CN106517742A - Glass mosaic and preparation method thereof - Google Patents
Glass mosaic and preparation method thereof Download PDFInfo
- Publication number
- CN106517742A CN106517742A CN201611065341.2A CN201611065341A CN106517742A CN 106517742 A CN106517742 A CN 106517742A CN 201611065341 A CN201611065341 A CN 201611065341A CN 106517742 A CN106517742 A CN 106517742A
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- CN
- China
- Prior art keywords
- parts
- glass mosaic
- glass
- frit
- mosaic
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a glass mosaic. The glass mosaic is prepared from glass raw materials and pigment. The glass raw materials are composed of, by weight, 30 to 45 parts of quartz sand, 15 to 30 parts of soda ash, 2 to 10 parts of calcite, 10 to 20 parts of feldspar, 3 to 8 parts of fluorite and 2 to 8 parts of alumina. The weight part of the pigment is 5 to 20. The invention also discloses a preparation method for the glass mosaic. The glass mosaic has a smooth and micro-crack-free surface, a brilliant and good color and good heat stability and wear resistance and is not prone to fading. The preparation method for the glass mosaic is simple, omits the step of secondary sintering in traditional preparation processes, produces no scraps, is simple to operate and small in production waste, and saves energy.
Description
Technical field
The present invention relates to decoration material field, more particularly to a kind of glass Mosaic and preparation method thereof.
Background technology
Glass Mosaic is a kind of safety and environmental protection, is suitable for decorating the building materials of nearly aqua region, and which has zero water absorption rate, antiacid
Alkali, it is anticorrosive the advantages of, can be used to decorate toilet, bathroom, bedroom, balcony, swimming pool, the veneer material in the place such as fountain landscape
Material, long service life, low cost, market application foreground are good.The production method of glass Mosaic is：First simple glass is cut into
The specification of suitable screen painting size, printing colouring, 200 DEG C～300 DEG C firings in kiln, enables colorant to be attached to glass table
Face, then cut by customer specification size, fire again for 550 DEG C～700 DEG C in kiln.Secondary cut, secondary kiln are fired, not only
The waste materials such as complex process, generation leftover pieces are more, and colorant layer is only attached to the top layer of glass Mosaic body, the gloss of color
Degree is poor, not wear-resisting, also variable to fade.
The content of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of glass Mosaic, its surfacing
Non-microcracked, color and luster bright in luster is good, and fugitive color, heat endurance and anti-wear performance be not good.
Another object of the present invention is to provide a kind of preparation method of glass Mosaic, the preparation method is simple, saves
In conventional preparation techniques the step of secondary firing, non waste edge is easy to operate, and production wastes few, energy saving.
The purpose of the present invention employs the following technical solutions realization：
A kind of glass Mosaic, the glass Mosaic are prepared from by frit and colorant；The glass is former
Material includes following component by weight：Quartz sand 30-45 parts, soda ash 15-30 parts, calcite 2-10 parts, feldspar 10-20
Part, fluorite 3-8 parts, aluminum oxide 2-8 parts；
The colorant is 5-20 parts.
By the formula obtain for transparent glass Mosaic.
Preferably, the frit includes following component by weight：35 parts of quartz sand, 21 parts of soda ash, Fang Xie
5 parts of stone, 14 parts of feldspar, 5 parts of fluorite, 5 parts of aluminum oxide；The colorant is 15 parts.
Preferably, the frit also includes 5-15 parts prodan and 1-5 part sodium nitrate.By what the formula was obtained it is
The glass Mosaic of milkiness shape.
Preferably, the frit also includes 10 parts of prodans and 3 parts of sodium nitrate.
Preferably, the quartz sand is purchased from Beihai Heng Tai quartz sands Co., Ltd, and the calcite is difficult to understand special purchased from Jiangxi
Fine breeze Co., Ltd, the feldspar shake Yang Fenti processing Co., Ltd purchased from Lingshou County, and the fluorite is purchased from Lingshou County gold
Source mining industry Co., Ltd.
The invention also discloses a kind of preparation method of above-mentioned glass Mosaic, comprises the following steps：
1) frit is configured by the proportioning of formula, adds kiln so that frit is fused into melt；
2) colorant is added in melt, and stirring makes colorant uniform, obtains melt of painting；
3) colouring melt is taken out from kiln, it is compressing using operated pressing tool, obtain formed glass body；
4) formed glass body is annealed, after cooling, obtains the glass Mosaic of the present invention.
Preferably, in step 1) in, divide 2-4 time and frit is added in kiln, every time charging 4-5 hours, kiln temperature
Spend for 800-1000 DEG C.
