CN101058522B - Leaf surface fertilizer for composite amino acid chelate complex - Google Patents
Leaf surface fertilizer for composite amino acid chelate complex Download PDFInfo
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- CN101058522B CN101058522B CN2007101036087A CN200710103608A CN101058522B CN 101058522 B CN101058522 B CN 101058522B CN 2007101036087 A CN2007101036087 A CN 2007101036087A CN 200710103608 A CN200710103608 A CN 200710103608A CN 101058522 B CN101058522 B CN 101058522B
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- amino acid
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- chelates
- foliage fertilizer
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Abstract
The invention discloses a leaf fertilizer and making method of composite amino acid chelate, which is characterized by the following: hydrolyzing protein waste into composite amino acid; adding trace element to chelate with the composite amino acid; improving usage of fertilizer; modifying and activating soil as well as the quality of crop.
Description
Technical field
The present invention relates to a kind of foliage fertilizer field of containing the needed chelates of composite amino acid of various crop.
Background technology
Foliage fertilizer is the forties in 18th century, and Gray Si has just begun research, proves on the blade face of iron deficiency to spray iron preparation, and the iron deficiency blade is restored.Later many people confirm to spray some element in succession and can rescue because of lacking the caused nutritional deficiency symptom of this kind element, as blooming when bearing pods to rape on boron deficient soil, spray the boron preparation and can eliminate rape " colored and unreal ".After pin bears pods under the peanut, spray the phosphorus preparation, it is full to promote that fruit enriches, and improves output.When corn lacks zinc, often cause corn " grey leaf disease ", the spray zinc fertilizer is rescued very soon.During the apple boron deficiency, can improve single fruit weight and ultimate production at full-bloom stage spray boron liquid.Chinese cabbage sprays potassium primary phosphate in earlier stage at lotus throne later stage and balling can improve output, and improves the commodity rate of I and II.Executing the foliage fertilizer volume increase in tobacco leaf fertility benefit in mid-term also clearly waits.Because these examples make people deepen understanding to replenishing plant nutrition by foliage fertilizer, since the forties in 19th century, the effective measure that handle is used as rescuing crop nutritional deficiency disease and regulates crop alimentary by leaf dressing in agricultural.Particularly under adverse environmental factor, the root absorbing function is subjected to obstacle, leaf dressing performance special-effect.Crop is few to micro-requirement, and trace element is not enough in the soil, often can satisfy the crop needs by foliage-spray, and effect is more obvious.
Foliage fertilizer have economy, efficiently, safely, absorb characteristics such as fast, therefore, more and more pay attention to exploitation, production and the application of foliage fertilizer in recent years both at home and abroad.The commodity foliage fertilizer is existing hundreds of, and majority is to name with the use method, and main component can be inorganic salt, also can be compositions such as amino acid, humic acids, the multiple often composition of commodity foliage fertilizer.The effect of increasing production of foliage fertilizer is different different because of soil, crop varieties.Show according to test statistics: increasing production 5%～10% on food crop, is 5%～15% on the oil crops, and fruit tree, vegetables are 5%～25%, and under special circumstances, amount of increase in production is bigger, and can promote quality improving.
Because foliage fertilizer has unique point, obviously promotion volume increase, improves crop quality, widespread use both at home and abroad, and active development foliage fertilizer new variety.Now chemical fertilizer is except that nitrogenous fertilizer, and foliage fertilizer fertilizer ubiquity aqueous fusion property is poor, and impurity is many, and is both uneconomical, easily stops up problem such as shower nozzle again and needs solution badly.
Summary of the invention
Except that nitrogenous fertilizer, foliage fertilizer fertilizer aqueous fusion property is poor at present chemical fertilizer, and impurity is many, and is both uneconomical, easily stops up limitations such as shower nozzle again, and it is a kind of with low cost that the object of the invention is to provide, good water solubility, the foliage fertilizer of the chelates of composite amino acid that utilization ratio is high.
The invention provides a kind of foliage fertilizer of chelates of composite amino acid, be specifically related to the protein raw materials hydrolysis is generated aminoacids complex, the compound that adds trace element makes itself and composite aminoacid chelating generate amino-acid chelate, adds plant-growth regulator and tensio-active agent again and mixes acquisition.
Simultaneously, the present invention also provides the production method of the foliage fertilizer of this chelates of composite amino acid.This method has possessed technical scale throughput.
The concrete preparation method of the foliage fertilizer of chelates of composite amino acid involved in the present invention: will generate aminoacids complex after the protein raw material hydrolysis, the compound and its chelating that add trace element again make amino-acid chelate, further merge mutually with tensio-active agent by adding plant-growth regulator.Specific absorption height, the fertilizer efficiency speed that has this bio-organic chelated trace fertilizer slowly has both, improvement and activating soil, improve function such as crops quality.
