CN1267238A - 使用金属配合物的均相氧化催化作用 - Google Patents

使用金属配合物的均相氧化催化作用 Download PDF

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Publication number
CN1267238A
CN1267238A CN98808220A CN98808220A CN1267238A CN 1267238 A CN1267238 A CN 1267238A CN 98808220 A CN98808220 A CN 98808220A CN 98808220 A CN98808220 A CN 98808220A CN 1267238 A CN1267238 A CN 1267238A
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active site
oxidable
group
described method
catalyst
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CN98808220A
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Chinese (zh)
Inventor
T·J·科林斯
S·W·戈顿-怀利
C·G·沃默
C·P·霍尔维茨
E·S·乌菲尔曼
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Carnegie Mellon University
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Carnegie Mellon University
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Publication of CN1267238A publication Critical patent/CN1267238A/zh
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00Asymmetric syntheses
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38Lanthanides other than lanthanum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/39Actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN98808220A 1997-06-20 1998-06-18 使用金属配合物的均相氧化催化作用 Pending CN1267238A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87975297A 1997-06-20 1997-06-20
US08/879,752 1997-06-20

Publications (1)

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CN1267238A true CN1267238A (zh) 2000-09-20

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CN98808220A Pending CN1267238A (zh) 1997-06-20 1998-06-18 使用金属配合物的均相氧化催化作用

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EP (1) EP0991468A1 (xx)
JP (1) JP2002505688A (xx)
KR (1) KR20010013986A (xx)
CN (1) CN1267238A (xx)
AP (1) AP9901723A0 (xx)
AU (1) AU8152998A (xx)
BR (1) BR9810754A (xx)
CA (1) CA2295006A1 (xx)
IL (1) IL133484A0 (xx)
NO (1) NO996282L (xx)
OA (1) OA11237A (xx)
PL (1) PL337523A1 (xx)
WO (1) WO1998058735A1 (xx)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104785296A (zh) * 2015-04-17 2015-07-22 中国石油大学(华东) 一种用于液化石油气脱硫醇的液体钴磺化酞菁催化剂
CN106082419A (zh) * 2016-05-10 2016-11-09 北京服装学院 大环酰胺金属配合物降解含有机污染物废水的方法及应用
CN106111199A (zh) * 2016-06-21 2016-11-16 中南民族大学 多含硫氮杂卟啉阵列纳米晶的制备与应用
CN112675908A (zh) * 2020-12-23 2021-04-20 清华大学 一种醇类的有氧氧化方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
JP4104966B2 (ja) 2002-03-06 2008-06-18 花王株式会社 漂白触媒
KR100561058B1 (ko) * 2004-09-23 2006-03-17 삼성토탈 주식회사 페녹시계 리간드가 포함된 올레핀 중합용 촉매 및 이를사용한 올레핀 (공)중합방법
JP5002761B2 (ja) * 2007-03-09 2012-08-15 国立大学法人大阪大学 オキソポルフィリン系電極触媒材料

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758682A (en) * 1983-03-17 1988-07-19 California Institute Of Technology Homogeneous coordination compounds as oxidation catalysts
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104785296A (zh) * 2015-04-17 2015-07-22 中国石油大学(华东) 一种用于液化石油气脱硫醇的液体钴磺化酞菁催化剂
CN106082419A (zh) * 2016-05-10 2016-11-09 北京服装学院 大环酰胺金属配合物降解含有机污染物废水的方法及应用
CN106082419B (zh) * 2016-05-10 2019-05-31 北京服装学院 大环酰胺金属配合物降解含有机污染物废水的方法及应用
CN106111199A (zh) * 2016-06-21 2016-11-16 中南民族大学 多含硫氮杂卟啉阵列纳米晶的制备与应用
CN106111199B (zh) * 2016-06-21 2018-10-12 中南民族大学 多含硫氮杂卟啉阵列纳米晶的制备与应用
CN112675908A (zh) * 2020-12-23 2021-04-20 清华大学 一种醇类的有氧氧化方法

Also Published As

Publication number Publication date
BR9810754A (pt) 2000-08-15
AU8152998A (en) 1999-01-04
IL133484A0 (en) 2001-04-30
NO996282L (no) 2000-02-21
NO996282D0 (no) 1999-12-17
KR20010013986A (ko) 2001-02-26
PL337523A1 (en) 2000-08-28
JP2002505688A (ja) 2002-02-19
AP9901723A0 (en) 1999-12-31
OA11237A (en) 2003-05-27
WO1998058735A1 (en) 1998-12-30
EP0991468A1 (en) 2000-04-12
CA2295006A1 (en) 1998-12-30

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