of artificial grantie decoration plate of adopting.
The present invention relates to a kind of structure and manufacture method of artificial grantie decoration plate.
1. the artificial grantie structure of decorating
Artificial grantie decoration plate of the present invention is for containing superficial layer, the three-layer composite structure plate of intermediate layer and bottom, surface bed thickness 3～6mm is compacted zone, is made by cullet, quartz filler and useless stained glass, has granitic light and character, hard, acid and alkali-resistance, weathering resistance, figure colour is elegant in appearance, will never change colour, loss of gloss not.Its chemical composition, physical and chemical index are identical with natural granite; Middle bed thickness 5～8mm adds quartz filler by useless variegated glass and makes, and is inferior compacted zone, and the contact-making surface of it and superficial layer has the darker thickness that interpenetrates, and can either protect superficial layer to make it can not burst, chap, and increases its rupture strength again; Thick 4～the 8mm of bottom is porous layer, is that the main body filling contains SiO with useless variegated glass
2Slag or sand, add an amount of blowing agent and make.Bottom can absorb water, and is good with the adhesive property of cement mortar, thereby improves the adhesive strength of decorative panel and cement mortar.
The apparent size of decorative panel meets the size of national regulation, and the thickness of decorative panel is 12～22mm, also can determine according to user's needs.
2. the processing of artificial grantie decoration plate
1) raw material processing
To give up white glass (glass sheet, bottle glass etc.) and various useless variegated glass cleaning, sorting, be divided into desired particle size through ultra-fine winnowing machine grinding screen;
2) batching
The batching of superficial layer, intermediate layer and bottom is as follows respectively:
The batching of superficial layer is:
The white glass 8～25% 0.5～2mm gives up
180～120 orders white glass powder 40～70% that gives up
80～20 orders stained glass powder 8～20% that gives up
150～100 orders stained glass powder 8～15% that gives up
150～100 order silica flours 1～1.5%
Waterglass 0.5～3%
(the raw material gross weight) 8～10% of purifying waste water
The batching in intermediate layer is:
150～100 orders variegated glass dust 10～15% that gives up
80～20 orders variegated glass dust 30～45% that gives up
The variegated glass 35～45% 0.5～2mm gives up
150～100 order silica flours 2～4%
Waterglass 1.5～3%
(the raw material gross weight) 8～10% of purifying waste water
The batching of bottom is:
150～100 orders variegated glass dust 10～20% that gives up
80～20 orders variegated glass dust 35～42% that gives up
The variegated glass 35～40% 0.5～2mm gives up
Contain SiO
2Slag or sand 2～5%
Blowing agent 0.1～0.5%
(the raw material gross weight) 8～10% of purifying waste water
The useless stained glass powder of 80～20 purposes adds inorganic dyestuff by the useless white glass powder of 80～20 purposes and mixes, the useless stained glass powder of 150～100 purposes adds inorganic dyestuff by the useless white glass powder of 150～100 purposes and is mixed and made into, described inorganic dyestuff is a chromic sulfide, selenium sulfide etc.Described blowing agent is an active carbon.
Allot three kinds of different compounds by the charge ratio of superficial layer, intermediate layer and bottom, send in the mixer respectively again and stir;
3) compression moulding
Three kinds of accurate meterings of compound are poured in the punching block by different level, adopt hydraulic press compression moulding, form the interpenetrative composite plate in three bed boundarys base just, the demoulding is placed on the high-al clay pallet;
4) low-temperature sintering:
Pallet is sent in the tunnel cave, heat to 30 ℃～685 ℃ and toast, and constant temperature five times, be warming up to 685 ℃～730 ℃ roastings again, and constant temperature three times, make filler, additive and inorganic dyestuff and cullet generation materialization variation and curing reaction, annealing when being cooled to 450 ℃～550 ℃ at the uniform velocity is cooled to 30 ℃ then to form the granite slab blank;
5) surface treatment
With grinder the blank superficial layer is carried out the level Four corase grind, six grades of fine grindings again with the polishing machine polishing, make its glossiness greater than 90 degree, cut in accordance with regulations with cutting machine.
Technological reaction principle of the present invention: be when making glass dust and particle near fusion temperature with additive, catalyst, flux, begin to take place chemical reaction and organizator shape atomic structure, thereby make the product of producing both have the character of glass, the characteristics that have the natural granite plate again, the intensity height, antiacid alkali, will never change colour, loss of gloss never.
