CN1277888C - 具有非线性电流-电压特性的聚合物和该聚合物的生产方法 - Google Patents
具有非线性电流-电压特性的聚合物和该聚合物的生产方法 Download PDFInfo
- Publication number
- CN1277888C CN1277888C CN02140255.8A CN02140255A CN1277888C CN 1277888 C CN1277888 C CN 1277888C CN 02140255 A CN02140255 A CN 02140255A CN 1277888 C CN1277888 C CN 1277888C
- Authority
- CN
- China
- Prior art keywords
- polymkeric substance
- filler
- kinds
- ratio
- nonlinear current
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000000945 filler Substances 0.000 claims abstract description 63
- 239000011159 matrix material Substances 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims description 92
- 239000000203 mixture Substances 0.000 claims description 20
- 238000005245 sintering Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 230000005611 electricity Effects 0.000 claims description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000002071 nanotube Substances 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- 230000005684 electric field Effects 0.000 description 7
- 239000011787 zinc oxide Substances 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- -1 polysiloxane Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/105—Varistor cores
- H01C7/108—Metal oxide
- H01C7/112—ZnO type
Abstract
Description
填料 | 填料组分(以wt%计) | |||
R1 | R2 | S1 | S2 | |
R1 | 100 | - | - | - |
R82 | 80 | 20 | - | - |
R55 | 50 | 50 | - | - |
R28 | 20 | 80 | - | - |
R2 | - | 100 | - | - |
S1 | - | - | 100 | - |
S73 | - | - | 70 | 30 |
S37 | - | - | 30 | 70 |
S2 | - | - | - | 100 |
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01810645.0 | 2001-07-02 | ||
EP01810645A EP1274102B1 (de) | 2001-07-02 | 2001-07-02 | Polymercompound mit nichtlinearer Strom-Spannungs-Kennlinie und Verfahren zur Herstellung eines Polymercompounds |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1394914A CN1394914A (zh) | 2003-02-05 |
CN1277888C true CN1277888C (zh) | 2006-10-04 |
Family
ID=8184001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN02140255.8A Expired - Lifetime CN1277888C (zh) | 2001-07-02 | 2002-07-02 | 具有非线性电流-电压特性的聚合物和该聚合物的生产方法 |
Country Status (10)
Country | Link |
---|---|
US (2) | US7320762B2 (zh) |
EP (1) | EP1274102B1 (zh) |
JP (1) | JP2003049084A (zh) |
CN (1) | CN1277888C (zh) |
AT (1) | ATE499691T1 (zh) |
AU (1) | AU5068402A (zh) |
CA (1) | CA2390195A1 (zh) |
DE (1) | DE50115800D1 (zh) |
PL (1) | PL206222B1 (zh) |
RU (1) | RU2282263C2 (zh) |
Families Citing this family (46)
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JPS6147424A (ja) * | 1984-08-10 | 1986-03-07 | Sumitomo Chem Co Ltd | ジアルキルベンゼンのパラ選択的脱アルキル化方法 |
US7825491B2 (en) * | 2005-11-22 | 2010-11-02 | Shocking Technologies, Inc. | Light-emitting device using voltage switchable dielectric material |
US7695644B2 (en) * | 1999-08-27 | 2010-04-13 | Shocking Technologies, Inc. | Device applications for voltage switchable dielectric material having high aspect ratio particles |
US20100044079A1 (en) * | 1999-08-27 | 2010-02-25 | Lex Kosowsky | Metal Deposition |
US20080035370A1 (en) * | 1999-08-27 | 2008-02-14 | Lex Kosowsky | Device applications for voltage switchable dielectric material having conductive or semi-conductive organic material |
WO2001017320A1 (en) | 1999-08-27 | 2001-03-08 | Lex Kosowsky | Current carrying structure using voltage switchable dielectric material |
US20100044080A1 (en) * | 1999-08-27 | 2010-02-25 | Lex Kosowsky | Metal Deposition |
US7446030B2 (en) * | 1999-08-27 | 2008-11-04 | Shocking Technologies, Inc. | Methods for fabricating current-carrying structures using voltage switchable dielectric materials |
ATE403935T1 (de) | 2004-04-06 | 2008-08-15 | Abb Research Ltd | Elektrisches nichtlineares material für anwendungen mit hoher und mittlerer spannung |
