CN1301932C - 有机硅酸盐体系的稳定剂 - Google Patents
有机硅酸盐体系的稳定剂 Download PDFInfo
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- CN1301932C CN1301932C CNB2003101232968A CN200310123296A CN1301932C CN 1301932 C CN1301932 C CN 1301932C CN B2003101232968 A CNB2003101232968 A CN B2003101232968A CN 200310123296 A CN200310123296 A CN 200310123296A CN 1301932 C CN1301932 C CN 1301932C
- Authority
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- China
- Prior art keywords
- stablizer
- mortar
- organosilicate
- pigment
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003381 stabilizer Substances 0.000 title abstract description 3
- 235000019353 potassium silicate Nutrition 0.000 title description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 title 1
- 239000000049 pigment Substances 0.000 claims description 22
- 239000004570 mortar (masonry) Substances 0.000 claims description 16
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000011505 plaster Substances 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- -1 amine compound Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Natural products NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
一种应用通式(I)的叔胺作为可用于室外或室内的有机硅酸盐灰浆和有机硅酸盐颜料的稳定剂。这里R＝(CH2)n，这里n＝1-8，最好为n＝2-6，以及R1＝-CH3；-CH2-CH3；-CH2-CH2-OH；-CH2-CH(OH)-CH3，其相互可为相同或不同。
Description
本发明涉及在普通有机硅酸盐体系中用于有机硅酸盐灰浆和有机硅酸盐颜料的稳定剂。该体系含有硅酸盐作为粘合剂。
实践表明，在过去无论是灰浆或颜料中所含有的硅酸盐均会和灰浆或颜料中的其它成分进行反应。这会使得产品变稠和使其无法使用。为防止该作用，按照目前已知的技术是加入稳定剂。在市场上可获得的产品含有季铵化的胺化合物。该化合物由于生产方法的原因含有相当大量的有机溶剂。
如果将有机硅酸盐灰浆和有机硅酸盐颜料在室内加以应用，那么其一定会在涂膜后在室内形成刺激的可察觉放射状的涂层。该放射状的产生原因主要是在颜料组成中所含有的醛或有机挥发溶剂。
特别是室内所喜欢的颜色中不能含有溶剂。溶剂既可含于这类有机硅酸盐灰浆和有机硅酸盐颜料的总成分中，也可含于单一组成中，例如在稳定剂中。
该附于有机硅酸盐灰浆和有机硅酸盐颜料的稳定剂有可能成为刺激的VOC-超标的一主要的原因，因为在稳定剂的生产中通常存在有机溶剂，如丙二醇。“VOC”意思是在组成中含有“挥发性有机成分”或挥发的有机化合物如溶剂。
本发明任务是提供稳定剂，其特别是使用它所生产的有机硅酸盐灰浆和有机硅酸盐颜料，含有特别低的溶剂含量，或仅是微量的含量。该稳定剂首先当然是不会使得流变学，即颜料和灰浆成分的粘度变差的。
该任务将通过使用通式(I)的叔胺作为可用于室外或室内的有机硅酸盐灰浆和有机硅酸盐颜料的稳定剂来解决，
通式(I)
这里
R要么是(CH2)n，n＝1-8，R1＝-CH3；-CH2-CH3；-CH2-CH2-OH；-CH2-CH(OH)-CH3，其相互可为相同或不同或R＝(CH2)n-X-(CH2)n，X＝N-R1和R1＝CH3；要么是CH2-CH3。
在通式(I)中优选的是系数n＝2至6。按照本发明所使用的稳定剂含有有机的，挥发性的溶剂低于100ppm，优选的是低于50ppm。
作为通式(I)的化合物所涉及适合按照本发明的稳定剂为R＝(CH2)n和R1＝CH3-CH2-CH3特别是N，N，N′，N′-四甲基乙二胺，N，N，N′，N′-四甲基-1，3-丙二胺，N，N-二乙基-，N′，N′-二甲基1，3-丙二胺和N，N，N′，N′-四甲基-1，6-己二胺。
作为具有R＝(CH2)n-X-(CH2)n，X＝N-R1和R1＝CH3；-CH2-CH3的这类化合物，值得一提的是N，N，N′，N″，N″-五甲基二乙基三胺和N，N，N′，N″，N″-五甲基二丙烯基三胺。
在通式(I)中所包括的化合物还有N，N，N′，N′-四-(2-羟丙基)-乙二胺特别合适和可被优选的采用。
通式(I)化合物的一种生产方法可采用US-2,697,118所列举的方法。另外优选的上述提及的该胺的代表N，N，N′，N′-四-(2-羟丙基)-乙二胺也可通过商业上从Fluka公司获得。该胺作为有机硅酸盐灰浆和有机硅酸盐颜料稳定剂的应用在该US专利中未被提及。
采用该化合物可将灰浆和颜料配方配方设计，其具有强的亲水性，在碱性水溶液中可溶和可长时间，以天或月计保持稳定。这里的术语稳定性本领域专业人员理解为粘度的稳定性，即较小的含有该稳定剂的成形物的稠度变化。
该按照通式(I)的稳定剂可在室外-和室内有机硅酸盐灰浆和有机硅酸盐颜料中加以使用。该稳定剂的特征是，其仅含有微量级的有机的，挥发性的溶剂，或完全不含这类溶剂。特别是按照本发明所应用的稳定剂仅含有少于100ppm，优选的少于50ppm的有机挥发性溶剂。
下面借助于含有按照本发明所应用的稳定剂的灰浆和颜料配方的例子，对本发明加以简述。
含有按照本发明所采用的稳定剂有机硅酸盐颜料的配方设计
例I.
