CN102775092B - Bowlder-imitated artificial stone plate and manufacturing method thereof - Google Patents
Bowlder-imitated artificial stone plate and manufacturing method thereof Download PDFInfo
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- CN102775092B CN102775092B CN201210133982.2A CN201210133982A CN102775092B CN 102775092 B CN102775092 B CN 102775092B CN 201210133982 A CN201210133982 A CN 201210133982A CN 102775092 B CN102775092 B CN 102775092B
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Abstract
The invention discloses a bowlder-imitated artificial stone plate and a manufacturing method thereof. The artificial stone plate comprises the following components in percentage by mass: 28-30% of unsaturated polyester resin, 40-65% of aluminum hydroxide, 5-30% of shells crushed into objects with diameters of 1-5 cm, 0.02-0.04% of cobalt naphthenate, 0.03-0.05% of methyl ethyl ketone peroxide and 1-2% of pigment paste. The bowlder-imitated artificial stone plate disclosed by the invention has the advantages that: the bowlder-imitated artificial stone plate is environmental-friendly, non-toxic and non-radiative; products are diversiform in color, bright in color and translucent; and the bowlder-imitated artificial stone plate can be produced according to various needs of customers, so that the stone plate is agile and changeable and convenient to decorate and collocate, thereby creating colorful life spaces. Compared with ceramic tiles, the product is light in weight and can be arbitrarily cut and processed; and the bowlder-imitated artificial stone plate has various thicknesses, so that the applicable range of the stone plate is wider than that of ceramic tiles in decoration. The production method disclosed by the invention is simple in process and safe and convenient in production, and a produced artificial stone plate has a smooth and non-porous surface, and a situation that dirt infiltrates into the plate does not occur in the process of application, so that the application of the artificial stone plate is cleaner and more sanitary.
Description
Technical field
The present invention relates to a kind of jade artificial stone plate and preparation method thereof technical field.
Background technology
Lithotome is mainly divided into two kinds: marble and granite.In general, every veined, be called " marble "; The stigma of take is master, is called " granite ".From narrowly, marble refers to the stone material that Dali produces.In fact, now all parts of the country have few stone be Dali out.Both also can distinguish from geology concept.Granite is volcanic rock, is also acidic crystallization plutonite, is the widest a kind of rock that distributes in volcanic rock, feldspar, quartz and mica, consists of, and rock matter is hard closely knit.Its composition be take silicon-dioxide as main, accounts for 65%～75%.So-called volcanic rock is exactly the rock that underground magma or the volcano lava condensation-crystallization of spraying and spoiling over forms.The content of silicon-dioxide in volcanic rock is, the character of feldspar and content thereof have determined the character of stone material.When the content of silicon-dioxide is greater than 65%, just belong to persilicic rock, when the essential mineral such as potash feldspar, plagioclase, quartz forms crystal in this rock, be material shape structure, be just called granite.And marble is the metamorphosed rock that in the earth's crust, original rock forms through High Temperature High Pressure effect in the earth's crust.The endogenic process of the earth's crust is impelled the variation of each original rocks generation matter, and the structure of original rocks, structure and mineralogical composition change.The new rock forming through qualitative change is called metamorphosed rock.
Because there is pore on lithotome surface, thus aspect resistant relative mistake some, generally in source mill, all can process on its surface.In interior decoration, the applicable use marbles such as televisor table top, windowsill, flooring.And threshold, cabinet table surface, outdoor ground are just applicable to using granite.Wherein the sight of cabinet platform is to use dark granite.The lithotome of selling on the market now, part color and luster is through manual handling, and these stone materials are generally used to manifest its true appearance half a year to one year.Be to be apparent that present Dark Green on the market, a lot of all dyeing forms, and is not real primary colors.Be noted that in addition back side grid, occur that this situation has two kinds: 1. stone material itself is more crisp, must add grid, for example Cream Marfil.2. use inferior materials and turn out substandard goods, the thickness of these stone materials is by skiving, and insufficient strength, so need add network.
