CN1301199C - Coloured resin three dimensional pattern artificial stone slab material - Google Patents
Coloured resin three dimensional pattern artificial stone slab material Download PDFInfo
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- CN1301199C CN1301199C CNB200310124225XA CN200310124225A CN1301199C CN 1301199 C CN1301199 C CN 1301199C CN B200310124225X A CNB200310124225X A CN B200310124225XA CN 200310124225 A CN200310124225 A CN 200310124225A CN 1301199 C CN1301199 C CN 1301199C
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- pattern
- resin
- color
- area
- artificial slabstone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
- B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
Abstract
The present invention relates to an artificial stone slab with color resin three-dimensional patterns, which contains organic resin material. The stone slab has more than one class of pattern regions which are composed of two kinds or two to ten kinds of colors or the same color of different color shade degree or different mixed colors. The total area of at least one or more than one pattern region which is composed of two classes of colors in the pattern regions is 10 to 90 percent of the area of the whole stone slab. The thickness of at least one kind of powder material color in the 50 to 100 percent of the area of the surface of the pattern regions is 90 to 100 percent of the thickness of the stone slab. The surface layer of the stone slab is provided with one hundred to one hundred thousand pattern blocks or grains which are composed of resin and inorganic class powder, and the area of the pattern blocks or the grains is 4MM <2> to 3000MM <2> at least. The present invention has three-dimensional stone-like material which likes natural stone so as to form a product of a new slab, and thereby, the density and the position of partial distribution of the product in the three-dimensional space in the product can be according to the characteristics of patterns of natural stone, and the present invention has the superior efficacy of veritably imitating natural stone.
Description
Technical field
The present invention relates to a kind of artificial slabstone, particularly relate to a kind of color resin three-D pattern artificial slabstone that is applicable to kitchen, toilet and interior decoration deck plate.
Background technology
Current raising along with development of science and technology and people's living standard, as the ornament materials such as deck plate in the kitchen panel in the household, toilet washbowl platen and the numerous public utility, present product has only the artificial colour table of age spot shape, so, people wish that it has the appearance of lithotome, the pattern of artificial grantie for example is to increase the top grade sense of product.
The artificial stone plate of prior art, a kind of is the very common age spot shape artificial board that panel is used between for kitchen use and bathroom, adopt organic resin to add the mineral-type filling powder, forming diameter is the hue pit of 0.1mm-0.8mm, wherein have and be convenient to the advantage of cutting, process, polishing, but dull coloring, pattern-free can be sayed, whole artistic feeling is poor, does not more have the advantage of the high-grade lithotome finishing of performance effect.Another kind is the big blocky artificial stone plate of parian who does with resin and stone flour, it mainly develops to the direction of the imitative jade half penetrating sense of translucent pursuit, perhaps adopt the artificial stone of the block full marble pattern of marble blocks material and resin-bonding, be mainly used in tea table and dinner table, it is owing to contain organic resin ratio big (pursuit translucent effect), so it is not wear-resisting, die and be not used in the place of use cutters such as kitchen, and its pattern is the marble of big block graphics, though one side attractive in appearance is arranged, but owing to be used for the kitchen after the cutting, the toilet upper platen, requirement is to being undertaken bonding or lengthened plate is bonding by the wall limit, just the problem that the basic splicing of pattern can not coincide occurs, can not form the effect of a watertight whole lithotome pattern plate.Though its also have be convenient to cut, polishing, bonding advantage, but in different kitchens, its size of toilet is also inconsistent or finishing when requiring shape different, come out with regard to there being not enough, the big sheet material material of platelet scantling to downcut the problem of wasting unnecessary material again, it is not wear-resisting in addition, easily scratch, so in the kitchen, the toilet can not adopt, limited to.
The inventor is in many inventions of ceramic field, because of its imitative stone effective, wear-resisting again, advantage such as "dead", but when being used for kitchen, toilet decoration, because hardness height, be difficult for cutting, more difficultly under little decoration construction condition, hold on-site cutting, the edge grind standard, bright and clean, straight very, so just must on big machine, process, bring the inconvenience in many practicalities.And, to processing the kitchen, defend by the wall limit cannot add voluntarily heat bonding because the resin artificial board just soften into plastic state at the hot blast that adds more than 100 ℃, can be bonding; Therefore the ceramic sheet material must be heated to 1100 ℃ just can it is softening bonding more than-1200 ℃, this is impossible certainly under little execution conditions, if and the porcelain plate material handle with jointing material, packing material defend, the metope in kitchen, obstructing surface joint portion often have the generation drainage, so also limited on the convenience that is suitable for.
Therefore, industry is just constantly improved the dalle structure of natural-like stone, the inventor has multinomial China and Europe in ceramic decoration sheet material field, beautiful, the developer of foreign patents such as day, reach ten multinomial patents at ceramic field, as once proposing a kind of stereo ceramic granite, the patent of marble technology, notification number is WO97/36840, on October 9th, 1997 is open, according to the made stone imitation material of this technology, its surface is formed with the pattern of clear boundary, and when standing Surface Machining, its pattern can not change basically, so can effectively promote its overall structure steadiness in the use.
