CN2454156Y - Artificial marble - Google Patents
Artificial marble Download PDFInfo
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- CN2454156Y CN2454156Y CN 00267154 CN00267154U CN2454156Y CN 2454156 Y CN2454156 Y CN 2454156Y CN 00267154 CN00267154 CN 00267154 CN 00267154 U CN00267154 U CN 00267154U CN 2454156 Y CN2454156 Y CN 2454156Y
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Abstract
The utility model relates to artificial marble which is used for overcoming the disadvantages of big labor strength and high cost of the sculpture of the existing natural marble. The utility model comprises a basal body 3. The surface of the basal body 3 is attached with raw materials which are composed of unsaturated resin gel coat or unsaturated resin gel, curing agents, accelerating agents, and an artificial layer 2 of stone granules, wherein, the curing agents use ethyl ketone or peroxide cyclohexanone; the accelerating agents use cobalt naphthenate solution or T-8A accelerating agents; the stone granules use natural or artificial stone granules of which the fineness is less than 20 meshes. The utility model has the advantage of favorable marble texture, the manufacturing cost of the utility model is only 20 percent of that of natural marble products, and the service life of the utility model can reach 50 years under the condition that the utility model is in the open air.
Description
The utility model relates to a kind of Scagliola.
The marble major part of building trade and construction decoration industry use at present is a natural marble, exploits natural marble in a large number, can destroy natural landscape, brings harmful effect to environmental protection.The needs that the natural marble that construction decoration uses has are through Carving Machining, yield rate is lower in the engraving process, cause the wasting of resources, and the engraving process of natural marble is generally carried out by hand, can not realize the mechanization batch process, the labour intensity of sculpting operation is big, and operator's technical merit is had relatively high expectations.Therefore, costing an arm and a leg of natural marble is difficult to popularization and application.
The purpose of this utility model is, the Scagliola that provides a kind of surface to have the texture of natural marble, and the manufacturing cost of this Scagliola is lower, the life-span is longer.
The purpose of this utility model is achieved in that Scagliola, comprises matrix 3.Its special character is to be attached with the simulation layer 2 that raw material contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain on the surface of matrix 3.
Raw material such as unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and Shi Li solidify after mixing very soon, and the stone grain is bonded in together, thereby form simulation layer 1.
The raw material curing agent that the utility model is made simulation layer 1 adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter, and it is the following natural or artificial stone grains of 20 orders that the stone grain adopts fineness.
The fineness that the utility model is made the raw material stone grain of simulation layer 1 is preferably 5～20 orders.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain that the utility model is made simulation layer 1 mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain
1 0.01～0.05 0.02～0.08 0.5～1.5
The utlity model has antiultraviolet, aging-resistant function in order to make, perhaps in order to regulate the color on surface, the raw material of making simulation layer 1 can also contain mica powder and mill base except containing unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain.
Raw material such as unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone grain, mica powder and mill base solidify after mixing very soon, and stone grain and mica powder are bonded in together, thereby form simulation layer 1.
Mica powder can antiultraviolet, and ageing resistace of the present utility model is improved.In addition, glittering when mica powder is subjected to the light irradiation, make the aesthetic feeling multiplication of simulation layer.Mill base is used for artificially regulating the color on simulation layer surface, and the color of mill base can be selected according to different needs.After adding mica powder and mill base, the emulation degree of simulation layer weakens.Therefore, generally just add mica powder and mill base under the situation of specific (special) requirements having.
The fineness that the utility model is made the raw material mica powder of simulation layer is preferably below 1000 orders.
Raw material unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter, stone grain, mica powder and mill base that the utility model is made simulation layer mix according to following weight ratio:
Unsaturated-resin gel coat or unsaturated-resin adhesive curing agent promoter stone grain mica powder mill base
1 0.01～0.05 0.02～0.08 0.5～1.5 0.1～0.5 is an amount of
Mill base can add as one feels fit according to concrete needs.
Have raw material between simulation layer 1 of the present utility model and the matrix 3 and contain the back-up coat 2 of unsaturated-resin glue, curing agent, promoter and glass fabric, on the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
After unsaturated-resin glue, curing agent and promoter are mixed, before solidifying, rapidly it is brushed on the inner surface of simulation layer 1, and rapidly glass fabric is layered on the inner surface of simulation layer 1.After the mixture of unsaturated-resin glue, curing agent and promoter solidified, glass fabric was bonded on the inner surface of simulation layer 1, thereby formed back-up coat 2.