EP1603140A1 (de) * | 2004-06-04 | 2005-12-07 | ABB Technology AG | Aktivteil für einen gekapselten Überspannungsableiter |
EP1736998A1 (en) * | 2005-06-21 | 2006-12-27 | Abb Research Ltd. | Varistor field control tape |
US20100264225A1 (en) * | 2005-11-22 | 2010-10-21 | Lex Kosowsky | Wireless communication device using voltage switchable dielectric material |
EP1969627A4 (en) | 2005-11-22 | 2010-01-20 | Shocking Technologies Inc | SEMICONDUCTOR DEVICES COMPRISING VOLTAGE SWITCHING MATERIALS PROVIDING OVERVOLTAGE PROTECTION |
FR2898427A1 (fr) * | 2006-03-08 | 2007-09-14 | Nexans Sa | Composition a haute permittivite pour cable elecrique ou dispositif de raccordement de tels cables |
US20080029405A1 (en) * | 2006-07-29 | 2008-02-07 | Lex Kosowsky | Voltage switchable dielectric material having conductive or semi-conductive organic material |
EP2054896B1 (en) * | 2006-07-29 | 2012-06-13 | Shocking Technologies, Inc. | Voltage switchable dielectric material having conductive or semi-conductive organic material |
US7968014B2 (en) * | 2006-07-29 | 2011-06-28 | Shocking Technologies, Inc. | Device applications for voltage switchable dielectric material having high aspect ratio particles |
US20080032049A1 (en) * | 2006-07-29 | 2008-02-07 | Lex Kosowsky | Voltage switchable dielectric material having high aspect ratio particles |
WO2008036423A2 (en) * | 2006-09-24 | 2008-03-27 | Shocking Technologies, Inc. | Formulations for voltage switchable dielectric material having a stepped voltage response and methods for making the same |
SE530587C2 (sv) * | 2006-10-31 | 2008-07-15 | Abb Research Ltd | Elektriskt fältstyrande material |
US20120119168A9 (en) * | 2006-11-21 | 2012-05-17 | Robert Fleming | Voltage switchable dielectric materials with low band gap polymer binder or composite |
US8288911B2 (en) * | 2006-12-15 | 2012-10-16 | General Electric Company | Non-linear dielectrics used as electrical insulation for rotating electrical machinery |
US7793236B2 (en) * | 2007-06-13 | 2010-09-07 | Shocking Technologies, Inc. | System and method for including protective voltage switchable dielectric material in the design or simulation of substrate devices |
US8206614B2 (en) * | 2008-01-18 | 2012-06-26 | Shocking Technologies, Inc. | Voltage switchable dielectric material having bonded particle constituents |
US8203421B2 (en) * | 2008-04-14 | 2012-06-19 | Shocking Technologies, Inc. | Substrate device or package using embedded layer of voltage switchable dielectric material in a vertical switching configuration |
US20100047535A1 (en) * | 2008-08-22 | 2010-02-25 | Lex Kosowsky | Core layer structure having voltage switchable dielectric material |
US20100065785A1 (en) * | 2008-09-17 | 2010-03-18 | Lex Kosowsky | Voltage switchable dielectric material containing boron compound |
CN102246246A (zh) * | 2008-09-30 | 2011-11-16 | 肖克科技有限公司 | 含有导电芯壳粒子的电压可切换电介质材料 |
US9208931B2 (en) * | 2008-09-30 | 2015-12-08 | Littelfuse, Inc. | Voltage switchable dielectric material containing conductor-on-conductor core shelled particles |
US8362871B2 (en) * | 2008-11-05 | 2013-01-29 | Shocking Technologies, Inc. | Geometric and electric field considerations for including transient protective material in substrate devices |
US9226391B2 (en) | 2009-01-27 | 2015-12-29 | Littelfuse, Inc. | Substrates having voltage switchable dielectric materials |
US8272123B2 (en) | 2009-01-27 | 2012-09-25 | Shocking Technologies, Inc. | Substrates having voltage switchable dielectric materials |
US8399773B2 (en) | 2009-01-27 | 2013-03-19 | Shocking Technologies, Inc. | Substrates having voltage switchable dielectric materials |
KR101679099B1 (ko) | 2009-03-26 | 2016-11-23 | 쇼킹 테크놀로지스 인코포레이티드 | 전압 스위칭형 유전 물질을 갖는 소자 |