In order to satisfy people's practicality demand, the back inventor also once proposed a kind of " porcelain imitation granite board and manufacture method thereof ", its notification number is WO99/28262, on June 10th, 1999 is open, above-mentioned porcelain imitation granite board and manufacture method thereof, though the imitative hilllock of the porcelain stone slab that can provide user one to have more practical effect, really has progressive, but when using, reality but finds also to have in its structure deficiency, goods according to this technology only have its surperficial pattern, there are not goods at three-dimensional pattern, and not as the mobile texture that forms pattern of natural lava, so product can not reflect natural granite pattern texture from inside to outside very truly, especially the middle and lower part of limit portion does not have pattern effect, if when the exposed edge of wall that is used for furniture table-board and construction and decoration or post must want opposite side portion to carry out the edging polishing, because wherein, the bottom is not the particle pattern of one with the top layer, so have untrue in practicality than lithotome, incomplete significant deficiency.
Free cloth product of the prior art, three dimensions pattern from the goods top layer to inside is more random, can not form as clone's lithotome from product surface the multicolour pattern zone of the complete uniformity in stable same district of the same colour is arranged all to the goods bottom, so than lithotome also have can not real simulation defective.
In order to satisfy people's practicality demand, patent that the back inventor once proposed again a kind of " the three-dimensional color pattern sheet material of porcelain powder sintering ", its publication number is CN 1339363A, on March 13rd, 2002 is open, the three-dimensional color pattern sheet material of above-mentioned porcelain powder sintering, though having proposed it is the powder that utilizes the porcelain colour raw material, repressed, and the porcelain product that is fired into, its goods have different color or same color but different color and luster weights of tool or the different porcelain that mixes the clear-cut that colour cell becomes burn till pattern area, pattern area all is even distribution the 70%-100% zone from the goods top layer to bottom thickness, can be made into the three-dimensional stone imitation material as lithotome; Though very much progress is arranged on effect, can make powder specified distribution be arranged in not homochromy district, 3-D effect is arranged, but in different pattern bulk districts, can only reflect some mixed powder looks, add the pattern colour that contains oarse-grained pattern colour or add intermingling flower colour, and the shortage natural marble, in the granitic pattern area just like abundant polygonal in the different pattern district that produces when moving with natural lava flow, the edge transition is soft, also have and enrich meticulous little pattern in the big pattern area of concave crescent shapes in some, and also can comprise other colored pattern of other fritter in the fine pattern that has, the edge of the meticulous fritter pattern that also has and two kinds of look districts have a common boundary, the effect that generation is flowed as natural lava, the area that this effect is especially arranged is at 1cm
2-2cm
2Fine pattern to adopt the previously presented die orifice technology of the inventor be to be difficult for realizing.But goods are all because hardness is too high, and intensity is too big, have that cost height when constructing among a small circle, the interval bonding water proofing property of plate are bad, a problem of applicability and convenience difference.
The inventor also once proposed a kind of " granite with stereo pattern of ceramic grains " patent, its Granted publication number is CN 1091756C, on October 02nd, 2002 was announced, above-mentioned granite with stereo pattern of ceramic grains patent, though having proposed it is the effect of utilizing porcelain colour particle artificial grantie, but in artificial stone, the pattern that how much forms by particle, obviously do not have diameter that the powder district forms and be 15mm-50mm contain oarse-grained pattern nature, more near the natural granite stone effect, so also have much room for improvement.
For the defective that the dalle that solves existing natural-like stone exists, relevant manufacturer there's no one who doesn't or isn't seeks solution painstakingly, but does not see always that for a long time suitable design finished by development, and this obviously is the problem that the anxious desire of relevant dealer solves.
The defective of depositing in view of the dalle of above-mentioned existing natural-like stone, the inventor is based on being engaged in this type of product design manufacturing abundant for many years practical experience and professional knowledge, actively studied innovation, in the hope of founding a kind of color resin three-D pattern artificial slabstone of new structure, can improve the general dalle structure of existing conventional artificial stone natural-like stone on the market, make it have more practicality, through constantly research, design, and, Now At Last create the present invention who has practical value through after studying sample and improvement repeatedly.
Summary of the invention
Main purpose of the present invention is, overcome the defective that existing artificial slabstone exists, and provide a kind of novel color resin three-D pattern artificial slabstone, technical problem underlying to be solved is to make it can make the three-dimensional stone imitation material that has as lithotome, form a kind of new board product, make the density of goods local distribution and the position can be by the feature of lithotome pattern, and have the good effect that to copy lithotome truly in goods interior three-dimensional space.
Main purpose of the present invention is, overcome the defective that existing artificial slabstone exists, and a kind of novel color resin three-D pattern artificial slabstone, technical problem underlying to be solved are provided is to make it can copy the particle pattern that contains 2.5mm-20mm to be beneficial to splice associative perception is arranged when bonding.
Main purpose of the present invention is, overcome the defective that existing artificial slabstone exists, and a kind of novel color resin three-D pattern artificial slabstone, technical problem underlying to be solved are provided is to make it the little pattern that contains the micro mist feature in the big pattern area of various colours occur.
