CN1303119C - 利用共轭二烯和芳族乙烯基化合物生产聚合物的方法,依此方法制备的聚合物及其应用 - Google Patents

利用共轭二烯和芳族乙烯基化合物生产聚合物的方法,依此方法制备的聚合物及其应用 Download PDF

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Publication number
CN1303119C
CN1303119C CNB038182807A CN03818280A CN1303119C CN 1303119 C CN1303119 C CN 1303119C CN B038182807 A CNB038182807 A CN B038182807A CN 03818280 A CN03818280 A CN 03818280A CN 1303119 C CN1303119 C CN 1303119C
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CN
China
Prior art keywords
compound
vinyl
styrene
butadiene
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB038182807A
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English (en)
Chinese (zh)
Other versions
CN1671760A (zh
Inventor
赫伯特·科吉
沃尔夫冈·奥道迈茨
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Sasol Germany GmbH
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Sasol Germany GmbH
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Publication of CN1671760A publication Critical patent/CN1671760A/zh
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Publication of CN1303119C publication Critical patent/CN1303119C/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/30Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Graft Or Block Polymers (AREA)
  • Tires In General (AREA)
CNB038182807A 2002-07-30 2003-07-24 利用共轭二烯和芳族乙烯基化合物生产聚合物的方法,依此方法制备的聚合物及其应用 Expired - Fee Related CN1303119C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10234746A DE10234746B4 (de) 2002-07-30 2002-07-30 Verfahren zur Herstellung von Polymerisaten unter Verwendung von konjugierten Dienen und vinylaromatischen Verbindungen, nach diesem Verfahren hergestellte Polymerisate und deren Verwendung
DE10234746.8 2002-07-30

Publications (2)

Publication Number Publication Date
CN1671760A CN1671760A (zh) 2005-09-21
CN1303119C true CN1303119C (zh) 2007-03-07

Family

ID=7714810

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038182807A Expired - Fee Related CN1303119C (zh) 2002-07-30 2003-07-24 利用共轭二烯和芳族乙烯基化合物生产聚合物的方法,依此方法制备的聚合物及其应用

Country Status (17)

Country Link
US (1) US7151147B2 (https=)
EP (1) EP1525239B1 (https=)
JP (1) JP4523410B2 (https=)
KR (1) KR100897844B1 (https=)
CN (1) CN1303119C (https=)
AT (1) ATE373027T1 (https=)
AU (1) AU2003258461A1 (https=)
BR (1) BR0312910B8 (https=)
CA (1) CA2493620A1 (https=)
DE (2) DE10234746B4 (https=)
ES (1) ES2294353T3 (https=)
MX (1) MXPA05001225A (https=)
NO (1) NO20050777L (https=)
PL (1) PL373291A1 (https=)
RU (1) RU2326895C2 (https=)
WO (1) WO2004016666A1 (https=)
ZA (1) ZA200500814B (https=)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5357012B2 (ja) * 2007-03-26 2013-12-04 旭化成ケミカルズ株式会社 熱可塑性組成物及びその成形体
DE102009009531A1 (de) * 2009-02-18 2010-08-19 Lanxess Deutschland Gmbh Initiatorsystem zur Synthese von Hochvinyl-Dienkautschuken, ein Verfahren zur Herstellung und dessen Verwendung zur Herstellung von Hochvinyl-Dienkautschuken
CN103459431B (zh) 2011-05-27 2015-01-21 旭化成化学株式会社 氢化共轭二烯系共聚物的制造方法
ES2695042T3 (es) 2011-06-22 2018-12-28 Trinseo Europe Gmbh Caucho estireno-butadieno con alto contenido de estireno y vinilo con distribución de peso molecular estrecha y procedimientos para su preparación
CN102977268B (zh) * 2011-09-05 2015-04-15 中国石油化工股份有限公司 共轭二烯烃聚合物和合成橡胶及其制备方法和应用
CN104098810B (zh) * 2013-04-12 2016-02-24 中国石油化工股份有限公司 一种组合物及其在制备阻尼材料中的应用和一种阻尼材料及其制备方法
CA2960005C (en) * 2014-09-04 2023-02-14 Kuraray Co., Ltd. Method for producing anionic polymer
KR102464763B1 (ko) 2017-11-17 2022-11-08 주식회사 엘지화학 블록 공중합체 조성물 제조방법, 이로부터 제조된 블록 공중합체 조성물을 포함하는 아스팔트 조성물
EP4148075A4 (en) * 2020-05-21 2023-11-08 China Petroleum & Chemical Corporation LIQUID BUTYLBENZENE POLYMER, PRODUCTION PROCESS THEREOF AND APPLICATION THEREOF, AS WELL AS COMPOSITION, POLYMER COATING, ADHESIVE AND CROSSLINKING AGENT