US9053844B2 (en) * | 2009-09-09 | 2015-06-09 | Littelfuse, Inc. | Geometric configuration or alignment of protective material in a gap structure for electrical devices |
EP2513913A1 (en) | 2009-12-14 | 2012-10-24 | 3M Innovative Properties Company | Dielectric material with non-linear dielectric constant |
US20110198544A1 (en) * | 2010-02-18 | 2011-08-18 | Lex Kosowsky | EMI Voltage Switchable Dielectric Materials Having Nanophase Materials |
US9224728B2 (en) * | 2010-02-26 | 2015-12-29 | Littelfuse, Inc. | Embedded protection against spurious electrical events |
US9082622B2 (en) | 2010-02-26 | 2015-07-14 | Littelfuse, Inc. | Circuit elements comprising ferroic materials |
US9320135B2 (en) * | 2010-02-26 | 2016-04-19 | Littelfuse, Inc. | Electric discharge protection for surface mounted and embedded components |
US8331074B2 (en) * | 2010-07-01 | 2012-12-11 | Cooper Technologies Company | Grading devices for a high voltage apparatus |
US20140287175A1 (en) * | 2013-03-19 | 2014-09-25 | Shawcor Ltd. | Products for stress control in electrical power cables |
JP6355492B2 (ja) * | 2013-10-03 | 2018-07-11 | アルパッド株式会社 | 複合樹脂及び電子デバイス |
TWI605029B (zh) * | 2016-10-12 | 2017-11-11 | 不含銻的壓敏電阻組成物及積層式壓敏電阻器 | |
US10720767B2 (en) | 2017-01-31 | 2020-07-21 | 3M Innovative Properties Company | Multilayer stress control article and dry termination for medium and high voltage cable applications |
CN110003656B (zh) * | 2019-04-11 | 2022-01-14 | 北京工业大学 | 一种硅橡胶复合材料及其制备方法 |
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US3689863A (en) * | 1969-12-08 | 1972-09-05 | Matsushita Electric Ind Co Ltd | Voltage dependent resistors in a surface barrier type |
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DE2363172C3 (de) | 1973-12-14 | 1978-08-03 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Spannungsabhängiger Widerstand |
US4003855A (en) * | 1975-06-23 | 1977-01-18 | General Electric Company | Nonlinear resistor material and method of manufacture |
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DE3470975D1 (en) * | 1983-12-22 | 1988-06-09 | Bbc Brown Boveri & Cie | Zinc oxide varistor |
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DE19824104B4 (de) | 1998-04-27 | 2009-12-24 | Abb Research Ltd. | Nichtlinearer Widerstand mit Varistorverhalten |
DE19821239C5 (de) * | 1998-05-12 | 2006-01-05 | Epcos Ag | Verbundwerkstoff zur Ableitung von Überspannungsimpulsen und Verfahren zu seiner Herstellung |
-
2001
- 2001-07-02 DE DE50115800T patent/DE50115800D1/de not_active Expired - Lifetime
- 2001-07-02 EP EP01810645A patent/EP1274102B1/de not_active Expired - Lifetime
- 2001-07-02 AT AT01810645T patent/ATE499691T1/de active
-
2002
- 2002-06-27 AU AU50684/02A patent/AU5068402A/en not_active Abandoned
- 2002-06-27 US US10/180,078 patent/US7320762B2/en not_active Expired - Lifetime
- 2002-06-28 CA CA002390195A patent/CA2390195A1/en not_active Abandoned
- 2002-07-01 JP JP2002192413A patent/JP2003049084A/ja active Pending
- 2002-07-01 RU RU2002117582/04A patent/RU2282263C2/ru not_active IP Right Cessation
- 2002-07-02 PL PL354829A patent/PL206222B1/pl unknown
- 2002-07-02 CN CN02140255.8A patent/CN1277888C/zh not_active Expired - Lifetime
-
2007
- 2007-08-20 US US11/892,148 patent/US7618550B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU5068402A (en) | 2003-01-09 |
PL354829A1 (en) | 2003-01-13 |
EP1274102A1 (de) | 2003-01-08 |
CN1394914A (zh) | 2003-02-05 |
EP1274102B1 (de) | 2011-02-23 |
RU2002117582A (ru) | 2004-01-20 |
JP2003049084A (ja) | 2003-02-21 |
US7320762B2 (en) | 2008-01-22 |
ATE499691T1 (de) | 2011-03-15 |
PL206222B1 (pl) | 2010-07-30 |
DE50115800D1 (de) | 2011-04-07 |
US7618550B2 (en) | 2009-11-17 |
RU2282263C2 (ru) | 2006-08-20 |
US20080023678A1 (en) | 2008-01-31 |
US20030010960A1 (en) | 2003-01-16 |
CA2390195A1 (en) | 2003-01-02 |
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