Purpose of the present invention and solve its technical problem underlying and realize by the following technical solutions.According to a kind of color resin three-D pattern artificial slabstone that the present invention proposes, it contains organic resin material, it is characterized in that: this sheet material has by 2-10 kind different color or same color but the different pattern area of color and luster weight; Have at least the gross area of the area of the pattern of forming by 2 kinds of colors more than one or to account for the 10%-90% of whole sheet material area in this pattern area, have the 90%-100% of a kind of thickness of powder look in the area of the 50%-100% on above-mentioned pattern area surface at least for this sheet metal thickness; The top layer of this sheet material have 100-100000, area is 4mm
2-3000mm
2Pattern area or particle by resin and mineral-type powder constituent.
The object of the invention to solve the technical problems can also adopt following technical measures further to realize.
Aforesaid color resin three-D pattern artificial slabstone, 80% the pattern area diameter that has a class pattern area in the wherein said pattern area at least is in 15mm-50mm.
Aforesaid color resin three-D pattern artificial slabstone, the diameter that contains in the wherein said resin material are that the inorganic powder of 0.01mm-1.5mm is as inserts.
Aforesaid color resin three-D pattern artificial slabstone, the inserts that contains in the wherein said resin material are that diameter is marble powder or granite powder or titanium dioxide class or the Paris white of 0.01mm-1.5mm.
Aforesaid color resin three-D pattern artificial slabstone, it is the pattern of 30mm-50mm that 30-3000, diameter are arranged in the wherein said pattern area.
Aforesaid color resin three-D pattern artificial slabstone contains 100-100000, diameter is the color grains of 2mm-10mm in the wherein said color resin three-D pattern artificial slabstone.
Aforesaid color resin three-D pattern artificial slabstone, the section of wherein said color resin three-D pattern artificial slabstone has the boundary line of 6-20 bar different colours, this boundary line stretches to its bottom from the top layer of described color resin three-D pattern artificial slabstone, and its length that stretches is the 80%-100% of this sheet metal thickness; The boundary line that forms between this boundary line and other color block areas is vertical with the top layer pattern or become two vertical angles, the error of perpendicularity to be no more than ± 20 degree; Or become two parallel lines, parallelism error to be no more than ± 20 degree.
Aforesaid color resin three-D pattern artificial slabstone, wherein said resin material are thermoplastic resin and/or interlink molecular structure resin.
Aforesaid color resin three-D pattern artificial slabstone, wherein said resin material are acrylic acid or polyester or polyformaldehyde or acrylonitrile-butadiene-phenylethylene (ABS) or epoxy resin or polypropylene or polyethylene
Aforesaid color resin three-D pattern artificial slabstone in the wherein said pattern area, contains the color material particle of 1-5 kind diameter at 2mm-20mm, and the surface area of this particle accounts for the 2%-80% of pattern area surface area.
Aforesaid color resin three-D pattern artificial slabstone, it is 1cm that a kind or 1-5 kind color, area are arranged in the wherein said pattern area
2-150cm
2The polygon of 3-1000 in concave crescent shape have micro mist material patterns of features, the distance of the concave point of the straight line that two the most outstanding points of concave crescent shape are linked to be in this and its is 1.5mm-10mm, and this sheet material top layer has 100-1000 area at least at 4mm
2-1000mm
2The little pattern color lump consistent with the crescent shape pattern color.
Aforesaid color resin three-D pattern artificial slabstone, the powder district of the edge that concave crescent shape has a micro mist patterns of features in the wherein said polygon and 2 kinds or 2-5 kind look or the little boundary, micro mist patterns of features district of containing.
Concave crescent shape has the micro mist patterns of features in the aforesaid color resin three-D pattern artificial slabstone, wherein said polygon the more fritter pattern that has surrounded other look more than.
Aforesaid color resin three-D pattern artificial slabstone, to have the distance of the concave point of straight line that two the most outstanding points of micro mist material patterns of features are linked to be and its be 3mm-10mm to concave crescent shape in the wherein said polygon.
Aforesaid color resin three-D pattern artificial slabstone, have the shape and the position of color lump pattern area more than 6, big can coincide at product surface in the wherein said pattern area, its error that coincides in the position, upper and lower, left and right of top layer pattern is no more than ± 5cm.
Aforesaid color resin three-D pattern artificial slabstone, the table plane of wherein said color resin three-D pattern artificial slabstone are the table planes of not polishing, or the table plane of polishing.
Aforesaid color resin three-D pattern artificial slabstone, the overall geometry of wherein said color resin three-D pattern artificial slabstone are surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, sphere, hemispherical, awl circle shape hemispherical or justify the shape that shape combines type by plane and half cone.
The present invention does not have the existing defective of existing artificial slabstone in use fully, and can be so that structure of the present invention more firmly reaches changeableization, therefore can reach suitable practicality, and have the extensive value on the industry, specify advantage of the present invention as follows now:
(1) color resin three-D pattern artificial slabstone of the present invention is clone's granite pattern, make the density and the position of goods local distribution can be by the feature of lithotome pattern in goods interior three-dimensional space, the manufacturing of control is arranged, and have the good effect that to copy lithotome truly.
(2) color resin three-D pattern artificial slabstone of the present invention can be copied the particle pattern that contains 2.5mm-20mm, and being beneficial to splice has associative perception when bonding, does not waste using the back sliceable use of remaining edge strip.