Effect of the present invention:
The artificial grantie decoration plate that utilizes manufacture method of the present invention to produce, its chemical analysis, physical and chemical index are identical with the natural granite decorative panel, and outward appearance is also similar to the natural granite decorative panel, and glossiness reaches more than 90 degree, color decorative pattern nature, third dimension is strong, has overcome the shortcoming of existing stonite's plate, and quality can match in excellence or beauty with the natural granite decorative panel, cost is less than the sixth of natural granite decorative panel, have good decoration practicality, it is convenient to implement, the success rate height.
The technical indicator of the artificial grantie decoration plate that manufacture method of the present invention is produced is as follows:
Compression strength: greater than 100MPa
Rupture strength: greater than 10MPa
Surface microhardness: greater than 3750MPa
Glossiness is greater than 90 degree
Water absorption rate (superficial layer) is less than 0.1%
Antiacid, alkalescence energy: sulfuric acid, hydrochloric acid, the sodium hydroxide solution with 1 molar concentration soaked not burn into nondiscolouring, not loss of gloss 35 days respectively.
The physical and chemical performance index comparison of the present invention and natural granite, marble slabs can see Table 1.
The structural representation of Fig. 1 artificial grantie decoration plate.
The manufacturing flow chart of Fig. 2 artificial grantie decoration plate.
By following embodiment can the invention will be further described.
Embodiment one:
Present embodiment has been described the structure and the manufacture method of artificial grantie decoration plate.
1. the structure of artificial grantie decoration plate
Artificial grantie decoration plate is for containing superficial layer 1, the three-layer composite structure plate of intermediate layer 2 and bottom 3, superficial layer 1 thick 4mm, be compacted zone, by cullet, quartz filler and useless stained glass are made, and have granitic light and character, hard, acid and alkali-resistance, weathering resistance, figure colour is elegant in appearance, will never change colour, loss of gloss never; Intermediate layer 2 thick 8mm; adding quartz filler by useless variegated glass makes; be inferior compacted zone; the contact-making surface of it and superficial layer 1 has the darker thickness that interpenetrates; can either protect superficial layer to make it can not burst, chap; increasing its rupture strength, bottom 3 thick 8mm again, be porous layer, is that the main body filling contains SiO with useless variegated glass
2Slag or sand, add an amount of blowing agent and make, bottom can absorb water, and is good with the adhesive property of cement mortar, thereby improves the adhesive strength of decorative panel and cement mortar.
2. the processing of artificial grantie decoration plate
1) raw material processing
To give up white glass (glass sheet, bottle glass etc.) and various useless variegated glass is rinsed well, presses color classification, becomes desired particle size through ultra-fine winnowing machine crushing and screening respectively,
2. prepare burden
By carrying out batching in batches, the batching of its superficial layer, intermediate layer and bottom is as follows respectively:
The 2mm white glass 20% that gives up
The 120 orders white glass powder 60% that gives up
The 20 orders stained glass powder 8% that gives up
The 100 orders stained glass powder 8% that gives up
100 order silica flours 1.5%
Waterglass 2.5%
(for the raw material gross weight) 10% of purifying waste water
The batching in intermediate layer is:
The 120 orders variegated glass dust 13% that gives up
The 20 orders variegated glass dust 40% that gives up
The 2mm variegated glass 40% that gives up
100 order silica flours 4%
Waterglass 3%
(the raw material gross weight) 10% of purifying waste water
The batching of bottom is:
The 120 orders variegated glass dust 20% that gives up
The 20 orders variegated glass dust 35% that gives up
The 2mm variegated glass 37% that gives up
Contain SiO
2Slag or sand 5%
Waterglass 2.5%
Blowing agent 0.5%
(the raw material gross weight) 10% of purifying waste water
The useless stained glass powder of 20 purposes adds inorganic dyestuff by the useless white glass powder of 20 orders and mixes, and the useless stained glass powder of 100 purposes adds inorganic dyestuff by the useless white glass powder of 100 orders and mixes, and described inorganic dyestuff is a chromic sulfide.Described blowing agent is an active carbon.
Allot three kinds of different compounds by the charge ratio of superficial layer, intermediate layer and bottom, send into respectively in the common mixer, it is stand-by to stir,
3) compression moulding
At the bottom of the superficial layer material that stirs accurately is distributed on punching block after the metering, the intermediate layer that to accurately measure respectively and bottom material layering are inferior thereon uniform again, use hydraulic press compression moulding, form the interpenetrative composite plate in three bed boundarys base just, with vacuum cup blank is moved on the high-al clay pallet, make superficial layer downward;
4) low-temperature sintering:
Pallet is sent in the tunnel cave, heat to 30 ℃～685 ℃ and toast, and constant temperature five times, be warming up to 685 ℃～730 ℃ roastings again, and constant temperature three times, make filler, additive and inorganic dyestuff and cullet generation materialization variation and curing reaction, annealing at the uniform velocity is cooled to 30 ℃ then when being cooled to 450 ℃～550 ℃, to form the granite slab blank.
