CN1314328A - An organic potassium fertilizer and its producing method - Google Patents

An organic potassium fertilizer and its producing method Download PDF

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Publication number
CN1314328A
CN1314328A CN 00113759 CN00113759A CN1314328A CN 1314328 A CN1314328 A CN 1314328A CN 00113759 CN00113759 CN 00113759 CN 00113759 A CN00113759 A CN 00113759A CN 1314328 A CN1314328 A CN 1314328A
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organic potassic
potassic fertilizer
fertilizer
organic
tensio
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CN 00113759
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刘兆宁
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Yang Yongxiang
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Abstract

The organic potassium fertilizer is produced in conventional chemical industry equipment and has wide material source. In has the features of superhigh energy, high efficiency and no pollution, and can be used to replenish potassium element essential for crop and to reach the goal of increasing yield and improving quality of crop.

Description

A kind of organic potassic fertilizer and production method thereof
The present invention relates to a kind of organic potassic fertilizer and production method thereof.
Potassium by Science Institute is proved already that to the trophism and the mechanism of plant organism potash fertilizer is generally accepted by people and used in agriculture production, thus, the demand of potash fertilizer is also increasing considerably.In recent years scientific research shows, when using nitrogen, phosphate fertilizer, must use the effect of the more effective performance nitrogen of a certain proportion of potash fertilizer ability, phosphate fertilizer simultaneously.China Ministry of Agriculture has also proposed to instruct to nitrogen, phosphorus, potassium balance fertilising joins the ratio of executing (ratio is: 1: 0.5: 0.4), and along with the raising of agrotechnical development and production level, agricultural is to the demand multiplication of potash fertilizer in addition.Yet the present potash fertilizer imbalance between supply and demand of China is very severe.Its reason, the one, although the potash fertilizer throughput of the present general potassium deficiency of the soil China of China is very low, domestic required potash fertilizer is almost entirely by import, annual nearly 5,000,000 tons import potash fertilizer still can not satisfy the existing demand of China; The 2nd, because China is to potash fertilizer dependence on import almost completely, our neck of card is gone up at be everlasting price and supply time by international potash fertilizer export State, raises the price, when dragging, peasant burden is increased the weight of, and often miss farming season because of potash fertilizer can not be in time.Also having a very severe new contradiction in addition is that a large amount of uses because of potash fertilizer produce, hardening and acidifying of Here it is soil, its reason is that present employed potash fertilizer all is inorganic potash fertilizer, and its inorganic acid radical can produce certain destruction to soil, and this has caused the extensive attention in the world.Therefore, research and development can be satisfied China's agricultural demand, and super, efficient, the non-harmful organic potassic fertilizer that is fit to China's national situation simultaneously again is current ten minutes instant problem.Purpose of the present invention just provides a kind of organic potassic fertilizer and production method thereof with this specific character.
The main ingredient of organic potassic fertilizer of the present invention is C 5H 7KO 3, add an amount of tensio-active agent and conditioning agent and form.