(3) color resin three-D pattern artificial slabstone of the present invention is the little pattern that contains the micro mist feature that can occur in the area of the pattern of clone's natural stone in the big pattern area of various colours, the edge transition that produces in the time of can flowing as natural lava is fine, the colourful polygon of form, many prism patterns, also have some in concave crescent shapes or many crescent shapes enrich fine pattern, and the fine pattern that also has has comprised the fritter pattern of other color, the edge of the meticulous fritter pattern that yet has is not to have a common boundary with a kind of look district, but have a common boundary with two or more more look district indentingly, the effect that generation is flowed as natural lava, especially at artificial stone, in the process of resin, can use moisture content, low adhesive forms mobile difference, so can use diameter less than 0.1mm reach 2-5 doubly or diameter reach 2-5 powder doubly greater than 0.3mm, form the difference of flowability effect, reach the purpose of the imitative tiny natural lava flow effect of producing the micro mist technology characteristics, thereby can copy all Rossa Veronas in the granite more realistically, Giallo Veneziano, Baltic Brown, green brill, Multicolor Red, Martiaca, Indian red, California Gilld, natural classical stone material such as Pink Salisbury.
(4) the present invention has carried out further improvement to artificial stone plate's equipment structure, its structure plan pattern followed rock, especially the artificial grantie pattern is splendid, and than natural stone have also that water absorption rate is low, aberration is little, the advantage of highly polished, "dead" element pollution, have again than porcelain plate and natural stone be convenient to process, polish, cut, polishing, characteristics that bonding composed pattern is very consistent, attractive in appearance.Be suitable for practicality in the use more, and can make the cost of making reduce relatively, meet economic benefit, and quite have the extensive value of industry by the machining mass industrialized production.
In sum, the color resin three-D pattern artificial slabstone of special construction of the present invention, have above-mentioned many advantages and practical value, and in like product, do not see have similar structural design to publish or use and really genus innovation, no matter it structurally or bigger improvement all arranged on the function, have large improvement technically, and produced handy and practical effect, and more existing artificial slabstone has the multinomial effect of enhancement, thereby be suitable for practicality more, and have the extensive value of industry, really be a new and innovative, progressive, practical new design.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technological means of the present invention, and can be implemented according to the content of specification, below with preferred embodiment of the present invention and conjunction with figs. describe in detail as after.
The specific embodiment of the present invention is provided in detail by following examples and accompanying drawing thereof.
Description of drawings
Fig. 1 is the goods the 1st of color resin three-D pattern artificial slabstone of the present invention and the planar structure schematic diagram of the 2nd embodiment.
Fig. 2 is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods the 1st embodiment of color resin three-D pattern artificial slabstone of the present invention.
Fig. 3 be color resin three-D pattern artificial slabstone of the present invention goods the 2nd embodiment different color look district boundary line and the structural representation of the local amplifier section in plane of micro mist characteristic pattern is arranged.
Fig. 4 is the structural representation of the local amplifier section of section of look district boundary line of different color of goods the 1st embodiment of color resin three-D pattern artificial slabstone of the present invention.
Fig. 5 be color resin three-D pattern artificial slabstone of the present invention goods the 2nd embodiment different color look district boundary line and the structural representation of the local amplifier section of section of micro mist characteristic pattern is arranged.
Fig. 6 is the planar structure schematic diagram of the die orifice mould of the essential steel matter of the goods the 1st of color resin three-D pattern artificial slabstone of the present invention and the 2nd embodiment.
Fig. 7 is the pattern position schematic diagram relatively of six goods in the same a collection of goods of the made same a collection of grain density proportioning ratio of the same die orifice of the goods the 1st of color resin three-D pattern artificial slabstone of the present invention and the 2nd embodiment.
Fig. 8 is interior sky, be of a size of 305mm * 305mm, thickness is the square box of the steel matter of 23mm.
3, the dark-brown powder is through the B district, big pattern colour district of the nahlock shape pattern area composition of HTHP formation
5, the powder of dark-brown district 3 and black region 11 hands over the powder of two kinds of looks that mix and form to hand over the transition region of mixing naturally naturally
6, the polygon-shaped sintering pattern area that interior concave crescent shape is arranged of yellow micro mist feature
7, another fritter micro mist feature district of grey
8, area is 3mm
2-1000mm
2Black starch material color lump
10, diameter is the light brown bulky grain material of 2mm-5mm
11, diameter is the light brown particle of 2mm-5mm and to contain diameter be the A district that shape is surrounded in dispersion that the black powder of 0.01mm-0.8mm is formed through HTHP
12, diameter is the black bulky grain material of 2mm-5mm
103, look district, A district is by the district
104, look district, B district is by the district
110, grid die orifice mould
The specific embodiment
Below in conjunction with accompanying drawing and preferred embodiment, to its specific embodiment of color resin three-D pattern artificial slabstone, structure, feature and the effect thereof that foundation the present invention proposes, describe in detail as after.
