CN1931779A - Color light wall tile and its making process - Google Patents
Color light wall tile and its making process Download PDFInfo
- Publication number
- CN1931779A CN1931779A CNA2006101136911A CN200610113691A CN1931779A CN 1931779 A CN1931779 A CN 1931779A CN A2006101136911 A CNA2006101136911 A CN A2006101136911A CN 200610113691 A CN200610113691 A CN 200610113691A CN 1931779 A CN1931779 A CN 1931779A
- Authority
- CN
- China
- Prior art keywords
- color light
- wall tile
- light wall
- waste
- base substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 25
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 19
- 239000011707 mineral Substances 0.000 claims abstract description 19
- 239000011521 glass Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002893 slag Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000003086 colorant Substances 0.000 claims abstract description 3
- 238000000227 grinding Methods 0.000 claims abstract description 3
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 3
- 239000000758 substrate Substances 0.000 claims description 32
- 239000002699 waste material Substances 0.000 claims description 25
- 238000001816 cooling Methods 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 20
- 235000010755 mineral Nutrition 0.000 claims description 18
- 238000010304 firing Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000010433 feldspar Substances 0.000 claims description 11
- 238000009837 dry grinding Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000007858 starting material Substances 0.000 claims description 8
- 239000005357 flat glass Substances 0.000 claims description 7
- -1 shale Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- 230000009970 fire resistant effect Effects 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 239000002956 ash Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000001095 magnesium carbonate Substances 0.000 claims description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 5
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 5
- 229960001708 magnesium carbonate Drugs 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 4
- 239000010451 perlite Substances 0.000 claims description 4
- 235000019362 perlite Nutrition 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 239000010455 vermiculite Substances 0.000 claims description 4
- 229910052902 vermiculite Inorganic materials 0.000 claims description 4
- 235000019354 vermiculite Nutrition 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 3
- 235000011132 calcium sulphate Nutrition 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 13
- 239000004927 clay Substances 0.000 description 8
- 230000006835 compression Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 8
- 239000005995 Aluminium silicate Substances 0.000 description 7
- 235000012211 aluminium silicate Nutrition 0.000 description 7
- 238000010276 construction Methods 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- 238000005034 decoration Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 208000002925 dental caries Diseases 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 230000009347 mechanical transmission Effects 0.000 description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 235000012736 patent blue V Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Finishing Walls (AREA)
Abstract
The present invention is color light wall tile and its making process, and belongs to the field of functional wall decorating material. The color light wall tile is made with the material including glass material 10-95 weight portions, mineral material and slag 30-65 weight portions, inorganic adhesive 2-6 weight portions, carbonate and sulfate as foaming agent 0.2-10 weight portions, inorganic pigment 0.5-6.5 weight portions, and water 5-10 weight portions, and through drying material, grinding, mixing, molding and baking. The color light wall tile has rich colors, high safety and excellent heat insulating performance, and is adhered to wall with adhesive.
Description
Technical field
A kind of chromatic light wall tile and manufacture method belong to the decorative material for wall surface field, are specifically related to a kind of novel wall surface and decorate color light wall tile and the manufacture method of using incubation and thermal insulation function.
Background technology
At present, ceramic tile, mosaic, stone decoration board are adopted in wall decoration usually, because they are than great, low with the cohesive strength of body of wall, one of potential safety hazard that becomes in buildings comes off.If adopt the coatings decoration metope, though color is gorgeous, its weather resisteant is poor, just takes place later on obviously to fade in 2 years.Ceramic tile, mosaic, stone decoration board, these products of coating do not have good function of heat insulation, are unfavorable for building energy-saving.Therefore, need that exploitation is a kind of to possess decoration, energy-conservation, safety and the incorporate functional metope finishing material of weather resistance.
Summary of the invention
The present invention is directed to the weak point of current material, provide a kind of appearance color abundant, good weather resisteant, better security and well the new type colorful light wall tile of thermal and insulating performance, this kind wall tile can directly be bonded on the metope by matrix material.
This kind wall tile inside is vesicular structure, is that frit, raw mineral materials and waste residue are mixed in proportion, and adding carbonate, vitriol are made whipping agent, mineral dye is made tinting material, with mineral binder bond bonding, pressing machine compression moulding, heating is fired into the porous color light wall tile.