Raw material unsaturated-resin glue, curing agent, promoter and glass fabric that the utility model is made back-up coat 2 are stocks, can add other satisfactory material on the basis of these stocks.
The unsaturated-resin glue of making back-up coat 2 is used for glass fabric and simulation layer 1 are bonded together, and glass fabric can improve the intensity of simulation layer 1, and it can lay one deck, also which floor can be laid.The curing agent of manufacturing back-up coat 2 is identical with the effect of the curing agent of making simulation layer 1 and promoter with the effect of promoter.
Curing agent in the raw material of the utility model manufacturing back-up coat 2 adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter.
The utility model is made raw material unsaturated-resin glue, curing agent and the promoter of back-up coat 2 and is mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
1 0.01～0.05 0.02～0.08
The raw material of manufacturing back-up coat 2 of the present utility model are except that containing unsaturated-resin glue, curing agent, promoter and glass fabric, and can also contain fineness is the above stone flours of 20 orders.Stone flour bonds together by unsaturated-resin glue, curing agent and promoter and glass fabric and simulation layer 1.
After unsaturated-resin glue, curing agent, promoter and stone flour mix, before solidifying, rapidly it is brushed on the inner surface of simulation layer 1, and rapidly glass fabric is layered on the inner surface of simulation layer 1.After the mixture of unsaturated-resin glue, curing agent, promoter and stone flour solidifies, stone flour be bonded on the glass fabric and the inner surface of simulation layer 1 on, glass fabric is bonded on the inner surface of simulation layer 1 together with stone flour, thereby forms back-up coat 2.
Adopt the packing material of an amount of stone flour, can reduce manufacturing cost of the present utility model as back-up coat 2.
Raw material unsaturated-resin glue, curing agent, promoter and stone flour that the utility model is made back-up coat 2 mix according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone flour
1 0.01～0.05?0.02～0.08?0.5～1.5
One of scheme of matrix 3 of the present utility model is that the raw material of making matrix 3 contain unsaturated-resin glue, curing agent, promoter and stone or stone flour.
Unsaturated-resin glue, curing agent, promoter and stone or stone flour were cast to it in inner chamber of back-up coat 2 rapidly before solidifying after mixing.The mixture solidification forming of unsaturated-resin glue, curing agent, promoter and stone or stone flour, thus matrix 3 formed.
Raw material unsaturated-resin glue, curing agent, promoter and stone or stone flour that the utility model is made matrix 3 are stocks, can add other satisfactory raw material on these raw-material bases.
The size of the particle diameter of the stone of manufacturing matrix 3 is generally unrestricted.The effect of unsaturated-resin glue, curing agent and the promoter of manufacturing matrix 3 is identical with the effect of the unsaturated-resin gel coat of making simulation layer 1 or unsaturated-resin glue, curing agent and promoter.
Stone, stone grain and stone flour alleged in the utility model are to divide from the size of particle diameter, and the particle diameter of stone is bigger, and the particle diameter of stone flour is less, and the stone grain is between stone and stone flour, and the three does not have strict boundary.One of raw material " stone or stone flour " of making matrix 3 in the utility model are meant can adopting of from the stone to the stone flour various particle diameters, comprise stone grain and sand.
Raw material unsaturated-resin glue, curing agent, promoter, stone or stone flour that the utility model is made matrix 3 mix according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone or stone flour
1 0.01～0.05 0.02～0.08 2～5
Two of the scheme of matrix 3 of the present utility model is, the raw material of making matrix 3 contain magnesia, magnesium chloride and stone or stone flour, and magnesium chloride is 20～30 Baume degrees.
Magnesia, magnesium chloride and stone or stone flour were cast to it in inner chamber of back-up coat 2 rapidly before solidifying after mixing.The mixture solidification forming of magnesia, magnesium chloride and stone or stone flour, thus matrix 3 formed.
Raw material magnesia, magnesium chloride and stone or stone flour that the utility model is made matrix 3 are stocks, can add other satisfactory raw material on these raw-material bases.
The implication of " stone or stone flour " in the implication of here " stone or stone flour " and one of scheme of making matrix 3 is identical.Magnesia, magnesium chloride and stone or stone flour mix the back and form magnesia cement.