Seeing also shown in Figure 1ly, is the imitative natural granite Baltic Brown pattern the 1st of color resin three-D pattern artificial slabstone of the present invention and the planar structure schematic diagram that the 2nd embodiment is of a size of the goods of 300mm * 300mm.The big look of the black district 11 that contains intensive white point 10, the expression diameter is the light brown particle of 2mm-5mm and to contain diameter be the A district that shape is surrounded in dispersion that the black powder of 0.01mm-0.8mm is formed through HTHP, and white point 10 represents that diameters are the light brown bulky grain material of 2mm-5mm; The B district, big pattern colour district that the nahlock shape pattern area that oblique line part 3 expression dark-brown powders form through HTHP is formed; Big stain 12 expression diameters are the black bulky grain material of 2mm-5mm.Thin portion amplifier section in the plane pattern shape look district, B district of the 2nd embodiment is replenished by Fig. 3.
Seeing also shown in Figure 2ly, is the structural representation of the local amplifier section in plane of look district boundary line of different color of goods the 1st embodiment of color resin three-D pattern artificial slabstone of the present invention.The pattern area of black part 11 is represented look district, black powder A district; The pattern area that pore part 3 is arranged of oblique line is represented the little part in look district, B district of the round shape pattern of dark-brown powder; Part between A district and the B district represents that the powder of dark-brown district 3 and black region 11 hands over the powder of two kinds of looks that mix and form to hand over mixed transition region 5 naturally naturally, pore wherein and middle stain represent that the friendship naturally of black powder and dark-brown powder mixes state, and it is 10: 50～30: 50 that the friendship of this transition region 5 mixes ratio; Big black bulk 12 expression diameters are the black particle of 2mm-5mm, and big white bulk 10 expression diameters reach the light brown particle of 2mm-5mm.
See also shown in Figure 3, be color resin three-D pattern artificial slabstone of the present invention goods the 2nd embodiment different color look district boundary line and the structural representation of the local amplifier section in plane of micro mist characteristic pattern is arranged.Be characterized in the little pattern of the mobile micro mist feature of having of polychrome being arranged in the inside of the local amplifier section of circular dark-brown pattern of Baltic Brown 30mm-80mm.Pattern area 11 expressions of black part are the look districts, A district of black, and the diameter of Da Bai group 10 expression light brown looks is the particle of 2mm-5mm; The pattern area that contains the pore part 3 expressions of oblique line are look districts, dark brown B district; Article two, the part between the dotted line represents that dark-brown district 3 and black chromatic color area 11 hand over the powder of two kinds of looks that mix and form to hand over the transition region 5 of mixing naturally naturally, and two kinds of mixed ratios of powders friendship of this transition region 5 are 10: 50～30: 50; The polygon-shaped sintering pattern area that interior concave crescent shape is arranged of the big yellow micro mist feature of right-angled intersection part pattern area 6 expressions; Another fritter micro mist feature district of black part sub-pattern district 7 expression grey; Little right-angled intersection part pattern area 8 expression areas are 3mm
2-1000mm
2Black starch material color lump; It is crossing with the right-angled intersection part pattern area 6 and pattern area 3 edges of crescent shape to be also shown in black pattern district 7, forms the mobile shape fine pattern of nature.The grey micro mist characteristic pattern district that little black block 7 expressions are surrounded by yellow micro mist characteristic pattern district 6.Big black bulk 12 is illustrated in the black particle that diameter in the dark-brown powder reaches 2mm-5mm.
See also shown in Figure 4ly, the thickness that is goods the 1st embodiment of color resin three-D pattern artificial slabstone of the present invention is the structural representation of the local amplifier section of section of look district boundary line of the different color of 15mm.The look district, A district of the pattern area 11 expression black of black part; The diameter of Da Bai group's 10 expression light browns is the particle of 2mm-5mm; The pattern area that contains the pore part 3 expressions of oblique line are look districts, dark brown B district; Article two, the part between the dotted line represents that dark-brown district 3 and black chromatic color area 11 hand over the powder of two kinds of looks that mix and form to hand over the transition region 5 of mixing naturally naturally, and two kinds of mixed ratios of powders friendship of this transition region 5 are 10: 50～30: 50; Big black bulk 12 is illustrated in the black particle that diameter in the dark-brown powder reaches 2mm-5mm.
See also shown in Figure 5, be color resin three-D pattern artificial slabstone of the present invention goods the 2nd embodiment different color look district boundary line and the thickness in micro mist characteristic pattern district is arranged is the structural representation of the goods part section amplifier section of 15mm.Be characterized in the little pattern of the mobile micro mist feature of having of polychrome being arranged in the inside of the local amplifier section of circular pattern of Baltic Brown 30mm-80mm.The look district, A district of the pattern area 11 expression black of black part; The diameter of Da Bai group's 10 expression light browns is the particle of 2mm-5mm; The pattern area that contains the pore part 3 expressions of oblique line are look districts, dark brown B district; Article two, the part between the dotted line represents that dark-brown district 3 and black chromatic color area 11 hand over the powder of two kinds of looks that mix and form to hand over the transition region 5 of mixing naturally naturally, and its two kinds of mixed ratios of powders friendship are 10: 50～30: 50; The polygon-shaped sintering pattern area that interior concave crescent shape is arranged of the big yellow micro mist feature of right-angled intersection part pattern area 6 expressions; Another fritter micro mist feature district of black part sub-pattern district 7 expression grey; Little right-angled intersection part pattern area 8 expression areas are 3mm
2-1000mm
2Black starch material color lump; It is crossing with the right-angled intersection part pattern area 6 and pattern area 3 edges of crescent shape to be also shown in black pattern district 7, forms the mobile shape fine pattern of nature.The grey micro mist characteristic pattern district that little black block 7 expressions are surrounded by yellow micro mist characteristic pattern district 6.Big black bulk 12 is illustrated in the black particle that diameter in the dark-brown powder reaches 2mm-5mm.
