CN110699127A - Efficient fuel oil activating material - Google Patents
Efficient fuel oil activating material Download PDFInfo
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- CN110699127A CN110699127A CN201910811421.5A CN201910811421A CN110699127A CN 110699127 A CN110699127 A CN 110699127A CN 201910811421 A CN201910811421 A CN 201910811421A CN 110699127 A CN110699127 A CN 110699127A
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- Prior art keywords
- ball
- fuel
- balls
- tourmaline
- fuel oil
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a fuel oil high-efficiency activation material which is prepared by carrying out ball milling on far infrared balls, tourmaline powder, magnetic balls, medical stone balls, negative ion balls and additives, and then sintering and cooling. The defects of poor fuel oil treatment effect and unobvious emission reduction effect caused by only using a single far infrared functional raw material in the conventional fuel oil activation material are overcome, and the raw materials comprise a plurality of different composite components such as far infrared balls, tourmaline powder, magnetic balls, anion balls, additives and the like. According to the invention, high-energy infrared rays are radiated by the far infrared balls and the tourmaline powder in a band of 2.5-22 mu m and the magnetization effect of the magnetic balls, and after the far infrared balls and the tourmaline powder are contacted with fuel for a period of time, large fuel molecular groups can be scattered, fuel molecular bond energy is excited by resonance, the combustion efficiency of the fuel is improved, good activity is generated, the fuel is promoted to be fully combusted, the emission of harmful gases is reduced, and the purposes of saving energy and reducing emission are achieved.
Description
Technical Field
The invention belongs to the technical field of fuel activation, and particularly relates to a high-efficiency fuel activation material.
Background
Energy conservation and emission reduction are urgent matters for energy shortage in the world at present, and the combustion efficiency of fuel oil directly influences the effects of energy conservation and emission reduction. The combustion efficiency of fuel is closely related to the combustion process of fuel in an internal combustion engine, and whether the fuel is a gasoline engine or a diesel engine, the atomization quality of the fuel before combustion determines whether the fuel is sufficiently combusted, so that the combustion efficiency is influenced. The atomization quality of the fuel oil can be improved by reducing the surface tension and viscosity of the fuel oil, so that the fuel oil is fully combusted, the emission of harmful gas is reduced, and the purposes of energy conservation and emission reduction are achieved. It is found that a great deal of C-C, C ═ C and C ═ C bonds exist in fuel molecules, the resonance absorption frequency of the C-C, C ═ C and C ═ C bonds is located in the infrared region of a wave number band of 3-6 microns, and if extra energy in the frequency band can be provided to cause the fuel molecules to resonate, and the activation energy is reduced, the agglomerated macromolecules in the fuel can be scattered, so that the agglomerated macromolecules can be easily converted into smaller liquid particles to be conveniently mixed with oxygen.
Research proves that the quality of vehicle fuel is one of important influencing factors directly influencing the emission of motor vehicles. Due to the ubiquitous van der Waals force among fuel oil hydrocarbon molecules, a plurality of fuel oil molecules are gathered into a large molecular group, and the fuel oil hydrocarbon molecules at the innermost part of the molecular group are not completely mixed with oxygen and burnt and are quickly discharged out of a cylinder in a short power stroke, so that the combustion efficiency of fuel oil is reduced, and harmful waste gas polluting the environment is formed. In order to reduce the emission of pollutants such as carbon monoxide, hydrocarbon, oxynitride, particulate matters and the like, the fuel quality is improved by refining fuel molecular groups, the full combustion of the fuel is promoted, and the method is a simple, easy, safe and efficient emission reduction technical means.
The existing fuel oil activation combustion-supporting material can improve the condition of fuel oil molecule agglomeration to a certain extent, but because the variety of the selected activation material is single and the infrared radiation efficiency is not enough, the fuel oil activation effect is not obvious, and the actual emission reduction effect is very limited.
Disclosure of Invention
The invention aims to overcome the defects in the prior art, and provides a fuel oil efficient activation material which can be widely applied to various different fuel oils such as gasoline, diesel oil, heavy oil and the like, has obvious effect and low cost, and can realize energy conservation and emission reduction.
