CN105218234B - A kind of prevention and treatment walnut yellowtop, ghost, organic fertilizer of white point and preparation method thereof - Google Patents
A kind of prevention and treatment walnut yellowtop, ghost, organic fertilizer of white point and preparation method thereof Download PDFInfo
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- CN105218234B CN105218234B CN201510636096.5A CN201510636096A CN105218234B CN 105218234 B CN105218234 B CN 105218234B CN 201510636096 A CN201510636096 A CN 201510636096A CN 105218234 B CN105218234 B CN 105218234B
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- 235000009496 Juglans regia Nutrition 0.000 title claims abstract description 35
- 235000020234 walnut Nutrition 0.000 title claims abstract description 35
- 239000003895 organic fertilizer Substances 0.000 title claims abstract description 23
- 241001479588 Packera glabella Species 0.000 title claims abstract description 16
- 230000002265 prevention Effects 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title description 7
- 240000007049 Juglans regia Species 0.000 title 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 70
- 241000758789 Juglans Species 0.000 claims abstract description 34
- 244000046052 Phaseolus vulgaris Species 0.000 claims abstract description 31
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims abstract description 31
- 238000000855 fermentation Methods 0.000 claims abstract description 19
- 230000004151 fermentation Effects 0.000 claims abstract description 19
- 239000003337 fertilizer Substances 0.000 claims abstract description 17
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 14
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 25
- 241000894006 Bacteria Species 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 12
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 12
- 229960001763 zinc sulfate Drugs 0.000 claims description 12
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 12
- 229910021538 borax Inorganic materials 0.000 claims description 11
- 239000004328 sodium tetraborate Substances 0.000 claims description 11
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 11
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 9
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 9
- 235000011151 potassium sulphates Nutrition 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 241000193830 Bacillus <bacterium> Species 0.000 claims description 7
- 238000010564 aerobic fermentation Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 201000010099 disease Diseases 0.000 claims description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
- 239000005864 Sulphur Substances 0.000 abstract description 6
- 235000013399 edible fruits Nutrition 0.000 abstract description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 5
- 150000001413 amino acids Chemical class 0.000 abstract description 5
- 239000011575 calcium Substances 0.000 abstract description 5
- 229910052791 calcium Inorganic materials 0.000 abstract description 5
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 abstract description 5
- 235000015097 nutrients Nutrition 0.000 abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 235000016709 nutrition Nutrition 0.000 abstract description 4
- 230000035764 nutrition Effects 0.000 abstract description 4
- 239000011574 phosphorus Substances 0.000 abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 4
- 239000011591 potassium Substances 0.000 abstract description 4
- 229910052700 potassium Inorganic materials 0.000 abstract description 4
- 108090000765 processed proteins & peptides Proteins 0.000 abstract description 4
- 239000011701 zinc Substances 0.000 abstract description 4
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052796 boron Inorganic materials 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 229920001184 polypeptide Polymers 0.000 abstract description 3
- 102000004196 processed proteins & peptides Human genes 0.000 abstract description 3
- 206010022971 Iron Deficiencies Diseases 0.000 abstract description 2
- 235000015165 citric acid Nutrition 0.000 description 18
- 229910052742 iron Inorganic materials 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- ASGCFBXFVSPILZ-UHFFFAOYSA-N [B].[Zn].[Fe] Chemical compound [B].[Zn].[Fe] ASGCFBXFVSPILZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- -1 phosphate anion Chemical class 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention discloses a kind of organic fertilizer formulas rich in active iron zinc, the fertilizer passes through citric acid chelated iron zinc ion, the amino acid and the secondary chelated iron zinc ion of polypeptides matter generated after fermented bean dregs coating and its bean pulp fermentation, increase the validity of iron zinc to the maximum extent, solve the problems, such as directly to apply ferrous sulfate validity is low and EDTA-Fe is expensive is difficult to be widely applied, nitrogen is rich in dregs of beans material, phosphorus, calcium, the nutrients such as sulphur, zinc is supplemented in right amount in fertilizer simultaneously, boron, potassium nutrition, efficiently solve walnut physiological iron deficiency " yellowtop ", walnut ghost, the problems such as numb walnut " white point " and physiological fallen fruit.