Seeing also shown in Figure 6ly, is the planar structure schematic diagram of the grid die orifice mould 110 of all essential steel matter of the goods the 1st of color resin three-D pattern artificial slabstone of the present invention and the 2nd embodiment.Black and wherein the white point subregion represent look district, A district the 1st embodiment or the contained various colorants of the 2nd embodiment, place colorant district and look district, A district in die orifice cavity and pass through to distinguish 103; Oblique line partly has a small amount of stain partly to represent look district, B district the 1st or the contained various colorants of the 2nd embodiment, places colorant district and look district, B district in the die orifice cavity by district 104; The outer white edge of black line is partly represented the head-down position on steel die orifice plane 110.
Seeing also shown in Figure 7ly, is the pattern position schematic diagram relatively of six goods in the same a collection of goods of the made same a collection of grain density proportioning ratio of the same die orifice of the goods the 1st of color resin three-D pattern artificial slabstone of the present invention and the 2nd embodiment.As seen, separately toroidal pattern area in each piece pattern has the pattern position and the shape that surpass more than 6 to coincide.
Embodiment 1
Now preparation method and the manufacturing process thereof with color resin three-D pattern artificial slabstone the 1st embodiment product of the present invention specifies as follows:
The first step, make a kind of sectional thickness consistent and be 20mm, die orifice hem width and be the steel matter die orifice mould that 2mm, housing be of a size of 305mm * 305mm (see Fig. 6 110 shown in), and its circular little pattern area 80% above diameter is all in 15mm-50mm with the differentiation of all kinds boundary line of required predetermined pattern.
In second step, prepare to contain calcium carbonate raw meal a that diameter is 0.01mm-0.8mm and black, dark-brown, three kinds of painted thermoplastic acrylic resin powder b of light brown.Every kind of the resin-oatmeal of three kinds of looks of b got identical 6 kilograms of equal portions be mixed into three parts of 10 kilograms every kind with 60: 40, and it is standby as compound of all kinds fully to mix the back as a material of portion and three parts every part 4 kilograms.
The 3rd step, adopt conventional electrical heating press technology the 100-180 degree the temperature in a black compound and a light brown compound part, adopt 600 kilograms of pressure to be pressed into the thin plate of 5mm respectively, smashing after the cooling sieves makes black that diameter is 2mm-5mm and the light brown particle is standby respectively.
The 4th step, prepare two containers of A, B, get the raw materials ready in following ratio:
Is the light brown diameter of the black mixed powder of 70% weight and 30% weight the container A of packing into after the 2mm-5mm particulate material mixes again; Is the black diameter of 15% weight to pack into after the dark-brown compound of the particulate material of 2mm-5mm and 85% weight mixes again in the container B.
The 5th step, empty 305mm in preparing as shown in Figure 8 * 305mm size but thickness are (as shown in Figure 8) in the square box of steel matter of 23mm, mixed in the container A contained the light brown particle and the black toner that mixes is inserted by the cavity of pattern die orifice shown in Figure 6 and inserted in the A district, district, fill, adorn flat; Mixed in the container B contained black particle and dark-brown mixed powder insert by the cavity of pattern die orifice shown in Figure 6 and insert in the B district, district, fill, adorn flat.
The 6th step, steel mould shown in Figure 6 is taken out, in the square box of steel, manifested the planar coloured pattern as shown in Figure 1 of zones of different this moment.
The 7th step, pressure cell plane pressing plate shown in Fig. 8 annex 1 is put in the top of pressure cell, be pressed on the powder of all kinds and particle of existing planar coloured pattern, adopt and progressively be pressurized to 1500 kilograms, and through vacuumizing 10 minutes technology, the temperature and the pressurize that are heated to 100-180 ℃ at last obtained goods in 10 minutes.
In the 8th step, the polishing of goods top layer, polishing has just obtained complete product.
Those skilled in the art can know, if the pressure heating box is accomplished 3 meters long 1 meter wide, adopt bigger pressure and stronger firing equipment, can produce the goods of bigger plate too, and, if make to become the thickness of 1m, also can cut into the sheet material of 40-50 piece 20mm thickness at the in-plane of pattern, polish respectively again, polish, obtain big slab products.
Embodiment 2
The preparation method and the manufacturing process thereof of color resin three-D pattern artificial slabstone the 2nd embodiment product of the present invention specify as follows:
The first step, making a kind of sectional thickness consistent with the differentiation of all kinds boundary line of required predetermined pattern is that 20mm, die orifice hem width are the steel matter die orifice mould (as shown in Figure 6) that 2mm, housing are of a size of 305mm * 305mm, and its circular little pattern area 80% above diameter is 15mm-50mm.
