CN102424528A - Preparation method of colored glass wall brick or glass tile - Google Patents
Preparation method of colored glass wall brick or glass tile Download PDFInfo
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- CN102424528A CN102424528A CN2011102563411A CN201110256341A CN102424528A CN 102424528 A CN102424528 A CN 102424528A CN 2011102563411 A CN2011102563411 A CN 2011102563411A CN 201110256341 A CN201110256341 A CN 201110256341A CN 102424528 A CN102424528 A CN 102424528A
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Abstract
The invention relates to a preparation method of colored glass wall bricks or glass tiles, comprising the following steps: (1) preparing raw materials, wherein, the raw materials comprise 74-90 wt% of waste glass, 4-6 wt% of flousper powder, 4-15 wt% of feldspar powder, and 2-6 wt% of soda ash; (2) mixing the ingredients in the step (1), then adding a coloring agent in an amount of 0.1-0.4 wt% based on the total weight of the raw materials, and sintering the mixture into a glass liquid at a temperature of 1050-1100 DEG C; (3) putting the glass liquid obtained in the step (2) in a die for pressing into shape; and (4) annealing the pressed product at a temperature of 400-600 DEG C, and cooling. The preparation method has the advantages of simple process, low cost, and low energy consumption, and the prepared product has abundant color and wide application.
Description
Technical field
The invention belongs to building material technical field, be specifically related to the preparation method of a kind of stained glass wall body brick or glass tile.
Background technology
Traditional production glass floor tile, the batching of face brick are mainly with high silicon content (SiO
2Weight ratio is nearly more than 90%) silica sand be main raw material; But because the silica sand composition is single; Can not satisfy and fire the product physicochemical property and the index that reach of needs in use,, so just increase raw materials cost so will add the various additives that improve product performance.In recent years; It is the method for feedstock production glass floor tile, face brick with useless silicates grogs such as cullet, waste ceramics that report is arranged; One Chinese patent application 92109877.4 (publication number 1083796A for example; Open day on March 16th, 1994) disclosing a kind of is that main raw material, employing are made the preparation method of colour glass stone brick with the novel process of hydration material with the cullet, but adopts this method to make to such an extent that product mainly is used as the glass facing tile that pastes wall, can't be used as the glass wall body brick; Thereby its intensity and suitability still can not be satisfactory, also has the raw materials cost problem of higher in addition.
Summary of the invention
To the defective that exists in the prior art, the purpose of this invention is to provide the preparation method of a kind of stained glass wall body brick or glass tile, the glassy product that adopts this method to make, ultimate compression strength is high, and suitability is strong, and the plate glass that makes can be used as wall body brick.
For reaching above purpose, the technical scheme that the present invention adopts is: the preparation method of a kind of stained glass wall body brick or glass tile, it is characterized in that, and may further comprise the steps:
(1) preparation comprises the raw material of cullet, fluorite powder, Feldspar Powder and soda ash, and the weight percent of each component is in the raw material:
(2) cullet in the step (1) is cleaned up, then each component is mixed, add the tinting material that consumption is raw material gross weight 0.1-0.4% again, it is to be fired into glass metal in 1050-1100 ℃ the cell furnace that the gained compound is directly sent into temperature;
(3) glass metal in the step (2) is sent into mould compression moulding, obtain the product of compression moulding;
(4) with the product of compression moulding in that annealing is after 5-10 minute under the 400-600 ℃ of temperature, naturally cooling promptly gets the finished product.
Further, in the step (1), the weight percent of each component is in the raw material:
Further, in the step (1), the weight percent of each component is in the raw material:
Further, in the step (2), said tinting material is the oxide compound of chromium, copper, manganese, nickel or cobalt.
Further, it is characterized in that in the step (1), the particle size of said fluorite powder and said Feldspar Powder is the 150-300 order.
Further, it is characterized in that in the step (3), the product of said compression moulding is hollow or solid.