Preferably, in step 2) in, the speed of stirring is 300-500r/min, and kiln temperature is 1200-1400 DEG C.
Preferably, annealing temperature is 600-800 DEG C, and annealing time is 5-8 hours.
Preferably, in step 1) in, kiln temperature is 900 DEG C；In step 2) in, kiln temperature is 1300 DEG C.
Compared to existing technology, the beneficial effects of the present invention is：
Frit is directly melted by the glass Mosaic of the present invention, and re-compacted shaping, cost of material are low, kiln
Once-firing, need not cut, and non waste edge is easy to operate, and production wastes few, energy saving；The glass Mosaic surface for obtaining
Smooth non-microcracked, color and luster bright in luster is good, and fugitive color, heat endurance and anti-wear performance be not good.
Specific embodiment
Below, with reference to specific embodiment, the present invention is described further：
In following examples, the quartz sand is purchased from Beihai Heng Tai quartz sands Co., Ltd, and the calcite is purchased from river
The special fine breeze Co., Ltd in Theo, the feldspar shake Yang Fenti processing Co., Ltd purchased from Lingshou County, and the fluorite is purchased from spirit
Shou County Jin Yuan mining industry Co., Ltd.
Embodiment 1
A kind of glass Mosaic, the glass Mosaic are prepared from by frit and colorant；The glass is former
Material includes following component by weight：35 parts of quartz sand, 21 parts of soda ash, 5 parts of calcite, 14 parts of feldspar, 5 parts of fluorite, oxygen
Change 5 parts of aluminium；
Colorant is 15 parts.
Above-mentioned glass Mosaic is that Jing following steps are prepared from：
1) frit is configured by the proportioning of formula, the temperature for arranging kiln is 900 DEG C, divides 3 times by frit
Kiln is added, each feed time is 4.5 hours so that frit is fused into melt；
2) kiln temperature is warming up to into 1300 DEG C, and keeps the temperature；Colorant is added in melt, and opens stirring dress
Put, mixing speed is 500r/min, until making colorant uniform, obtain melt of painting；
3) colouring melt is taken out from kiln, be added in mould, it is compressing using oil pressure tool melt of painting, obtain
To formed glass body；
4) formed glass body is annealed, annealing temperature is 700 DEG C, annealing time is 6 hours；Glass after to be annealed
After body cooling, that is, obtain the glass Mosaic of the present invention.
Embodiment 2
A kind of glass Mosaic, the glass Mosaic are prepared from by frit and colorant；The glass is former
Material includes following component by weight：30 parts of quartz sand, 15 parts of soda ash, 2 parts of calcite, 10 parts of feldspar, 3 parts of fluorite, oxygen
Change 2 parts of aluminium, 5 parts of prodan, 1 part of sodium nitrate；
Colorant is 5 parts.
Above-mentioned glass Mosaic is that Jing following steps are prepared from：
1) frit is configured by the proportioning of formula, the temperature for arranging kiln is 800 DEG C, divides 2 times by frit
Kiln is added, each feed time is 5 hours so that frit is fused into melt；
2) kiln temperature is warming up to into 1200 DEG C, and keeps the temperature；Colorant is added in melt, and opens stirring dress
Put, mixing speed is 400r/min, until making colorant uniform, obtain melt of painting；
3) colouring melt is taken out from kiln, be added in mould, it is compressing using oil pressure tool melt of painting, obtain
To formed glass body；
4) formed glass body is annealed, annealing temperature is 600 DEG C, annealing time is 8 hours；Glass after to be annealed
After body cooling, that is, obtain the glass Mosaic of the present invention.
Embodiment 3
A kind of glass Mosaic, the glass Mosaic are prepared from by frit and colorant；The glass is former
Material includes following component by weight：45 parts of quartz sand, 30 parts of soda ash, 10 parts of calcite, 20 parts of feldspar, 8 parts of fluorite, oxygen
Change 8 parts of aluminium, 15 parts of prodan, 5 parts of sodium nitrate；
Colorant is 20 parts.
Above-mentioned glass Mosaic is that Jing following steps are prepared from：
1) frit is configured by the proportioning of formula, the temperature for arranging kiln is 1000 DEG C, divides 4 times by frit
Kiln is added, each feed time is 4 hours so that frit is fused into melt；
2) kiln temperature is warming up to into 1400 DEG C, and keeps the temperature；Colorant is added in melt, and opens stirring dress
Put, mixing speed is 300r/min, until making colorant uniform, obtain melt of painting；
3) colouring melt is taken out from kiln, be added in mould, it is compressing using oil pressure tool melt of painting, obtain
To formed glass body；
4) formed glass body is annealed, annealing temperature is 800 DEG C, annealing time is 5 hours；Glass after to be annealed
After body cooling, that is, obtain the glass Mosaic of the present invention.
