OA11237A - Homogeneous oxidation catalysis using metal complexes - Google Patents

Homogeneous oxidation catalysis using metal complexes Download PDF

Info

Publication number
OA11237A
OA11237A OA9900283A OA9900283A OA11237A OA 11237 A OA11237 A OA 11237A OA 9900283 A OA9900283 A OA 9900283A OA 9900283 A OA9900283 A OA 9900283A OA 11237 A OA11237 A OA 11237A
Authority
OA
OAPI
Prior art keywords
oxidizable
sites
site
catalyst
cation
Prior art date
Application number
OA9900283A
Other languages
English (en)
Inventor
Terrence J Collins
Scott W Gordon-Wylie
Colin P Horwitz
Erich S Uffelman
Christine G Woomer
Original Assignee
Univ Carnegie Mellon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Carnegie Mellon filed Critical Univ Carnegie Mellon
Publication of OA11237A publication Critical patent/OA11237A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/39—Actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
OA9900283A 1997-06-20 1999-12-15 Homogeneous oxidation catalysis using metal complexes OA11237A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US87975297A 1997-06-20 1997-06-20

Publications (1)

Publication Number Publication Date
OA11237A true OA11237A (en) 2003-05-27

Family

ID=25374825

Family Applications (1)

Application Number Title Priority Date Filing Date
OA9900283A OA11237A (en) 1997-06-20 1999-12-15 Homogeneous oxidation catalysis using metal complexes

Country Status (13)

Country Link
EP (1) EP0991468A1 (xx)
JP (1) JP2002505688A (xx)
KR (1) KR20010013986A (xx)
CN (1) CN1267238A (xx)
AP (1) AP9901723A0 (xx)
AU (1) AU8152998A (xx)
BR (1) BR9810754A (xx)
CA (1) CA2295006A1 (xx)
IL (1) IL133484A0 (xx)
NO (1) NO996282L (xx)
OA (1) OA11237A (xx)
PL (1) PL337523A1 (xx)
WO (1) WO1998058735A1 (xx)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
JP4104966B2 (ja) * 2002-03-06 2008-06-18 花王株式会社 漂白触媒
KR100561058B1 (ko) * 2004-09-23 2006-03-17 삼성토탈 주식회사 페녹시계 리간드가 포함된 올레핀 중합용 촉매 및 이를사용한 올레핀 (공)중합방법
JP5002761B2 (ja) * 2007-03-09 2012-08-15 国立大学法人大阪大学 オキソポルフィリン系電極触媒材料
CN104785296B (zh) * 2015-04-17 2017-03-08 中国石油大学(华东) 一种用于液化石油气脱硫醇的液体钴磺化酞菁催化剂
CN106082419B (zh) * 2016-05-10 2019-05-31 北京服装学院 大环酰胺金属配合物降解含有机污染物废水的方法及应用
CN106111199B (zh) * 2016-06-21 2018-10-12 中南民族大学 多含硫氮杂卟啉阵列纳米晶的制备与应用
CN112675908A (zh) * 2020-12-23 2021-04-20 清华大学 一种醇类的有氧氧化方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758682A (en) * 1983-03-17 1988-07-19 California Institute Of Technology Homogeneous coordination compounds as oxidation catalysts
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Also Published As

Publication number Publication date
EP0991468A1 (en) 2000-04-12
CN1267238A (zh) 2000-09-20
BR9810754A (pt) 2000-08-15
NO996282D0 (no) 1999-12-17
NO996282L (no) 2000-02-21
AU8152998A (en) 1999-01-04
CA2295006A1 (en) 1998-12-30
IL133484A0 (en) 2001-04-30
AP9901723A0 (en) 1999-12-31
KR20010013986A (ko) 2001-02-26
JP2002505688A (ja) 2002-02-19
WO1998058735A1 (en) 1998-12-30
PL337523A1 (en) 2000-08-28

Similar Documents

Publication Publication Date Title
Larson et al. Iron and manganese oxo complexes, oxo wall and beyond
Belda et al. Bispyridylamides—coordination chemistry and applications in catalytic reactions
Conte et al. Vanadium and molybdenum peroxides: synthesis and catalytic activity in oxidation reactions
Du Bois et al. Nitridomanganese (V) complexes: Design, preparation, and use as nitrogen atom-transfer reagents
Mikhalyova et al. A new efficient iron catalyst for olefin epoxidation with hydrogen peroxide
Spencer et al. Copper chemistry of β-diketiminate ligands: monomer/dimer equilibria and a new class of bis (μ-oxo) dicopper compounds
Kühn et al. Organorhenium (VII) and organomolybdenum (VI) oxides: synthesis and application in oxidation catalysis
Chatterjee Asymmetric epoxidation of unsaturated hydrocarbons catalyzed by ruthenium complexes
Gamelas et al. Molybdenum (vi) catalysts obtained from η 3-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation
Ye et al. Enantioselective transition metal catalysis directed by chiral cations
Bo et al. Highly Active and Robust Ruthenium Complexes Based on Hemilability of Hybrid Ligands for C–H Oxidation
Schroeder et al. Design of and mechanistic studies on a biomimetic iron–imidazole catalyst system for epoxidation of olefins with hydrogen peroxide
Brewer et al. Increase of direct C–C coupling reaction yield by identifying structural and electronic properties of high-spin iron tetra-azamacrocyclic complexes
Zámbó et al. Organometallic 3d transition metal NHC complexes in oxidation catalysis
Rajeev et al. Rational design of first-row transition metal complexes as the catalysts for oxidation of arenes: a homogeneous approach
Schlachta et al. Cyclic iron tetra N-heterocyclic carbenes: synthesis, properties, reactivity, and catalysis
Kühn et al. Synthesis and catalytic application of octahedral Lewis base adducts of dichloro and dialkyl dioxotungsten (VI)
OA11237A (en) Homogeneous oxidation catalysis using metal complexes
Carsch et al. Intramolecular C–H and C–F bond oxygenation by site-differentiated tetranuclear manganese models of the OEC
Guillemot et al. Synthesis and Metal Complexes of Chiral C2‐Symmetric Diamino–Bisoxazoline Ligands
Chan Chiral manganese and iron complexes of binaphthyl Schiff bases: syntheses, crystal structures and asymmetric epoxidation of alkenes
A Brito et al. cis-Dioxomolybdenum (VI) Complexes Containing Chiral Ligands: Synthesis and Catalytic Application in Olefin Epoxidation
Karamé et al. Easy Synthesis of New Chiral Tetradentate N4 Schiff Bases and Their Use as Ligands for Metal Complexes
JP2009136807A (ja) 酸化触媒およびその利用
Gómez et al. Chiral manganese complexes with pinene appended tetradentate ligands as stereoselective epoxidation catalysts