CN102775092A - Bowlder-imitated artificial stone plate and manufacturing method thereof - Google Patents

Bowlder-imitated artificial stone plate and manufacturing method thereof Download PDF

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Publication number
CN102775092A
CN102775092A CN2012101339822A CN201210133982A CN102775092A CN 102775092 A CN102775092 A CN 102775092A CN 2012101339822 A CN2012101339822 A CN 2012101339822A CN 201210133982 A CN201210133982 A CN 201210133982A CN 102775092 A CN102775092 A CN 102775092A
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Prior art keywords
stone plate
artificial stone
slabstone
bowlder
polyester resin
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CN2012101339822A
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CN102775092B (en
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李铮标
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ZHOUSHAN OUPOSHI ENVIRONMENTAL PROTECTION TECHNOLOGY DEVELOPMENT CO LTD
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ZHOUSHAN OUPOSHI ENVIRONMENTAL PROTECTION TECHNOLOGY DEVELOPMENT CO LTD
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Priority to CN201210133982.2A priority Critical patent/CN102775092B/en
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Abstract

The invention discloses a bowlder-imitated artificial stone plate and a manufacturing method thereof. The artificial stone plate comprises the following components in percentage by mass: 28-30% of unsaturated polyester resin, 40-65% of aluminum hydroxide, 5-30% of shells crushed into objects with diameters of 1-5 cm, 0.02-0.04% of cobalt naphthenate, 0.03-0.05% of methyl ethyl ketone peroxide and 1-2% of pigment paste. The bowlder-imitated artificial stone plate disclosed by the invention has the advantages that: the bowlder-imitated artificial stone plate is environmental-friendly, non-toxic and non-radiative; products are diversiform in color, bright in color and translucent; and the bowlder-imitated artificial stone plate can be produced according to various needs of customers, so that the stone plate is agile and changeable and convenient to decorate and collocate, thereby creating colorful life spaces. Compared with ceramic tiles, the product is light in weight and can be arbitrarily cut and processed; and the bowlder-imitated artificial stone plate has various thicknesses, so that the applicable range of the stone plate is wider than that of ceramic tiles in decoration. The production method disclosed by the invention is simple in process and safe and convenient in production, and a produced artificial stone plate has a smooth and non-porous surface, and a situation that dirt infiltrates into the plate does not occur in the process of application, so that the application of the artificial stone plate is cleaner and more sanitary.