Organic potassic fertilizer of the present invention prepares as follows: one, raw material 1, potassium hydroxide (KOH), content are that liquid or the content of 30-50% is the solid of 75-98%; 2, levulinic acid (C 5H 8O 3), content is liquid or the crystal of 90-98%; 3, conditioning agent; 4, tensio-active agent.Two, method 1, place dissolving tank to be dissolved in water KOH, make the aqueous solution of 30-70%, slowly add the C in the reactor 5H 8O 3In, stirring reaction generates the essential substance C of organic potassic fertilizer under normal temperature or 60-120 degree Celsius 5H 7KO 32, reaction is after 2-3 hour, and the ratio adding conditioning agent in 0.5-5% continues to stir; 3, reaction is after 30 minutes, and the ratio adding tensio-active agent in 0.5-10% continues to stir; 4, reaction was transferred to 6-8 with the pH value of solution, the conventional sense potassium oxide content after 30 minutes; 5, at normal temperatures with liquid organic potassic fertilizer finished product packing or under 100-120 degree Celsius with liquid heat crystallization or granulation or dust and make the solid finished product packing.Three, the key technical indexes of this organic potassic fertilizer is:
PH value: 6-8 organic matter: 30-46%
K 2O:8-25% ash content: 15-32%
Tensio-active agent: 0.5~10% conditioning agent: 0.5-5%
Wherein contain trace element:
Sodium Na:0.1~4.6% sulphur S:0.01~0.1%
Chlorine Cl:0.1~0.4% nitrogen N:0.8~2%
Nickel: 0.01-0.05% zinc Zn:0.01~0.15%
What organic potassic fertilizer production method provided by the present invention was used is the construction equipment that routinizes, the production process normal temperature and pressure, and technology is simple and easy to do, no waste discharge, and raw material sources are extensive.
Organic potassic fertilizer provided by the present invention will fundamentally solve the imbalance between supply and demand of the present potash fertilizer of China and harden and the acidifying drawback because of the inorganic potash fertilizer of life-time service produces soil.
Organic potassic fertilizer provided by the present invention can be executed or foliage-spray to root of the crop according to a conventional method.
Organic potassic fertilizer provided by the present invention can need the potassium peak period potassium element that supplement the nutrients effectively at any time in plant growth, to reach volume increase and to improve the purpose of crop quality.
Organic potassic fertilizer provided by the present invention has the following advantages: nontoxic, noresidue, good water solubility, easy to use, absorb fast, the utilization ratio height, produce effects is rapid, and amount of increase in production is big, fruit quality is improved significantly, cheap, can not cause soil compaction, acidifying, pollution, can improve disease-resistant, the insect pest ability of crop greatly simultaneously.
Be part experiment effect and the explanation thereof of the organic potassic fertilizer produced with the present invention below to grain, vegetables, fruit tree:
Experiment 1: organic potassic fertilizer is to the influence of the growth of apple, quality, output
Experimental program: on the identical basis of all farming, water and fertilizer condition four groups of processing are set at random, promptly blank (CK) and three different organic potassic fertilizer spraying concentrations (0.3%, 0.5%, 0.7%) are handled, and repeat four times.10 days " Invest, Then Investigate " results.
Table 1 organic potassic fertilizer is to the influence of leaf growth amount
Handle Blade long (cm) Leaf maximum wide (cm) Blinds heavy (g) The leaf look Lobate
CK 0.3% 0.5% 0.7% ????8.4 ????9.4 ????9.5 ????9.6 ????5.8 ????5.9 ????7.0 ????6.6 ?24.6 ?29.3 ?35.8 ?31.7 Green Thin, that mattness is thick, the surface is glossy is thick, the surface is glossy is thick, the surface is glossy
Annotate: find out by table 1, show that after spraying 10 days organic potassic fertilizer has obvious facilitation to leaf growth.
Table 2 organic potassic fertilizer is to the influence of apple tree branch increment
Project CK ????0.3% ????0.5% ????0.7%
Long (cm) shoot of shoot thick (cm) ?85.1 ?0.635 ????58.7 ????0.612 ????57.6 ????0.515 ????43.2 ????0.476
Annotate: find out that by table 2 organic potassic fertilizer can effectively suppress the prosperous length of newborn branch of later stage, reduce nutrient consumption, the growth of fruit tree is useful to the coming year.
Table 3 organic potassic fertilizer is to the influence of apple diameter, sugar degree, output
Handle The vertical footpath of fruit (cm) Fruit transverse diameter (cm) Sugar degree (%) Single plant yield (kg) Volume increase (kg)
CK ????5.96 ????6.60 ????15 ????25.0
0.3% ????6.16 ????6.77 ????16.2 ????30.5 ????22.0
0.5% ????6.57 ????7.34 ????17.0 ????34.8 ????39.2
0.7% ????5.66 ????7.0 ????18.1 ????39.0 ????56.0