Description
Technical field
The present invention relates to a kind of organic fertilizer, walnut iron-deficient " yellowtop ", sky on especially a kind of prevention and treatment calacareous soil
The organic fertilizer and preparation method thereof rich in active iron zinc boron of shell and numb walnut " white point ".
Background technique
North of China calacareous soil pH value is higher to cause the nutrient contents such as effective iron content, zinc low.Walnut is the region
One of main cultivation fruit tree, walnut iron-deficient " yellowtop ", ghost, numb walnut " white point " etc. are to lead to the reduction of walnut yield and quality
Principal element, the upper blindly excessive application nitrogen of production at present, phosphorus, potassium fertilizer have aggravated the physiology of above-mentioned walnut to a certain extent
Disease, and solve the problems, such as that Chlorosis in Fruit trees " yellowtop " is always that the world is difficult to capture, it is primarily due to plant absorption
Iron is Fe2+, and Fe in the soil liquid2+Easily it is oxidized to form Fe3+, or with phosphate anion in the soil liquid etc. form indissoluble
Property compound and cannot be absorbed and used by plants, therefore, directly in the soil apply ferrous sulfate validity it is extremely low.Theoretically
Fe can be chelated by macromolecular organic compounds such as EDTA2+Increase its validity, but due to difficult in the expensive production of EDTA-Fe
To be widely applied, meets the needs of its growth and development since plant mainly absorbs nutrient by root system, pass through in production
The supplement melt quality such as foliage-spray or overground part infusion, which only plays one kind, to be controlled " table " and does not control " sheet " booster action, and increase is native
The content of the effective iron of earth is only the method for solving the above problems and controlling " sheet ".Studies have shown that nitrogen and phosphorus nutrient is rich in dregs of beans material, and
Nitrogen is mostly protein and amino acids substance, and it is organic nitrogen P form that phosphorus element, which is phytic acid substance, has slow releasing function,
The moderate-elements such as calcium, sulphur, magnesium are rich in material simultaneously, supplement active iron, zinc, boron, potassium nutrition in right amount in fertilizer, therefore, application
This organic fertilizer not only improves soil balance and supplies big, middle and trace element ability；Bacillus, ferment bacterium are added in fertilizer
Equal beneficial microbes, can be effectively improved walnut rhizosphere soil micro-ecological environment, the strong tree of promoting root growth be realized, to effectively prevent walnut
The problems such as iron-deficient " yellowtop " and edible walnut ghost, numb walnut " white point " and physiological fallen fruit, reach walnut good quality and high output
Purpose.After retrieving the relevant literature, not being found to have the finished product organic fertilizer report of above-mentioned effect in the prior art.
Summary of the invention
The purpose of the present invention is to provide it is a kind of prevention and treatment walnut yellowtop, ghost, white point organic fertilizer, using citric acid,
Amino acid, polypeptides matter and Fe in fermented bean dregs2+、Zn2+Chelating improves its validity, and it is expensive to solve EDTA-Fe
The problems such as large-area applications are difficult in production.
The object of the invention is also to provide it is a kind of prevention and treatment walnut yellowtop, ghost, white point organic fertilizer preparation method.
Technical concept of the invention is such.Using organic materials such as fermented bean dregs, citric acids, cooperate a certain amount of sulfuric acid
Ferrous iron, zinc sulfate, potassium sulfate etc. and a kind of organic regulation fertilizer rich in active Meso- and micro-nutrients is made.Wherein Fe2+、Zn2+
It chelates etc. and chemically and physically to act on again by citric acid chelating, fermented bean dregs coating and its amino acid, polypeptides matter, avoid
Fe2+It is oxidized to Fe3+And Fe2+、Zn2+Insoluble phosphate is formed with phosphate radical etc., to improve Fe in soil2+、Zn2+'s
Validity.
