CN102424528B - Preparation method of colored glass wall brick or glass tile - Google Patents
Preparation method of colored glass wall brick or glass tile Download PDFInfo
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- CN102424528B CN102424528B CN2011102563411A CN201110256341A CN102424528B CN 102424528 B CN102424528 B CN 102424528B CN 2011102563411 A CN2011102563411 A CN 2011102563411A CN 201110256341 A CN201110256341 A CN 201110256341A CN 102424528 B CN102424528 B CN 102424528B
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Abstract
The invention relates to a preparation method of colored glass wall bricks or glass tiles, comprising the following steps: (1) preparing raw materials, wherein, the raw materials comprise 74-90 wt% of waste glass, 4-6 wt% of flousper powder, 4-15 wt% of feldspar powder, and 2-6 wt% of soda ash; (2) mixing the ingredients in the step (1), then adding a coloring agent in an amount of 0.1-0.4 wt% based on the total weight of the raw materials, and sintering the mixture into a glass liquid at a temperature of 1050-1100 DEG C; (3) putting the glass liquid obtained in the step (2) in a die for pressing into shape; and (4) annealing the pressed product at a temperature of 400-600 DEG C, and cooling. The preparation method has the advantages of simple process, low cost, and low energy consumption, and the prepared product has abundant color and wide application.
Description
Technical field
The invention belongs to building material technical field, be specifically related to the preparation method of a kind of stained glass wall body brick or glass tile.
Background technology
Traditional production glass floor tile, the batching of face brick are mainly with high silicon content (SiO
2Weight ratio is nearly more than 90%) silica sand be main raw material, but because the silica sand composition is single, can not meet and fire the in use physicochemical property and the index that reach of needs of product,, so will add the various additives that improve product performance, so just increase raw materials cost.In recent years, there is report to prepare the method for glass floor tile, face brick as raw material take useless silicates grogs such as cullet, waste ceramics, Chinese patent application 92109877.4 (publication number 1083796A for example, open day on March 16th, 1994) disclose a kind of take cullet as main raw material, adopt the preparation method who makes colour glass stone brick with the novel process of hydration material, but adopt the method to make to such an extent that product mainly is used as the glass facing tile that pastes wall, can't be used as the glass wall brick, thereby its intensity and suitability still can not be satisfactory, also has in addition the higher problem of raw materials cost.
Summary of the invention
For the defect that exists in prior art, the purpose of this invention is to provide the preparation method of a kind of stained glass wall body brick or glass tile, the glassy product that adopts the method to make, ultimate compression strength is high, and suitability is strong, and the plate glass that makes can be used as wall body brick.
For reaching above purpose, the technical solution used in the present invention is: the preparation method of a kind of stained glass wall body brick or glass tile, it is characterized in that, and comprise the following steps:
(1) prepare to comprise the raw material of cullet, Fluorspar Powder, Feldspar Powder and soda ash, in raw material, the weight percent of each component is:
(2) cullet in step (1) is cleaned up, then each component is mixed, adding consumption is the tinting material of raw material gross weight 0.1-0.4% again, and it is to be fired into glass metal in the cell furnace of 1050-1100 ℃ that the gained compound is directly sent into temperature;
(3) glass metal in step (2) is sent into mould compression moulding, obtain the product of compression moulding;
(4) with the product of compression moulding at 400-600 ℃ of temperature annealing 5-10 minute after, naturally cooling, obtain the finished product.
Further, in step (1), in raw material, the weight percent of each component is:
Further, in step (1), in raw material, the weight percent of each component is:
Further, in step (2), described tinting material is the oxide compound of chromium, copper, manganese, nickel or cobalt.
Further, it is characterized in that, in step (1), the granular size of described Fluorspar Powder and described Feldspar Powder is the 150-300 order.
Further, it is characterized in that, in step (3), the product of described compression moulding is hollow or solid.
The coloured glass tile that provides in the present invention or watt the preparation method in, in raw material, the effect of each component is as follows: in raw material, cullet mainly plays the effect of skeleton; Fluorspar Powder is a kind of important ore of producing colored glass, because the main component of Fluorspar Powder is CaF
2, F wherein can play milky white effect, thereby obtains the uniform glass of milkiness, can also play the effect of hydrotropy simultaneously; Feldspar Powder contains makes the required framework material silicon of glassy product, aluminium etc.; Soda ash is solubility promoter, its role is to improve glass melting speed, lowers the glass melt temperature.The present invention also adds a certain amount of tinting material, its role is to make plate glass or watt presents shades of colour.
Preparation method of the present invention, mainly take cullet as main, adopts ore as much as possible, thus can also add other ore in formula of the present invention, as rhombspar, calcite, feldspar etc.
The present invention compared with prior art has the following advantages:
(1) the present invention takes full advantage of cullet and ore, and the stone raw material that uses can namely carry out raw material without any processing and mix, and technique is simple, and cost is low, and environmental protection is easy to realize the serialization suitability for industrialized production.
(2) preparation method provided by the invention, firing temperature is low, and energy consumption is low.
(3) glassy product that adopts method of the present invention to make, ultimate compression strength is high, and acid and alkali-resistance is difficult for agingly, and rich color, the plate glass that for example makes not only can be used as wall body brick, floor tile, can also be used as the ornamental face brick that is affixed on body of wall, are widely used.
Embodiment
The invention will be further described below in conjunction with embodiment.
Raw material in following examples and reagent all can be buied from market.For the stability of the composition that guarantees ore, preferably, the Fluorspar Powder or the Feldspar Powder that use same mineral reserve to produce.