A kind of color light wall tile of the present invention, it is characterized in that, comprise following component: 10～95 parts of frits in parts by weight, ratio is 30～65 parts in 1～6.5: 1 raw mineral materials and a waste residue, 2～6 parts of mineral binder bonds, 0.2～10 part of carbonate, vitriol whipping agent, 0.5～6.5 part of inorganic pigment coloring agent, 5～10 parts in water.
Described frit is various discarded glass, comprises waste bottles and cans glass, waste and old sheet glass, waste and old ware glass, waste and old laboratory glass wares.
Described raw mineral materials is a kind of or several arbitrarily in volcanic ash, quartz, feldspar, shale, talcum, triphane, vermiculite mine tailing, the perlite tailing.
Described waste residue is that a kind of in slag, the slag or two kinds are all used.
Described carbonate, vitriol whipping agent are a kind of or several arbitrarily in lime carbonate, magnesiumcarbonate, rhombspar, yellow soda ash, Strontium carbonate powder, sodium sulfate, calcium sulfate, the barium sulfate.
Described mineral binder bond is one or both in clay, the kaolin.
Described mineral dye is any one or a few pigment in various resistant to elevated temperatures ceramic pigments, the enamel dye.
The effect of various raw materials is: color light wall tile sintering linking agent is mainly played in the effect of frit, the foaming agent gas lapping, raw materials such as slag, slag, volcanic ash, quartz, feldspar, shale, talcum, triphane, vermiculite mine tailing, perlite tailing act as the propping material of color light wall tile agglomerated material, reduce the body shrinkage strain in the color light wall tile sintering process, strengthen structural strength.It is in sintering process that whipping agent mainly acts on, and produces carbonic acid gas, sulfur dioxide gas, makes the inner air hole structure that produces of color light wall tile, makes color light wall tile inside become loose, makes color light wall tile play function of heat insulation.Clay, kaolin effect are to make in the color light wall tile compression moulding process, play low temperature bonding agent effect.The mineral dye effect is to make the color light wall tile products appearance present shades of colour.The water effect is wetting various raw material and binding agent, realizes powder plastic forming in the pressing process.
The invention provides a kind of manufacture method of color light wall tile, it is characterized in that, may further comprise the steps:
1) with above-mentioned various raw material drying;
2) dried starting material are carried out dry grinding, obtaining granularity is that 40～400 orders grind fine powder;
The grinding fine powder that 3) will obtain is puddled in mixing equipment, adds entry in puddling process, obtains compound;
4) compound is moved in the mould, use the pressing machine of 10～10000kN to be pressed into the demoulding behind the base substrate;
5) base substrate after the demoulding is placed on the fire-resistant supporting plate that is covered with separant, putting into process furnace then fires, the firing temperature system is: by 5～15 ℃/min heat-up rate, goods are heated to 700～1100 ℃, are incubated 10～40 minutes, by 10～20 ℃/min cooling rate, be cooled to 540 ℃～580 ℃, by 1～5 ℃/min cooling rate to 360 ℃～400 ℃, according to 3～10 ℃/min cooling, obtain the finished product color light wall tile then then.
The wall tile that burns till is a kind of air hole structure agglomerated material that has, it has chromatic decorative effect, has high-strength light, preferable fire resistance, the characteristics of lower water-intake rate, its product decoration surface can be made into has flush type and three-dimensional convex-concave effect Art Stone profile, and the size deviation of profile is ± 3mm all around, and product can independently use and cut use.The color light wall tile characteristics are that apparent density is little, generally at 350～1050kg/m
3, resistance to compression, folding strength are at 1.2～3.65Mpa, and water-intake rate is generally at 1～5vol%, and thermal conductivity is between 0.096～0.238W/mk.And the apparent density of ceramic tile, mosaic, stone material is at 2100～2800kg/m
3, their resistance to compression, folding strength are at 1.6～6.5Mpa, and water-intake rate is generally at 0.5～15vol%, and thermal conductivity is between 0.356～0.536W/mk.Color light wall tile is a kind of pure inorganic materials, has good fire resistance, and the product thickness scope is 6～24mm, and the heat-insulating capability of this product is equivalent to the thick construction wall of 80～150mm; And have excellent chemical stability, good weathering resistance.Its coefficient of expansion is 6.5～7.8 * 10 in addition
-6The coefficient of expansion 6.0～8.4 * 10 of/K and wall covering
-6/ K ten minutes is approaching, can ensure itself and construction wall thermostability, can be because of wind and weather, and freeze-thaw cycle, wall tile and materials for wall quality inspection cracking, perhaps the weathering off phenomenon takes place, and makes it have security.
