CN1264778C - Ceramic material with activated fluid fuel molecule and combustion aid function and its preparing method and use - Google Patents
Ceramic material with activated fluid fuel molecule and combustion aid function and its preparing method and use Download PDFInfo
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- CN1264778C CN1264778C CN 200410062705 CN200410062705A CN1264778C CN 1264778 C CN1264778 C CN 1264778C CN 200410062705 CN200410062705 CN 200410062705 CN 200410062705 A CN200410062705 A CN 200410062705A CN 1264778 C CN1264778 C CN 1264778C
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- stupalith
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- fluid fuel
- aid function
- fuel molecule
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- 239000000446 fuel Substances 0.000 title claims abstract description 81
- 239000012530 fluid Substances 0.000 title claims abstract description 71
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 8
- 229910010293 ceramic material Inorganic materials 0.000 title abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 58
- 239000000919 ceramic Substances 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 14
- 239000011707 mineral Substances 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 229910052768 actinide Inorganic materials 0.000 claims abstract description 11
- 150000001255 actinides Chemical class 0.000 claims abstract description 11
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 11
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 238000000465 moulding Methods 0.000 claims description 25
- 230000005855 radiation Effects 0.000 claims description 21
- 239000011230 binding agent Substances 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 238000007599 discharging Methods 0.000 claims description 12
- 239000006210 lotion Substances 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 11
- 238000000498 ball milling Methods 0.000 claims description 10
- -1 fully stir Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229910000245 dravite Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- 239000010438 granite Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000013467 fragmentation Methods 0.000 claims description 5
- 238000006062 fragmentation reaction Methods 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004113 Sepiolite Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 4
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 229910000244 elbaite Inorganic materials 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004579 marble Substances 0.000 claims description 4
- 229910052590 monazite Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 150000002910 rare earth metals Chemical class 0.000 claims description 4
- 229910052895 riebeckite Inorganic materials 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 229910052624 sepiolite Inorganic materials 0.000 claims description 4
- 235000019355 sepiolite Nutrition 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- 229910052613 tourmaline Inorganic materials 0.000 claims description 4
- 239000011032 tourmaline Substances 0.000 claims description 4
- 229940070527 tourmaline Drugs 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- JKCNLFMVVZFQNT-UHFFFAOYSA-K [Yb+3].P(=O)([O-])([O-])[O-].[Ce+3] Chemical compound [Yb+3].P(=O)([O-])([O-])[O-].[Ce+3] JKCNLFMVVZFQNT-UHFFFAOYSA-K 0.000 claims description 2
- 229910052656 albite Inorganic materials 0.000 claims description 2
- 239000005030 aluminium foil Substances 0.000 claims description 2
- 229910052612 amphibole Inorganic materials 0.000 claims description 2
- 229910052896 arfvedsonite Inorganic materials 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- BBEWQVDYSULNPB-UHFFFAOYSA-K cerium(3+) lanthanum(3+) phosphate Chemical compound [La+3].[Ce+3].[O-]P([O-])([O-])=O BBEWQVDYSULNPB-UHFFFAOYSA-K 0.000 claims description 2
- 229910052887 cummingtonite Inorganic materials 0.000 claims description 2
- 229910052892 hornblende Inorganic materials 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 229910052611 pyroxene Inorganic materials 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 239000011044 quartzite Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 abstract description 11
- 239000003921 oil Substances 0.000 abstract description 5
- 239000002737 fuel gas Substances 0.000 abstract description 4
- 239000007789 gas Substances 0.000 abstract description 4