In order to achieve the purpose, the invention provides the following technical scheme: the fuel oil high-efficiency activation material is prepared by grinding and heating a tourmaline block after crushing, and then sintering and cooling the ground tourmaline block after ball milling with a far infrared ball, a magnetic ball, a medical stone ball, an anion ball and an additive, wherein:
the method comprises the following steps: selecting tourmaline blocks, and crushing in a crusher;
step two: and putting the crushed tourmaline blocks into a vibration sample grinder to be ground for 3 hours, and putting the crushed tourmaline blocks into a jet mill to be ground for 3 hours.
Step three: the prepared tourmaline powder is placed in a vacuum drying oven to be heated for 3 hours, and the radiation frequency of the tourmaline powder in a high wave band is improved.
Step four: the material composition according to the mass percentage is that the far infrared ball 35% -50%, the tourmaline powder 20% -30%, the magnetic ball 10% -20%, the medical stone ball 0% -25%, the negative ion ball 0% -10%, the additive 0% -5%, ball milling all the materials to below 200 mesh, and sintering at 950 ℃.
Preferably, the magnetic ball is a ferrimagnetic ball.
Preferably, the tourmaline powder after gas milling in the second step has an average diameter of 1.43 μm.
Preferably, the anion ball is formed by mixing tourmaline and clay and grinding into particles with the diameter of 6-140 um, and accounts for 3% -98% of the total weight; the clay accounts for 97-2% of the total weight; adding water, stirring, molding, drying and sintering to obtain the small balls with the diameter of 5-50 mm.
Preferably, the additive is one or more of alkali metal oxide, alkaline earth metal oxide, boron oxide and titanium dioxide.
Preferably, the effective wave band of the far infrared ball and the tourmaline powder is 2.5-22 μm wave band.
Preferably, the heating temperature in the third step is 500-1000 ℃, wherein the emissivity is 0.65-0.89.
Preferably, the tourmaline selected in the first step is black or purple.
Compared with the prior art, the invention has the beneficial effects that: the fuel oil high-efficiency activating material overcomes the defects of poor fuel oil treatment effect and unobvious emission reduction effect caused by only using a single far infrared functional raw material in the conventional fuel oil activating material, and the raw materials comprise various different composite components such as far infrared balls, tourmaline powder, magnetic balls, anion balls, additives and the like. According to the invention, high-energy infrared rays are radiated by the far infrared balls and the tourmaline powder in a band of 2.5-22 mu m and the magnetization effect of the magnetic balls, and after the far infrared balls and the tourmaline powder are contacted with fuel for a period of time, large fuel molecular groups can be scattered, fuel molecular bond energy is excited by resonance, the combustion efficiency of the fuel is improved, good activity is generated, the fuel is promoted to be fully combusted, the emission of harmful gases is reduced, and good purposes of energy conservation and emission reduction are achieved. Under the background of severe haze in Jingjin Ji area of China at present, the method is suitable for large-scale application in oil refineries and finished oil sales industries.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
The invention will be explained in more detail below with reference to specific examples:
the fuel oil high-efficiency activation material is prepared by grinding and heating a tourmaline block after crushing, and then sintering and cooling the ground tourmaline block after ball milling with a far infrared ball, a magnetic ball, a medical stone ball, an anion ball and an additive, wherein:
the method comprises the following steps: selecting black or purple tourmaline with good radiation rate, and crushing in a crusher;
step two: and putting the crushed tourmaline blocks into a vibration sample grinder to carry out vibration grinding for 3 hours for crushing, and putting the crushed tourmaline blocks into a jet mill to carry out gas grinding for 3 hours after crushing to obtain tourmaline powder with the average particle size of 1.43 mu m.
Step three: the prepared tourmaline powder is placed in a vacuum drying oven to be heated for 3 hours, and the radiation frequency of the tourmaline powder in a high wave band is improved.