Raw material magnesia, magnesium chloride and stone or stone flour that the utility model is made matrix 3 mix according to following weight ratio:
Magnesia magnesium chloride stone or stone flour
40～50 40～50 50～100
The utility model is made the raw material of matrix 3 except that containing magnesia, magnesium chloride and stone or stone flour, can also contain talcum powder and hydrochloric acid.
Talcum powder is a kind of additive, and it can reduce manufacturing cost of the present utility model.Hydrochloric acid is used to regulate the acid-base value of matrix 3.
Raw material magnesia, magnesium chloride, stone or stone flour, talcum powder and hydrochloric acid that the utility model is made matrix 3 mix according to following weight ratio:
Magnesia magnesium chloride stone or stone flour talcum powder hydrochloric acid
40～50 40～50 50～100 2～5 1～5 wherein: the concentration of hydrochloric acid is 20～36 Baume degrees.
Three of the scheme of matrix 3 of the present utility model is that the raw material of making matrix 3 contain white cement, stone and water.
White cement, stone and water were cast to it in inner chamber of back-up coat 2 rapidly before solidifying after mixing.The mixture solidification forming of white cement, stone and water, thus matrix 3 formed.
Raw material white cement, stone and water that the utility model is made matrix 3 are stocks, can add other satisfactory raw material on these raw-material bases.
Raw material white cement, stone and water that the utility model is made matrix 3 mix according to following weight ratio:
White cement stone water
50 10～40 20～40
The raw material of making matrix 3 can also contain gluewater in use for construction and pigment except that containing white cement, stone and water.
Gluewater in use for construction can adopt 107 glue, resin glue etc., and it can improve the intensity of matrix 3.Pigment is used to regulate the color of matrix 3.
Raw material white cement, stone, water, gluewater in use for construction and pigment that the utility model is made matrix 3 mix according to following weight ratio:
White cement stone water gluewater in use for construction pigment
50 10～40 20～40 1～3 is an amount of
Pigment can add as one feels fit according to concrete needs.
The utility model Scagliola has good marmorean texture, and its surface can access as required than natural marble abundant colors more.It surperficial firm, acid and alkali-resistance, anti-aging, its life-span can reach 50 years under the service condition in the open.Because the utility model adopts cheap raw material manufacturing, and manufacturing process is simple, so manufacturing cost is lower.Compare with similar natural marble goods, manufacturing cost of the present utility model has only 20% of natural marble goods.Adopt the utility model can save a large amount of lithotomes, avoid the exhaustive exploitation of lithotome, help protecting environment.The utility model not only can be selected different profiles according to concrete needs, and can produce in batches owing to can adopt model manufacturing, helps realizing mechanization, reduces manufacturing cost.Manufacture process of the present utility model improves effect more than 200 times than hand engraving natural marble, and greatly reduces operator's labour intensity.
Below in conjunction with accompanying drawing embodiment of the present utility model is described in detail.
Fig. 1 is the outline drawing of embodiment 1 of the present utility model.
Fig. 2 is the profile of embodiment 1 of the present utility model.
Fig. 3 is the outline drawing of embodiment 2 of the present utility model.
Fig. 4 is the A-A view among Fig. 3.
Fig. 5 is the outline drawing of embodiment 3 of the present utility model.
Fig. 6 is the cutaway view of embodiment 3 of the present utility model.