- 239000003570 air Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 230000007613 environmental effect Effects 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 229910052755 nonmetal Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 19
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 description 12
- 239000003502 gasoline Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 239000006260 foam Substances 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 238000004134 energy conservation Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- HUWSZNZAROKDRZ-RRLWZMAJSA-N (3r,4r)-3-azaniumyl-5-[[(2s,3r)-1-[(2s)-2,3-dicarboxypyrrolidin-1-yl]-3-methyl-1-oxopentan-2-yl]amino]-5-oxo-4-sulfanylpentane-1-sulfonate Chemical compound OS(=O)(=O)CC[C@@H](N)[C@@H](S)C(=O)N[C@@H]([C@H](C)CC)C(=O)N1CCC(C(O)=O)[C@H]1C(O)=O HUWSZNZAROKDRZ-RRLWZMAJSA-N 0.000 description 3
- 238000005411 Van der Waals force Methods 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- ABJSOROVZZKJGI-OCYUSGCXSA-N (1r,2r,4r)-2-(4-bromophenyl)-n-[(4-chlorophenyl)-(2-fluoropyridin-4-yl)methyl]-4-morpholin-4-ylcyclohexane-1-carboxamide Chemical compound C1=NC(F)=CC(C(NC(=O)[C@H]2[C@@H](C[C@@H](CC2)N2CCOCC2)C=2C=CC(Br)=CC=2)C=2C=CC(Cl)=CC=2)=C1 ABJSOROVZZKJGI-OCYUSGCXSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003462 bioceramic Substances 0.000 description 2
- 229910052729 chemical element Inorganic materials 0.000 description 2
- 229940127573 compound 38 Drugs 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- PIDFDZJZLOTZTM-KHVQSSSXSA-N ombitasvir Chemical compound COC(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@H]1C(=O)NC1=CC=C([C@H]2N([C@@H](CC2)C=2C=CC(NC(=O)[C@H]3N(CCC3)C(=O)[C@@H](NC(=O)OC)C(C)C)=CC=2)C=2C=CC(=CC=2)C(C)(C)C)C=C1 PIDFDZJZLOTZTM-KHVQSSSXSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- UDQTXCHQKHIQMH-KYGLGHNPSA-N (3ar,5s,6s,7r,7ar)-5-(difluoromethyl)-2-(ethylamino)-5,6,7,7a-tetrahydro-3ah-pyrano[3,2-d][1,3]thiazole-6,7-diol Chemical compound S1C(NCC)=N[C@H]2[C@@H]1O[C@H](C(F)F)[C@@H](O)[C@@H]2O UDQTXCHQKHIQMH-KYGLGHNPSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- PSLUFJFHTBIXMW-WYEYVKMPSA-N [(3r,4ar,5s,6s,6as,10s,10ar,10bs)-3-ethenyl-10,10b-dihydroxy-3,4a,7,7,10a-pentamethyl-1-oxo-6-(2-pyridin-2-ylethylcarbamoyloxy)-5,6,6a,8,9,10-hexahydro-2h-benzo[f]chromen-5-yl] acetate Chemical compound O([C@@H]1[C@@H]([C@]2(O[C@](C)(CC(=O)[C@]2(O)[C@@]2(C)[C@@H](O)CCC(C)(C)[C@@H]21)C=C)C)OC(=O)C)C(=O)NCCC1=CC=CC=N1 PSLUFJFHTBIXMW-WYEYVKMPSA-N 0.000 description 1
- SMNRFWMNPDABKZ-WVALLCKVSA-N [[(2R,3S,4R,5S)-5-(2,6-dioxo-3H-pyridin-3-yl)-3,4-dihydroxyoxolan-2-yl]methoxy-hydroxyphosphoryl] [[[(2R,3S,4S,5R,6R)-4-fluoro-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-hydroxyphosphoryl]oxy-hydroxyphosphoryl] hydrogen phosphate Chemical compound OC[C@H]1O[C@H](OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(=O)OC[C@H]2O[C@H]([C@H](O)[C@@H]2O)C2C=CC(=O)NC2=O)[C@H](O)[C@@H](F)[C@@H]1O SMNRFWMNPDABKZ-WVALLCKVSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 229940125936 compound 42 Drugs 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 230000005610 quantum mechanics Effects 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Feeding And Controlling Fuel (AREA)
Abstract
The present invention discloses a ceramic material having the functions of activating fluid fuel molecules and supporting combustion, and a making method and the application thereof, which belongs to the technical field of energy saving and environmental protection materials. The ceramic material is made from 60 to 90 wt% of radiative far infrared ray material, 5 to 30 wt% of adhesive and 2 to 10 wt% of natural inorganic nonmetal mineral material of lanthanide elements or actinide elements, or compound additive. The making method comprises: the materials are thoroughly mixed, milled with water, formed, sintered at 600 DEG C to 1000 DEG C, crushed and milled into balls so as to prepare the superfine ceramic powder with the average grain size of smaller than 5.0 micrometers. When added to adhesive such as resin or the like in a dispersion mode, the ceramic powder can be made into functional products, such as combustion-supporting coating materials, paste, belt materials, plates, etc.; when coated and pasted to the surface of a pipeline or container through which molecules of fuel oil, fuel gas and air pass, the functional products can activate fluid molecules with high efficiency, promote fuels to be combusted and achieve the goals of energy saving and environmental protection of oil saving, energy saving and harmful gas discharge reduction.
Description
Technical field
The present invention relates to a kind of stupalith and uses thereof, belong to energy-conservation and the environment-friendly materials technical field with activated fluid fuel molecule and combustion aid function.
Background technology
Promote fuel oil, fuel gas buring for saving energy consumption, reducing pollutant emission, have important practical significance.Especially in recent years in short supply along with the fast development of automotive industry and world energy sources improves fuel oil, the fuel gas buring efficiency techniques has caused showing great attention to of whole world scientist and government.Therefore many correlation techniques have appearred in the world.
Cause fuel oil in cylinder the major cause of perfect combustion to be: ubiquity Van der Waals force between the fuel oil hydrocarbon molecules, it forms a macromolecular mass with the number hydrocarbon molecule, make the dark inner most hydrocarbon molecules of this molecular grouping of ensconcing in short quick-fried journey in the period, also have no chance and oxygen mixed firing is just discharged rapidly outside the cylinder, become the main component of harmful tail gas.At this problem, the investigator sets about from vehicle fuel, the viewpoint of activation of fuel oil is proposed, the intermolecular forces of breaking between the fuel oil hydrocarbon polymer by the whole bag of tricks fetters, and breaks up the fuel oil macromolecular mass, and it is fully atomized, with oxygen mixed firing, thereby promote fuel oil in in-engine efficiency of combustion, promote engine output, but and fuel-economizing and reduction exhaust gas emission.
In automobile engine system, add magnetic field device so that the technology of fuel magnetization can be improved the combustion in IC engine situation to a certain extent, but DeGrain, and behind the installation magnetic field, influential to automobile circuit work, also must carry out necessary shielding to magnetic field, use and be subjected to bigger restriction.
Document CN1356287A will have Ceramic Balls, the ceramic of radiation infrared function and put into automotive oil tank, can effectively promote oil inflame, reduce noxious gas emission, after but stupalith was deposited in the fuel tank midium or long term, ceramic material surfaces is seriously polluted, be not easy to clean and regeneration, there is inconvenience in life-time service.
Document CN1431395A relates to a kind of oil engine auxiliary combustion equipment, mainly is a kind of apparatus assembly of ore that the tourmalinite crystal maybe can be emitted the tritium element of micro-ray that comprises was installed before carburettor.The negative charge that produces during machine works enters the combustion chamber, promotes burning.But this method tooling complexity is not easy to promote.
Document CN2581708Y discloses a kind of energy-efficient utility model patent technology, is made up of nano silicon, nano-calcium carbonate particulate and carrier for this energy-conservation.Directly be attached to automobile oil inlet pipe and inlet pipe outside surface with energy-conservation, can realize automobile fuel saving and reduce the exhaust pollutant discharging.But this technical products comes unglued easily when using and comes off.
Document US 2004/0056208 A1 discloses material technology promotion combustion in IC engine, fuel gas buring, the water-purifying apparatus that a kind of usefulness can produce far infrared rays and negative ion simultaneously.The active material that the US6402991 patent provides is used in this invention, it is made up of bioceramic material powder and oxide powder two portions that can be radiation infrared, bioceramic material is made by sintering such as silicon oxide, aluminum oxide, ferric oxide, magnesium oxide, and cost is higher.
Summary of the invention
The present invention is intended to overcome the deficiency on the prior art, and a kind of application rare earth material and efficient far-infrared radiation material synergy are provided, and the material of activated fluid fuel molecule and air ingredient is realized the energy-conserving and environment-protective target.
Calculate according to electronic gas theoretical model in the quantum mechanics, the electronic potential that Van der Waals force caused is about 0.06～0.2eV.Derived by planck formula, the formula of reduction of photon kinetic energy is:
λ＝1.2398(eV·μm)/E
In the formula: λ is the wavelength of photon, and unit is μ m; E then is the kinetic energy of photon, and unit is eV.
Can calculate from above formula: the kinetic energy of wavelength far infrared rays photon between 6.2～20 μ m, can provide enough energy to overcome the potential energy of 0.06～0.2eV, make the electronics that sinks in this Van der Waals field of force to be escaped by resonance excitation, therefore, this wave band far ir ray can overcome Van der Waals force and break up hydrocarbon molecules group.On the other hand, show the saturated covalent linkage of carbon-hydrogen (C-H) in the hydrocarbon molecules, photon that can resonance absorption 3.2～3.6 mum wavelengths according to vitochemical infrared ray absorption frequency spectrum; The divalence C-C (C=C) of unsaturation and trivalent C-C (C=C) then absorb the photon of 5.8～6.2 μ m and 4.4～4.7 mu m wavebands respectively.
By selecting suitable far-infrared ray material for use, can realize following functional characteristics: (1) high efficient radiation 6.2～20 mu m waveband far ir rays, can break up fuel molecule group, make it be easy to change into liquid particle, reduce surface tension of liquid; And when burning, in cylinder, meet heat volatilization and oxygen uniform mixing easily, promote its burning degree and spend fully.(2) bond energy that the far ir ray of radiation 3.2～6.2 mu m wavebands can the resonance excitation fuel molecule, therefore when burning, only need less heat energy can break up covalent linkage between the hydrocarbon and carbon carbon in the fuel molecule, order reassemble into carbonic acid gas and water vapor, released energy.The far ir ray of this wave band can reduce flash-point, the vaporization of promotion fuel molecule of fuel oil.
The general far-infrared radiation rate of synthetic normal temperature far-infrared material promotes that incendiary effect is not obvious about 80%-85%, practical application has certain difficulty, and this class material cost is higher.
Group of the lanthanides or actinide elements have complicated outer electronic structure in the periodic table of chemical element, the electronics of its transfer can interact with far-infrared radiation material, the radiation infrared ability of strongthener, its far-infrared radiation rate can reach more than 90%, can obviously improve fuel combustion efficiency.In addition, contain the natural radioactivity of the normal association trace of natural minerals of these elements, can give off slight β and gamma-rays, these rays help activation, destroy the fuel molecule structure, improve efficiency of combustion.
Based on above-mentioned principle, the technical scheme that stupalith adopted that the present invention has activated fluid fuel molecule and combustion aid function is to use following prescription: the natural inorganic nonmetallic mineral material that contains radiation infrared material, binding agent, group of the lanthanides or actinide elements in the component of this stupalith; Wherein various weight percentages of components are: radiation infrared material 60-90%, binding agent 5-30%, the natural inorganic nonmetallic mineral material 2-10% of group of the lanthanides or actinide elements.Described radiation infrared material is one or more in iron tourmaline, dravite, iron dravite, the elbaite, this class material belongs to natural Mineral with Polar Electricity material, itself have stronger electric field, its ultrafine powder is reunited easily influences the radiation effect of far infrared rays, the far infrared radiation ability is strong, cost is low, applies easily.Described binding agent is one or more in wilkinite, kaolin, Suzhou soil, zeolite, sepiolite, attapulgite, silicon pyroxene, potassium felspar sand, the albite, using binding agent can avoid the tourmalinite micro mist to reunite, the material granule diameter is more little, infrared emittance is high more, the median size of general material should be less than 5 microns, preferred 0.1-2.0 micron considers that mainly this particle size range materials processing difficulty is little, cost is lower.The natural inorganic nonmetallic mineral material of described group of the lanthanides or actinide elements is for containing cerium, lanthanum, neodymium, phosphorus, zirconium, yttrium, the natural rare-earth mineral material of silicon, be mainly quartz porphyry, marble porphyry, Black Warrior amphibole, pegmatite, granite porphyry, granite pegmatite, cummingtonite, hornblende, arfvedsonite, tamarite, kaersutite, riebeckite, greisen, quartzite, miaskite, monazite, fenite, the alkalescence bowralite, Cerium monophosphate ytterbium ore, Cerium monophosphate lanthanum ore, in the grouan one or more, group of the lanthanides or actinide elements have complicated outer electronic structure in the periodic table of chemical element, the electronics of its transfer can interact with far-infrared radiation material, the radiation infrared ability of strongthener, its far-infrared radiation rate can reach more than 90%, can obviously improve fuel combustion efficiency.
Above-described preparation method with stupalith of activated fluid fuel molecule and combustion aid function contains and has the following steps:
1. at first join the natural inorganic nonmetallic mineral material 2-10% of radiation infrared material 60-90%, binding agent 5-30%, group of the lanthanides or actinide elements in the ball mill respectively, ratio in powder gross weight 3045% adds water then, ball milling is to slip fineness 400 orders, the base substrate of Ceramic Balls or ceramic block or ceramic plate is made in discharging, moulding;
2. with the oven dry of the base substrate of the Ceramic Balls after the moulding, ceramic block or ceramic plate, come out of the stove after the 600-1000 ℃ of sinter molding, be cooled to room temperature,, make median size less than 5 microns ceramics powder through fragmentation, ball milling, ultra-fine mill; Median size the best of made stupalith powder is the 0.1-2.0 micron.With base substrate oven dry, the 600-1000 ℃ sinter molding of the Ceramic Balls after the moulding or ceramic block, ceramic plate, mainly consider this temperature sintering, the tourmalinite activity is the strongest, and the ceramics powder activity of making is also the strongest, and infrared emittance is the highest.
The purposes of stupalith on combustion-supporting coating of preparation or lotion with activated fluid fuel molecule and combustion aid function of the present invention, mainly be that stupalith 3-70%, binding agent silicone resin or acrylic resin or the glass cement 30-97% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes, can be made into combustion-supporting coating of fluid fuel or lotion.
The purposes of stupalith on combustion-supporting band of preparation or sheet material with activated fluid fuel molecule and combustion aid function of the present invention, mainly be the stupalith 3-50% that will have activated fluid fuel molecule and combustion aid function by weight percentage, slowly join in 50-97% fused resin or the rubber, fully stir, mix, moulding, can be made into the combustion-supporting band of fluid fuel, sheet material or foam board.
The purposes of stupalith another kind on combustion-supporting band of preparation or sheet material with activated fluid fuel molecule and combustion aid function of the present invention is to have the stupalith of activated fluid fuel molecule and combustion aid function according to 100-500g/m
2Ratio cover at carrier surface, make band or sheet material with efficient combustion-supporting function, described carrier is to have flexible porous plastics, spongy rubber, foamex or aluminium foil.
Beneficial effect with stupalith of activated fluid fuel molecule and combustion aid function of the present invention is, this stupalith or functional product are applied, paste pipeline, the vessel surface of fuel oil, combustion gas and air molecule process, efficient activation fluid molecule, promote fuel combustion, realize fuel-economizing, energy-conservation, the energy-conserving and environment-protective target that reduces noxious gas emission.
Embodiment
Embodiment 1:
(1) has the prescription of the stupalith of activated fluid fuel molecule and combustion aid function: iron dravite 85%, wilkinite 10%, riebeckite 2%, granite porphyry 3%.
(2) above-mentioned preparation method with stupalith of activated fluid fuel molecule and combustion aid function contains and has the following steps:
1. by weight percentage iron dravite 85%, wilkinite 10%, riebeckite 2%, granite porphyry 3% are joined respectively in the ball mill, the ratio in powder gross weight 35% adds water then, and ball milling is to slip fineness 400 orders; Discharging, the base substrate of Ceramic Balls or ceramic block, ceramic plate is made in moulding;
2. with the base substrate oven dry of the Ceramic Balls after the moulding or ceramic block, ceramic plate, 650 ℃ of sinter moldings, come out of the stove, be cooled to room temperature then, through fragmentation, ball milling, ultra-fine mill, the fluid fuel molecule of making median size and be 1.2 microns activates and combustion-supporting ceramics powder.
(3) the described application of stupalith on the combustion-supporting coating of preparation with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith 30% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes with silicone resin binding agent 70%, makes the coating with efficient combustion-supporting function.Prepared coating is coated in car engine air admittance mouth and oil-in pipeline external surface.Test shows: can save gasoline 12% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 38%, reduce discharging carbon monoxide 35%.
(4) the described application of stupalith on the combustion-supporting lotion of preparation with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith 70% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes with silicone resin binding agent 30%, makes the lotion with efficient combustion-supporting function.Prepared lotion is coated in car engine air admittance mouth and oil-in pipeline external surface.Test shows: can save gasoline 20% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 45%, reduce discharging carbon monoxide 38%.
(5) the described application of stupalith on the combustion-supporting band of preparation, sheet material of present embodiment: the stupalith 50% that will have activated fluid fuel molecule and combustion aid function by weight percentage with activated fluid fuel molecule and combustion aid function, slowly join in the 50% fused resin, fully stir, mix, moulding can be made into the combustion-supporting band of fluid fuel, sheet material.Prepared band swathed at car engine air admittance mouth and oil-in pipeline external surface fix.Test shows: can save gasoline 16% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 32.8%, carbon monoxide 30%.
(6) the described application of stupalith on preparation combustion-supporting band, sheet material or foam board of present embodiment: the stupalith 50% that will have activated fluid fuel molecule and combustion aid function by weight percentage with activated fluid fuel molecule and combustion aid function, slowly join in the 50% fused rubber, fully stir, mix, moulding can be made into the combustion-supporting band of fluid fuel, sheet material or foam board.Prepared band swathed at car engine air admittance mouth and oil-in pipeline external surface fix.Test shows: can save gasoline 18% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 40%, carbon monoxide 36.5%.
Embodiment 2:
(1) has the prescription of the stupalith of activated fluid fuel molecule and combustion aid function: dravite 60%, elbaite 15%, zeolite 10%, potassium felspar sand 10%, marble porphyry 5%.
(2) above-mentioned preparation method with stupalith of activated fluid fuel molecule and combustion aid function contains and has the following steps:
1. by weight percentage dravite 60%, elbaite 15%, zeolite 10%, potassium felspar sand 10%, marble porphyry 5% are joined respectively in the ball mill, the ratio in powder gross weight 38% adds water then, and ball milling is to slip fineness 400 orders; Discharging, the base substrate of Ceramic Balls or ceramic block, ceramic plate is made in moulding;
2. with the base substrate oven dry of the Ceramic Balls after the moulding or ceramic block, ceramic plate, 800 ℃ of sinter moldings, come out of the stove, be cooled to room temperature then, through fragmentation, ball milling, ultra-fine mill, the fluid fuel molecule of making median size and be 1.2 microns activates and combustion-supporting stupalith powder.
(3) the described application of stupalith on the combustion-supporting coating of preparation fluid fuel with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith 30% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes with acrylic resin binder 70%, makes the coating with efficient combustion-supporting function.Prepared coating is coated in car engine air admittance mouth and oil-in pipeline external surface.Test shows: can save gasoline 17% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 38%, reduce discharging carbon monoxide 35%.
(4) the described application of stupalith on the combustion-supporting lotion of preparation with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith 70% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes with acrylic resin binder 30%, makes the lotion with efficient combustion-supporting function.Prepared lotion is coated in car engine air admittance mouth and oil-in pipeline external surface.Test shows: can save gasoline 22% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 40%, reduce discharging carbon monoxide 35%.
(5) the described application of stupalith on the combustion-supporting band of preparation, sheet material of present embodiment: the stupalith 50% that will have activated fluid fuel molecule and combustion aid function by weight percentage with activated fluid fuel molecule and combustion aid function, slowly join in the 50% fused resin, fully stir, mix, moulding can be made into the combustion-supporting band of fluid fuel, sheet material.Prepared band swathed at car engine air admittance mouth and oil-in pipeline external surface fix.Test shows: can save gasoline 13% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 35%, carbon monoxide 30%.
(6) the described application of stupalith on preparation combustion-supporting band, sheet material or foam board of present embodiment: the stupalith 50% that will have activated fluid fuel molecule and combustion aid function by weight percentage with activated fluid fuel molecule and combustion aid function, slowly join in the 50% fused rubber, fully stir, mix, moulding can be made into the combustion-supporting band of fluid fuel, sheet material or foam board.Prepared band swathed at car engine air admittance mouth and oil-in pipeline external surface fix.Test shows: can save gasoline 13% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 35%, carbon monoxide 30%.
Embodiment 3:
(1) has the prescription of the stupalith of activated fluid fuel molecule and combustion aid function: iron tourmaline 65%, kaolin 20%, sepiolite 10%, monazite 5%.
(2) above-mentioned preparation method with stupalith of activated fluid fuel molecule and combustion aid function contains and has the following steps:
1. by weight percentage iron tourmaline 65%, kaolin 20%, sepiolite 10%, monazite 5% are joined respectively in the ball mill, the ratio in powder gross weight 45% adds water then, and ball milling is to slip fineness 400 orders; Discharging, the base substrate of Ceramic Balls or ceramic block, ceramic plate is made in moulding;
2. with the base substrate oven dry of the Ceramic Balls after the moulding or ceramic block, ceramic plate, 850 ℃ of sinter moldings, come out of the stove, be cooled to room temperature then, through fragmentation, ball milling, ultra-fine mill, the fluid fuel molecule of making median size and be 1.2 microns activates and combustion-supporting stupalith powder.
(3) the described application of stupalith on the combustion-supporting coating of preparation with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith 30% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes with glass cement binding agent 70%, makes the coating with efficient combustion-supporting function.Prepared coating is coated in car engine air admittance mouth and oil-in pipeline external surface.Test shows: can save gasoline 15% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 40%, reduce discharging carbon monoxide 35%.
(4) the described application of stupalith on the combustion-supporting lotion of preparation with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith 70% that will have activated fluid fuel molecule and combustion aid function by weight percentage fully stirs, mixes with glass cement binding agent 30%, makes the lotion with efficient combustion-supporting function.Prepared lotion is coated in car engine air admittance mouth and oil-in pipeline external surface.Test shows: can save gasoline 21% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 42%, reduce discharging carbon monoxide 35%.
(5) the described application of stupalith on the combustion-supporting band of preparation, sheet material with activated fluid fuel molecule and combustion aid function of present embodiment: the stupalith that will have activated fluid fuel molecule and combustion aid function by weight percentage has the stupalith 50% of activated fluid fuel molecule and combustion aid function, slowly join in the 50% fused resin, fully stir, mix, moulding can be made into the combustion-supporting band of fluid fuel, sheet material.Prepared band swathed at car engine air admittance mouth and oil-in pipeline external surface fix.Test shows: can save gasoline 15% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 34%, carbon monoxide 33%.
(6) the described application of stupalith on preparation combustion-supporting band, sheet material or foam board of present embodiment: the stupalith 50% that will have activated fluid fuel molecule and combustion aid function by weight percentage with activated fluid fuel molecule and combustion aid function, slowly join in the 50% fused rubber, fully stir, mix, moulding can be made into the combustion-supporting band of fluid fuel, sheet material or foam board.Prepared band swathed at car engine air admittance mouth and oil-in pipeline external surface fix.Test shows: can save gasoline 12% behind 100 kms of driving a vehicle, reduce emission of carbon hydrogen compound 32.5%, carbon monoxide 30%.
Claims (9)
1. stupalith with activated fluid fuel molecule and combustion aid function, it is characterized in that: the natural inorganic nonmetallic mineral material that contains radiation infrared material, binding agent, group of the lanthanides or actinide elements in the component of this stupalith, the weight percent of each component is: radiation infrared material 60-90%, binding agent 5-30%, the natural inorganic nonmetallic mineral material 2-10% of group of the lanthanides or actinide elements; The method for preparing above-mentioned materials contains and has the following steps:
(1) at first join the natural inorganic nonmetallic mineral material 2-10% of radiation infrared material 60-90%, binding agent 5-30%, group of the lanthanides or actinide elements in the ball mill respectively, ratio in powder gross weight 30-45% adds water then, ball milling is to slip fineness 400 orders, the base substrate of Ceramic Balls or ceramic block or ceramic plate is made in discharging, moulding;
(2) with the oven dry of the base substrate of the Ceramic Balls after the moulding, ceramic block or ceramic plate, come out of the stove after the 600-1000 ℃ of sinter molding, be cooled to room temperature,, make median size less than 5.0 microns stupalith powder through fragmentation, ball milling, ultra-fine mill.
2. the stupalith with activated fluid fuel molecule and combustion aid function as claimed in claim 1 is characterized in that: the median size of made stupalith powder is the 0.1-2.0 micron.
3. the stupalith with activated fluid fuel molecule and combustion aid function as claimed in claim 1 is characterized in that: described radiation infrared material is one or more in iron tourmaline, dravite, iron dravite, the elbaite.
4. the stupalith with activated fluid fuel molecule and combustion aid function as claimed in claim 1 is characterized in that: described binding agent is one or more in wilkinite, kaolin, Suzhou soil, zeolite, sepiolite, attapulgite, silicon pyroxene, potassium felspar sand, the albite.
5. the stupalith with activated fluid fuel molecule and combustion aid function as claimed in claim 1 is characterized in that: the natural inorganic nonmetallic mineral material of described group of the lanthanides or actinide elements is to contain in the natural rare-earth mineral material of cerium, lanthanum, neodymium, phosphorus, zirconium, yttrium, silicon one or more.
6. the stupalith with activated fluid fuel molecule and combustion aid function as claimed in claim 5 is characterized in that: the described natural rare-earth mineral material that contains cerium, lanthanum, neodymium, phosphorus, zirconium, yttrium, silicon is quartz porphyry, marble porphyry, Black Warrior amphibole, pegmatite, granite porphyry, granite pegmatite, cummingtonite, hornblende, arfvedsonite, tamarite, kaersutite, riebeckite, greisen, quartzite, miaskite, monazite, fenite, alkaline bowralite, Cerium monophosphate ytterbium ore, Cerium monophosphate lanthanum ore, grouan.
7. the purposes with stupalith of activated fluid fuel molecule and combustion aid function as claimed in claim 1, it is characterized in that: the stupalith 3-70% that will have activated fluid fuel molecule and combustion aid function by weight percentage, fully stir, mix with binding agent silicone resin or acrylic resin or glass cement 30-97%, can be made into combustion-supporting coating or lotion.
8. the purposes with stupalith of activated fluid fuel molecule and combustion aid function as claimed in claim 1, it is characterized in that: the stupalith 3-50% that will have activated fluid fuel molecule and combustion aid function by weight percentage, slowly join in 50-97% fused resin or the rubber, fully stir, mix, moulding, can be made into combustion-supporting band or sheet material.
9. the purposes with stupalith of activated fluid fuel molecule and combustion aid function as claimed in claim 1 is characterized in that: the stupalith that will have activated fluid fuel molecule and combustion aid function is according to 100-500g/m
2Ratio cover at carrier surface, make band or sheet material with efficient combustion-supporting function, described carrier is to have flexible porous plastics, spongy rubber, foamex or aluminium foil.
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| CN101104555B (en) * | 2006-07-13 | 2014-08-06 | 廖宗文 | Composite fuel gas energy-saving material composition and application thereof |
| EP2119901B1 (en) | 2007-01-29 | 2013-11-13 | Beijing Unifly Scientific & Technology Co., Ltd. | Environment protective and energy saving type filter for internal combustion engine |
| CN102517134B (en) * | 2011-12-09 | 2014-07-16 | 北京联飞翔科技股份有限公司 | Lubricating oil additive and preparation method thereof |
| CN103017195A (en) * | 2013-01-07 | 2013-04-03 | 陈志成 | Novel energy-saving and emission-reducing industrial combustion furnace |
| CN104074597A (en) * | 2013-03-25 | 2014-10-01 | 叶俊德 | Heat dissipating device with nanometer heat dissipating coating layer and heat dissipating method |
| CN103333381B (en) * | 2013-06-17 | 2016-04-06 | 沈阳化工大学 | The preparation method of far infrared fuel-economizing rubber composite |
| WO2018120486A1 (en) * | 2016-12-31 | 2018-07-05 | 徐杰 | Energy saving and emission reduction device for diesel engine |
| ES2712867A1 (en) * | 2017-11-15 | 2019-05-16 | Phillip Weil | MODULAR REACTOR FOR COMBUSTIBLE GAS TREATMENT (Machine-translation by Google Translate, not legally binding) |
| CN110591785A (en) * | 2019-08-30 | 2019-12-20 | 深圳市厚和科技有限公司 | High-efficiency activating material suitable for various different fuels |
| CN111362618A (en) * | 2020-03-30 | 2020-07-03 | 豪宗（海口）新材料节能技术工程有限公司 | Far infrared energy-saving material for oil-saving of oil delivery pipe and manufacturing method thereof |
| CN114452716A (en) * | 2020-11-09 | 2022-05-10 | 西安昊锐电子科技有限公司 | Production method of microporous filtering material |
| CN115028993A (en) * | 2022-08-10 | 2022-09-09 | 广东粤港澳大湾区黄埔材料研究院 | Light sustainable-emission far infrared composite material and preparation method thereof |
| CN115028995A (en) * | 2022-08-10 | 2022-09-09 | 广东粤港澳大湾区黄埔材料研究院 | Sustainable far infrared emission composite material and preparation method thereof |
| CN115028994A (en) * | 2022-08-10 | 2022-09-09 | 广东粤港澳大湾区黄埔材料研究院 | Far infrared radiation material with adjustable resistivity and preparation method thereof |
| CN115448692A (en) * | 2022-09-28 | 2022-12-09 | 郭玮玲 | Nano-material ceramic ball and preparation method and application thereof |
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