Artificial stone-like material be take unsaturated polyester resin as cakingagent, be equipped with the inorganics powders such as natural marble or calcite, rhombspar, silica sand, glass powder, and appropriate fire retardant, color etc., through method forming and hardenings such as batching mixing, porcelain casting, vibrocompression, extruding, make.Artificial stone-like material finds out according to the problem that lithotome is actual in using, and it is having significant progress aspect protection against the tide, acid-proof, high temperature resistant, piecing together property.But during artificial stone-like material's shortcoming, rostone general nature is obviously not enough, texture is relatively false, thus be generally used to cabinet etc. for the higher place of real requirement, and in some severe environment, such as kitchen, toilet etc.; Ornamental place is emphasized on windowsill, ground etc.Another shortcoming is.Because the manufacture craft of rostone is widely different, performance, feature are also not quite identical.And a lot of domestic rostones obviously can not be supported this floating of professionals, more polishing is more rotten.So produce qualified artificial stone-like material and rational manufacture craft, ready-made is the requirements that people urgently wish.
Existing a kind of application number is 03118884.2 and is called < < artificial stone plate's formula and the Chinese invention patent of production technique > >, disclose a kind of structure, this invention is characterised in that: described artificial stone plate's raw material is comprised of unsaturated polyester and mica powder substantially.The problem such as this artificial stone plate can effectively solve distortion that traditional artificial stone plate occurs in use for some time, fade, also has exquisite decorative pattern and abundant color, is good building materials and decorative materials.But its shortcoming is that formula is unreasonable, and the wood-based plate surface of production has pore, and slickness is inadequate.So in use just there will be dirt to penetrate into the phenomenon of sheet material, easily diseaseful growing, is not easy to clean.Described its formula needs to improve with making method.
Summary of the invention
First technical problem to be solved by this invention is to provide a kind of even density from the inside to surface, solid one, smooth surface impunctate and the artificial stone plate who in use there will not be dirt to penetrate into for above-mentioned prior art present situation.
Second technical problem to be solved by this invention is to provide a kind of technique simple for above-mentioned prior art present situation, make safe ready, the artificial stone plate of making has smooth surface impunctate and in use there will not be dirt to penetrate into the artificial stone plate's making method in entering plate.
The present invention solves the technical scheme that above-mentioned first technical problem adopts: this jade artificial stone plate, it is characterized in that: described jade artificial stone plate's formula consists of: unsaturated polyester resin 28%～30.64%, aluminium hydroxide 69%～71.64%, cobalt naphthenate 0.02%～0.03%, methylethyl ketone peroxide 0.02%～0.03%, pigment paste 0.1%～0.3%, above-mentioned is mass percent.
As improvement, described pigment paste is preferably particle fineness and is less than the pigment that 30um is made by grinding by saturated polyester resin and pigment powder.
As improvement, described unsaturated polyester resin is preferably selected as the unsaturated polyester resin of adjacent benzene-series.
The present invention solves the technical scheme that above-mentioned second technical problem adopt: this jade artificial stone plate's making method, is characterized in that: the step of described making method is as follows:
One, according to above-mentioned formula, be ready to material;
Two, first on the inwall of mould, wax, standby;
Three, will in unsaturated polyester resin, add cobalt naphthenate, and stir;
Four, then add aluminium hydroxide, pigment paste, then stir;
Five, add methylethyl ketone peroxide again, after stirring, miscellany is slowly poured in mould, then mould is advanced in vacuum forming case, vibrations limit, limit is evacuated to 3～5 minutes;
Six, then mould is taken out from vacuum forming case, under state of nature, solidify 2～3 hours;
Seven, again the sheet material after solidifying is taken out from mould to sizing;
Eight, again that the slabstone of sizing is smooth fixed thick through grinder, be finished product jade artificial stone plate.
As improvement, in described step 3, described stirring can preferably be stirred by electric hand drill, and churning time is 3 to 4 minutes.
Improve again described mould Xuan Ze Wei Gui sealing rubber die.
Improve, the preparation method of Suo Shu Gui sealing rubber die is: according to required pattern, make by hand the model of a solid, and polish smooth, then at stereoscopic model, by glasscloth, gypsum and silica gel, turn over mould and go out silica gel mould again.
Compared with prior art, the utility model has the advantage of: jade parquets is selected polymer composite, through modern production technique, be made that environmental protection, nontoxic, radiationless property are environment-friendly building materials products of new generation.
This product pattern is various, bright in luster, glittering and translucent, can go to manufacture according to client's various requirement, flexible and changeable, and convenient decoration arranged in pairs or groups, and creates colourful living space.
With respect to ceramic tile, this product weight is light, and moulding property is strong, arbitrarily cutting processing; Thickness all can, light transmission is strong, so more extensive than ceramic tile in the application of decorating.