Embodiment 1:
As depicted in figs. 1 and 2, present embodiment is a kind of Scagliola ornamental blocks, and it has simulation layer 1, back-up coat 2 and matrix 3.On the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.The raw material of making simulation layer 1 adopt unsaturated-resin gel coat, curing agent, promoter and stone grain.It is the natural or artificial stone grains of 5～20 purposes that the stone grain adopts fineness.Unsaturated-resin gel coat, curing agent, promoter and stone grain mix according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain
1 0.02 0.03 1
After above-mentioned raw material mix, solidify very soon, the stone grain is bonded in together, thereby forms simulation layer 1.The raw material of making back-up coat 2 adopt unsaturated-resin glue, curing agent, promoter and glass fabric.Glass fabric adopts 0.1～0.4 purpose glass fabric.Unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
Inner surface with glass fabric and simulation layer 1 after the mixture of 1 0.02 0.03 unsaturated-resin glue, curing agent and promoter solidifies bonds together.The raw material of making matrix 3 adopt unsaturated-resin glue, curing agent, promoter and stone.Unsaturated-resin glue, curing agent, promoter, stone mix according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone
The mixture of 1 0.03 0.04 3 unsaturated-resin glue, curing agent, promoter and stone solidifies the back and forms matrix 3, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
Curing agent in the raw material of above-mentioned manufacturing simulation layer 1, back-up coat 2 and matrix 3 adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter,
This Scagliola ornamental blocks is to adopt model to make, be ready to model after, concrete manufacture method is operated according to following step:
1. unsaturated-resin gel coat, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain
1 0.02 0.03 1
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, brush 2～3 times after treating to solidify a little again, these raw material that mix solidify the back and form simulation layer 1;
3. unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
1 0.02 0.03
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer 1 that 2. forms in step rapidly with these raw material that mix, brush is spread 2～3 layers of glass fabric altogether, after these raw material that mix solidify, glass fabric is bonded in forms back-up coat 2 on the inner surface of simulation layer;
5. matched moulds;
6. unsaturated-resin glue, curing agent, promoter, stone are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone
1 0.03 0.04 3 these mixtures stir with mixer;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly with these raw material that mix in the inner chamber of the back-up coat 2 in the model, make these raw material be full of the inner chamber of back-up coat 2 through vibration, and closely knit in the inner chamber of back-up coat 2, even;
8. behind the raw material solidification forming of step in 7., form matrix 3:
9. the product that is shaped is taken out in die sinking.
Embodiment 2:
As shown in Figure 3 and Figure 4, present embodiment is the Scagliola decorative railing, and it has simulation layer 1, back-up coat 2 and matrix 3.On the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.The raw material of making simulation layer 1 adopt unsaturated-resin gel coat, curing agent, promoter, stone grain, mica powder and mill base, and it is the natural or artificial stone grains of 5～20 purposes that the stone grain adopts fineness, and the fineness of mica powder is below 20 orders.Unsaturated-resin gel coat, curing agent, promoter, stone grain, mica powder and mill base mix according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain mica powder mill base
1 0.02 0.03 1 0.1 is an amount of
Mill base adds as one feels fit according to concrete needs.After above-mentioned raw material mix, solidify very soon, stone grain and mica powder are bonded in together, thereby form simulation layer 1.The raw material of making back-up coat 2 adopt unsaturated-resin glue, curing agent, promoter, stone flour and glass fabric.The fineness of stone flour is more than 20 orders, and glass fabric adopts 0.1～0.4 purpose glass fabric.Unsaturated-resin glue, curing agent, promoter and stone flour mix according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone flour
1 0.02 0.03 1
Inner surface with glass fabric and simulation layer 1 after the mixture of unsaturated-resin glue, curing agent, promoter and stone flour solidifies bonds together.The raw material of making matrix 3 adopt magnesia, magnesium chloride and stone, and magnesium chloride is 20～30 Baume degrees.Magnesia, magnesium chloride and stone mix according to following weight ratio:
Magnesia magnesium chloride stone
45 50 60
The raw material of making matrix 3 can also adopt magnesia, magnesium chloride, stone, talcum powder and hydrochloric acid, and magnesium chloride is 26 Baume degrees, and the concentration of hydrochloric acid is 36 Baume degrees.Magnesia, magnesium chloride, stone, talcum powder and hydrochloric acid mix according to following weight ratio:
Magnesia magnesium chloride stone talcum powder hydrochloric acid
45 50 60 2 1
Raw-material two kinds of mixtures of above-mentioned manufacturing matrix 3 solidify the back and form matrix 3, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
Curing agent in the raw material of above-mentioned manufacturing simulation layer 1 and back-up coat 2 adopts MEK or cycloethanone peroxide, and promoter is adopted cobalt naphthenate solution or T-8A promoter,
This Scagliola decorative railing is to adopt model to make, be ready to model after, concrete manufacture method is operated according to following step:
1. unsaturated-resin gel coat, curing agent, promoter, stone grain, mica powder and mill base are mixed according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain mica powder mill base
1 0.02 0.03 1 0.1 an amount of mill bases add as one feels fit according to concrete needs.