5) surface treatment
With grinder the blank superficial layer is carried out level Four corase grind, six grades of correct grindings,, make its glossiness, cut by specification with cutting machine greater than 90 degree again with the polishing machine polishing.
Embodiment two
Embodiment two is identical with structure and the manufacture method of embodiment one, and different is the thickness of superficial layer, intermediate layer and bottom and prepares burden different.Surface bed thickness 3mm, middle bed thickness 6mm, the thick 6mm of bottom.
The batching of superficial layer, intermediate layer and bottom is as follows respectively:
The batching of superficial layer is:
0.5mm useless white glass 21%
The 180 orders white glass powder 40% that gives up
The 80 orders stained glass powder 20% that gives up
The 150 orders stained glass powder 15% that gives up
150 order silica flours 1%
Waterglass 3%
(the raw material gross weight) 8% of purifying waste water
The batching in intermediate layer is:
The 150 orders variegated glass dust 15% that gives up
The 80 orders variegated glass dust 45% that gives up
0.5mm useless variegated glass 35%
150 order silica flours 3%
(the raw material gross weight) 8% of purifying waste water
The batching of bottom is
The 150 orders variegated glass dust 11% that gives up
The 80 orders variegated glass dust 42% that gives up
0.5mm useless variegated glass 40%
Contain SiO
2Slag or sand 4%
Waterglass 2.8%
Blowing agent 0.2%
(the raw material gross weight) 8% of purifying waste water
Embodiment three
Embodiment three is identical with structure and the manufacture method of embodiment one, and different is the thickness of superficial layer, intermediate layer and bottom and prepares burden different.Surface bed thickness 6mm, middle bed thickness 5mm, the thick 4mm of bottom.
The batching of superficial layer, intermediate layer and bottom is as follows respectively:
The batching of superficial layer is:
The 1mm white glass 8% that gives up
The 150 orders white glass powder 70% that gives up
The 60 orders stained glass powder 8% that gives up
The 120 orders stained glass powder 12% that gives up
120 order silica flours 1%
(the raw material gross weight) 9% of purifying waste water
The batching in intermediate layer is:
The 100 orders variegated glass dust 10% that gives up
The 60 orders variegated glass dust 40% that gives up
The 1mm variegated glass 45% that gives up
120 order silica flours 2%
Waterglass 3%
(the raw material gross weight) 9% of purifying waste water
The batching of bottom is
The 100 orders variegated glass dust 18% that gives up
The 60 orders variegated glass dust 40% that gives up
The 1mm variegated glass 36% that gives up
Contain SiO
2Slag or sand 3%
Waterglass 2.7%
Blowing agent 0.3%
(the raw material gross weight) 9% of purifying waste water
Table 1: artificial grantie decoration plate and natural granite, marble slabs
Physical and chemical performance index comparison sheet
Claims (5)
1, a kind of artificial grantie decoration plate, with the cullet is that primary raw material is through processing such as pulverizing, base, roasting, grinding, polishings, make the composite construction board that contains superficial layer, intermediate layer and bottom, the invention is characterized in that superficial layer is a compacted zone, make by cullet, quartz filler and useless stained glass, the intermediate layer is a time compacted zone, adds quartz filler by cullet and makes, and bottom is that porous layer is that the main body filling contains SiO with the cullet
2Slag or sand, add an amount of blowing agent and make.
2, artificial grantie decoration plate according to claim 1 is characterized in that described surperficial bed thickness 3～6mm, middle bed thickness 5～8mm, the thick 4～8mm of bottom.
3, artificial grantie decoration plate according to claim 1 and 2 is characterized in that the batching of described superficial layer, intermediate layer and bottom is as follows:
The batching of superficial layer is:
The white glass 8～25% 0.5～2mm gives up
180～120 orders white glass powder 40～70% that gives up
80～20 orders stained glass powder 8～20% that gives up
150～100 orders stained glass powder 8～15% that gives up
150～100 order silica flours 1～1.5%
Waterglass 0.5～3%
(the raw material gross weight) 8～10% of purifying waste water
The batching in intermediate layer is:
150～100 orders variegated glass dust 10～15% that gives up
80～20 orders variegated glass dust 30～45% that gives up
The variegated glass 35～45% 0.5～2mm gives up
150～100 order silica flours 2～4%
Waterglass 1.5～3%
(the raw material gross weight) 8～10% of purifying waste water
The batching of bottom is:
150～100 orders variegated glass dust 10～20% that gives up
80～20 orders variegated glass dust 35～42% that gives up
The variegated glass 35～40% 0.5～2mm gives up
Contain SiO
2Slag or sand 2～5%
Waterglass 1～3%
Blowing agent 0.1～0.5%
(the raw material gross weight) 8～10% of purifying waste water
4, artificial grantie decoration plate according to claim 3, it is characterized in that the useless stained glass powder of described 80～20 purposes adds inorganic dyestuff by the useless white glass powder of 80～20 orders and mixes, the useless stained glass powder of 150～100 purposes adds inorganic dyestuff by the useless white glass powder of 150～100 purposes and mixes.
