WO2007071186A1 - Organic potassium fertilizer containing urea - Google Patents
Organic potassium fertilizer containing urea Download PDFInfo
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- WO2007071186A1 WO2007071186A1 PCT/CN2006/003498 CN2006003498W WO2007071186A1 WO 2007071186 A1 WO2007071186 A1 WO 2007071186A1 CN 2006003498 W CN2006003498 W CN 2006003498W WO 2007071186 A1 WO2007071186 A1 WO 2007071186A1
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- organic
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- fertilizer
- potassium
- potassium fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
Definitions
- the invention belongs to the technical field of production and preparation of fertilizers, and relates to an organic (acid) potassium fertilizer containing urea. Background technique
- Foliar fertilizer is a new type of fertilizer developed in recent years, especially the effect of crop topdressing is better than the use of potassium alone.
- Organic acids are not only receptors for nitrogen assimilation, but also regulate the physiological functions of crops. Potassium can promote photosynthesis, and the combination of the two is better.
- the organic (acid) potash produced by the applicant of the present application is also a foliar fertilizer (see Chinese invention patent number).
- R is at least one of CH plant, CH 3 CH 2 -, CH 3 C0CH z CH 2 -, CH 3 CHNH 2 -, H00CCH 2 CH 2 -, and K is potassium.
- This patented product has been produced and become a commodity. Since its launch in 1996, the product has become a fertilizer for the production of "green food" because of its high fertilizer efficiency, easy absorption, low dosage, low cost, obvious increase in yield, and non-toxic, harmless and residue-free. The brand is very popular among farmers. However, as a foliar fertilizer, the organic potassium fertilizer of Patent No. ZL96118644. 5 is lacking in organic (acid) potassium fertilizer and does not contain nitrogen.
- the object of the present invention is to provide an organic potassium fertilizer containing urea.
- the organic potassium fertilizer obtained not only contains organic acid, but also contains potassium and nitrogen inorganic nutrients, and is a new type of liquid organic compound fertilizer.
- organic potassium fertilizer containing urea which has the following chemical structure formula of organic potassium fertilizer
- the specific preparation method of the above organic potassium fertilizer containing urea is to add urea at room temperature (20 ° C) in the organic liquid potassium fertilizer produced by the patent No. ZL96118644.
- the theoretical basis of the invention :
- the solubility of urea in water at a normal temperature of 20 ° C is 105 g / 100 g
- the solubility in commercial organic clock fertilizer has reached 37. 5g / 100g
- the commercial organic potassium fertilizer already contains 60% of the solute.
- urea is very soluble in liquid organic potassium fertilizer, and organic acid and nitrogen are assimilated under the coordination of potassium.
- the use of the fertilizer is more significant, and the application value of the fertilizer is higher.
- the present invention adds a certain amount of urea to the organic (acid) potassium fertilizer to make it an organic (acid) potassium fertilizer with urea added.
- the prepared fertilizer contains not only organic acid, but also potassium and nitrogen inorganic nutrients. It is a new liquid organic compound fertilizer.
- urea as the foliar fertilizer is the best kind of nitrogen fertilizer, and it is easily absorbed by crops.
- the water solubility of the urea is excellent.
- the addition of 1-37. 5% of the urea when the ratio of the weight of the urea added to the liquid organic potassium fertilizer reaches 37.5%, the liquid organic compound obtained after the addition
- the content of urea in the mixed fertilizer is up to 27.3%, the nitrogen content is increased by 0.46% to 12.5%, and the content of potassium oxide is reduced from 18, 0% to 17.82-13. 09%;
- the relative increase in the total amount of (nitrogen and potassium oxide) is more suitable for crops for multiple nutrient needs.
- the urea-containing organic (acid) potassium fertilizer of the present invention has two ways in the preparation of the product; one way is to maintain the commercial brand of the organic potassium fertilizer obtained by the patent number ZL96118644. 5, that is, in the company's existing above 0 ⁇ 10 ⁇
- the product is analyzed, when the product K 2 0% -18. 5-20. 0, add 1. 0-10.