Annotate: find out that by table 3 organic potassic fertilizer can improve percentage of fertile fruit, improve the output and the sugar content of fruit, reduce shedding, this effect is particularly outstanding in the great drought time.
Experiment 2: the organic potassic fertilizer seed soaking is to the influence of wheat seedling growth
Experimental program: with experiment 1.Soaked seed 22 days investigation results 2 hours.
The seed soaking of table 4 organic potassic fertilizer is to the influence of wheat seedling growth amount
Handle Percentage of germination (%) Highly (mm) Radical (bar) Root long (MM) 10 strain cauline leaf fresh weights (G) 10 fresh weights (G)
CK ?90.0 ????125 ????5 ????110 ????0.905 ????0.593
0.3% ?88.3 ????145 ????5 ????130 ????1.001 ????0.640
0.5% ?90.0 ????149 ????5 ????140 ????1.045 ????0.678
0.7% ?93.3 ????152 ????5 ????145 ????1.049 ????0.720
Annotate: find out that by table 4 the organic potassic fertilizer seed soaking helps the growth of wheat seedling.
Experiment 3: organic potassic fertilizer is to the influence of the yield and quality of Radix Dauci Sativae
Experimental program: identical with experiment 1.Spray twice (seedling stage, vigorous period).
Table 5 organic potassic fertilizer is to the influence of Radix Dauci Sativae stem, leaf, root growth amount
Handle Leaf long (mm) Ye Chong (g) Fleshy root heavy (g) Fleshy root long (mm) Fleshy root diameter (mm) Per mu yield (kg) Volume increase (%)
On In Down
CK ?62.5 ??100 ?123.5 ?18.55 ?2.95 ?2.8 ?2.8 ?2223
0.3% ?64.5 ?117.5 ?214.5 ?19.85 ?3.7 ?3.7 ?3.85 ?3861 ?73.7
0.5% ?64.0 ?117.0 ?165.9 ?17.35 ?3.4 ?3.4 ?3.8 ?2986 ?34.3
0.7% ?67.0 ?122.5 ?152.5 ?17.0 ?3.7 ?3.37 ?3.05 ?2745 ?23.5
Annotate: find out that by table 5 organic potassic fertilizer has tangible effect of increasing production to Radix Dauci Sativae.
Table 6 organic potassic fertilizer is to the influence of Radix Dauci Sativae sugar degree
Handle CK ?0.3% ????0.5% ????0.7%
Top (KG) 12.5 ????12.0 ????12.0 ????11.5
Middle part (KG) 12.0 ????10.5 ????10.5 ????10.2
Bottom (KG) 11.0 ????10.0 ????10.0 ????9.0
Total reducing sugar amount (KG/ mu) 262.3 ????417.0 ????322.5 ????280.0
Annotate: find out that by table 6 organic potassic fertilizer has certain influence to the Radix Dauci Sativae sugar degree.The individual plant sugar degree descends, but the total reducing sugar amount significantly improves.
Experiment 4: organic potassic fertilizer is to the influence of growth of rape and output.
Experimental program: identical with experiment 1.Spray 2-3 time.
Table 7 organic potassic fertilizer is to the influence of growth of rape amount
Project CK 0.3% once 0.5% secondary 0.3% secondary 0.5% secondary
Plant height (cm) 60.5 ?64.1 ????73.9 ?74.5 ????78.7
Root long (cm) 17.6 ?24.3 ????25.2 ?22.6 ????27.2
Root thick (cm) 1.5 ?2.2 ????2.1 ?3.7 ????2.6
Root heavy (g) 10.6 ?24.1 ????21.6 ?39.8 ????26.5
Lateral root Few Flourishing Flourishing Flourishing Flourishing
Annotate: find out that by table 7 organic potassic fertilizer can make the rape plant strain growth vigorous.
Increment when table 8 organic potassic fertilizer is gathered in the crops rape, the influence of output
Project CK 0.3% once 0.5% once 0.3% secondary 0.5% secondary 0.3% 3 time 0.5% 3 time
Plant height (cm) 125.4 ?131.8 ?140.6 ?147.6 ?148.2 ????141.4 ???159.2
Root long (cm) 18.8 ?21.9 ?22.4 ?21.9 ?22.7 ????23.1 ????24.4
Root thick (cm) 1.30 ?1.60 ?1.80 ?1.76 ?2.04 ????1.96 ????2.32
Single-strain legumen number 264.6 ?267.5 ?282.5 ?288.8 ?311.4 ????306.0 ????334.9
Single pod grain number 20.3 ?23.2 ?25.4 ?27.4 ?26.5 ????28.7 ????29.1
Single-strain grain weight (g) 7.58 ?8.57 ?8.94 ?11.09 ?13.45 ????12.76 ????13.96
Per mu yield (kg) 111.2 ?125.8 ?131.2 ?142.7 ?157 ????167.3 ????177.3
Volume increase (%) ?13.1 ?18.0 ?28.33 ?41.54 ????50.45 ????59.44
Annotate: find out that by table 8 spraying behind the organic potassic fertilizer every index all compares and shine.
Experiment 5: organic potassic fertilizer is to the influence of cigarette quality
Testing program: handle CK and 0.3%, triplicate for two.Spraying once the back detects.
Table 9 organic potassic fertilizer is to the influence of cigarette quality
Handle Nicotine (%) Potassium content (%) Nitrogen (%) Total reducing sugar (%) Nitrogen/sugar
CK ?0.818 ?1.89 ?0.98 ?29.76 ?32.42
0.3 middle part ?1.89 ?1.79 ?1.46 ?22.50 ?15.41
(%) bottom ?1.04 ?2.13 ?0.978 ?25.90 ?26.48
Annotate: find out that by table 9 organic potassic fertilizer has significant improvement effect to the quality of tobacco.