In second step, prepare to contain the calcium carbonate raw meal a and black, dark brown, shallow palm fibre, ash, pale brown five kinds of painted thermoplastic acrylic resin powder b that diameter is 0.01mm-0.8mm.Every kind of the resin-oatmeal of five kinds of looks of b got identical 6 kilograms of equal portions be mixed into five parts of 10 kilograms every part with 60: 40, and it is standby as compound of all kinds fully to mix the back as a material of portion and five parts every part 4 kilograms.
The 3rd step, adopt conventional electrical heating press technology the 100-180 degree the temperature in a black compound and a light brown compound part, adopt 600 kilograms of pressure to be pressed into the thin plate of 5mm respectively, smashing after the cooling sieves makes black that diameter is 2mm-5mm and the light brown particle is standby respectively.
The 4th step was the light brown diameter of the black mixed powder of 70% weight and 30% weight the container A of packing into after the 2mm-5mm particulate material mixes again;
65% dark brown yellow mixed powder, 15% black particle, add gray powder and pale brown toner and be equipped with 10% respectively, and to gray powder with pale brown toner adds the moisture content of 5%-10% respectively or add the acryloid cement of 1%-11% in water, these four kinds of materials are mixed, wherein gray powder and pale brown toner are mobile bad in mixing, have agglomerating or draw into polygon or the oblong state, be difficult for the same with particle even mixing, with the favourable meniscate little pattern of concavity that has the interlocking of micro mist feature with the dark-brown powder.These four kinds of compounds are packed in the container B.
The 5th step, empty 305mm in preparing as shown in Figure 8 * 305mm size but thickness are (as shown in Figure 8) in the square box of steel matter of 23mm, mixed in the container A contained the light brown particle and the black toner that mixes is inserted by the cavity of pattern die orifice shown in Figure 6 and inserted in the A district, district, fill, adorn flat; Mixed in the container B contained black particle and dark-brown mixed powder and mobile bad grey and pale brown toner material mix, insert by the cavity of pattern die orifice shown in Figure 6 and insert in the B district, district, fill, adorn flat.
The 6th step, steel mould shown in Figure 6 is taken out, in the square box of as shown in Figure 8 steel, manifested the planar coloured pattern shown in Fig. 1,3 of zones of different at this moment.
The 7th step, pressure cell plane pressing plate shown in Fig. 8 annex 1 is put in the top of pressure cell, be pressed on the powder of all kinds and particle of existing planar coloured pattern, adopt and progressively be pressurized to 1500 kilograms, and through vacuumizing 10 minutes technology, the temperature and the pressurize that are heated to 100-180 ℃ at last obtained goods in 10 minutes.
In the 8th step, the polishing of goods top layer, polishing has just obtained complete product.
Those skilled in the art can know, if the pressure heating box is accomplished 3 meters long 1 meter wide, adopt bigger pressure and stronger firing equipment, can produce the goods of bigger plate too, and, if make to become the thickness of 1m, also can cut into the sheet material of 40-50 piece 20mm thickness at the in-plane of pattern, polish respectively again, polish, obtain big slab products.
The above, only be for preferable preferred embodiment of the present invention is described, yet it is not to be limitation of the present invention, any personnel that are familiar with this technology may utilize the technology contents of above-mentioned prompting to be changed or be modified to the equivalent embodiment of equivalent variations, every content that does not break away from technical solution of the present invention, to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention according to technical spirit of the present invention.
Claims (10)
1, a kind of color resin three-D pattern artificial slabstone, it contains organic resin material, it is characterized in that: this sheet material has by 2-10 kind different color or same color but the different pattern area of color and luster weight; Have at least the gross area of the area of the pattern of forming by 2 kinds of colors more than one or to account for the 10%-90% of whole sheet material area in this pattern area, have the 90%-100% of a kind of thickness of powder look in the area of the 50%-100% on above-mentioned pattern area surface at least for this sheet metal thickness; The top layer of this sheet material have 100-100000, area is pattern area or the particle by resin and mineral-type powder constituent of 4mm2-3000mm2; 80% the pattern area diameter that has a class pattern area at least is in 15mm-50mm.
2, color resin three-D pattern artificial slabstone according to claim 1, the inorganic powder that it is characterized in that containing in the wherein said resin material diameter and be 0.01mm-1.5mm is as inserts.
3, color resin three-D pattern artificial slabstone according to claim 2, it is characterized in that containing in the wherein said resin material inserts is that diameter is marble powder or granite powder or titanium dioxide class or the Paris white of 0.01mm-1.5mm.
4, color resin three-D pattern artificial slabstone according to claim 1, it is characterized in that having in the wherein said pattern area 30-3000, diameter is the pattern area of 30mm-50mm.
5, color resin three-D pattern artificial slabstone according to claim 1 is characterized in that containing in the wherein said color resin three-D pattern artificial slabstone 100-100000, diameter is the color grains of 2mm-10mm.
6, color resin three-D pattern artificial slabstone according to claim 1 is characterized in that wherein said resin material is thermoplastic resin and/or interlink molecular structure resin.
7, color resin three-D pattern artificial slabstone according to claim 1 is characterized in that wherein said resin material is acrylic acid or polyester or polyformaldehyde or acrylonitrile-butadiene-phenylethylene (ABS) or epoxy resin or polypropylene or polyethylene.