Comparative example 1
Commercially available glass Mosaic.
Experimental example
The glass Mosaic of Example 1-3 and comparative example 1, specification are the square of 20mm × 20mm, and respectively which is entered
Row outward appearance, wearability and heat stability test.
Outward appearance is detected：The glass Mosaic of random Example 1-3 and comparative example 1 is each 10 pieces, lies in well-lighted
Place, estimates to its crizzle, glossiness, the results are shown in Table 1.
Heat stability test：50 blocks of glass without neat embodiment 1-3 in obvious crack, corner and comparative example 1 are taken respectively
Mosaic, block-by-block are laid in gabion, basket is put into constant temperature in 90 ± 2 DEG C of tank, makes water logging not have sample.Keep
Propose after 30min, be immediately placed in 18～25 DEG C of water, propose after keeping 10min, block-by-block range estimation has flawless or breakage, as a result
It is shown in Table 2.
Wearability is detected：The wearability of glass Mosaic is detected according to the method that GB11950-89 specifies, it is wear-resisting
Property evaluation index as shown in table 3, acquired results are shown in Table 4.
The visual condition of 1 embodiment 1-3 of table and comparative example 1
As can be seen from Table 1, the glossiness of the glass Mosaic of embodiment 1-3 is good, better than the glass Marseille of comparative example 1
Gram；The glass Mosaic of embodiment 1-3 is to observe crizzle, and has 3 pieces to occur in that in the glass Mosaic of comparative example 1
Micro-crack, this is, as the glass Mosaic of embodiment 1-3 is without secondary firing, and to be made annealing treatment, eliminate in
The thermal stress in portion, so micro-crack is not observed on surface.
The thermal stability results of 2 embodiment 1-3 of table and comparative example 1
As shown in Table 2, in heat stability test, the glass Mosaic of only embodiment 2 occurs in that a face crack,
And have 10 pieces to occur in that face crack in comparative example 1,2 pieces there is rupture, show embodiment 1-3 glass Mosaic it is thermally-stabilised
Property is substantially better than comparative example 1.This is primarily due to the glass Mosaic of embodiment 1-3 only through once firing, and have passed through and move back
Fire is processed, and eliminates built-in thermal stress, therefore heat endurance is more preferable.
3 evaluating abrasion resistance index of table
The abrasion resistance results of 4 embodiment 1-3 of table and comparative example 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| Wear-resisting grade | Ⅲ | III | III | Ⅱ |
As shown in Table 4, the wear-resisting grade of the glass Mosaic of embodiment 1-3 is III grade, the glass Mosaic of comparative example 1
Wear-resisting grade be II grade, show that the glass Mosaic wearability of embodiment 1-3 is more preferable.
It will be apparent to those skilled in the art that technical scheme that can be as described above and design, make other various
It is corresponding to change and deformation, and all these change and deformation should all belong to the protection domain of the claims in the present invention
Within.
Claims (10)
1. a kind of glass Mosaic, it is characterised in that the glass Mosaic is prepared from by frit and colorant；Institute
State the following component that frit includes by weight：Quartz sand 30-45 parts, soda ash 15-30 parts, calcite 2-10 parts, length
Stone 10-20 parts, fluorite 3-8 parts, aluminum oxide 2-8 parts；
The colorant is 5-20 parts.
2. glass Mosaic as claimed in claim 1, it is characterised in that it is as follows that the frit includes by weight
Component：35 parts of quartz sand, 21 parts of soda ash, 5 parts of calcite, 14 parts of feldspar, 5 parts of fluorite, 5 parts of aluminum oxide；The colorant is 15 parts.
3. glass Mosaic as claimed in claim 1, it is characterised in that the frit also includes 5-15 part prodans
With 1-5 part sodium nitrate.
4. glass Mosaic as claimed in claim 3, it is characterised in that the frit also including 10 parts of prodans and
3 parts of sodium nitrate.
5. the glass Mosaic as described in claim 1-4, it is characterised in that the quartz sand is purchased from the permanent Thailand's quartz sand in Beihai
Co., Ltd, purchased from Jiangxi breeze Co., Ltd difficult to understand special fine, the feldspar adds the calcite purchased from the Lingshou County Yang Fenti that shakes
Work Co., Ltd, the fluorite are purchased from Lingshou County Jin Yuan mining industry Co., Ltd.