Embodiment
Embodiment 1
The color light wall tile prescription is, in parts by weight:
Waste bottles and cans glass 10
Slag 4
Slag 6
Volcanic ash 10
Quartzy 20
Feldspar 20
Shale 3
Talcum 2
Lime carbonate 2
Rhombspar 2.5
Sodium sulfate 1.0
Kaolin 6
Coffee-like mineral dye 3.5
Water 6
Various starting material are carried out drying, and weighing is to scale put into horizontal ball mill and is carried out dry grinding, finally reaches grind size 40 orders.Dry powder joined in the concrete mixer mix, mixing time guaranteed the compound homogeneity at 10 minutes, divided 3 addings by the spray mode with corresponding umber water in machine operation procedure.Adopt friction type press as forming machine, the combined steel tool is of a size of (L*B*H) 100*50*16mm, have 12 die cavitys on the mould,, moisture admixtion is filled up die cavity by autofeed, the unnecessary admixtion in mould top is wipeed off along the mould top with straight plate, adopt 10kN pressure compacting admixtion, admixtion forms dense green, and base substrate thickness is 4mm, by mechanical stripping, shift out base substrate.By mechanical transmission, base substrate to be sent into process furnace heat, process furnace is a pushed bat kiln.
The firing process process is: base substrate should be placed on the fireclay brick supporting plate that is covered with separant, and release agent material is a silica powder, and thickness is smeared at 1mm in separant shop, can ensure in the blank sintering process the glutinous company to supporting plate.
The temperature schedule of firing the color light wall tile base substrate is: by 5 ℃/min heat-up rate, goods are heated to 1100 ℃, be incubated 40 minutes, by 10 ℃/min cooling rate, lower the temperature 540 ℃, then by 1 ℃/min cooling rate to 360 ℃, according to 3 ℃/min cooling, the color light wall tile product surface of coming out of the stove has coffee color then, and profile is concordant substantially all around, the thickness uniformity, upper and lower surface is smooth, and external wall construction uses in being beneficial to, and a large amount of bubbles are contained in goods inside, products thickness is 6mm, apparent density 1050kg/m
3, resistance to compression and folding strength are respectively 3.65Mpa, 2.87Mpa, and water-intake rate is generally at 1.0vol%, and thermal conductivity is at 0.238W/mk.
Embodiment 2
Color light wall tile prescription is as follows, in parts by weight:
Waste bottles and cans glass 35
Waste and old sheet glass 30
Waste and old ware glass 30
Slag 5
Slag 10
Feldspar 15
Magnesiumcarbonate 5
Barium sulfate 3
Calcium sulfate 2
Clay 2
Mineral dye grey 0.5
Water 5
Various starting material are carried out drying, and weighing to scale beyond dewatering is put into horizontal ball mill and is carried out dry grinding, finally reaches grind size 400 orders.Dry powder joined in the V-type agitator mix, mixing time added water for 1 time by the spray mode at 30 minutes.Adopt hydraulic press as forming machine; the steel die size of product is (L*B*H) 200*80*20mm, has 4 die cavitys on the mould, can autofeed or hand-fed; with adding the diffusing admixtion of yew die cavity is filled up; the unnecessary admixtion in mould top is wipeed off along the mould top with straight plate, adopted 10000kN pressure, the compacting admixtion; admixtion forms dense green; base substrate thickness only has 4mm, by mechanical stripping or hand ejection, shifts out base substrate.By mechanical transmission or manual handling, base substrate is sent into process furnace heats, process furnace be pushed bat kiln, metal mesh belt stove, continuous tunnel furnace, roller kiln any one.