Specifically, the organic fertilizer of a kind of prevention and treatment walnut yellowtop, ghost, white point, consisting of: dregs of beans 400-420kg, sulphur
Sour ferrous iron 140-160 kg, zinc sulfate 25-35 kg, borax 5-15 kg, potassium sulfate 25-35 kg, citric acid 60-80 kg, ferment
Plain bacterium or ferment bacterium and bacillus press Mixed Microbes 0.5-1.5 kg, the water 279-319 kg of quality 1:1 composition.
A kind of prevention and treatment walnut yellowtop that the present invention provides, ghost, white point organic fertilizer preparation method, including following step
It is rapid:
(1) bean pulp fermentation
Dregs of beans, water, ferment bacterium or ferment bacterium and bacillus are mixed by the Mixed Microbes of quality 1:1 composition, 25-35 DEG C of item
Aerobic fermentation 5-7 d under part, ferment under 20 DEG C of the following conditions 7-10 d, in fermentation process, by material turning 4-6 times, obtains beans
Dregs of rice tunning A；
(2) citric acid and sulfate mixing
Citric acid, ferrous sulfate, zinc sulfate, borax, potassium sulfate are mixed, the mixture B of citric acid and sulfate is obtained；
(3) tunning A is mixed with the mixture B of citric acid and sulfate
50% of tunning A mass obtained by step (1) is mixed with mixture B obtained by step (2), utilizes bean pulp fermentation
The stickum generated in the process bonds the mixture of above-mentioned citric acid and sulfate, obtains mixture C；
(4) fertilizer is coated with
50% of tunning A mass obtained by step (1) is mixed with mixture C obtained by step (3), tunning A coating
In the mixture C obtained by the step (3), can be obtained prevention and treatment walnut yellowtop, ghost, white point organic fertilizer.
Through examining, organic matter >=45%, N+P in prepared organic fertilizer2O5+K2O >=5.0%, pH6.0 or so, moisture≤
30%, meanwhile, ferrous sulfate 15%, zinc sulfate 3%, borax 1% are contained in fertilizer, and rich in the nutrition such as calcium, sulphur, magnesium member in fertilizer
Element.
What the present invention obtained has the beneficial effect that: the present invention is according to walnut uptake characters, for calacareous soil pH high, soil
The effective iron of earth is low and highlights the physiological disease of walnut iron-deficient yellow leaf, directly application ferrous sulfate effect difference and EDTA-Fe price
The problems such as expensive, being reached using the Fe2+ in the amino acid and peptide material chelating ferrous sulfate in citric acid, fermented bean dregs is had
Effect prevents the purpose of walnut physiological iron deficiency, adds zinc, boron, potassium nutrition element in right amount at the same time, in fertilizer, effectively solves food
The problems such as with walnut ghost, numb walnut " white point " and physiological fallen fruit, best fruiting period fruit tree recommendation dosage 25-50 kg/667m2, and not
Apply the processing of this organic fertilizer habits fertilization to compare, apply the organic fertilizer of the rich active iron of the present invention, eat walnut yield increase by 30% with
On, the number of numb walnut best buy walnut increases by 50% or more.
Specific embodiment
The following examples are intended to illustrate the invention.
Embodiment 1
It is a kind of prevention and treatment walnut yellowtop, ghost, white point organic fertilizer, consisting of: dregs of beans 410kg, ferrous sulfate
150kg, zinc sulfate 30kg, 10 kg of borax, 30 kg of potassium sulfate, 70 kg of citric acid, ferment bacterium 0.5kg, bacillus 0.5
Kg, 299 kg of water.
Preparation method is as follows:
(1) bean pulp fermentation
Bacillus is added after dregs of beans is mixed with water and ferment bacterium Mixed Microbes mix, aerobic fermentation under the conditions of 25-35 DEG C
5-7 d, ferment 7-10 d under the conditions of being lower than 20 DEG C, in fermentation process, by material turning 4-6 times, obtains bean pulp fermentation product A；
(2) citric acid is mixed with sulfate, and citric acid is mixed with ferrous sulfate, zinc sulfate, borax, potassium sulfate, obtains lemon
The mixture B of lemon acid and sulfate；
(3) the half material of the bean pulp fermentation product A mass obtained by step (1) is mixed with mixture B obtained by step (2),
The mixture of above-mentioned citric acid and sulfate is bonded using the stickum generated during bean pulp fermentation, is mixed
Object C；
(4) fertilizer is coated with
Residual mass bean pulp fermentation product A obtained by step (1) is coated in mixture C obtained by step (3), can be obtained
Prevent and treat walnut yellowtop, ghost, white point organic fertilizer.