- the second way is to continue to add urea on the basis of adding 1-10% urea in the first way, so that the weight of urea reaches 37.5%, and finally the nitrogen content of the product is greatly increased, and the urea content is up to 27 3%, the nitrogen nutrient content of the fertilizer increased from 4.18% to 12. 55%, the potassium oxide content decreased slightly; while the total nutrient content increased, the applicant prepared the product of the second route as a product separately. , declare new product brands. Table 2 gives some practical examples:
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The present invention provides an organic potassium fertilizer comprising an organic potassium salt and urea. The chemical structural formula of the organic potassium salt is R-COOK, wherein R is at least one of CH3- CH3CH2- CH3COCH2CH2- CH3CHNH2- and HOOCCH2CH2- K is potassium. The ratio of the organic potassium salt and urea is 100:(1-37.5). Such fertilizer contains organic acid and inorganic nutrient which consists of potassium and nitrogen, wherein the amount of urea can reach to 27.3%, while the content of nitrogen increases by 12.56%. The invention provides a new liquid organic compound fertilizer which satisfies the need of crop nutrition.
Description
一种含有尿素的有机钟肥 Organic clock fertilizer containing urea
技术领域 Technical field
本发明属于肥料的生产与制备技术领域， 涉及一种含有尿素的有机 (酸）钾肥。 背景技术 The invention belongs to the technical field of production and preparation of fertilizers, and relates to an organic (acid) potassium fertilizer containing urea. Background technique
叶面肥是近年来发展的一种新型的肥料， 特别是作物追肥效果比单 独使用钾肥更好。 有机酸不仅是氮同化的受体， 也能调节作物的生理功 能， 钾可以促进光合作用， 两者结合效果更好。 例如， 本申请的申请人 生产的有机 （酸） 钾肥也是一种叶面肥， （参见中国发明专利号 Foliar fertilizer is a new type of fertilizer developed in recent years, especially the effect of crop topdressing is better than the use of potassium alone. Organic acids are not only receptors for nitrogen assimilation, but also regulate the physiological functions of crops. Potassium can promote photosynthesis, and the combination of the two is better. For example, the organic (acid) potash produced by the applicant of the present application is also a foliar fertilizer (see Chinese invention patent number).
ZL96118644. 5 , 申请日 1996年 3月 19日）， 其化学结构式为： ZL96118644. 5 , Application date March 19, 1996), its chemical structure is:
o o
// //
R-C R-C
\ \
OK 式中 R为 CH厂， CH3CH2-, CH3C0CHzCH2-, CH3CHNH2-, H00CCH2CH2-中的 至少一种， K为钾。该专利产品已进行生产、成为商品。该产品自从 1996 年投放市场以来， 以其具有肥效高、 易吸收、 用量少、 费用低、 增产幅 度明显， 并且无毒、 无害、 无残留等特点， 已经成为生产 "绿色食品" 的肥料品牌， 深受广大农民的欢迎。 但是作为叶面肥， 专利号 ZL96118644. 5的有机钾肥美中不足的是有机（酸）钾肥中并不含有氮元 素， 如果能将尿素添加至上述有机（酸）钾肥中， 更好的发挥有机酸同 化氮的作用， 使肥料中的氮、 钾和有机酸发挥协同效应， 其效果会更显 著。 目前尚未发现这方面的相关报道。 In the formula, R is at least one of CH plant, CH 3 CH 2 -, CH 3 C0CH z CH 2 -, CH 3 CHNH 2 -, H00CCH 2 CH 2 -, and K is potassium. This patented product has been produced and become a commodity. Since its launch in 1996, the product has become a fertilizer for the production of "green food" because of its high fertilizer efficiency, easy absorption, low dosage, low cost, obvious increase in yield, and non-toxic, harmless and residue-free. The brand is very popular among farmers. However, as a foliar fertilizer, the organic potassium fertilizer of Patent No. ZL96118644. 5 is lacking in organic (acid) potassium fertilizer and does not contain nitrogen. If urea can be added to the above organic (acid) potassium fertilizer, the organic acid assimilation can be better played. The effect of nitrogen makes the synergistic effect of nitrogen, potassium and organic acids in the fertilizer, and the effect will be more significant. No relevant reports have been found in this regard.