6. a kind of preparation method of the glass Mosaic as described in any one of claim 1-5, it is characterised in that including following step
Suddenly：
1) frit is configured by the proportioning of formula, adds kiln so that frit is fused into melt；
2) colorant is added in melt, and stirring makes colorant uniform, obtains melt of painting；
3) colouring melt is taken out from kiln, it is compressing using operated pressing tool, obtain formed glass body；
4) formed glass body is annealed, after cooling, obtains the glass Mosaic of the present invention.
7. the preparation method of glass Mosaic as claimed in claim 6, it is characterised in that in step 1) in, point 2-4 time to kiln
Frit is added in stove, every time charging 4-5 hours, kiln temperature is 800-1000 DEG C.
8. the preparation method of glass Mosaic as claimed in claim 6, it is characterised in that in step 2) in, the speed of stirring
For 300-500r/min, kiln temperature is 1200-1400 DEG C.
9. the preparation method of glass Mosaic as claimed in claim 6, it is characterised in that annealing temperature is 600-800 DEG C, is moved back
The fiery time is 5-8 hours.
10. the preparation method of glass Mosaic as claimed in claim 6, it is characterised in that in step 1) in, kiln temperature is
900℃；In step 2) in, kiln temperature is 1300 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611065341.2A CN106517742A (en) | 2016-11-28 | 2016-11-28 | Glass mosaic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611065341.2A CN106517742A (en) | 2016-11-28 | 2016-11-28 | Glass mosaic and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106517742A true CN106517742A (en) | 2017-03-22 |
Family
ID=58357672
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611065341.2A Pending CN106517742A (en) | 2016-11-28 | 2016-11-28 | Glass mosaic and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106517742A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108218251A (en) * | 2018-03-16 | 2018-06-29 | 厦门艾迪建材工业有限公司 | The production line and production technology of a kind of glass Mosaic |
| CN109133619A (en) * | 2018-09-17 | 2019-01-04 | 枣庄市超福钻石饰品有限公司 | A kind of glass drill mosaic and preparation method thereof and ornament materials |
| CN113562981A (en) * | 2021-07-20 | 2021-10-29 | 广东伟祺艺术玻璃有限公司 | Hydrophobic glass mosaic and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5233909A (en) * | 1975-09-12 | 1977-03-15 | Tanto Kk | Method of production of vitreous mosaic tile |
| CN1792922A (en) * | 2005-11-08 | 2006-06-28 | 徐州亿龙玉石有限公司 | Emulsifying glass decorating material and preparation tech. thereof |
| CN102424528A (en) * | 2011-09-01 | 2012-04-25 | 田长生 | Preparation method of colored glass wall brick or glass tile |
| CN102503138A (en) * | 2011-10-18 | 2012-06-20 | 武汉理工大学 | Colorizing method of building decoration microcrystalline glass produced by sintering method |
| CN102765882A (en) * | 2012-08-15 | 2012-11-07 | 黄炳炼 | Milk white glass wine bottle |
-
2016
- 2016-11-28 CN CN201611065341.2A patent/CN106517742A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5233909A (en) * | 1975-09-12 | 1977-03-15 | Tanto Kk | Method of production of vitreous mosaic tile |
| CN1792922A (en) * | 2005-11-08 | 2006-06-28 | 徐州亿龙玉石有限公司 | Emulsifying glass decorating material and preparation tech. thereof |
| CN102424528A (en) * | 2011-09-01 | 2012-04-25 | 田长生 | Preparation method of colored glass wall brick or glass tile |
| CN102503138A (en) * | 2011-10-18 | 2012-06-20 | 武汉理工大学 | Colorizing method of building decoration microcrystalline glass produced by sintering method |
| CN102765882A (en) * | 2012-08-15 | 2012-11-07 | 黄炳炼 | Milk white glass wine bottle |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108218251A (en) * | 2018-03-16 | 2018-06-29 | 厦门艾迪建材工业有限公司 | The production line and production technology of a kind of glass Mosaic |
| CN109133619A (en) * | 2018-09-17 | 2019-01-04 | 枣庄市超福钻石饰品有限公司 | A kind of glass drill mosaic and preparation method thereof and ornament materials |
| CN113562981A (en) * | 2021-07-20 | 2021-10-29 | 广东伟祺艺术玻璃有限公司 | Hydrophobic glass mosaic and preparation method thereof |
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Application publication date: 20170322 |
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