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496154A (en) * 1965-10-15 1970-02-17 Phillips Petroleum Co Random copolymerization
EP0304589A1 (de) * 1987-07-28 1989-03-01 Hüls Aktiengesellschaft Verfahren zur Herstellung von Polymerisaten auf Basis von konjugierten Dienen und ggf. monovinylaromatischen Verbindungen
EP0798339A2 (en) * 1996-03-29 1997-10-01 Bridgestone Corporation Stryrene-butadiene copolymer and rubber composition comprising the copolymer

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3294768A (en) * 1963-11-14 1966-12-27 Phillips Petroleum Co Preparation of conjugated diene polymers
US3781261A (en) * 1972-02-03 1973-12-25 Firestone Tire & Rubber Co Metalating rubber polymers
JPS5465787A (en) * 1977-11-07 1979-05-26 Denki Kagaku Kogyo Kk Preparation of conjugated diolefin polymer
JPS57100112A (en) * 1980-12-16 1982-06-22 Asahi Chem Ind Co Ltd Perfectly random styrene-butadiene copolymer rubber
GB8316052D0 (en) * 1983-06-13 1983-07-20 Shell Int Research Elastomeric copolymers
CA2035229A1 (en) * 1990-10-22 1992-04-23 Wen-Liang Hsu Process for preparing a rubbery terpolymer of styrene, isoprene and butadiene
US5534592A (en) * 1995-09-22 1996-07-09 The Goodyear Tire & Rubber Company High performance blend for tire treads
DE19613195A1 (de) * 1996-04-02 1997-10-09 Huels Chemische Werke Ag Reifenlaufflächen mit geringem Rollwiderstand und verbessertem ABS-Bremsen
DE19941314A1 (de) * 1999-08-31 2001-03-01 Bayer Ag Verfahren zur Herstellung eines Copolymerisats auf der Basis von vinylaromatischen Verbindungen und konjugierten Dienen sowie dessen Verwendung zur Herstellung von Vulkanisaten mit einem hervorragenden Dämpfungsverhalten
DE10036055A1 (de) * 2000-07-25 2002-02-07 Bayer Ag Verfahren zur Herstellung von di- oder trifunktionellen Initiatorsystemen auf Lithiumbasis sowie deren Verwendung
DE10053324A1 (de) * 2000-10-27 2002-05-08 Basf Ag Verfahren zum Kettenabbruch bei der anionischen Polymerisation
DE10105401A1 (de) * 2001-02-07 2002-08-22 Bayer Ag Kontinuierliches Verfahren zur Herstellung von Elastomeren
EP1453869A2 (de) * 2001-11-23 2004-09-08 Walter Hellermann Mikrostrukturregler für die anionische polymerisation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496154A (en) * 1965-10-15 1970-02-17 Phillips Petroleum Co Random copolymerization
EP0304589A1 (de) * 1987-07-28 1989-03-01 Hüls Aktiengesellschaft Verfahren zur Herstellung von Polymerisaten auf Basis von konjugierten Dienen und ggf. monovinylaromatischen Verbindungen
EP0798339A2 (en) * 1996-03-29 1997-10-01 Bridgestone Corporation Stryrene-butadiene copolymer and rubber composition comprising the copolymer

Also Published As

Publication number Publication date
RU2326895C2 (ru) 2008-06-20
BR0312910B8 (pt) 2013-02-19
ATE373027T1 (de) 2007-09-15
KR20050033638A (ko) 2005-04-12
ZA200500814B (en) 2006-07-26
RU2005105558A (ru) 2005-08-10
WO2004016666A1 (de) 2004-02-26
CA2493620A1 (en) 2004-02-26
DE50308182D1 (de) 2007-10-25
KR100897844B1 (ko) 2009-05-15
CN1671760A (zh) 2005-09-21
US7151147B2 (en) 2006-12-19
BR0312910B1 (pt) 2013-01-08
JP4523410B2 (ja) 2010-08-11
US20060122343A1 (en) 2006-06-08
NO20050777L (no) 2005-02-14
DE10234746A1 (de) 2003-02-27
DE10234746B4 (de) 2004-04-29
JP2006500435A (ja) 2006-01-05
PL373291A1 (en) 2005-08-22
AU2003258461A1 (en) 2004-03-03
MXPA05001225A (es) 2005-10-18
EP1525239A1 (de) 2005-04-27
ES2294353T3 (es) 2008-04-01
BR0312910A (pt) 2005-06-14
EP1525239B1 (de) 2007-09-12

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