5, the manufacture method of artificial grantie decoration plate according to claim 1 is characterized in that described step of manufacturing is as follows:
1) raw material processing
To give up white glass (glass sheet, bottle glass etc.) and various useless variegated glass cleaning, sorting, be divided into desired particle size through ultra-fine winnowing machine grinding screen;
2) batching
Allot three kinds of different compounds by the charge ratio of superficial layer, intermediate layer and bottom, send into respectively again to stir in the mixer and tremble evenly;
3) compression moulding
Three kinds of compounds are accurately measured, pour into by different level in the punching block, adopt hydraulic press compression moulding, form the interpenetrative composite construction board in three bed boundarys base just, the demoulding is placed on the high-al clay pallet,
4) end temperature sintering
Pallet is sent in the tunnel cave, heat to 30 ℃～685 ℃ and toast, and constant temperature five times, be warming up to 685 ℃～730 ℃ roastings again, and constant temperature three times, make filler, additive and inorganic dyestuff and cullet generation materialization variation and curing reaction, annealing when being cooled to 450 ℃～550 ℃ at the uniform velocity is cooled to 30 ℃ to form the granite slab blank after the combustion;
5) surface treatment
With grinder the blank superficial layer is carried out the level Four corase grind, six grades of fine grindings again with the polishing machine polishing, make its glossiness greater than 90 degree, cut by specification with cutting machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93111877 CN1084120A (en) | 1993-06-29 | 1993-06-29 | Artificial grantie decoration plate and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93111877 CN1084120A (en) | 1993-06-29 | 1993-06-29 | Artificial grantie decoration plate and manufacture method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1084120A true CN1084120A (en) | 1994-03-23 |
Family
ID=4989630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93111877 Pending CN1084120A (en) | 1993-06-29 | 1993-06-29 | Artificial grantie decoration plate and manufacture method thereof |
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| Country | Link |
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| CN (1) | CN1084120A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0688740A2 (en) * | 1994-05-10 | 1995-12-27 | Schott Glaswerke | Method for the production of sheets for building and decoration which resemble natural stone |
| WO2013163807A1 (en) * | 2012-05-03 | 2013-11-07 | Kao Chin Fa | Construction method for wall surface with glazed layer, wall surface structure and brick structure |
| CN103643771A (en) * | 2013-12-27 | 2014-03-19 | 吕国兵 | Ceramic thermal-insulation decorative plate and manufacturing method thereof |
| CN107804993A (en) * | 2017-10-31 | 2018-03-16 | 佛山市欧泊石业有限公司 | A kind of novel artificial quartzite plate and preparation method thereof |
| CN109928740A (en) * | 2019-04-15 | 2019-06-25 | 蒙娜丽莎集团股份有限公司 | A kind of heat-insulation integral Ceramic Tiles and preparation method thereof |
-
1993
- 1993-06-29 CN CN 93111877 patent/CN1084120A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0688740A2 (en) * | 1994-05-10 | 1995-12-27 | Schott Glaswerke | Method for the production of sheets for building and decoration which resemble natural stone |
| EP0688740A3 (en) * | 1994-05-10 | 1996-05-08 | Schott Glaswerke | Method for the production of sheets for building and decoration which resemble natural stone |
| WO2013163807A1 (en) * | 2012-05-03 | 2013-11-07 | Kao Chin Fa | Construction method for wall surface with glazed layer, wall surface structure and brick structure |
| CN103643771A (en) * | 2013-12-27 | 2014-03-19 | 吕国兵 | Ceramic thermal-insulation decorative plate and manufacturing method thereof |
| CN107804993A (en) * | 2017-10-31 | 2018-03-16 | 佛山市欧泊石业有限公司 | A kind of novel artificial quartzite plate and preparation method thereof |
| CN109928740A (en) * | 2019-04-15 | 2019-06-25 | 蒙娜丽莎集团股份有限公司 | A kind of heat-insulation integral Ceramic Tiles and preparation method thereof |
| CN109928740B (en) * | 2019-04-15 | 2024-05-17 | 蒙娜丽莎集团股份有限公司 | Heat-preservation and heat-insulation integrated ceramic tile and preparation method thereof |
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