The coloured glass tile that provides among the present invention or watt the preparation method in, the effect of each component is following in the raw material: cullet mainly plays the effect of skeleton in the raw material; The fluorite powder is a kind of important ore of producing colored glass, because the staple of fluorite powder is CaF
2, F wherein can play opal effect, thereby obtains the uniform glass of milkiness, can also play the effect of hydrotropy simultaneously; Feldspar Powder contains makes the required framework material silicon of glassy product, aluminium etc.; Soda ash is solubility promoter, its role is to improve glass melting speed, lowers the glass melt temperature.The present invention also adds a certain amount of tinting material, its role is to make plate glass or watt demonstrates shades of colour.
Preparing method of the present invention is main with cullet mainly, adopts ore as much as possible, thus in prescription of the present invention, can also add other ore, like rhombspar, calcite, feldspar etc.
The present invention compared with prior art has the following advantages:
(1) the present invention makes full use of cullet and ore, and the stone raw material that uses can promptly carry out raw materials mix without any processing, and technology is simple, and cost is low, and environmental protection is easy to realize the serialization suitability for industrialized production.
(2) preparation method provided by the invention, firing temperature is low, and energy consumption is low.
(3) glassy product that adopts method of the present invention to make, ultimate compression strength is high, and acid and alkali-resistance is difficult for wearing out, and rich color, the plate glass that for example makes not only can be used as wall body brick, floor tile, can also be widely used as being affixed on the ornamental face brick on the body of wall.
Embodiment
Below in conjunction with embodiment the present invention is further described.
Raw material in following examples and reagent all can be buied from market.Be the stability of the composition that guarantees ore, preferably, the fluorite powder or the Feldspar Powder that use same mineral reserve to produce.
Embodiment 1
The clean cullet of 800 kilograms of raw materials, 50 kilograms fluorite powder, 120 kilograms Feldspar Powder and 30 kilograms soda ash are mixed, add 2 kilograms CuO again; The gained compound is sent in the cell furnace of working continuously, under 1050-1100 ℃ temperature, be fired into glass metal; The gained glass metal is sent into the hollow brick that is pressed into required specification in the cast iron drum die; With conveying belt the hollow brick of compression moulding is sent in the tunnel annealing furnace, after annealing under 400-600 ℃ the temperature, naturally cooling promptly gets the finished product.
Embodiment 2
The clean cullet of 950 kilograms of raw materials, 80 kilograms fluorite powder, 60 kilograms Feldspar Powder and 22 kilograms soda ash are mixed, add 4.5 kilograms NiO again; The gained compound is sent in the cell furnace of working continuously, under 1050-1100 ℃ temperature, be fired into glass metal; The gained glass metal is sent into the glass tile that is pressed into required specification in the cast iron drum die; With conveying belt the glass tile of compression moulding is sent in the tunnel annealing furnace, after annealing under 400-600 ℃ the temperature, naturally cooling promptly gets the finished product.
Embodiment 3
The clean cullet of 600 kilograms of raw materials, 40 kilograms fluorite powder, 80 kilograms Feldspar Powder, 50 kilograms rhombspar and 16 kilograms soda ash are mixed, add 0.79 kilogram Cr again
2O
3The gained compound is sent in the cell furnace of working continuously, under 1050-1100 ℃ temperature, be fired into glass metal; The gained glass metal is sent into the hollow brick that is pressed into required specification in the cast iron drum die; With conveying belt the hollow brick of compression moulding is sent in the tunnel annealing furnace, after annealing under 400-500 ℃ the temperature, naturally cooling promptly gets the finished product.
Adopt preparation method of the present invention to make and adopt glass wall body brick or glass tile, ultimate compression strength is high, and raw material is easy to get, and technology is simple; Cost is lower, and energy consumption is lower, can realize continuous production; And the product color that makes is abundant, and suitability is strong, and for example the glass wall body brick can be processed the hollow brick that connects in length and breadth; Electric wire, pipeline or color lamp etc. can be placed in inside, and are not only beautiful and clean, and have insulation and soundproof effect.