The foliar nutrient of chelates of composite amino acid of the present invention is made up of the compounded amino acid starting material of 10-20%, the trace element of 2-8%, the plant-growth regulator of 0.5-4%, the tensio-active agent of 0.5-2% and the water solvent of 66-87% by weight percentage.
The present invention specifically provides the foliar nutrient preparation method of chelates of composite amino acid.By will being raw material with the compound of protein such as donkey bone, donkey hide, cottonseed cake, hoof tips, metallic element (Fe, Cu, Zn, Mn, Se, B, Mo, Ca, Mg, N, P, K etc.).Make through technologies such as proteolysis, chelatings, its main component is a chelated trace element of compound amino acid.
Realization of the present invention is by following concrete technical scheme:
The present invention specifically provides the process that obtains the compounded amino acid starting material, will add in the reactor with protein raw materials such as donkey bone, donkey hide, cottonseed cake, hoof tips, and meter adds water 30%-40% by volume, adds the 4mol/L Ba (OH) of 10%-15% simultaneously
2With the 6mol/L NaOH of 0.5%-1.0%, hydrolysis under 100 ℃ of-110 ℃ of conditions, and keep 8-10h, and hydrolyzed solution is cooled to 60 ℃, obtain the compounded amino acid starting material.
The present invention fully takes into account demand property and the tolerance of various farm crop for trace elements such as boron, manganese, zinc, molybdenum, nitrogen, phosphorus, potassium, by the optimization method that adopts one-factor experiment and orthogonal test to match, utilize the pot experiment and the test of domestic various places of Different Crop, investigate the application effect of different proportionings and each major ingredient different content level, determine its best proportioning, finally determined to can be used for producing the prescription of amino-acid chelate.
The present invention selects the salt of trace elements such as containing boron, manganese, zinc, molybdenum, nitrogen, phosphorus, potassium for use, and addition selects for use concrete different trace elements to constitute according to being suitable for different crops, and it totally is controlled at the 2-8% of weight percent.
The plant-growth regulator that the present invention selects for use is selected the mixture of nitro phenates for use, preferentially selects the 0.5-4% of 5-nitro hydroxyanisole sodium weight percent for use.
The present invention selects for use tensio-active agent to select soil temperature 80, sodium lauryl sulfate and peregal for use, the 0.5-2% of preferred sodium lauryl sulfate weight percent.
Product of the present invention detects through the appointed product quality supervision and test, and every index is qualified fully.
The present invention specifies the innoxious index of finished product and the detected result that detect the detection of Beijing spectrum Buddhist nun physico-chemical analysis test center of unit to show that every index is qualified fully through national Ministry of Agriculture quality inspection center.
Can reach following beneficial effect by implementing content of the present invention:
Specific absorption height, the fertilizer efficiency speed that has the foliage fertilizer of this chelates of composite amino acid slowly has both, improvement and activating soil, improve advantage such as crops quality.Can use field crop volume increase 10-20%, vegetables and melon and fruit increase production more than the 20-45%, and the volume increase probability can reduce the 10-30 applying quantity of chemical fertilizer up to more than 98%.Be that a kind of ideal green food is special-purpose fertile.And can improve disease-resistant crops evil ability, can substitute sterilant fully with this fertilizer.Suppress the harmful microorganism growth effectively, promote the beneficial microorganism breeding, improve its biological activity, thereby, improved Soil structure, improve the ability of the gas permeability of soil and water conservation, guarantor's fertilizer, have fertilizer efficiency height, quality better, cost is low, consumption is few, pollution-free, toxicological harmless, degeneration-resistant strong, short precocious, easy to use, cheap advantage.
The foliage fertilizer of this chelates of composite amino acid can satisfy the required trace element of farm crop and exist with the chelating form, thoroughly solve the chemical precipitation problem, the fertilizer that adopts chelating technology to be prepared from can be dissolved in water rapidly, put for a long time after the dissolving and do not have flocculation, there is not precipitation, add in the time of can cooperating the spray drip irrigation to supply water, realize water and fertilizer coupling, can be widely used in the operation of spray drip irrigation.Utilization rate of fertilizer height, the fertilizer efficiency speed that has this biology chelating foliar nutrient slowly has both, improvement and activating soil, improve advantage such as crop quality.This method technology is simple, easy to operate, production cost is low, raw material sources are wide, pollution-free, toxicological harmless.This product has fertilizer efficiency height, quality better, cost is low, consumption is few, easy to use, cheap advantage.