The firing process process is as follows:
Color light wall tile is the cutting prod of exempting from by blank sintering, base substrate should be placed on the silicon carbide and the fire-resistant supporting plate of clay matter that is covered with separant, release agent material can any one or a few mixing of Feldspar Powder, thickness is smeared at 5mm in separant shop, can ensure in the blank sintering process the glutinous company to supporting plate.
The temperature schedule of firing the color light wall tile base substrate is: by 15 ℃/min heat-up rate, goods are heated to 700 ℃, be incubated 10 minutes, by 20 ℃/min cooling rate, be cooled to 580 ℃, then by 5 ℃/min cooling rate to 400 ℃, lower the temperature according to 10 ℃/min then, the product of coming out of the stove is a grey, and appearance profile is straight around the goods, and upper surface is three-dimensional convex-concave effect, the convex-concave difference of altitude is at 2～5mm, goods mean thickness 9mm, lower surface have groove shape structure, groove depth 1～3mm, when helping the wall construction use, strengthen goods and metope adhesion strength, a large amount of bubbles, apparent density 350kg/m are contained in goods inside
3, resistance to compression and folding strength are at 1.45Mpa, 1.20Mpa, and water-intake rate is generally at 5.0vol%, and thermal conductivity is at 0.096W/mk.
Embodiment 3
Color light wall tile prescription is as follows, in parts by weight:
Waste and old laboratory glass wares 55
Waste and old sheet glass 15
Slag 10
Perlite tailing oil 5
Feldspar 20
Triphane 30
Magnesiumcarbonate 10
Clay 2
Kaolin 4
Mineral dye khaki color 5
Water 6
Various starting material are carried out drying, and dewater in addition umber weighing in accordance with regulations and batching are put into horizontal ball mill and are carried out dry grinding, finally reach grind size 240 orders.Dry powder joined in the spiral stirrer mix, mixing time added water for 4 times by the spray mode at 20 minutes.Adopt hydraulic press as forming machine, the steel die size of product is (L*B*H) 160*80*18mm, have 8 die cavitys on the mould, can autofeed, with adding the yew admixtion that looses die cavity is filled up, with the unnecessary admixtion in mould top with straight plate along the strickling of mould top, adopt 100kN pressure compacting admixtion, base substrate thickness is 16mm, by mechanical stripping, shifts out base substrate.By mechanical transmission base substrate is sent into process furnace and heat, process furnace is a continuous tunnel furnace.Firing process cross for: base substrate is placed on the cordierite refractory supporting plate of separant, release agent material is a talcum powder, thickness is smeared at 2mm in the shop, the temperature schedule of firing base substrate is: by 10 ℃/min heat-up rate, goods are heated to 800 ℃, are incubated 30 minutes, by 15 ℃/min cooling rate, lower the temperature 580 ℃, by 4 ℃/min cooling rate to 400 ℃, according to 5 ℃/min cooling, the product surface of coming out of the stove has khaki color Art Stone effect then then, goods mean thickness 24mm, profile is concordant substantially all around, and lower surface has groove, helps wall construction and uses, a large amount of bubbles, apparent density 746kg/m are contained in goods inside
3, resistance to compression and folding strength are at 2.13Mpa, 1.79Mpa, and water-intake rate is generally at 3.4vol%, and thermal conductivity is between 0.136W/mk.