Claims (4)

1, a kind of organic potassic fertilizer is characterized in that: by C 5H 7KO 3, tensio-active agent, conditioning agent form.
2, a kind of production method of organic potassic fertilizer is characterized in that: place dissolving tank to be dissolved in water KOH, make the aqueous solution of 30-70%, slowly add the C in the reactor 5H 8O 3In; under normal temperature or 60-120 degree Celsius, stir; react after 2-3 hour; add conditioning agent; react after 30 minutes, add tensio-active agent, react after 30 minutes; the pH value of solution is transferred to 6-8 and detects its content promptly can be made into liquid organic potassic fertilizer finished product, or under 100-120 degree Celsius, add thermal crystalline or granulation or dust and make SOLID ORGANIC potash fertilizer finished product.
3, the production method of organic potassic fertilizer according to claim 1, tensio-active agent is as: alkylsulfonate, alkylbenzene sulfonate, soil temperature 20, valeric acid, butyric acid ammonium or 2,3,6-three phenylformic acid.
4, the production method of organic potassic fertilizer according to claim 1, conditioning agent is as: hydoxyisoxazole, indolic acid, alkene profit, alar-85,2-4-D, zinc sulfate, ferrous sulfate, ammonium molybdate.
CN 00113759 2000-03-16 2000-03-16 An organic potassium fertilizer and its producing method Pending CN1314328A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007071186A1 (en) * 2005-12-22 2007-06-28 Shaanxi Ju Chuan Fu Wan Jia Stock Company, Ltd. Organic potassium fertilizer containing urea
CN101165011B (en) * 2006-10-16 2010-07-07 陕西汉唐环保农业有限公司 Organic potassium fertilizer prepared from composite organic acid and producing method thereof
CN102320869A (en) * 2011-08-16 2012-01-18 江门市英豪农科有限公司 Sorbose potassium alcoholate liquid fertilizer
CN104609947A (en) * 2015-01-04 2015-05-13 咸阳三精科工贸有限公司 Organic water-soluble fertilizer containing organic acid and chitosan and preparation method thereof
CN105503354A (en) * 2016-01-08 2016-04-20 贵州省烟草科学研究院 Foliar application agent for improving potassium content of tobacco leaves and application method thereof
CN105669255A (en) * 2016-01-29 2016-06-15 杨美玲 Preparation of novel green potash fertilizer
CN110981587A (en) * 2019-11-28 2020-04-10 张家港美景荣化学工业有限公司 Organic potassium fertilizer for drip irrigation and preparation method thereof
CN111116258A (en) * 2019-11-28 2020-05-08 张家港美景荣化学工业有限公司 Organic potassium composition containing polyhydric alcohol and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007071186A1 (en) * 2005-12-22 2007-06-28 Shaanxi Ju Chuan Fu Wan Jia Stock Company, Ltd. Organic potassium fertilizer containing urea
CN101165011B (en) * 2006-10-16 2010-07-07 陕西汉唐环保农业有限公司 Organic potassium fertilizer prepared from composite organic acid and producing method thereof
CN102320869A (en) * 2011-08-16 2012-01-18 江门市英豪农科有限公司 Sorbose potassium alcoholate liquid fertilizer
CN102320869B (en) * 2011-08-16 2014-10-29 江门市英豪农科有限公司 Potassium sorbitol liquid fertilizer
CN104609947A (en) * 2015-01-04 2015-05-13 咸阳三精科工贸有限公司 Organic water-soluble fertilizer containing organic acid and chitosan and preparation method thereof
CN105503354A (en) * 2016-01-08 2016-04-20 贵州省烟草科学研究院 Foliar application agent for improving potassium content of tobacco leaves and application method thereof
CN105669255A (en) * 2016-01-29 2016-06-15 杨美玲 Preparation of novel green potash fertilizer
CN110981587A (en) * 2019-11-28 2020-04-10 张家港美景荣化学工业有限公司 Organic potassium fertilizer for drip irrigation and preparation method thereof
CN111116258A (en) * 2019-11-28 2020-05-08 张家港美景荣化学工业有限公司 Organic potassium composition containing polyhydric alcohol and preparation method thereof

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