Description of drawings:
Fig. 1 is the foliage fertilizer operational path of chelates of composite amino acid
Embodiment
Embodiment one: the preparation one of the foliage fertilizer of chelates of composite amino acid
In reactor, add water 400ml, add Ba (OH)
2400ml adds NaOH 20ml, adds donkey bone, donkey hide, cottonseed cake, hoof tips successively and amounts to 800-1000g, hydrolysis under 100 ℃ of-110 ℃ of conditions, and keep 8-10h, hydrolyzed solution is cooled to 60 ℃, add the compound of trace element, be heated to 95-110 ℃, and keep 0.4-1.0h.After this inner complex reaction solution is cooled to room temperature, promptly get liquid chelates of composite amino acid, mix acquisition foliage fertilizer product by adding plant-growth regulator and tensio-active agent again, by weight percentage, plant-growth regulator is preferentially selected 0.5% 5-nitro hydroxyanisole sodium for use, and tensio-active agent is preferentially selected 0.5% sodium lauryl sulfate for use.Concrete operational path is referring to accompanying drawing 1.
Embodiment two: the preparation two of the foliage fertilizer of chelates of composite amino acid
As above-mentioned embodiment concrete steps, obtain liquid chelates of composite amino acid, mix by adding plant-growth regulator and tensio-active agent again, by weight percentage, plant-growth regulator is preferentially selected 4% 5-nitro hydroxyanisole sodium for use, tensio-active agent is preferentially selected 2% sodium lauryl sulfate for use, the technique effect that the foliage fertilizer product application effect of acquisition such as the present invention set forth.
Embodiment three: the manure trial effect of the foliage fertilizer of chelates of composite amino acid on cotton
The test of the foliage fertilizer of chelates of composite amino acid on cotton is that the Shandong cotton is ground No. 22 for the examination cotton variety, emerges 127 days breeding times of this kind, and seedling stage, growing way was strong, and plant type is compact, colony's neat and consistent, and genetic stability is strong.The field permeability is good, and the bell shell is thin, and blow-of-cottons are smooth, and bell weighs 5.9 grams, ginning outturn 42.1%.Have bollworm resisting, anti-withered, multiple resistance such as anti-Huang withers, drought resisting, anti-(anti-) are saline and alkaline, resistant to lodging.The advantage that this kind is the most outstanding is comprehensive better.Yield potential is big, and later stage leaf function is strong, and leaf wadding posterior lobe comes off gently, still is not early ageing of green.
This test is established and is handled 666.7m2, and contrast 666.7m2 does not establish repetition.The foliage fertilizer of handling with chelates of composite amino acid sprays, and the foliage fertilizer of chelates of composite amino acid is not used in contrast, and other aspects are identical with processing.Simultaneously with handle on the same day sowing on April 18th, 1, all mulch film cover-seedings.
April 28 was put seedling in the experimental plot, put seedling after, on the growth of cereal crop seedlings, treatment zone is emerged neatly, blade is luxuriant.The check plot is neat not as treatment zone, and blade is thin and weak.After emerging in cotton, putting seedling, in whole seedling stage, the cotton seedling growth differences of treatment zone and check plot is bigger, and the cotton seedling performance of treatment zone is good, and anti-disease is disease-resistant.The cotton seedling of check plot is then obviously vigorous not as the cotton seedling of treatment zone.Particular case sees Table 1:
The foliage fertilizer cotton test field basic condition investigation of table 1 chelates of composite amino acid
As can be seen from the above table, in the foliage fertilizer cotton test of chelates of composite amino acid, cotton in seedling stage is in the cotton seedling of the foliage fertilizer that uses chelates of composite amino acid, disease resistance strengthens greatly, by three investigation, using the cotton seedling sickness rate of the foliage fertilizer processing of chelates of composite amino acid is 11.7%, and mortality ratio is 2.3%, and the cotton seedling sickness rate of check plot is 27%, and mortality ratio is 4.7%.Contrast zoning cotton disease occurring degree and dead degree are respectively more than 2 times of occurring degree of treatment zone cotton.
After final singling, treatment zone has sprayed 100 times the foliage fertilizer of chelates of composite amino acid twice June 5 and July 10, and so far, the treatment zone processing finishes, from then on treatment zone is identical with the check plot management, and cotton growing way then treatment zone more and more significantly is better than the check plot.October 15, to investigate at last, investigation result sees Table 2:
The foliage fertilizer cotton test field basic condition investigation of table 2 chelates of composite amino acid
As can be seen from Table 5, under the identical condition of density, the cotton of treatment zone is significantly better than the check plot, and Zhu's height, treatment zone are compared according to going average plant height to increase by 5 centimetres, and the average fruit branch of individual plant is counted treatment zone than the check plot, and the individual plant fruit branch increases by 1.Average fruit branch bell number, treatment zone increases by 3 than the check plot.