Embodiment 4
Color light wall tile prescription is as follows, in parts by weight:
Waste and old sheet glass 50
Waste and old ware glass 15
Slag 10
Feldspar 40
Vermiculite mine tailing 15
Magnesiumcarbonate 3
Lime carbonate 2
Kaolin 2
Clay 2
Mineral dye sky blue 5
Water 5.5
Various starting material are carried out drying, and weighing to scale beyond dewatering is put into horizontal ball mill and is carried out dry grinding, finally reaches grind size 200.The dry powder raw material joined in the concrete mixer mix, mixing time added water for 4 times by the spray mode at 15 minutes.Adopt hydraulic press as forming machine, the steel die size of product is (L*B*H) 160*80*16mm, have 10 die cavitys on the mould, can autofeed, admixtion is filled up die cavity, the unnecessary admixtion in mould top is wipeed off along the mould top with straight plate, adopt 800kN pressure compacting admixtion, the base substrate thickness that forms only has 10mm, shifts out base substrate by mechanical stripping.By mechanical transmission, base substrate to be sent into process furnace heat, process furnace is roller kiln.The firing process process is: base substrate is placed on the fire-resistant supporting plate of the silicon carbide that is covered with separant, and release agent material was mixed kaolin and Feldspar Powder with 3: 2, and thickness is smeared at 3mm in the separant shop.The temperature schedule of firing base substrate is: by 8 ℃/min heat-up rate, goods are heated to 780 ℃, are incubated 25 minutes, by 15 ℃/min cooling rate, be cooled to 550 ℃, then by 4 ℃/min cooling rate to 380 ℃, lower the temperature according to 6 ℃/min then, the product of coming out of the stove is sky blue for the surface, and products thickness is 15mm, and profile is concordant substantially all around, the thickness uniformity, upper and lower surface is smooth, and a large amount of bubbles, apparent density 903kg/m are contained in goods inside
3, resistance to compression, folding strength are at 3.12Mpa, 2.35Mpa, and water-intake rate is generally at 1.6vol%, and thermal conductivity is at 0.206W/mk.
Embodiment 5
Color light wall tile prescription, in parts by weight:
Waste and old sheet glass 45
Waste and old ware glass 5
Waste and old laboratory glass wares 25
Volcanic ash 10
Quartzy 15
Triphane 25
Talcum 2
Yellow soda ash 0.2
Clay 5
Mineral dye emerald green 6.5
Water 8
Various starting material are carried out drying, and weighing to scale beyond dewatering is put into horizontal ball mill and is carried out dry grinding, finally reaches grind size 120 orders.The dry powder raw material joined in the spiral stirrer mix, mixing time is at 25 minutes, by the spray mode corresponding umber water added for 1 time in machine operation procedure.
Adopt hydraulic press as forming machine, combined steel tool specification is (L*B*H) 1200*60*16mm, have 12 product die cavitys on the mould, admixtion fills up die cavity, the unnecessary admixtion in mould top is wipeed off along the mould top with straight plate, adopt 600kN pressure compacting admixtion, base substrate thickness is 8mm, and base substrate is shifted out in mechanical stripping.Manual handling is sent base substrate into process furnace and is heated, process furnace adopts the metal mesh belt stove, the firing process process is: base substrate should be placed on the fire-resistant supporting plate of the silicon carbide that is covered with separant, release agent material is a talcum powder, thickness is smeared at 5mm in the separant shop, and the firing temperature system is: by 15 ℃/min heat-up rate, goods are heated to 960 ℃, be incubated 10 minutes, by 20 ℃/min cooling rate, be cooled to 570 ℃, then by 5 ℃/min cooling rate to 370 ℃, lower the temperature according to 10 ℃/min then, the product of coming out of the stove has emerald green Art Stone effect, and the goods mean thickness is 11mm, and profile is concordant substantially all around, upper surface is a convex-concave Art Stone effect, the lower surface fluting, external wall construction uses in helping, and increases the metope adhesion strength, a large amount of bubbles, apparent density 657kg/m are contained in goods inside
3, resistance to compression, folding strength are at 2.41Mpa, 1.98Mpa, and water-intake rate is generally at 3.2vol%, and thermal conductivity is at 0.156W/mk.