Description

A kind of imitative jade worker makes slabstone and preparation method thereof
Technical field
The present invention relates to a kind of imitative jade worker and make slabstone and preparation method thereof technical field.
Background technology
Lithotome mainly is divided into two kinds: marble and granite.In general, every veined, be called " marble "; With the stigma is main, is called " granite ".On narrow sense, marble refers to the stone material that the Dali produces.In fact, now to have few stone be to come out in Dali in all parts of the country.Both also can distinguish from the geology notion.Granite is volcanic rock, also is the acidic crystallization plutonite, is the widest a kind of rock that distributes in the volcanic rock, is made up of feldspar, quartz and mica, and rock matter is hard closely knit.Its composition is main with silicon-dioxide, accounts for 65%~75%.So-called volcanic rock is exactly the rock that underground magma or the volcano lava condensation-crystallization of spraying and spoiling over forms.The content of silicon-dioxide, felspathic character and content thereof have determined the character of stone material in the volcanic rock.When the content of silicon-dioxide greater than 65%, just belong to persilicic rock, when essential minerals such as potash feldspar, plagioclase, quartz form crystal in this rock, be material shape structure, just be called granite.And marble is the metamorphosed rock that original rock forms through HTHP effect in the earth's crust in the earth's crust.The endogenic process of the earth's crust is impelled the variation of each original rocks generation matter, and promptly the structure of original rocks, structure and mineralogical composition change.The new rock that forms through qualitative change is called metamorphosed rock.
Because there is pore on the lithotome surface, thus aspect resistant relative mistake some, generally all can handle on its surface in source mill.In interior decoration, suitable use marbles such as televisor table top, windowsill, flooring.And threshold, cabinet table top, outdoor ground just are fit to use granite.Wherein the cabinet platform is seen and is to use dark granite.The lithotome of selling on the market now, part color and luster be through manual handling, and these stone materials generally use year will manifest its true appearance half a year to one.Be to be apparent that present Dark Green on the market, a lot of all dyeing form, and are not real primary colors.Be noted that back side grid in addition, this situation occurring has two kinds: 1. stone material itself is more crisp, must add grid, for example Cream Marfil.2. use inferior materials and turn out substandard goods, the thickness of these stone materials is by skiving, and insufficient strength be so need add network.
The artificial stone-like material is to be cakingagent with the unsaturated polyester resin; Be equipped with inorganics powders such as natural marble or calcite, rhombspar, silica sand, glass powder; And an amount of fire retardant, color etc., process through method forming and hardenings such as batch mixes, porcelain casting, vibrocompression, extruding.The artificial stone-like material finds out according to the problem that lithotome is actual in using, and it is all having significant progress aspect protection against the tide, acid-proof, high temperature resistant, the piecing together property.But during artificial stone-like material's shortcoming, rostone general nature property is obviously not enough, and texture is relatively false, thus generally be used to the place that cabinet etc. is had relatively high expectations for practicality, and in the certain adverse environment, for example kitchen, toilet etc.; Ornamental place is stressed on windowsill, ground etc.Another shortcoming is.Because the manufacture craft of rostone is widely different, performance, characteristic are also not quite identical.And a lot of home-made rostones obviously can not be supported this floating of professionals, and polishing is mashed more more.So produce qualified artificial stone-like material and rational manufacture craft, ready-made is the requirements that people urgently hope.
Existing a kind of application number is 03118884.2 and is called the Chinese invention patent of " artificial stone plate's prescription and production technique ", discloses a kind of structure, and this invention is characterised in that: described artificial stone plate's raw material is made up of unsaturated polyester and mica powder basically.Problems such as this artificial stone plate can effectively solve distortion that traditional artificial stone plate occurs in use for some time, fade also have exquisite decorative pattern and abundant colors, are good building materials and decorative materials.But its shortcoming is that prescription is unreasonable, and the wood-based plate surface of production has pore, and slickness is not enough.So in use the phenomenon that dirt penetrates into sheet material will occur, be easy to generate growing of bacterium, be not easy to cleaning.Said its prescription awaits to improve with making method.
Summary of the invention
First technical problem to be solved by this invention is to above-mentioned prior art present situation and provide a kind of density from the inside to surface even, solid one, smooth surface impunctate and in use the artificial stone plate that dirt penetrates into can not occur.
Second technical problem to be solved by this invention is to provide a kind of technology simple to above-mentioned prior art present situation; Make safe ready, the artificial stone plate of making has the smooth surface impunctate and dirt in use can not occur and penetrates into the artificial stone plate's making method in the entering plate.
The present invention solves the technical scheme that above-mentioned first technical problem adopts: this imitative jade worker makes slabstone; It is characterized in that: the prescription that said imitative jade worker makes slabstone consists of: unsaturated polyester resin 28%~30.64%; White lake 69%~71.64%, cobalt naphthenate 0.02%~0.03%, methylethyl ketone peroxide 0.02%~0.03%, pigment paste 0.1%~0.3%, above-mentioned is mass percent.
As improvement, said pigment paste is preferably the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.
As improvement, said unsaturated polyester resin preferably is selected as the unsaturated polyester resin of adjacent benzene series row.
The present invention solves above-mentioned second technical scheme that technical problem adopted: this imitative jade worker makes the making method of slabstone, and it is characterized in that: the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, on the inwall of mould, wax earlier, subsequent use;
Three,, and stir with adding cobalt naphthenate in the unsaturated polyester resin;