发明内容
本发明的目的在于， 提供一种含有尿素的有机钾肥， 制得的该有机 钾肥不仅含有机酸， 还含有钾、 氮无机营养， 是一秤新的液体有机复混 肥品种。 Summary of the invention The object of the present invention is to provide an organic potassium fertilizer containing urea. The organic potassium fertilizer obtained not only contains organic acid, but also contains potassium and nitrogen inorganic nutrients, and is a new type of liquid organic compound fertilizer.
为了实现上述任务， 本发明提供的技术方案是： In order to achieve the above tasks, the technical solution provided by the present invention is:
一种含有尿素的有机钾肥 , 含有如下化学结构式的有机钾肥， An organic potassium fertilizer containing urea, which has the following chemical structure formula of organic potassium fertilizer,
〃 O 〃 O
R-C R-C
\ \
OK 式中 R为 CH3— , CH3CH2-， CH3C0CH2CH2-, CH3CHNH2- , HOOCCH2CH2-中的 至少一种， -. K为钾， 其中： 还含有如下重量比例的尿素： 即有机钟肥： 尿素 = 100: ( 1 ~ 37. 5 )。 具体而言， 本发明得到的一种含有尿素的有机钾肥， 是在专利号 96118644. 5有机钾肥中添加尿素, 其重量比为: 有机钾肥： 尿素 = 100: ( 1 - 37. 5 λ In the formula, R is at least one of CH 3 — , CH 3 CH 2 —, CH 3 C0CH 2 CH 2 —, CH 3 CHNH 2 — , HOOCCH 2 CH 2 —, and K is potassium, wherein: Urea in the following weight ratio: organic clock fertilizer: urea = 100: (1 ~ 37. 5). Specifically, the organic potassium fertilizer containing urea obtained by the invention is added with urea in the organic potassium fertilizer of Patent No. 96118644. The weight ratio thereof is: organic potassium fertilizer: urea = 100: (1 - 37. 5 λ
上述含有尿素的有机钾肥具体的制备方法是， 在以专利号 ZL96118644. 5生产的有机液体钾肥中常温（20 °C ) 下加入尿素， 其重量 比为： 有机 4甲肥： 尿素 = 100: ( 1 - 37. 5 ), 而后搅拌， 使尿素充分溶解 到有机钾肥中即成。 本发明的理论基础： The specific preparation method of the above organic potassium fertilizer containing urea is to add urea at room temperature (20 ° C) in the organic liquid potassium fertilizer produced by the patent No. ZL96118644. The weight ratio of the compound is: organic 4 fertilizer: urea = 100: ( 1 - 37. 5 ), and then stir, so that the urea is fully dissolved in the organic potassium fertilizer. The theoretical basis of the invention:
尿素在常温 20 °C下水中的溶解度为 105g/100g, 在商品有机钟肥中 溶解度已经达到 37. 5g/100g, 而商品有机钾肥中已经含有 60%的溶质。 显而易见， 这是一种非常有意义的发现。 经申请人的实验证明， 尿素在 液体有机钾肥中溶解性非常好， 有机酸和氮在钾元素的协调下， 同化作
用更加显著， 使肥料的应用价值更高， 本发明将有机（酸）钾肥中加入 一定量的尿素， 使其成为添加尿素的有机（酸）钾肥。 制得的肥料中不 仅含有机酸， 还含有钾、 氮无机营养， 是一种新的液体有机复混肥品种。 The solubility of urea in water at a normal temperature of 20 ° C is 105 g / 100 g, the solubility in commercial organic clock fertilizer has reached 37. 5g / 100g, and the commercial organic potassium fertilizer already contains 60% of the solute. Obviously, this is a very meaningful discovery. Applicant's experiments prove that urea is very soluble in liquid organic potassium fertilizer, and organic acid and nitrogen are assimilated under the coordination of potassium. The use of the fertilizer is more significant, and the application value of the fertilizer is higher. The present invention adds a certain amount of urea to the organic (acid) potassium fertilizer to make it an organic (acid) potassium fertilizer with urea added. The prepared fertilizer contains not only organic acid, but also potassium and nitrogen inorganic nutrients. It is a new liquid organic compound fertilizer.