The per mu yield of theoretical yield treatment zone is 398.95 kilograms, 341.96 kilograms of check plot per mu yields, and treatment zone increases by 56.99 kilograms than check plot per mu yield, and amount of increase in production is 16.7%, and economic benefit is very objective.
By evidence, the foliage fertilizer of chelates of composite amino acid is cheap, and is easy to use, and effect of increasing production is obvious, in Cotton Production, the value of popularization, use arranged very.
Claims (1)
1. the foliage fertilizer of a chelates of composite amino acid, it is characterized in that, by weight percentage, the foliar nutrient of chelates of composite amino acid is made up of the compounded amino acid starting material of 10-20%, the trace element of 2-8%, the 5-nitro hydroxyanisole sodium of 0.5-4%, the sodium lauryl sulphate of 0.5-2% and the water solvent of 66-87%, wherein, trace element is for containing the salt of boron, manganese, zinc, molybdenum, nitrogen, phosphorus, potassium; The compounded amino acid starting material is by adding donkey bone, donkey hide, cottonseed cake, hoof tips protein raw materials in the reactor successively, and meter adds water 30%-40% by volume, adds the 4mol/L Ba (OH) of 10%-15% simultaneously
2With the 6mol/L NaOH of 0.5%-1.0%, hydrolysis under 100 ℃ of-110 ℃ of conditions, and keep 8-10h, hydrolyzed solution is cooled to 60 ℃ of acquisitions.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2007101036087A CN101058522B (en) | 2007-04-30 | 2007-04-30 | Leaf surface fertilizer for composite amino acid chelate complex |
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| CN2007101036087A CN101058522B (en) | 2007-04-30 | 2007-04-30 | Leaf surface fertilizer for composite amino acid chelate complex |
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| CN101058522A CN101058522A (en) | 2007-10-24 |
| CN101058522B true CN101058522B (en) | 2011-03-30 |
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| CN101717281B (en) * | 2009-12-11 | 2012-10-03 | 湖北大学 | Method for preparing edible fungi growth promoter by protein-containing waste |
| CN102153418A (en) * | 2011-05-19 | 2011-08-17 | 湖南省中科农业有限公司 | Efficient amino acid chelated leaf fertilizer containing trace elements |
| CN102838404A (en) * | 2011-06-24 | 2012-12-26 | 汉枫缓释肥料(江苏)有限公司 | Amino acid-containing water-soluble fertilizer added with black bone coal, and preparation method thereof |
| CN102432398A (en) * | 2011-09-28 | 2012-05-02 | 崔广荣 | Insecticidal foliar fertilizer for tripterygium wilfordii |
| CN102992873A (en) * | 2012-10-19 | 2013-03-27 | 田淦平 | Cotton foliar fertilizer |
| CN103232283B (en) * | 2013-03-28 | 2016-03-30 | 张山虎 | Composite fertilizer containing short long guiding element and preparation method thereof |
| CN105110949A (en) * | 2015-09-06 | 2015-12-02 | 定远县绿森苑农林开发有限公司 | Antifreezing amino acid foliage fertilizer and preparation method thereof |
| CN105110950A (en) * | 2015-09-06 | 2015-12-02 | 定远县绿森苑农林开发有限公司 | Cucumber planting high-efficiency foliage fertilizer and preparation method thereof |
| CN105237152A (en) * | 2015-09-06 | 2016-01-13 | 定远县绿森苑农林开发有限公司 | Foliar fertilizer prepared from spoiled milk and preparation method thereof |
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| CN105218234B (en) * | 2015-09-30 | 2019-02-01 | 河北农业大学 | A kind of prevention and treatment walnut yellowtop, ghost, organic fertilizer of white point and preparation method thereof |
| CN105218263A (en) * | 2015-11-20 | 2016-01-06 | 安徽思福农业科技有限公司 | A kind of ammino acid liquid fertilizer |
| CN106316644A (en) * | 2016-08-30 | 2017-01-11 | 山东省寿光蔬菜产业集团有限公司 | Fertilizer production method capable of increasing utilization rate of water-soluble compound fertilizer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049440A (en) * | 1990-09-10 | 1991-02-27 | 四川大学 | Plant growth nutrient |
| CN1154352A (en) * | 1996-01-06 | 1997-07-16 | 北京市思达尔化工新技术公司 | Plant leaves fertilizer |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049440A (en) * | 1990-09-10 | 1991-02-27 | 四川大学 | Plant growth nutrient |
| CN1154352A (en) * | 1996-01-06 | 1997-07-16 | 北京市思达尔化工新技术公司 | Plant leaves fertilizer |
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