Four, add white lake, pigment paste then, restir is even;
Five, add methylethyl ketone peroxide again, after stirring, miscellany is slowly poured in the mould, again mould is advanced in the vacuum forming case, be evacuated to 3~5 minutes while shaking;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2~3 hours;
Seven, the sheet material after will solidifying again takes out from mould, typing;
Eight, the slabstone with typing is smooth fixed thick through grinder again, is the imitative jade worker of finished product and makes slabstone.
As improvement, in the said step 3, said stirring can preferably be stirred through electric hand drill, and churning time is 3 to 4 minutes.
Further improvements, the mold is selected for Gui plastic molds.
Further improvements, Gui rubber mold of the preparation method: According to the desired pattern, with a perspective model of hand made and polished smooth, and then the three-dimensional model through a glass fiber cloth, silicone molds of plaster and silicone mold.
Compared with prior art, the invention has the advantages that: imitative beautiful parquets is selected polymer composite for use, is made through modern production technique, and environmental protection, nontoxic, radiationless property are the environment-friendly building materials products of a new generation.
This product pattern is various, bright in luster, glittering and translucent, can go according to client's various requirement to manufacture, and is flexible and changeable, and convenient the decoration arranged in pairs or groups, and creates colourful living space.
With respect to ceramic tile, this product weight is light, and moulding property is strong, arbitrarily cutting processing; Thickness all can, light transmission is strong, so more extensive than ceramic tile in the application of decorating.
Making method technology of the present invention is simple, makes safe ready, and the artificial stone plate of making has the smooth surface impunctate and dirt in use can not occur and penetrates in the entering plate, uses more sanitation and hygiene.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail;
Embodiment one; The imitative jade worker of present embodiment makes slabstone; The prescription that said imitative jade worker makes slabstone consists of: the unsaturated polyester resin 28% of adjacent benzene series row; The pigment paste 0.3% that white lake 71.64%, cobalt naphthenate 0.03%, methylethyl ketone peroxide 0.03%, particle fineness are made through grinding by saturated polyester resin and pigment powder less than 30um, above-mentioned is mass percent.
The imitative jade worker of present embodiment makes the making method of slabstone, and the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, on the inwall of mould, wax earlier, subsequent use;
Three,, and use through electric hand drill and stir with adding cobalt naphthenate in the unsaturated polyester resin;
Four, add white lake, pigment paste then, restir is even;
Five, then add methyl ethyl ketone peroxide, stirring evenly, the mixture was slowly poured into Gui plastic mold, then vacuum forming box mold advancement, while shaking side evacuated to 3 to 5 minutes; said Gui plastic mold preparation method: according to the desired pattern by hand to make a three-dimensional model, and polished smooth, and then in the three-dimensional model through a glass fiber cloth, plaster and silicone molds out of silicone molds;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2~3 hours;
Seven, the sheet material after will solidifying again takes out from mould, typing;
Eight, the slabstone with typing is smooth fixed thick through grinder again, is the imitative jade worker of finished product and makes slabstone.
Embodiment two; The imitative jade worker of present embodiment makes slabstone; The prescription that said imitative jade worker makes slabstone consists of: the unsaturated polyester resin 29% of adjacent benzene series row; The pigment paste 0.3% that white lake 70.64%, cobalt naphthenate 0.03%, methylethyl ketone peroxide 0.03%, particle fineness are made through grinding by saturated polyester resin and pigment powder less than 30um, above-mentioned is mass percent.
The imitative jade worker of present embodiment makes the making method of slabstone, and the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, on the inwall of mould, wax earlier, subsequent use;
Three,, and use through electric hand drill and stir with adding cobalt naphthenate in the unsaturated polyester resin;
Four, add white lake, pigment paste then, restir is even;
Five, then add methyl ethyl ketone peroxide, stirring evenly, the mixture was slowly poured into Gui plastic mold, then vacuum forming box mold advancement, while shaking side evacuated to 3 to 5 minutes; said Gui plastic mold preparation method: according to the desired pattern by hand to make a three-dimensional model, and polished smooth, and then in the three-dimensional model through a glass fiber cloth, plaster and silicone molds out of silicone molds;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2~3 hours;
Seven, the sheet material after will solidifying again takes out from mould, typing;
Eight, the slabstone with typing is smooth fixed thick through grinder again, is the imitative jade worker of finished product and makes slabstone.
Embodiment three; The imitative jade worker of present embodiment makes slabstone; The prescription that said imitative jade worker makes slabstone consists of: the unsaturated polyester resin 30% of adjacent benzene series row; The pigment paste 0.1% that white lake 69.86%, cobalt naphthenate 0.02%, methylethyl ketone peroxide 0.02%, particle fineness are made through grinding by saturated polyester resin and pigment powder less than 30um, above-mentioned is mass percent.
The imitative jade worker of present embodiment makes the making method of slabstone, and the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, on the inwall of mould, wax earlier, subsequent use;
Three,, and use through electric hand drill and stir with adding cobalt naphthenate in the unsaturated polyester resin;
Four, add white lake, pigment paste then, restir is even;
Five, then add methyl ethyl ketone peroxide, stirring evenly, the mixture was slowly poured into Gui plastic mold, then vacuum forming box mold advancement, while shaking side evacuated to 3 to 5 minutes; said Gui plastic mold preparation method: according to the desired pattern by hand to make a three-dimensional model, and polished smooth, and then in the three-dimensional model through a glass fiber cloth, plaster and silicone molds out of silicone molds;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2~3 hours;
Seven, the sheet material after will solidifying again takes out from mould, typing;
Eight, the slabstone with typing is smooth fixed thick through grinder again, is the imitative jade worker of finished product and makes slabstone.