Through examining, organic matter >=45%, N+P in prepared organic fertilizer2O5+K2O >=5.0%, pH6.0, moisture≤30%, together
When, in fertilizer containing in ferrous sulfate 15%, zinc sulfate 3%, borax 1% and fertilizer rich in nutrients such as calcium, sulphur, magnesium.
Embodiment 2
A kind of organic fertilizer rich in active iron zinc, consisting of: dregs of beans 410kg, ferrous sulfate 150kg, zinc sulfate 30kg,
10 kg of borax, 30 kg of potassium sulfate, 70 kg of citric acid, ferment bacterium 1.0kg, 299 kg of water.
Preparation method is as follows:
(1) bean pulp fermentation
Dregs of beans, water, ferment bacterium are mixed, aerobic fermentation 5-7 d under the conditions of 25-35 DEG C, ferment 7- under 20 DEG C of the following conditions
10 d in fermentation process, by material turning 4-6 times, obtain bean pulp fermentation product A；
(2) citric acid, ferrous sulfate, zinc sulfate, borax, potassium sulfate are mixed, obtains the mixing of citric acid and sulfate
Object B；
(3) the half material of the bean pulp fermentation product A mass obtained by step (1) is mixed with mixture B obtained by step (2),
The mixture of above-mentioned citric acid and sulfate is bonded using the stickum generated during bean pulp fermentation, is mixed
Object C；
(4) fertilizer is coated with
Residual mass bean pulp fermentation product A obtained by step (1) is coated in mixture C obtained by step (3), can be obtained
Prevent and treat walnut yellowtop, ghost, white point organic fertilizer.
Through examining, organic matter >=45%, N+P in prepared organic fertilizer2O5+K2O >=5.0%, pH6.1, moisture≤30%, fertilizer
Contain ferrous sulfate 15%, zinc sulfate 3%, borax 1% in material, meanwhile, rich in nutrients such as calcium, sulphur, magnesium in fertilizer.
Claims (1)
1. the organic fertilizer of a kind of prevention and treatment walnut yellowtop, ghost, white point, it is characterised in that composition is in mass ratio are as follows: dregs of beans 400-
420kg, ferrous sulfate 140-160 kg, zinc sulfate 25-35 kg, borax 5-15 kg, potassium sulfate 25-35 kg, citric acid 60-
80 kg, ferment bacterium or ferment bacterium and bacillus press Mixed Microbes 0.5-1.5 kg, the water 279-319 kg of quality 1:1 composition；
The method of being prepared as follows is prepared:
(1) bean pulp fermentation
Dregs of beans, water, ferment bacterium or ferment bacterium and bacillus are mixed by the Mixed Microbes of quality 1:1 composition, under the conditions of 25-35 DEG C
Aerobic fermentation 5-7 d, ferment 7-10 d under the conditions of being lower than 20 DEG C, in fermentation process, by material turning 4-6 times, obtains dregs of beans
Mixed fermentation product A；
(2) citric acid and sulfate mixing
Citric acid, ferrous sulfate, zinc sulfate, borax, potassium sulfate are mixed, the mixture B of citric acid and sulfate is obtained；
(3) tunning A is mixed with the mixture B of citric acid and sulfate
50% of tunning A mass obtained by step (1) is mixed with mixture B obtained by step (2), obtains mixture C；
(4) fertilizer is coated with
50% of tunning A mass obtained by step (1) is mixed with mixture C obtained by step (3), obtains prevention and treatment walnut yellow leaf
Disease, ghost, white point organic fertilizer finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN106187612A (en) * | 2016-07-20 | 2016-12-07 | 安徽三星化工有限责任公司 | A kind of long-acting zinc supplement fertilizer |
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