粘合剂(Acronal 290 D) 80.00
矿物填充材料，共计 620.00
(滑石，硅酸钾，碳酸钙，以不同的
粒度和重量比例)
颜料/TiO2 100.00
成膜助剂 5.00
增稠剂 5.00
疏水剂 20.00
用于调整所需PH-值的
苛性钾溶液(10％) 1.00
按照本发明所应用的稳定剂 5.00
水 164.00
所有给出的数据是重量份数
含有按照本发明所采用的稳定剂有机硅酸盐灰浆的配方设计
例II.
粘合剂(Acronal 290 D) 50.00
矿物填充材料，共计 825.00
(不同粒度的大理石，硅酸钾，
碳酸钙，云母)
玻璃纤维 5.00
成膜助剂 5.00
增稠剂 2.50
按照本发明所应用的稳定剂 4.00
疏水剂 20.00
水 88.50
所有给出的数据是重量份数
应用技术试验
室内应用的有机硅酸盐-颜料配方设计的粘度按照施用1天后，14天后和28天后采用Brookfield旋转粘度计在室温下进行测定。对此获得下述的以mpas计的数据值：
1天 14天 28天
按照技术状况的颜料
所获得的季铵化的
稳定剂 20000 47000 48250
无稳定剂的配方设计 22000 47500 69000
商业上通常的配方设计1* 22750 41050 47500
商业上通常的配方设计2* 21750 42000 46000
按照本发明的配方设计** 19000 40750 44100
●*这是含有VOC的季胺化胺-稳定剂的配方设计。
●**在按照本发明的配方设计中，会发现其VOC较少和无季铵化的稳定剂，VOC少于100ppm，例如N，N，N′，N′-四-(2-羟丙基)-乙二胺。
在所述的颜料配方中，按照本发明所应用的稳定剂，其粘度在28天后还保持稳定，即该稳定剂与商业上通常的季铵化的和含有大量VOC的配方设计相比保持较低的变化。该粘度值对该颜料的可应用性是有利的，即它们有利于涂抹和分布。
Claims (5)
1.通式(I)的叔胺在作为用于室外或室内的有机硅酸盐灰浆和有机硅酸盐颜料的稳定剂中的用途，
通式(I)
这里
R＝(CH2)n，这里n＝1-8，以及R1＝-CH3；-CH2-CH3；-CH2-CH2-OH；-CH2-CH(OH)-CH3，其相互为相同或不同。
2.按照权利要求1的用途，其特征是n＝2-6。
3.按照权利要求1的用途，其特征是，稳定剂中所含有的有机挥发性溶剂低于100ppm。
4.按照权利要求1的用途，其特征是，稳定剂中所含有的有机挥发性溶剂低于50ppm。
5.一种有机硅酸盐灰浆或有机硅酸盐颜料，其特征是其含有按照权利要求1或2的稳定剂。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10260540A DE10260540B3 (de) | 2002-12-21 | 2002-12-21 | Verwendung tertiärer Amine als Stabilisatoren für Wasserglassysteme |
| DE10260540.8 | 2002-12-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1511798A CN1511798A (zh) | 2004-07-14 |
| CN1301932C true CN1301932C (zh) | 2007-02-28 |
Family
ID=32336577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003101232968A Expired - Lifetime CN1301932C (zh) | 2002-12-21 | 2003-12-22 | 有机硅酸盐体系的稳定剂 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1431354B1 (zh) |
| CN (1) | CN1301932C (zh) |
| AT (1) | ATE406418T1 (zh) |
| DE (2) | DE10260540B3 (zh) |
| PT (1) | PT1431354E (zh) |
| SI (1) | SI1431354T1 (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006045853A1 (de) * | 2006-09-28 | 2008-04-03 | Cognis Ip Management Gmbh | Zusammensetzungen zur Viskositätsstabilisierung von Silikatbinder-haltigen Formulierungen |
| DE102016207877A1 (de) | 2016-05-09 | 2017-11-09 | Clariant International Ltd | Stabilisatoren für Silikatfarben |
| FI3712216T3 (fi) * | 2019-03-18 | 2023-03-08 | Bk Giulini Gmbh | Stabilointiaineet dispersiosilikaattimaaleja varten |