Structure according to the invention is not limited to the embodiment described in the embodiment, and those skilled in the art's technical scheme according to the present invention draws other embodiment, belongs to technological innovation scope of the present invention equally.
Claims (6)
1. the preparation method of stained glass wall body brick or glass tile is characterized in that, may further comprise the steps:
(1) preparation comprises the raw material of cullet, fluorite powder, Feldspar Powder and soda ash, and the weight percent of each component is in the raw material:
(2) cullet in the step (1) is cleaned up, then each component is mixed, add the tinting material that consumption is raw material gross weight 0.1-0.4% again, it is to be fired into glass metal in 1050-1100 ℃ the cell furnace that the gained compound is directly sent into temperature;
(3) glass metal in the step (2) is sent into mould compression moulding, obtain the product of compression moulding;
(4) with the product of compression moulding in that annealing is after 5-10 minute under the 400-600 ℃ of temperature, naturally cooling promptly gets the finished product.
2. preparation method according to claim 1 is characterized in that, in the step (1), the weight percent of each component is in the raw material:
3. preparation method according to claim 1 is characterized in that, in the step (1), the weight percent of each component is in the raw material:
4. preparation method according to claim 1 is characterized in that, in the step (2), said tinting material is the oxide compound of chromium, copper, manganese, nickel or cobalt.
5. preparation method according to claim 1 is characterized in that, in the step (1), the particle size of said fluorite powder and said Feldspar Powder is the 150-300 order.
6. preparation method according to claim 1 is characterized in that, in the step (3), the product of said compression moulding is hollow or solid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102563411A CN102424528B (en) | 2011-09-01 | 2011-09-01 | Preparation method of colored glass wall brick or glass tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102563411A CN102424528B (en) | 2011-09-01 | 2011-09-01 | Preparation method of colored glass wall brick or glass tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102424528A true CN102424528A (en) | 2012-04-25 |
| CN102424528B CN102424528B (en) | 2013-11-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102563411A Expired - Fee Related CN102424528B (en) | 2011-09-01 | 2011-09-01 | Preparation method of colored glass wall brick or glass tile |
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| Country | Link |
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| CN (1) | CN102424528B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517742A (en) * | 2016-11-28 | 2017-03-22 | 四会市伟祺玻璃建材有限公司 | Glass mosaic and preparation method thereof |
| CN107226618A (en) * | 2017-06-30 | 2017-10-03 | 合肥利裕泰玻璃制品有限公司 | A kind of stained glass wall body brick and its production technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083796A (en) * | 1992-09-09 | 1994-03-16 | 董绍明 | The prescription of colour glass stone brick and manufacture method thereof |
| CN1087325A (en) * | 1992-11-26 | 1994-06-01 | 郝学礼 | Glass-glaze sulfide glass article |
| CN101942889A (en) * | 2009-12-11 | 2011-01-12 | 田长生 | Stained glass tile |
| CN101942881A (en) * | 2009-12-11 | 2011-01-12 | 田长生 | Air brick of stained glass wall body |
-
2011
- 2011-09-01 CN CN2011102563411A patent/CN102424528B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083796A (en) * | 1992-09-09 | 1994-03-16 | 董绍明 | The prescription of colour glass stone brick and manufacture method thereof |
| CN1087325A (en) * | 1992-11-26 | 1994-06-01 | 郝学礼 | Glass-glaze sulfide glass article |
| CN101942889A (en) * | 2009-12-11 | 2011-01-12 | 田长生 | Stained glass tile |
| CN101942881A (en) * | 2009-12-11 | 2011-01-12 | 田长生 | Air brick of stained glass wall body |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517742A (en) * | 2016-11-28 | 2017-03-22 | 四会市伟祺玻璃建材有限公司 | Glass mosaic and preparation method thereof |
| CN107226618A (en) * | 2017-06-30 | 2017-10-03 | 合肥利裕泰玻璃制品有限公司 | A kind of stained glass wall body brick and its production technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102424528B (en) | 2013-11-20 |
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