而且尿素作为叶面肥是氮肥最好的一种， 极易被作物吸收。 尿素的 水溶性极好，在申请人的液体有机钾肥中添加 1-37. 5%的尿素， 当尿素添 加的重量与液体有机钾肥的比例达到 37. 5%时，添加后得到的液体有机复 混肥中尿素含量可达 27. 3%, 氮营养含量增加 0. 46%- 12. 55%, 氧化钾含 量由 18, 0%减少到 17. 82-13. 09%; 鉴于产品中营养成分（氮和氧化钾） 的总量相对增加， 更适合作物对多种营养的需要。 具体实施方式 Moreover, urea as the foliar fertilizer is the best kind of nitrogen fertilizer, and it is easily absorbed by crops. The water solubility of the urea is excellent. In the liquid organic potassium fertilizer of the applicant, the addition of 1-37. 5% of the urea, when the ratio of the weight of the urea added to the liquid organic potassium fertilizer reaches 37.5%, the liquid organic compound obtained after the addition The content of urea in the mixed fertilizer is up to 27.3%, the nitrogen content is increased by 0.46% to 12.5%, and the content of potassium oxide is reduced from 18, 0% to 17.82-13. 09%; The relative increase in the total amount of (nitrogen and potassium oxide) is more suitable for crops for multiple nutrient needs. Detailed ways
本发明的含有尿素的有机（酸）钾肥， 在制备产品时有两种途径； 一种途径是保持以专利号 ZL96118644. 5 制得的有机钾肥的商品品牌不 变， 即在公司现有的上述商品的液体有机钟肥生产过程中， 对产品进行 分析， 当产品的 K20%-18. 5-20. 0时， 加入 1. 0—10。/«的工业尿素 （具体 操作指标见附表 1 ), 产品中氮营养增加 0. 46-4. 18%; 而后进行搅拌（冬 季生产尿素溶解性能下降,可加热到 40-60°C ),尿素全部溶解并均匀后产 品即成。 表 1 : 尿素添加量计算表The urea-containing organic (acid) potassium fertilizer of the present invention has two ways in the preparation of the product; one way is to maintain the commercial brand of the organic potassium fertilizer obtained by the patent number ZL96118644. 5, that is, in the company's existing above 0至10。 When the product is in the process of the production of the liquid organic fertilizer, the product is analyzed, when the product K 2 0% -18. 5-20. 0, add 1. 0-10. /«Industrial urea (see Table 1 for specific operating indicators), the nitrogen nutrient in the product is increased by 0.446 - 4.18%; and then stirred (the urea solubility in winter production is reduced, can be heated to 40-60 ° C), After the urea is completely dissolved and even, the product is ready. Table 1: Urea addition amount calculation table
20°/α 添力口尿素 添力口后 氮营养增 20% 添力口尿素 添力口后 氮营养增20°/α Adding force to the urea after adding the force to increase the nitrogen nutrition by 20 %