Claims (7)

1. an imitative jade worker makes slabstone; It is characterized in that: the prescription that said imitative jade worker makes slabstone consists of: unsaturated polyester resin 28%~30.64%, white lake 69%~71.64%, cobalt naphthenate 0.02%~0.03%, methylethyl ketone peroxide 0.02%~0.03%, pigment paste 0.1%~0.3%, above-mentioned is mass percent.
2. imitative jade worker according to claim 1 makes slabstone, it is characterized in that: said pigment paste is the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.
3. imitative jade worker according to claim 2 makes slabstone, it is characterized in that: said unsaturated polyester resin is the unsaturated polyester resin of adjacent benzene series row.
4. arbitrary said imitative jade worker makes the making method of slabstone in the claim 1 to 3, and it is characterized in that: the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, on the inwall of mould, wax earlier, subsequent use;
Three,, and stir with adding cobalt naphthenate in the unsaturated polyester resin;
Four, add white lake, pigment paste then, restir is even;
Five, add methylethyl ketone peroxide again, after stirring, miscellany is slowly poured in the mould, again mould is advanced in the vacuum forming case, be evacuated to 3~5 minutes while shaking;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2~3 hours;
Seven, the sheet material after will solidifying again takes out from mould, typing;
Eight, the slabstone with typing is smooth fixed thick through grinder again, is the imitative jade worker of finished product and makes slabstone.
5. imitative jade worker according to claim 4 makes the making method of slabstone, it is characterized in that: in the said step 3, said stirring is stirred through electric hand drill, and churning time is 3 to 4 minutes.
As claimed in claim 4, wherein the production of imitation jade artificial stone, characterized in that: said mold is Gui plastic molds.
As claimed in claim 6, wherein the production of imitation jade artificial stone, characterized in that: said Gui plastic mold preparation method: According to the desired pattern, with a perspective model of hand made and polished smooth, and then in the three-dimensional model through a glass fiber cloth, plaster and silicone molds out of silicone mold.
CN201210133982.2A 2012-04-28 2012-04-28 Bowlder-imitated artificial stone plate and manufacturing method thereof Expired - Fee Related CN102775092B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103085162A (en) * 2013-01-30 2013-05-08 广东道氏技术股份有限公司 Ceramic tile mould preparation method
CN103709697A (en) * 2013-12-17 2014-04-09 成都顺美国际贸易有限公司 Production process of fiber composite material tea table mesa and table top board
CN104692711A (en) * 2015-02-09 2015-06-10 陈真全 Artificial jade spar material and preparation method thereof
CN104802279A (en) * 2014-01-23 2015-07-29 吴文鸿 Method for preparing an artificial stone with decorative patterns
CN106082934A (en) * 2016-06-12 2016-11-09 安徽广燕新材料科技有限责任公司 A kind of preparation method of the artificial stone with anion function
CN107311520A (en) * 2017-07-29 2017-11-03 南通戈雅石业有限公司 A kind of bionical marble formula
CN107459289A (en) * 2017-07-29 2017-12-12 南通戈雅石业有限公司 A kind of marble formula

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673498A (en) * 2016-12-01 2017-05-17 深圳中凝科技有限公司 Aerogel heat insulation artificial stone plate and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003183A (en) * 2006-01-20 2007-07-25 金国华 Method for fabricating artificial stone, and artificial stone with luminescence function, and products

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003183A (en) * 2006-01-20 2007-07-25 金国华 Method for fabricating artificial stone, and artificial stone with luminescence function, and products

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103085162A (en) * 2013-01-30 2013-05-08 广东道氏技术股份有限公司 Ceramic tile mould preparation method
CN103085162B (en) * 2013-01-30 2014-10-29 广东道氏技术股份有限公司 Ceramic tile mould preparation method
CN103709697A (en) * 2013-12-17 2014-04-09 成都顺美国际贸易有限公司 Production process of fiber composite material tea table mesa and table top board
CN103709697B (en) * 2013-12-17 2016-04-13 成都顺美国际贸易有限公司 The production technique of fibre composite tea table table top and desktop
CN104802279A (en) * 2014-01-23 2015-07-29 吴文鸿 Method for preparing an artificial stone with decorative patterns
CN104692711A (en) * 2015-02-09 2015-06-10 陈真全 Artificial jade spar material and preparation method thereof
CN106082934A (en) * 2016-06-12 2016-11-09 安徽广燕新材料科技有限责任公司 A kind of preparation method of the artificial stone with anion function
CN107311520A (en) * 2017-07-29 2017-11-03 南通戈雅石业有限公司 A kind of bionical marble formula
CN107459289A (en) * 2017-07-29 2017-12-12 南通戈雅石业有限公司 A kind of marble formula

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