| CZ2019507A3 (cs) * | 2019-08-06 | 2020-09-09 | First Point a.s. | Izolační materiál a způsob jeho výroby |
| CZ309105B6 (cs) * | 2019-08-06 | 2022-02-02 | First Point a.s. | Protipožární zateplovací materiál a způsob jeho výroby |
| CZ308490B6 (cs) * | 2019-08-07 | 2020-09-16 | First Point a.s. | Izolační materiál a způsob jeho výroby |
| US20230042328A1 (en) | 2019-12-17 | 2023-02-09 | Basf Se | Ionic liquid for stabilizing viscosity of silicate-based coatings |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035487A (zh) * | 1988-01-14 | 1989-09-13 | 山道士有限公司 | 稳定混凝土残余物的方法 |
| JP2002053815A (ja) * | 2000-04-14 | 2002-02-19 | Sk Kaken Co Ltd | エナメル粒子分散液及びその製造方法ならびに多彩模様塗料組成物 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL124542C (zh) * | 1963-01-30 | |||
| DE1667538B2 (de) * | 1967-01-13 | 1977-06-02 | Henkel & Cie GmbH, 4000 Düsseldorf | Verfahren zur herstellung bestaendiger alkalisilikatloesungen |
| JPS5682859A (en) * | 1979-12-11 | 1981-07-06 | Sakura Color Prod Corp | Ink composition |
| EP0383492A3 (en) * | 1989-02-14 | 1991-08-07 | Thoro System Products Inc. | Dispersion system for rapid curing cement compositions |
| KR100802886B1 (ko) * | 2000-09-13 | 2008-02-13 | 아크조 노벨 엔.브이. | 강철의 프라이머 코팅방법 |
-
2002
- 2002-12-21 DE DE10260540A patent/DE10260540B3/de not_active Expired - Fee Related
-
2003
- 2003-12-17 PT PT03028935T patent/PT1431354E/pt unknown
- 2003-12-17 DE DE50310404T patent/DE50310404D1/de not_active Expired - Lifetime
- 2003-12-17 SI SI200331433T patent/SI1431354T1/sl unknown
- 2003-12-17 AT AT03028935T patent/ATE406418T1/de not_active IP Right Cessation
- 2003-12-17 EP EP03028935A patent/EP1431354B1/de not_active Expired - Lifetime
- 2003-12-22 CN CNB2003101232968A patent/CN1301932C/zh not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035487A (zh) * | 1988-01-14 | 1989-09-13 | 山道士有限公司 | 稳定混凝土残余物的方法 |
| JP2002053815A (ja) * | 2000-04-14 | 2002-02-19 | Sk Kaken Co Ltd | エナメル粒子分散液及びその製造方法ならびに多彩模様塗料組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE10260540B3 (de) | 2004-07-29 |
| EP1431354B1 (de) | 2008-08-27 |
| ATE406418T1 (de) | 2008-09-15 |
| DE50310404D1 (de) | 2008-10-09 |
| EP1431354A1 (de) | 2004-06-23 |
| SI1431354T1 (sl) | 2009-02-28 |
| CN1511798A (zh) | 2004-07-14 |
| PT1431354E (pt) | 2008-10-17 |
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