( % ) 20% 加 W ( % ) Κ20% 加 （％ )( % ) 2 0% plus W ( % ) Κ 2 0% plus (%)
20 10 18. 18 4. 18 19. 5 8 18. 05 3, 4120 10 18. 18 4. 18 19. 5 8 18. 05 3, 41
20 9 18. 35 3. 80 19. 5 7 18. 22 3. 0120 9 18. 35 3. 80 19. 5 7 18. 22 3. 01
20 8 18. 52 3. 41 19. 5 6 18. 40 2. 6120 8 18. 52 3. 41 19. 5 6 18. 40 2. 61
20 7 18. 69 3. 01 19. 5 5 18. 57 2. 19
20 6 18. 87 2. 61 19. 5 4 18. 75 1. 7720 7 18. 69 3. 01 19. 5 5 18. 57 2. 19 20 6 18. 87 2. 61 19. 5 4 18. 75 1. 77
20 5 19. 05 2. 19 19. 5 3 18. 93 1. 3420 5 19. 05 2. 19 19. 5 3 18. 93 1. 34
19. 0 5 18. 10 2. 19 18. 5 2 18. 14 0. 9019. 0 5 18. 10 2. 19 18. 5 2 18. 14 0. 90
19. 0 4 18. 27 1. 77 18. 5 1 18. 32 0. 4619. 0 4 18. 27 1. 77 18. 5 1 18. 32 0. 46
19. 0 3 18. 45 1. 34 18. 5 0. 5 18. 41 0. 2319. 0 3 18. 45 1. 34 18. 5 0. 5 18. 41 0. 23
19. 0 2 18. 63 0. 90 18. 5 0. 4 18. 43 0. 1819. 0 2 18. 63 0. 90 18. 5 0. 4 18. 43 0. 18
19. 0 1 18. 81 0. 46 18. 5 0. 3 18. 45 0. 1419. 0 1 18. 81 0. 46 18. 5 0. 3 18. 45 0. 14
19. 0 0. 5 18. 91 0. 23 18. 5 0. 2 18. 46 0. 0919. 0 0. 5 18. 91 0. 23 18. 5 0. 2 18. 46 0. 09
18. 4 1 18. 22 0. 46 18. 3 1 18. 11 0. 4618. 4 1 18. 22 0. 46 18. 3 1 18. 11 0. 46
18. 4 0. 5 18. 31 0. 23 18. 3 0. 5 18. 21 0. 2318. 4 0. 5 18. 31 0. 23 18. 3 0. 5 18. 21 0. 23
18. 4 0. 4 18. 33 0. 18 18. 3 0. 4 18. 23 0. 1818. 4 0. 4 18. 33 0. 18 18. 3 0. 4 18. 23 0. 18
18. 4 0. 3 18. 35 0. 14 18. 3 0. 3 18. 25 0. 1418. 4 0. 3 18. 35 0. 14 18. 3 0. 3 18. 25 0. 14
18. 4 0. 2 18. 36 0. 09 18. 3 0. 2 18. 26 0. 0918. 4 0. 2 18. 36 0. 09 18. 3 0. 2 18. 26 0. 09
18. 4 0. 1 18. 38 0. 05 18. 3 0. 1 18. 28 0. 05 从表 1可以看出， 添加尿素含量小于 1 % , K20 %变化和氮营养增加 都很小， 无实际意义， 在这种途径下添加尿素得到的产品， 有机钾肥的 总质量不变， 氮营养增加， 维持公司现有的有机钾肥的商品品牌。 18. 4 0. 1 18. 38 0. 05 18. 3 0. 1 18. 28 0. 05 As can be seen from Table 1, the addition of urea content is less than 1%, K 2 0 % change and nitrogen nutrient increase are very small. , no practical significance, the product obtained by adding urea under this route, the total quality of organic potassium fertilizer is unchanged, the nitrogen nutrition is increased, and the company's existing organic potash product brand is maintained.