Making method technique of the present invention is simple, makes safe ready, and the artificial stone plate of making has smooth surface impunctate and in use there will not be dirt to penetrate in entering plate, uses more sanitation and hygiene.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail;
Embodiment mono-, the jade artificial stone plate of the present embodiment, described jade artificial stone plate's formula consists of: the unsaturated polyester resin 28% of adjacent benzene-series, aluminium hydroxide 71.64%, cobalt naphthenate 0.03%, methylethyl ketone peroxide 0.03%, particle fineness are less than the pigment paste 0.3% that 30um is made by grinding by saturated polyester resin and pigment powder, and above-mentioned is mass percent.
The jade artificial stone plate's of the present embodiment making method, the step of described making method is as follows:
One, according to above-mentioned formula, be ready to material;
Two, first on the inwall of mould, wax, standby;
Three, will in unsaturated polyester resin, add cobalt naphthenate, and use by electric hand drill and stir;
Four, then add aluminium hydroxide, pigment paste, then stir;
Five, add methylethyl ketone peroxide again, after stirring, by the slow Gui of the Daoing Ru sealing rubber die of miscellany, then mould is advanced in vacuum forming case, vibrations limit, limit is evacuated to 3～5 minutes; The preparation method of Suo Shu Gui sealing rubber die is: according to required pattern, make by hand the model of a solid, and polish smooth, then at stereoscopic model, by glasscloth, gypsum and silica gel, turn over mould and go out silica gel mould;
Six, then mould is taken out from vacuum forming case, under state of nature, solidify 2～3 hours;
Seven, again the sheet material after solidifying is taken out from mould to sizing;
Eight, again that the slabstone of sizing is smooth fixed thick through grinder, be finished product jade artificial stone plate.
Embodiment bis-, the jade artificial stone plate of the present embodiment, described jade artificial stone plate's formula consists of: the unsaturated polyester resin 29% of adjacent benzene-series, aluminium hydroxide 70.64%, cobalt naphthenate 0.03%, methylethyl ketone peroxide 0.03%, particle fineness are less than the pigment paste 0.3% that 30um is made by grinding by saturated polyester resin and pigment powder, and above-mentioned is mass percent.
The jade artificial stone plate's of the present embodiment making method, the step of described making method is as follows:
One, according to above-mentioned formula, be ready to material;
Two, first on the inwall of mould, wax, standby;
Three, will in unsaturated polyester resin, add cobalt naphthenate, and use by electric hand drill and stir;
Four, then add aluminium hydroxide, pigment paste, then stir;
Five, add methylethyl ketone peroxide again, after stirring, by the slow Gui of the Daoing Ru sealing rubber die of miscellany, then mould is advanced in vacuum forming case, vibrations limit, limit is evacuated to 3～5 minutes; The preparation method of Suo Shu Gui sealing rubber die is: according to required pattern, make by hand the model of a solid, and polish smooth, then at stereoscopic model, by glasscloth, gypsum and silica gel, turn over mould and go out silica gel mould;
Six, then mould is taken out from vacuum forming case, under state of nature, solidify 2～3 hours;
Seven, again the sheet material after solidifying is taken out from mould to sizing;
Eight, again that the slabstone of sizing is smooth fixed thick through grinder, be finished product jade artificial stone plate.
Embodiment tri-, the jade artificial stone plate of the present embodiment, described jade artificial stone plate's formula consists of: the unsaturated polyester resin 30% of adjacent benzene-series, aluminium hydroxide 69.86%, cobalt naphthenate 0.02%, methylethyl ketone peroxide 0.02%, particle fineness are less than the pigment paste 0.1% that 30um is made by grinding by saturated polyester resin and pigment powder, and above-mentioned is mass percent.
The jade artificial stone plate's of the present embodiment making method, the step of described making method is as follows:
One, according to above-mentioned formula, be ready to material;
Two, first on the inwall of mould, wax, standby;
Three, will in unsaturated polyester resin, add cobalt naphthenate, and use by electric hand drill and stir;
Four, then add aluminium hydroxide, pigment paste, then stir;
Five, add methylethyl ketone peroxide again, after stirring, by the slow Gui of the Daoing Ru sealing rubber die of miscellany, then mould is advanced in vacuum forming case, vibrations limit, limit is evacuated to 3～5 minutes; The preparation method of Suo Shu Gui sealing rubber die is: according to required pattern, make by hand the model of a solid, and polish smooth, then at stereoscopic model, by glasscloth, gypsum and silica gel, turn over mould and go out silica gel mould;
Six, then mould is taken out from vacuum forming case, under state of nature, solidify 2～3 hours;
Seven, again the sheet material after solidifying is taken out from mould to sizing;
Eight, again that the slabstone of sizing is smooth fixed thick through grinder, be finished product jade artificial stone plate.