Embodiment 1
The clean cullet of 800 kilograms of raw materials, the Fluorspar Powder of 50 kilograms, the Feldspar Powder of 120 kilograms and the soda ash of 30 kilograms are mixed, then add the CuO of 2 kilograms; The gained compound is sent in the cell furnace of working continuously, be fired into glass metal at the temperature of 1050-1100 ℃; The gained glass metal is sent into the hollow brick that is pressed into required specification in the cast iron drum die; With conveying belt, the hollow brick of compression moulding is sent in the tunnel annealing furnace, after annealing at the temperature of 400-600 ℃, naturally cooling, obtain the finished product.
Embodiment 2
The clean cullet of 950 kilograms of raw materials, the Fluorspar Powder of 80 kilograms, the Feldspar Powder of 60 kilograms and the soda ash of 22 kilograms are mixed, then add the NiO of 4.5 kilograms; The gained compound is sent in the cell furnace of working continuously, be fired into glass metal at the temperature of 1050-1100 ℃; The gained glass metal is sent into the glass tile that is pressed into required specification in the cast iron drum die; With conveying belt, the glass tile of compression moulding is sent in the tunnel annealing furnace, after annealing at the temperature of 400-600 ℃, naturally cooling, obtain the finished product.
Embodiment 3
The clean cullet of 600 kilograms of raw materials, the Fluorspar Powder of 40 kilograms, the Feldspar Powder of 80 kilograms, the rhombspar of 50 kilograms and the soda ash of 16 kilograms are mixed, then add the Cr of 0.79 kilogram
2O
3The gained compound is sent in the cell furnace of working continuously, be fired into glass metal at the temperature of 1050-1100 ℃; The gained glass metal is sent into the hollow brick that is pressed into required specification in the cast iron drum die; With conveying belt, the hollow brick of compression moulding is sent in the tunnel annealing furnace, after annealing at the temperature of 400-500 ℃, naturally cooling, obtain the finished product.
Adopt preparation method of the present invention to make and adopt glass wall brick or glass tile, ultimate compression strength is high, and raw material is easy to get, technique is simple, cost is lower, and energy consumption is lower, can realize continuous production, and the product color that makes is abundant, suitability is strong, and for example the glass wall brick can be made the hollow brick that connects in length and breadth, and electric wire, pipeline or color lamp etc. can be placed in inside, not only beautiful and clean, and have insulation and soundproof effect.
Structure of the present invention is not limited to the embodiment described in embodiment, and those skilled in the art's technical scheme according to the present invention draws other embodiment, belongs to equally technological innovation scope of the present invention.
Claims (6)
1. the preparation method of a stained glass wall body brick or glass tile, is characterized in that, comprises the following steps:
(1) prepare to comprise the raw material of cullet, Fluorspar Powder, Feldspar Powder and soda ash, in raw material, the weight percent of each component is:
(2) cullet in step (1) is cleaned up, then each component is mixed, adding consumption is the tinting material of raw material gross weight 0.1-0.4% again, and it is to be fired into glass metal in the cell furnace of 1050-1100 ℃ that the gained compound is directly sent into temperature;
(3) glass metal in step (2) is sent into mould compression moulding, obtain the product of compression moulding;
(4) with the product of compression moulding at 400-600 ℃ of temperature annealing 5-10 minute after, naturally cooling, obtain the finished product.
2. preparation method according to claim 1, is characterized in that, in step (1), in raw material, the weight percent of each component is:
3. preparation method according to claim 1, is characterized in that, in step (1), in raw material, the weight percent of each component is:
4. preparation method according to claim 1, is characterized in that, in step (2), described tinting material is the oxide compound of chromium, copper, manganese, nickel or cobalt.
5. preparation method according to claim 1, is characterized in that, in step (1), the granular size of described Fluorspar Powder and described Feldspar Powder is the 150-300 order.
6. preparation method according to claim 1, is characterized in that, in step (3), the product of described compression moulding is hollow or solid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102563411A CN102424528B (en) | 2011-09-01 | 2011-09-01 | Preparation method of colored glass wall brick or glass tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102563411A CN102424528B (en) | 2011-09-01 | 2011-09-01 | Preparation method of colored glass wall brick or glass tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102424528A CN102424528A (en) | 2012-04-25 |
| CN102424528B true CN102424528B (en) | 2013-11-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102563411A Expired - Fee Related CN102424528B (en) | 2011-09-01 | 2011-09-01 | Preparation method of colored glass wall brick or glass tile |
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| Country | Link |
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| CN (1) | CN102424528B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517742A (en) * | 2016-11-28 | 2017-03-22 | 四会市伟祺玻璃建材有限公司 | Glass mosaic and preparation method thereof |
| CN107226618A (en) * | 2017-06-30 | 2017-10-03 | 合肥利裕泰玻璃制品有限公司 | A kind of stained glass wall body brick and its production technology |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034068C (en) * | 1992-09-09 | 1997-02-19 | 董绍明 | Prescription of colour glass stone brick and its manufacture method |
| CN1087325A (en) * | 1992-11-26 | 1994-06-01 | 郝学礼 | Glass-glaze sulfide glass article |
| CN101942889A (en) * | 2009-12-11 | 2011-01-12 | 田长生 | Stained glass tile |
| CN101942881A (en) * | 2009-12-11 | 2011-01-12 | 田长生 | Air brick of stained glass wall body |
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2011
- 2011-09-01 CN CN2011102563411A patent/CN102424528B/en not_active Expired - Fee Related
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| CN102424528A (en) | 2012-04-25 |
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Granted publication date: 20131120 Termination date: 20180901 |