8, color resin three-D pattern artificial slabstone according to claim 1 is characterized in that containing in the wherein said pattern area color material particle of 1-5 kind diameter at 2mm-20mm, and the surface area of this particle accounts for the 2%-80% of pattern area surface area.
9, color resin three-D pattern artificial slabstone according to claim 1, the table plane that it is characterized in that wherein said color resin three-D pattern artificial slabstone is the table plane of not polishing, or the table plane of polishing.
10, color resin three-D pattern artificial slabstone according to claim 1, the overall geometry that it is characterized in that wherein said color resin three-D pattern artificial slabstone are surface plate shape, cylindrical, cambered plate shape, partial circle cylindricality, sphere, hemispherical, awl circle shape hemispherical or justify the shape that shape combines type by plane and half cone.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200310124225XA CN1301199C (en) | 2003-12-31 | 2003-12-31 | Coloured resin three dimensional pattern artificial stone slab material |
| PCT/CN2004/001574 WO2005063503A1 (en) | 2003-12-31 | 2004-12-30 | Three-dimensional pattern synthetic stone material comprising colored resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200310124225XA CN1301199C (en) | 2003-12-31 | 2003-12-31 | Coloured resin three dimensional pattern artificial stone slab material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1555984A CN1555984A (en) | 2004-12-22 |
| CN1301199C true CN1301199C (en) | 2007-02-21 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200310124225XA Expired - Fee Related CN1301199C (en) | 2003-12-31 | 2003-12-31 | Coloured resin three dimensional pattern artificial stone slab material |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1301199C (en) |
| WO (1) | WO2005063503A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11845235B2 (en) | 2014-08-19 | 2023-12-19 | Cambria Company Llc | Synthetic molded slabs, and systems and methods related thereto |
| US11845198B2 (en) | 2015-01-30 | 2023-12-19 | Cambria Company Llc | Processed slabs, and systems and methods related thereto |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100888334B1 (en) * | 2007-01-26 | 2009-03-12 | 주식회사 엘지화학 | Artificial marble having various designs and process for preparing the same |
| CN101850687A (en) * | 2009-12-14 | 2010-10-06 | 利奥纸袋(1982)有限公司 | Method for preparing stone-imitation decorative veneer with stereoeffect |
| CN109291210B (en) * | 2018-09-20 | 2020-04-28 | 重庆大学 | Multi-scale three-dimensional artificial stone preparation method |
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|---|---|---|---|---|
| US5364672A (en) * | 1988-05-27 | 1994-11-15 | Schultze Kraft Andreas | Artificial stones |
| JPH11347989A (en) * | 1998-04-23 | 1999-12-21 | Premark Rwp Holdings Inc | Manufacture of solid surface sheet, and solid surface material manufactured thereby |
| JP2001080945A (en) * | 1999-09-08 | 2001-03-27 | Nippon Shokubai Co Ltd | Artificial slate |
| CN1288826A (en) * | 2000-05-26 | 2001-03-28 | 杨德宁 | Imitation granite board with three-dimensional color grains |
| CN1339363A (en) * | 2001-09-10 | 2002-03-13 | 杨德宁 | Three-dimensional colour patteru plate sintered with porcelain powder |
| CN1357462A (en) * | 2000-12-14 | 2002-07-10 | 吕明良 | Scagliola |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5500259A (en) * | 1990-11-05 | 1996-03-19 | Kohjin Co., Ltd. | Artificial granite solid material |
| CN1180010C (en) * | 2001-09-10 | 2004-12-15 | 杨德宁 | Stone-like slab with 3D colour pattern composed of uniform particles |
| CN1204009C (en) * | 2001-09-10 | 2005-06-01 | 杨德宁 | Three-dimensional pattern slip casting products with porcelain colour even particle blank |
-
2003
- 2003-12-31 CN CNB200310124225XA patent/CN1301199C/en not_active Expired - Fee Related
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2004
- 2004-12-30 WO PCT/CN2004/001574 patent/WO2005063503A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5364672A (en) * | 1988-05-27 | 1994-11-15 | Schultze Kraft Andreas | Artificial stones |
| JPH11347989A (en) * | 1998-04-23 | 1999-12-21 | Premark Rwp Holdings Inc | Manufacture of solid surface sheet, and solid surface material manufactured thereby |
| JP2001080945A (en) * | 1999-09-08 | 2001-03-27 | Nippon Shokubai Co Ltd | Artificial slate |
| CN1288826A (en) * | 2000-05-26 | 2001-03-28 | 杨德宁 | Imitation granite board with three-dimensional color grains |
| CN1357462A (en) * | 2000-12-14 | 2002-07-10 | 吕明良 | Scagliola |
| CN1339363A (en) * | 2001-09-10 | 2002-03-13 | 杨德宁 | Three-dimensional colour patteru plate sintered with porcelain powder |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11845235B2 (en) | 2014-08-19 | 2023-12-19 | Cambria Company Llc | Synthetic molded slabs, and systems and methods related thereto |
| US11845198B2 (en) | 2015-01-30 | 2023-12-19 | Cambria Company Llc | Processed slabs, and systems and methods related thereto |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005063503A1 (en) | 2005-07-14 |
| CN1555984A (en) | 2004-12-22 |
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