Claims (7)
1. a jade artificial stone plate, it is characterized in that: described jade artificial stone plate's formula consists of: unsaturated polyester resin 28%～30.64%, aluminium hydroxide 69%～71.64%, cobalt naphthenate 0.02%～0.03%, methylethyl ketone peroxide 0.02%～0.03%, pigment paste 0.1%～0.3%, above-mentioned is mass percent.
2. jade artificial stone plate according to claim 1, is characterized in that: described pigment paste is that particle fineness is less than the pigment that 30 μ m are made by grinding by saturated polyester resin and pigment powder.
3. jade artificial stone plate according to claim 2, is characterized in that: the unsaturated polyester resin that described unsaturated polyester resin is adjacent benzene-series.
4. arbitrary described jade artificial stone plate's a making method in claims 1 to 3, is characterized in that: the step of described making method is as follows:
One, according to above-mentioned formula, be ready to material;
Two, first on the inwall of mould, wax, standby;
Three, will in unsaturated polyester resin, add cobalt naphthenate, and stir;
Four, then add aluminium hydroxide, pigment paste, then stir;
Five, add methylethyl ketone peroxide again, after stirring, miscellany is slowly poured in mould, then mould is advanced in vacuum forming case, vibrations limit, limit is evacuated to 3～5 minutes;
Six, then mould is taken out from vacuum forming case, under state of nature, solidify 2～3 hours;
Seven, again the sheet material after solidifying is taken out from mould to sizing;
Eight, again that the slabstone of sizing is smooth fixed thick through grinder, be finished product jade artificial stone plate.
5. jade artificial stone plate's according to claim 4 making method, is characterized in that: in described step 3, described stirring is stirred by electric hand drill, and churning time is 3 to 4 minutes.
6. jade artificial stone plate's according to claim 4 making method, is characterized in that: described mould is silica gel mould.
7. jade artificial stone plate's according to claim 6 making method, it is characterized in that: the preparation method of described silica gel mould is: according to required pattern, make by hand the model of a solid, and polish smooth, then at stereoscopic model, by glasscloth, gypsum and silica gel, turn over mould and go out silica gel mould.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210133982.2A CN102775092B (en) | 2012-04-28 | 2012-04-28 | Bowlder-imitated artificial stone plate and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210133982.2A CN102775092B (en) | 2012-04-28 | 2012-04-28 | Bowlder-imitated artificial stone plate and manufacturing method thereof |
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| CN102775092A CN102775092A (en) | 2012-11-14 |
| CN102775092B true CN102775092B (en) | 2014-04-16 |
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Cited By (1)
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|---|---|---|---|---|
| CN106673498A (en) * | 2016-12-01 | 2017-05-17 | 深圳中凝科技有限公司 | Aerogel heat insulation artificial stone plate and preparation method thereof |
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| CN103085162B (en) * | 2013-01-30 | 2014-10-29 | 广东道氏技术股份有限公司 | Ceramic tile mould preparation method |
| CN103709697B (en) * | 2013-12-17 | 2016-04-13 | 成都顺美国际贸易有限公司 | The production technique of fibre composite tea table table top and desktop |
| CN104802279A (en) * | 2014-01-23 | 2015-07-29 | 吴文鸿 | Method for preparing an artificial stone with decorative patterns |
| CN104692711B (en) * | 2015-02-09 | 2017-01-11 | 陈真全 | Artificial jade spar material and preparation method thereof |
| CN106082934A (en) * | 2016-06-12 | 2016-11-09 | 安徽广燕新材料科技有限责任公司 | A kind of preparation method of the artificial stone with anion function |
| CN107311520A (en) * | 2017-07-29 | 2017-11-03 | 南通戈雅石业有限公司 | A kind of bionical marble formula |
| CN107459289A (en) * | 2017-07-29 | 2017-12-12 | 南通戈雅石业有限公司 | A kind of marble formula |
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| CN101003183B (en) * | 2006-01-20 | 2010-09-08 | 金国华 | Method for fabricating artificial stone, and artificial stone with luminescence function, and products |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106673498A (en) * | 2016-12-01 | 2017-05-17 | 深圳中凝科技有限公司 | Aerogel heat insulation artificial stone plate and preparation method thereof |
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