第二种途径是在第一种途径已添加 1-10%尿素基础上， 继续添加尿 素，使尿素的重量达到 37. 5%以内，最终使得到的产品氮含量大幅度上升， 尿素含量达 27. 3%,肥料的氮营养含量从 4. 18%增加到 12. 55%, 氧化钾含 量小幅度下降； 而养分总量升高， 申请人将第二种途径制备的产品另行 作为一种产品， 申报新的商品品牌。 表 2给出一些实际的例子： The second way is to continue to add urea on the basis of adding 1-10% urea in the first way, so that the weight of urea reaches 37.5%, and finally the nitrogen content of the product is greatly increased, and the urea content is up to 27 3%, the nitrogen nutrient content of the fertilizer increased from 4.18% to 12. 55%, the potassium oxide content decreased slightly; while the total nutrient content increased, the applicant prepared the product of the second route as a product separately. , declare new product brands. Table 2 gives some practical examples:
表 2 Table 2
申请人在实验基地种植小麦， 采用原有的商品有机钾肥（专利号
ZL96118644. 5 ) 和含有尿素的有机钾肥及其清水进行了对比试验， 实验 证明， 本发明的含有尿素的有机钾肥较原有的有机钾肥有更好的增产效 果。 试验及方差分析数据如表 3: 表 3 不同肥料对小麦产量的影响 The applicant planted wheat in the experimental base, using the original commercial organic potash fertilizer (patent number ZL96118644. 5) Contrast test with organic potassium fertilizer containing urea and its clean water. Experiments show that the organic potassium fertilizer containing urea of the invention has better yield increasing effect than the original organic potassium fertilizer. The test and analysis of variance data are shown in Table 3: Table 3 Effect of different fertilizers on wheat yield
Claims
1. 一种含有尿素的有机钾肥， 含有如下化学结构式的有机 4甲肥， o 1. An organic potassium fertilizer containing urea, which has the following chemical structure: organic 4 fertilizer, o
// //
R-C R-C
\ \
OK 式中 R为 CH3-， CH3CH2— , CH3C0CH2CH2-, CH3CHNH2-, H00CCH2CH2-中的 至少一种， K为钾， 其特征在于： In the formula, R is at least one of CH 3 -, CH 3 CH 2 — , CH 3 C0CH 2 CH 2 -, CH 3 CHNH 2 -, H00CCH 2 CH 2 -, and K is potassium, which is characterized by:
还含有如下重量比例的尿素： 即有机钾肥: 尿素 = 100: ( 1 - 37. 5 Χ
It also contains urea in the following proportion by weight: ie organic potash: urea = 100: ( 1 - 37. 5 Χ
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100227020A CN100363307C (en) | 2005-12-22 | 2005-12-22 | Organic potassium fertilizer containing urea |
| CN200510022702.0 | 2005-12-22 |
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| WO2007071186A1 true WO2007071186A1 (en) | 2007-06-28 |
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| PCT/CN2006/003498 WO2007071186A1 (en) | 2005-12-22 | 2006-12-20 | Organic potassium fertilizer containing urea |
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| WO (1) | WO2007071186A1 (en) |
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| CN101165011B (en) * | 2006-10-16 | 2010-07-07 | 陕西汉唐环保农业有限公司 | Organic potassium fertilizer prepared from composite organic acid and producing method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135469A (en) * | 1996-03-19 | 1996-11-13 | 西安海宏生化高新技术有限公司 | Organic potassium fertilizer |
| CN1221716A (en) * | 1998-12-30 | 1999-07-07 | 王长山 | Method for prodcing high effective ureido compound fertilizer |
| CN1314328A (en) * | 2000-03-16 | 2001-09-26 | 刘兆宁 | An organic potassium fertilizer and its producing method |
| CN1435396A (en) * | 2002-01-28 | 2003-08-13 | 郑秀兴 | Method for producing binary compound urea-based N and K fertilizer |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100401247B1 (en) * | 2000-12-29 | 2003-10-17 | 윤채혁 | Non-fermented compost, organic manure and a preparation method thereof |
| CN1206192C (en) * | 2002-12-10 | 2005-06-15 | 李兰廷 | Humic acid multiple fertilizer with mixed organic and inorganic components as well as its preparation technique |
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- 2005-12-22 CN CNB2005100227020A patent/CN100363307C/en not_active Expired - Fee Related
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- 2006-12-20 WO PCT/CN2006/003498 patent/WO2007071186A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1135469A (en) * | 1996-03-19 | 1996-11-13 | 西安海宏生化高新技术有限公司 | Organic potassium fertilizer |
| CN1221716A (en) * | 1998-12-30 | 1999-07-07 | 王长山 | Method for prodcing high effective ureido compound fertilizer |
| CN1314328A (en) * | 2000-03-16 | 2001-09-26 | 刘兆宁 | An organic potassium fertilizer and its producing method |
| CN1435396A (en) * | 2002-01-28 | 2003-08-13 | 郑秀兴 | Method for producing binary compound urea-based N and K fertilizer |
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| Publication number | Publication date |
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| CN100363307C (en) | 2008-01-23 |
| CN1793063A (en) | 2006-06-28 |
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