Embodiment 6
Color light wall tile prescription, in parts by weight:
Waste and old sheet glass 55
Triphane 45
Feldspar 18
Talcum 2
Strontium carbonate powder 5
Clay 5
Mineral dye reddish-brown 3.5
Water 10
Various starting material are carried out drying, and weighing to scale beyond dewatering is put into and is carried out dry grinding in the airflow milling, finally reaches grind size 320 orders.The dry powder raw material joined in the spiral stirrer mix, mixing time is at 25 minutes, by the spray mode corresponding umber water added for 1 time in machine operation procedure.Adopt hydraulic press as forming machine, adopt 8 die cavity, size of product is (L*B*H) 100*50*16mm, hand-fed, admixtion fills up die cavity, and the unnecessary admixtion in mould top is wipeed off along the mould top with straight plate, adopt 1000kN pressure compacting admixtion, base substrate thickness is 7mm, by hand ejection, shifts out base substrate.Manual handling is sent base substrate into process furnace and is heated, process furnace adopts the metal mesh belt stove, the firing process process is: base substrate should be placed on the fire-resistant supporting plate of the silicon carbide that is covered with separant, release agent material is in 2: 1: 3: ratio cooperated silica powder in 2: 1, Feldspar Powder, kaolin, shale powder, talcum powder forms and mixes separant, thickness is smeared at 5mm in the separant shop, the firing temperature system is: by 15 ℃/min heat-up rate, goods are heated to 890 ℃, be incubated 10 minutes, by 20 ℃/min cooling rate, be cooled to 560 ℃, by 5 ℃/min cooling rate to 380 ℃, according to 10 ℃/min cooling, the color light wall tile product surface of coming out of the stove has reddish-brown Art Stone effect then then, the goods mean thickness is 10mm, profile is concordant substantially all around, and upper surface has scraggly stereoeffect, and lower surface has groove shape structure, help wall construction and use, can effectively increase adhesion strength with metope.Goods apparent density 486kg/m
3, resistance to compression, folding strength are respectively 1.69Mpa, 1.15Mpa water-intake rate generally at 4.2vol%, and thermal conductivity is at 0.132W/mk.
Claims (6)
1. color light wall tile, it is characterized in that, comprise following component: 10～95 parts of frits in parts by weight, ratio is 30～65 parts in 1～6.5: 1 raw mineral materials and a waste residue, 2～6 parts of mineral binder bonds, 0.2～10 part of carbonate, vitriol whipping agent, 0.5～6.5 part of inorganic pigment coloring agent, 5～10 parts in water.
2. a kind of color light wall tile according to claim 1 is characterized in that described frit is various discarded glass, comprises waste bottles and cans glass, waste and old sheet glass, waste and old ware glass, waste and old laboratory glass wares are a kind of or several arbitrarily.
3. a kind of color light wall tile according to claim 1 is characterized in that, described raw mineral materials is a kind of or several arbitrarily in volcanic ash, quartz, feldspar, shale, talcum, triphane, vermiculite mine tailing, the perlite tailing.
4. a kind of color light wall tile according to claim 1 is characterized in that, described waste residue is that a kind of in slag, the slag or two kinds are all used.
5. a kind of color light wall tile according to claim 1, it is characterized in that described carbonate, vitriol whipping agent are a kind of or several arbitrarily in lime carbonate, magnesiumcarbonate, rhombspar, Strontium carbonate powder, yellow soda ash, sodium sulfate, calcium sulfate, the barium sulfate.
6. the manufacture method of a color light wall tile is characterized in that, may further comprise the steps:
1) with above-mentioned various raw material drying;
2) dried starting material are carried out dry grinding, obtaining granularity is that 40～400 orders grind fine powder;
The grinding fine powder that 3) will obtain is puddled in mixing equipment, adds entry in puddling process, obtains compound;
4) compound is moved in the mould, use the pressing machine of 10～10000kN to be pressed into the demoulding behind the base substrate;
5) base substrate after the demoulding is placed on the fire-resistant supporting plate that is covered with separant, putting into process furnace then fires, the firing temperature system is: by 5～15 ℃/min heat-up rate, goods are heated to 7001100 ℃, are incubated 10～40 minutes, by 10～20 ℃/min cooling rate, be cooled to 540 ℃～580 ℃, by 1～5 ℃/min cooling rate to 360 ℃～400 ℃, according to 3～10 ℃/min cooling, obtain the finished product color light wall tile then then.
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| CNB2006101136911A CN100497237C (en) | 2006-10-13 | 2006-10-13 | Color light wall tile and its making process |
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| CNB2006101136911A CN100497237C (en) | 2006-10-13 | 2006-10-13 | Color light wall tile and its making process |
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| CN1931779A true CN1931779A (en) | 2007-03-21 |
| CN100497237C CN100497237C (en) | 2009-06-10 |
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