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, brush 2～3 times after treating to solidify a little again, these raw material that mix solidify the back and form simulation layer 1;
3. unsaturated-resin glue, curing agent, promoter and stone flour are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter stone flour
1 0.02 0.03 1
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer 1 that 2. forms in step rapidly with these raw material that mix, brush is spread 2～3 layers of glass fabric altogether, after these raw material that mix solidify, glass fabric is bonded in forms back-up coat 2 on the inner surface of simulation layer;
5. matched moulds;
6. magnesia, magnesium chloride and stone are mixed according to following weight ratio:
Magnesia magnesium chloride stone
45 50 60 magnesium chlorides are 20～30 Baume degrees.This mixture stirs with mixer;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly with these raw material that mix in the inner chamber of the back-up coat 2 in the model, make these raw material be full of the inner chamber of back-up coat 2 through vibration, and closely knit in the inner chamber of back-up coat 2, even;
8. behind the raw material solidification forming of step in 7., form matrix 3;
9. the product that is shaped is taken out in die sinking.
Embodiment 3:
As shown in Figure 5 and Figure 6, present embodiment is a kind of Scagliola door lion, and it has simulation layer 1, back-up coat 2 and matrix 3.On the inner surface of the outer surface of back-up coat 2 attached to simulation layer 1, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.The raw-material component that present embodiment is made simulation layer 1 and manufacturing back-up coat 2 and proportioning are identical with embodiment's 1.The raw material of making matrix 3 adopt white cement, stone and water.White cement, stone and water mix according to following weight ratio:
White cement stone water
50 30 30
The raw material of making matrix 3 can also adopt white cement, stone, water, gluewater in use for construction and pigment.White cement, stone, water, gluewater in use for construction and pigment mix according to following weight ratio:
White cement stone water gluewater in use for construction pigment
50 30 30 1.5 an amount of pigment can add as one feels fit according to concrete needs.
Raw-material two kinds of mixtures of above-mentioned manufacturing matrix 3 solidify the back and form matrix 3, on the inner surface of the outer surface of matrix 3 attached to back-up coat 2.
This Scagliola door lion is to adopt model to make, be ready to model after, concrete manufacture method is operated according to following step:
1. unsaturated-resin gel coat, curing agent, promoter and stone grain are mixed according to following weight ratio:
Unsaturated-resin gel coat curing agent promoter stone grain
1 0.02 0.03 1
2. before the raw material that step mixes in 1. solidify, rapidly it is brushed on the inner surface of preprepared model, brush 2～3 times after treating to solidify a little again, these raw material that mix solidify the back and form simulation layer 1;
3. unsaturated-resin glue, curing agent and promoter are mixed according to following weight ratio:
Unsaturated-resin adhesive curing agent promoter
1 0.02 0.03
4. before the raw material that step mixes in 3. solidify, shop, limit glass fabric is brushed in the inner surface top of the simulation layer 1 that 2. forms in step rapidly with these raw material that mix, brush is spread 2～3 layers of glass fabric altogether, after these raw material that mix solidify, glass fabric is bonded in forms back-up coat 2 on the inner surface of simulation layer;
5. matched moulds;
6. white cement, stone and water are mixed according to following weight ratio:
White cement stone water
50 30 30 these mixtures stir with mixer;
7. before the raw material that step mixes in 6. solidify, be cast to rapidly with these raw material that mix in the inner chamber of the back-up coat 2 in the model, make these raw material be full of the inner chamber of back-up coat 2 through vibration, and closely knit in the inner chamber of back-up coat 2, even;
8. behind the raw material solidification forming of step in 7., form matrix 3;
9. the product that is shaped is taken out in die sinking.
Claims (2)
1. Scagliola comprises matrix (3), it is characterized in that, is attached with the simulation layer (2) that raw material contain unsaturated-resin gel coat or unsaturated-resin glue, curing agent, promoter and stone grain on the surface of matrix (3).
2. Scagliola according to claim 1, it is characterized in that, have raw material between simulation layer (1) and the matrix (3) and contain the back-up coat (2) of unsaturated-resin glue, curing agent, promoter and glass fabric, on the inner surface of outer surface attached to simulation layer (1) of back-up coat (2), on the inner surface of outer surface attached to back-up coat (2) of matrix (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00267154 CN2454156Y (en) | 2000-12-14 | 2000-12-14 | Artificial marble |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00267154 CN2454156Y (en) | 2000-12-14 | 2000-12-14 | Artificial marble |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN2454156Y true CN2454156Y (en) | 2001-10-17 |
Family
ID=33621058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00267154 Expired - Fee Related CN2454156Y (en) | 2000-12-14 | 2000-12-14 | Artificial marble |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN2454156Y (en) |
-
2000
- 2000-12-14 CN CN 00267154 patent/CN2454156Y/en not_active Expired - Fee Related
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| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |