CN1919930A - Organic/inorganic composite material with molecule activation function and preparation method thereof - Google Patents
Organic/inorganic composite material with molecule activation function and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an organic/inorganic composite material with activated molecule function and preparing method, which comprises the following parts: 30-50% far IR function ceramics dust, 50-70% polymer material, wherein the far IR function ceramics dust is the stupalith designs in NO. ZL200410062705.2 Pat or multifunction health ceramic powder which is set in NO. ZL02125487.7 Pat. The method comprises the following steps: 1, preparing far IR function ceramics dust; 2, modifying the far IR function ceramics dust; 3, preparing the organic/inorganic composite material with activated molecule function.
Description
Technical field
The present invention relates to a kind of composite technology, be specially a kind of molecule activation function that has, be of value to energy-conservation and organic/inorganic composite material and manufacture method thereof environment protection, international Patent classificating number intends being Int.Cl.C04B35/00 (2006.01).
Technical background
At present, the atmospheric pollution in big or middle city has caused the common concern of the whole society.On the one hand, non-complete combustion of fuel institute discharged flue gas causes urban air pollution, wherein, and petroleum products incendiary emissions account significant proportion, especially automobile, oil-firing boiler and industrial furnace etc.; On the other hand, crude oil price is constantly soaring, and the price of oil related products also one the tunnel skyrockets, and the combustion energy saving of fuel, subtracts useless technology and is subjected to showing great attention to of people especially.
Cause the major cause that fuel oil can't perfect combustion to be: molecule aggregates is the universal phenomenon that fluid molecule has.Fuel oil is the stronger flowing material of a kind of aggregation.Most fuel molecule exists with dimer, tripolymer or polymeric form, the fuel molecule aggregate can not in time disperse during burning, directly with polymeric form reaction, the fuel molecule that is positioned at polymer inside is discharged away without complete reaction, caused the oil consumption height, fume emission is many, pollutes big.Therefore, how the fuel molecule aggregate being reduced, is the important means that improves efficiency of combustion.
At this phenomenon, many improvement burnings have appearred in the world, improve the correlation technique of efficiency of combustion, mainly comprise:
One, improves combustion unit, promptly by improving fuel oil injection system, the fuel spray quality is improved, burning is technology more completely, as patent CN1388860, CN1388861 and disclosed several fuel injection valve devices of CN1388862 or improvement combustion unit, can obviously improve combustion position, yet it only is applicable to equipment newly developed, powerless to the combustion equipment that is moving;
Two, additive technology promptly uses fuel oil additive, and the fuel aggregation is weakened, and improves burning quality, the technology of being reported as patent CN1421512 and CN1341700, but the problem that fuel dope exists is that performance is single, and actual rate of economizing gasoline is lower, and oil soluble is poor.Particularly when existing organic salt to exist in the additive, not only easily make cylinder wear during burning, and jelly and carbon distribution can occur after the burning, oil circuit is stopped up; If when solvent adopts dimethylbenzene, then be prone to carcinogenic residue, and rate of economizing gasoline is low, inconvenience is promoted;
Three, molecule activation technology is promptly utilized magnetic field effect, far infrared rays or negative ion activation of fuel oil, with the fuel molecule granular, breaks up the fuel molecule aggregate, thereby improves the technology of efficiency of combustion.For example: the disclosed a kind of magnetizing fuel economizer that is used for oil engine of Chinese patent CN1121560A document, be provided with the relative permanent magnet of magnetic pole in its magnetization chamber, fuel oil flows through from the gap between the permanent magnet, under the effect in magnetic field, Van der Waals force between fuel molecule weakens, thereby make burning more complete, the effect that reach energy-conservation, reduces blowdown.U.S. Pat P5271369 proposes at first to flow through magnetic field before fuel oil enters the combustion chamber, utilize magnetic field force effect fuel molecule to produce nucleus magnetic resonance, the fuel molecule chain final fracture that in the frequent vibration process, dies down gradually, macromolecular chain becomes small molecules, thereby activation of fuel oil promotes burning.Then the introducing method at magnetic field has experienced long change again, and from the ferro-magnetic to the electromagnet, that introduces in the CN2522632Y patent again has magnetic energy micropartical of wave-motion radiation characteristic or the like.But, this magnetizing fuel economizer complex structure, the installation requirement height, and the fault of combustion equipment may be caused in magnetic field.
In addition, Chinese patent CN2581708Y discloses a kind of energy-efficient technology, form by silicon-dioxide, nano-calcium carbonate particulate and carrier for this energy-conservation, directly be attached to automobile oil inlet pipe and inlet pipe outside surface with energy-conservation after, can realize automobile fuel saving and reduce the exhaust pollutant discharging.Chinese patent CN1587185A discloses a kind of stupalith with activated fluid fuel molecule and combustion aid function and its production and use.This material is mainly made the form of energy-conservation subsides, is affixed on motor car engine oil inlet pipe and inlet pipe outside surface.Above-mentioned two technical products need pass through tube wall when using, and have weakened the activation effect of infrared rays to fuel oil and air, and come unglued easily during the product use and come off.Chinese patent CN1356287A report will have Ceramic Balls, the ceramic of radiation infrared function and put in the automotive oil tank, can effectively promote oil inflame, reduce noxious gas emission, but this stupalith palpus high temperature sintering moulding, power consumption is big, the cost height, use, ceramic surface vulnerable to pollution, inconvenience are cleaned and regeneration, and there is inconvenience in life-time service.
Also have some infrared oil-saving devices in addition, for example Chinese patent CN1066488A, Canadian Patent CANP2344583 and U.S. Pat P5632254 etc., they need be installed on the automobile oil circuit, and complicated operation is extremely inconvenient, also breaks down easily.
Summary of the invention
At the deficiencies in the prior art, the technical problem to be solved in the present invention is to design a kind of organic/inorganic composite material and manufacture method thereof with molecule activation function.This matrix material component is simple, easy to manufacture, has environmental protection, energy-saving function, is mainly used in activation of fuel oil, simultaneously, combustion gas, air, water or other fluid molecule are also had activation effect, and cost is low, and is easy to use, respond well.This method for composite material need not high temperature sintering to inorganic functional material, and technology is simple, and is with low cost, save energy, useful environmental protection.
The technical scheme that the present invention solves described composite technology problem is: design a kind of organic/inorganic composite material with molecule activation function, its mass percent prescription is: far-infrared function ceramic powder 30～50%; Macromolecular material 50～70%; Described far-infrared function ceramic powder is a stupalith designed in the ZL200410062705.2 patent; It perhaps is the multifunctinoal health ceramics powder of ZL02125487.7 defined for the patent No.; Described macromolecular material is meant a kind of in resin or the plastics.
The technical scheme that the present invention solves described method for composite material technical problem is: design a kind of manufacture method with organic/inorganic composite material of molecule activation function, this method comprises following processing step:
1. the preparation of far-infrared function ceramic powder: far-infrared function ceramic powder body material of the present invention is joined in the ball mill, ratio in powder total mass 30～45% adds water again, ball milling is to slip fineness 400 orders, discharging then, oven dry is come out of the stove after 600～800 ℃ of calcinings, is cooled to room temperature, through fragmentation, ball milling, ultra-fine mill, make median size less than 4 microns far-infrared function ceramic powder;
2. the modification of far-infrared function ceramic powder is handled: the far-infrared function ceramic powder of gained is dry in high-speed mixer for dry, drying temperature is controlled at 100～110 ℃, be 0.5～1.0 hour time of drying, the organic silicone oil that with consumption is described far-infrared function ceramic powder weight 0.8～1.0% then directly joins in the high-speed mixer, high speed violent stirring 15～30 minutes gets final product discharging;
3. the manufacturing that has the organic/inorganic composite material of molecule activation function: far infrared multifunctional ceramic powder after the gained modification and described macromolecular material is compound in the ratio of organic/inorganic composite material mass percent prescription of the present invention, promptly can be made into inorganic/organic composite material with activated molecule function.
Compared with prior art, the organic/inorganic composite material with molecule activation function of the present invention is though comprise organic/inorganic component, but component is simple, easy to manufacture, designed matrix material can directly join among prime the fuel system or the fuel tank, need not install, therefore simple to operate, easy to use, and composite material surface vulnerable to pollution not, be convenient to clean and regeneration, stable performance, life-time service can still keep advantages such as good efficacy; Organic/inorganic composite material manufacture method with molecule activation function of the present invention, because its modification process that far-infrared material is carried out, can improve the interface bonding state of matrix material, and inorganic and organic polymer material system need not high temperature sintering (promptly in the end ceramic powder and macromolecular material compound tense can carry out at normal temperatures, without sinter molding) through compound and preparation moulding, therefore energy consumption is little, cost is low, and technology is simple, useful environmental protection.Matrix material of the present invention is mainly used in the fuel feed system of oil-burning apparatus, add matrix material of the present invention after, the oil consumption of oil-burning apparatus can obviously reduce, incomplete combustion product C O, HC and harmful product S O in the flue gas
2, NO
XAlso can obviously reduce, have good environmental protection effect.
Description of drawings
Fig. 1 is a kind of embodiment solid body structure (comprising a sphere, b ellipse, c spindle-type and d dumbbell shape) synoptic diagram of matrix material of the present invention;
Fig. 2 is a kind of embodiment body central through hole globosity synoptic diagram of matrix material of the present invention;
Fig. 3 is a kind of embodiment body central through hole ellipsoidal structure synoptic diagram of matrix material of the present invention;
Fig. 4 is a matrix material Function detection of the present invention---the time dependent correlation curve figure of deionized water surface tension.Among Fig. 4: A represents present commercially available prod activated water; B represents matrix material activated water of the present invention; C represents without the activatory ortho-water.
Embodiment
Further narrate the present invention below in conjunction with embodiment and accompanying drawing thereof:
The present invention design a kind of has molecule activation function organic/inorganic composite material (hereinafter to be referred as matrix material), and its mass percent prescription is: far-infrared function ceramic powder 30～50%; Macromolecular material 50～70%; Described far-infrared function ceramic powder is a stupalith designed in the ZL200410062705.2 patent; It perhaps is the multifunctinoal health ceramics powder of 02125487.7 defined by number of patent application; Described macromolecular material is meant a kind of in resin or the plastics.
Far-infrared function ceramic powder in the composite-material formula of the present invention has the spontaneous generation infrared rays of normal temperature, can activation of fuel oil, the combustion gas molecule, promote burning, energy-conservation and subtract useless function, also can activate fluid molecules such as air molecule, water molecules.It is simple in structure, cost is low, long service life, effect are obvious.A kind of stupalith that far-infrared function ceramic powder of the present invention can adopt the contriver formerly to design.This stupalith is by in 90～98% iron tourmaline, dravite, elbaite, the iron dravite one or more, add 2～10% rare-earth mineral materials, handle gained through surface modification technology, concrete technology is applicable to that name is called the ZL200410062705.2 patented technology of " having stupalith of activated fluid fuel molecule and combustion aid function and its production and use ".But utilize the far infrared rays activation of fuel oil molecule of its self radiation, the vibration of fuel molecule, degree of rotation are strengthened, intermolecular forces reduces, cluster miniaturization, more complete, the minimizing pollution of burning.With respect to applicant's patent application formerly, the present invention is further the improving of stupalith of former activated fluid fuel molecule and combustion aid function, and it is had on the more obvious activation effect basis, prescription is simpler, it is easier to prepare, and energy consumption is lower, uses convenient.
Far-infrared function ceramic powder of the present invention also can adopt the ceramic powder of contriver's another design formerly.The concrete technology of this ceramic powder is applicable to that name is called the ZL02125487.7 patented technology of " multifunctinoal health ceramic material and its production and use ".This ceramics powder drops into actual production, commercial getting by joint patentees's Shandong Zibo Beaune development in science and technology company limited.
The manufacture method of matrix material of the present invention adopts following processing step:
1. the preparation of far-infrared function ceramic powder: the described far-infrared function ceramic powder body material of claim 1 is joined in the ball mill, ratio in powder total mass 30～45% adds water again, ball milling 2～2.5 hours is to slip fineness 400 orders, discharging then, oven dry, 600～800 ℃ of calcinings were come out of the stove after 3～5 hours, were cooled to room temperature, through fragmentation, ball milling, ultra-fine mill, make median size less than 4 microns far-infrared function ceramic powder; Preferred 0.1～2.0 micron of the median size of the described far-infrared function ceramic powder of the embodiment of the invention, this considers that mainly the ceramic powder material difficulty of processing of this particle size range is little, cost is lower, and the infrared emittance of ceramic powder is also higher.
2. the modification of far-infrared function ceramic powder is handled: main technique is: at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled at 100～110 ℃ with ceramic powder, 0.5～1.0 hour time of drying, decides on the moisture situation of ceramic powder; Then organic silicone oil is directly joined in the high-speed mixer, consumption is 0.8～1.0% of a far-infrared function ceramic powder weight, and high speed violent stirring 15～30 minutes gets final product discharging.The surface modification main purpose is the absorption peak of excitation material at the organism wave band, and the surface energy that reduces powder, helps in the preparation process of back compound with organic polymer material.
3. the manufacturing that has the organic/inorganic composite material of molecule activation function: far infrared multifunctional ceramic powder after the gained modification and macromolecular materials such as described resin or plastics is compound in the ratio of organic/inorganic composite material mass percent prescription of the present invention, promptly can be made into inorganic/organic composite material with activated molecule function.Macromolecular materials such as described resin or plastics are commercial product.Resin can be selected any in adjacent benzene type resin, unsaturated polyester type resin or the adjacent benzene type modified unsaturated polyester type resin for use, does not have particular requirement.Plastics also are conventional industrial plastic.The compound of described organic also is existing process method.
Described product with inorganic/last moulding of organic composite material of activated molecule function is the single product with definite shape, is called the matrix material body.The body shape structure embodiment of matrix material of the present invention mainly comprises solid sphere, ellipse, fusiform and dumbbell shape etc., also comprises central through hole globosity and central through hole ellipsoidal structure etc. (participating in Fig. 1-3); Certainly, the shape of listed matrix material body and size are not subjected to the restriction of embodiment, fully can be according to client's needs customization.The shape of matrix material body and size are decided by working conditions.
The present invention is directed to the matrix material that the problem of present existence is developed, select the natural far infrared mineral material of high-quality, through selecting materials, batching, batch mixing, thermal treatment, technologies such as surface modification, be composited with macromolecular material then, need not high temperature sintering, energy consumption is little, manufacturing process itself just is of value to environmental protection, and this matrix material is directly joined in the fuel tank or gas tank of combustion equipment, its radiating far ir ray is absorbed by fuel oil or combustion gas molecular resonance, thereby can improve the atomization quality of fuel oil or combustion gas, and it is more abundant to burn, can be implemented in and reduce exhaust gas emission energy-conservation the time, further help environmental protection.
One of purposes of matrix material of the present invention is: in the fuel tank of the fuel feed system of motor vehicles such as gasoline car, diesel vehicle, directly add matrix material body of the present invention, perhaps go here and there and join on metal wire in the described fuel tank; Addition accounts for 3.0～4.0% of fuel weight, has activation gasoline, diesel oil effect, makes the macromolecular mass miniaturization by far infrared rays, and the contact probability of increase fuel oil and oxygen promotes burning fully, saves the quantity discharged of fuel oil, reduction CO and soot particulate.
Two of the purposes of matrix material of the present invention is: with various petroleum productss be the combustion equipment of fuel as burning diesel oil, in the fuel tank of plenum systems such as the boiler of heavy gas oil or heavy oil, industrial furnace, directly add matrix material body of the present invention; Addition accounts for 4.0～6.0% of fuel weight, has the activation of fuel oil molecule, promotes burning fully, energy-conservationly subtracts useless effect.
Three of the purposes of matrix material of the present invention is: in the air supply system that with gases such as Sweet natural gas, coal gas is the plenum system of fuel and various combustion equipment, directly add matrix material body of the present invention; Addition accounts for 2.0～3.0% of combustion gas weight, has the function of activated gas molecule, thereby makes burning more complete, reduces discharge of harmful gases, reaches effect in energy saving and environmental protection.
Four of the purposes of matrix material of the present invention is: in industry, agricultural and domestic water supply system, directly add matrix material body of the present invention; Addition accounts for 3.0～5.0% of water weight, can the activated water molecule, reduce the cluster of water, and reduce the degree of association of water, make water help HUMAN HEALTH and plant-growth.
The present invention does not address part and is applicable to prior art.
Provide specific embodiments of the invention below, but the present invention is not subjected to the restriction of embodiment.
Embodiment 1
(1). composite-material formula (quality %, down together) is: far-infrared function ceramic powder 50%, resin 50%.Described far-infrared function ceramic powder prescription is dravite 60%, iron tourmaline 35%, monazite 5%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL200410062705.2 patented method to make, being about to preferred raw material dravite, iron tourmaline, monazite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 30% adds water then, wet-milling 3.5 hours, the discharging oven dry, 600 ℃ of thermal treatment is 5 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 100 ℃, 1 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 1.0% of a ceramic powder weight, high speed violent stirring 30 minutes, discharging.Then with modification ceramic powder and molten resin mix at 1: 1 in proportion, resin curing agent (the commercially available prod of adding 1%, down together), 2% resin promotor (commercially available prod, down together) is stirred the back in spherical mould centre-run mould, make spheric matrix material body, at vacuum drying oven internal heating to 40 ℃, 1.5 hours time, get rid of the intrinsic bubble of matrix material promptly again.
(3). the application of matrix material, prepared spherical matrix material body 4g joins in the 0# diesel oil of 100g with present embodiment, tests its surface tension, flash-point and viscosity change.
Testing data shows that the diesel oil surface tension has dropped to 26.524mN/m from the 27.198mN/m of virgin state, and flash-point drops to 64.0 ℃ from 65.5 ℃ of virgin state, and viscosity is by the 2.4827mm of virgin state
2/ s has dropped to 2.3907mm
2/ s.
Embodiment 2
(1). composite-material formula is: far-infrared function ceramic powder 30%, resin 70%.Described far-infrared function ceramic powder prescription is dravite 60%, iron tourmaline 35%, monazite 5%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL200410062705.2 patented method to make, being about to preferred raw material dravite, iron tourmaline, monazite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 35% adds water then, wet-milling 3 hours, the discharging oven dry, 650 ℃ of thermal treatment is 4.5 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 105 ℃, 0.8 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 0.9% of a ceramic powder weight, high speed violent stirring 20 minutes, discharging.Then with modification ceramic powder and molten resin mix at 3: 7 in proportion, the resin curing agent of adding 1.5%, 2% resin promotor, stir back punch die centre-run mould in the sphere of 15mm, make spheric matrix material body, at vacuum drying oven internal heating to 45 ℃, 1.3 hours time, get rid of the intrinsic bubble of matrix material promptly again.
(3). the application of matrix material, 35 of the spherical matrix material bodies of the 15mm that present embodiment is prepared, with the metal wire string together, fixing, and join in the boiler fuel tank that volume is 15L, with activation diesel oil, improve by the radiation infrared diesel oil atomization quality that makes, promote burning fully, save fuel oil, reduce pollutent.
Multiple comparison test shows: rate of economizing gasoline is 0.66～2.41%, and CO, NO content have reduced by 15.9～21.9%, 3.4～8.0% respectively in the flue gas.Low-cost energy-conservation down obvious with environment protecting.
Embodiment 3
(1). composite-material formula is: far-infrared function ceramic powder 50%, resin 50%.Described far-infrared function ceramic powder prescription is dravite 50%, iron tourmaline 40%, albite 10%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL02125487.7 patented method to make, being about to preferred raw material dravite, iron tourmaline, albite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 40% adds water then, wet-milling 3 hours, the discharging oven dry, 700 ℃ of thermal treatment is 4 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 110 ℃, 0.5 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 0.8% of a ceramic powder weight, high speed violent stirring 15 minutes, discharging.Then with modification ceramic powder and molten resin mix at 1: 1 in proportion, add 1% resin curing agent, 2% resin promotor is stirred back punch die centre-run mould in the sphere of 15mm.Make spheric matrix material body,, 1.2 hours time, get rid of the intrinsic bubble of matrix material promptly again at vacuum drying oven internal heating to 50 ℃.
(3). present embodiment is used and is same as embodiment 2.
Multiple comparison test shows: rate of economizing gasoline is 1.83～4.00%, and CO, NO quantity discharged have reduced by 7.0～11.7%, 18.3～34.3% respectively in the flue gas.
Embodiment 4
(1). composite-material formula is: far-infrared function ceramic powder 40%, resin 60%.Described far-infrared function ceramic powder prescription is dravite 60%, iron tourmaline 35%, monazite 5%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL200410062705.2 patented method to make, being about to preferred raw material dravite, iron tourmaline, monazite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 45% adds water then, wet-milling 3.5 hours, the discharging oven dry, 750 ℃ of thermal treatment is 3.5 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 110 ℃, 0.5 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 0.8% of a ceramic powder weight, high speed violent stirring 30 minutes, discharging.Then with modification ceramic powder and molten resin mix at 4: 6 in proportion, add 1% resin curing agent, 2% resin promotor is stirred back punch die centre-run mould in the sphere of 15mm.Make spheric matrix material body,, 1 hour time, get rid of the intrinsic bubble of matrix material promptly again at vacuum drying oven internal heating to 55 ℃.
(3). present embodiment is used and is same as embodiment 2.
Multiple comparison test shows: rate of economizing gasoline is 2.87～4.94%, and the content of CO, NO has reduced by 15.0～31.8% and 14.0～19.9% respectively in the flue gas.Low-cost energy-conservation down obvious with environment protecting.
Embodiment 5
(1). composite-material formula is: multifunctinoal health ceramics powder 40%, plastics 60%.Described far-infrared function ceramic powder prescription is dravite 50%, iron tourmaline 40%, montomorillonite 10%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL02125487.7 patented method to make, being about to preferred raw material dravite, iron tourmaline, montomorillonite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 40% adds water then, wet-milling 3 hours, the discharging oven dry, 800 ℃ of thermal treatment is 3 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 105 ℃, 0.8 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 1.0% of a ceramic powder weight, high speed violent stirring 30 minutes, discharging.Then ceramic powder after the modification and molten plastic are mixed in proportion at 4: 6, stir, make the master batch with mobilizing function, at last molten plastic and master batch are mixed stirring, injection moulding is spherical matrix material body.
(3). present embodiment is done following contrast and used: prepared spherical matrix material 2g joins in the deionized water of 50g with present embodiment, get in the deionized water that commercial like product 2g joins 50g the surface tension of the DCAT21 type surface/interface tensiometer test water of producing with German Data physics company simultaneously.
Test result shows, add material of the present invention after, the surface tension of water has dropped to 68.033mN/m by 71.427mN/m, with the commercial like product relatively, (referring to accompanying drawing 4) has a significant effect.
Embodiment 6
(1). composite-material formula is: far-infrared function ceramic powder 40%, resin 60%.Described far-infrared function ceramic powder prescription is dravite 60%, iron tourmaline 35%, monazite 3%, riebeckite 2%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL200410062705.2 patented method to make, being about to preferred raw material dravite, iron tourmaline, monazite, riebeckite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 40% adds water then, wet-milling 3 hours, the discharging oven dry, 750 ℃ of thermal treatment is 3.5 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 110 ℃, 0.5 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 1.0% of a ceramic powder weight, high speed violent stirring 30 minutes, discharging.Then with modification ceramic powder and molten resin mix at 4: 6 in proportion, add 1% resin curing agent, 2% resin promotor is stirred back punch die centre-run mould in the sphere of 20mm.Make spheric matrix material body,, 1 hour time, get rid of the intrinsic bubble of matrix material promptly again at vacuum drying oven internal heating to 55 ℃.
(3). the application of matrix material, fixing with the metal wire string together 35 of matrix material bodies, join volume and be in the stand engine oil tank of 20L (fuel is 90# gasoline), in engine air inlet tube, also add 10 described matrix material bodies simultaneously.Carry out engine load characteristic simultaneous test and idle exhaust emission simultaneous test, motor speed is respectively 2000r/min, 2500r/min and 3000r/min; Rotating speed is respectively 650r/min and 1500r/min during idling.
Experimental result shows, by each operating point under motor speed 2000r/min, 2500r/min and the 3000r/min rotating speed being installed additional the accumulative total summation of sample front and back fuel consumption, resulting specific fuel oil consumption under above-mentioned rotating speed reduces by 2.8%, 3.1% and 3.7% respectively.Under the 650r/min idling speed, CO reduced rate 20%, HC reduced rate 28%; Under the 1500r/min idling speed, CO reduced rate 25%, HC reduced rate 30%.Low-cost energy-conservation down obvious with environment protecting.
Embodiment 7
(1). composite-material formula is: described multifunctinoal health ceramics powder 35%, resin 65%.Described far-infrared function ceramic powder prescription is dravite 60%, iron tourmaline 35%, montomorillonite 3%, riebeckite 2%.
(2). the manufacture method of matrix material: adopt the designed ceramic material method of ZL02125487.7 patented method to make, being about to preferred raw material dravite, iron tourmaline, montomorillonite, riebeckite mixes by proportioning, join in the ball mill, the ratio in powder gross weight 40% adds water then, wet-milling 3 hours, the discharging oven dry, 750 ℃ of thermal treatment is 3.5 hours under reducing atmosphere, after the cooling, and fragmentation, with ball mill dry grinding 1 hour, make the far-infrared function ceramic powder.Then the far-infrared function ceramic powder is carried out surface modification with organic silicone oil, key step is: with ceramic powder at the dry moisture of removing of high-speed mixer for dry, drying temperature is controlled to be 100 ℃, 1 hour time, directly join organic silicone oil in the high-speed mixer then, consumption is 1.0% of a ceramic powder weight, high speed violent stirring 30 minutes, discharging.Then with modification ceramic powder and molten resin mix at 4: 6 in proportion, add 1% resin curing agent, 2% resin promotor is stirred the spherical mould centre-run mould of back at 10mm.Make spheric matrix material body,, 1 hour time, get rid of the intrinsic bubble of matrix material promptly again at vacuum drying oven internal heating to 55 ℃.
(3). the application of matrix material, respectively 10 of matrix material bodies, join in the fuel feed and air supply pipe road of combustion of natural gas device, test its energy-conservation and environment protecting.
Experimental result shows: the saving of fuel rate reaches 3.54～5.55%, and CO content in smoke has reduced by 24%, SO
2Content has reduced by 32%.Low-cost energy-conservation obvious down with environment protecting.
Claims (2)
1. organic/inorganic composite material with molecule activation function, its mass percent prescription is: far-infrared function ceramic powder 30～50%; Macromolecular material 50～70%; Described far-infrared function ceramic powder is a stupalith designed in the ZL200410062705.2 patent; It perhaps is the multifunctinoal health ceramics powder of ZL02125487.7 defined for the patent No.; Described macromolecular material is meant a kind of in resin or the plastics.
2. manufacture method with organic/inorganic composite material of molecule activation function, this manufacture method adopts following processing step:
(1). the preparation of far-infrared function ceramic powder: the described far-infrared function ceramic powder body material of claim 1 is joined in the ball mill, ratio in powder total mass 30～45% adds water again, ball milling is to slip fineness 400 orders, discharging then, oven dry is come out of the stove after 600～800 ℃ of calcinings, is cooled to room temperature, through fragmentation, ball milling, ultra-fine mill, make median size less than 4 microns far-infrared function ceramic powder;
(2). the modification of far-infrared function ceramic powder is handled: the far-infrared function ceramic powder of gained is dry in high-speed mixer for dry, drying temperature is controlled at 100～110 ℃, be 0.5～1.0 hour time of drying, the organic silicone oil that with consumption is described far-infrared function ceramic powder weight 0.8～1.0% then directly joins in the high-speed mixer, high speed violent stirring 15～30 minutes gets final product discharging;
(3). have the manufacturing of the organic/inorganic composite material of molecule activation function: far infrared multifunctional ceramic powder after the gained modification and described macromolecular material is compound in the ratio of the described organic/inorganic composite material mass percent prescription of claim 1, promptly can be made into inorganic/organic composite material with activated molecule function.
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2006100154236A CN1919930A (en) | 2006-08-23 | 2006-08-23 | Organic/inorganic composite material with molecule activation function and preparation method thereof |
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| CNA2006100154236A CN1919930A (en) | 2006-08-23 | 2006-08-23 | Organic/inorganic composite material with molecule activation function and preparation method thereof |
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| CN1919930A true CN1919930A (en) | 2007-02-28 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111393068A (en) * | 2020-03-30 | 2020-07-10 | 豪宗（海口）新材料节能技术工程有限公司 | Infrared energy-saving material and preparation method thereof |
-
2006
- 2006-08-23 CN CNA2006100154236A patent/CN1919930A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111393068A (en) * | 2020-03-30 | 2020-07-10 | 豪宗（海口）新材料节能技术工程有限公司 | Infrared energy-saving material and preparation method thereof |
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Open date: 20070228 |