Step four: the material composition according to the mass percentage is that the far infrared ball 35% -50%, the tourmaline powder 20% -30%, the magnetic ball 10% -20%, the medical stone ball 0% -25%, the negative ion ball 0% -10%, the additive 0% -5%, ball milling all the materials to below 200 mesh, and sintering at 950 ℃.
The tourmaline block is made of tourmaline powder produced in Altai area of Xinjiang, the magnetic ball, the medical stone ball and the anion ball are all made of materials produced by Zibobona technology development Limited company, and the anion ball can release micro current and increase fuel activity.
Wherein, the magnetic ball is selected to have ferrimagnetism, increases the degree of fusion with other mixed materials.
The additive is one or more of alkali metal oxide, alkaline earth metal oxide, boron oxide and titanium dioxide, and the material can reduce the sintering temperature of the raw material, effectively adjust the energy band structure of the material, improve the infrared radiance in the low-band range (2.5-6.2 microns) and greatly improve the activity effect of the material.
Example 1
The fuel oil efficient activation material comprises the following raw materials in percentage by mass: 50% of far infrared ball, 25% of tourmaline powder, 10% of magnetic ball and 15% of medical stone ball. The preparation method comprises mixing all the raw materials, ball-milling to below 200 meshes, sintering at 950 deg.C, cooling to obtain the fuel oil high-efficiency activating material, and processing into spherical shape with diameter of 3 mm.
The prepared spherical fuel oil efficient activation material can break up large fuel oil molecular groups after contacting with fuel oil for 30min, and excite fuel oil molecular bond energy by resonance, so that the combustion efficiency of the fuel oil is improved, the fuel oil generates good activity, the fuel oil is promoted to be fully combusted, the emission of harmful gas is reduced, and the purposes of saving energy and reducing emission are achieved.
Example 2
The formula of the fuel oil efficient activation material comprises the following components in percentage by weight: 40% of far infrared balls, 30% of tourmaline powder, 15% of magnetic balls, 10% of negative ion balls and 5% of alkali metal oxide, ball-milling all the raw materials to be below 200 meshes, sintering at 950 ℃, cooling to obtain the fuel oil efficient activation material, and processing the fuel oil efficient activation material into balls with the diameter of 4 mm.
The prepared spherical fuel oil efficient activation material can break up large fuel oil molecular groups after contacting with fuel oil for 35min, and excite fuel oil molecular bond energy by resonance, so that the combustion efficiency of the fuel oil is improved, the fuel oil generates good activity, the fuel oil is promoted to be fully combusted, the emission of harmful gas is reduced, and the purposes of saving energy and reducing emission are achieved well.
Example 3
The formula of the fuel oil efficient activation material comprises the following components in percentage by weight: 35% of far infrared balls, 30% of tourmaline powder, 20% of magnetic balls and 15% of negative ion balls, wherein all the raw materials are subjected to ball milling to be below 200 meshes, then sintering is carried out at 950 ℃, cooling is carried out, the fuel efficient activation material obtained by the fuel efficient activation material is processed into the ball shape with the diameter of 4mm, and the obtained fuel efficient activation material is processed into the ball shape with the diameter of 5 mm.
The prepared spherical fuel oil efficient activation material can break up large fuel oil molecular groups after contacting with fuel oil for 53min, and excite fuel oil molecular bond energy by resonance, so that the combustion efficiency of the fuel oil is improved, the fuel oil generates good activity, the fuel oil is promoted to be fully combusted, the emission of harmful gas is reduced, and the purposes of saving energy and reducing emission are achieved well.
Example 4
The formula of the fuel oil efficient activation material comprises the following components in percentage by weight: 45% of far infrared ball, 20% of tourmaline powder, 20% of magnetic ball, 10% of medical stone ball and 5% of negative ion ball, and the obtained fuel oil high-efficiency activation material is processed into a ball shape with the diameter of 6 mm.
The prepared spherical fuel high-efficiency activation material can break up large fuel molecular groups after contacting with fuel for 1h, and can excite fuel molecular bond energy by resonance, so that the combustion efficiency of the fuel is improved, the fuel generates good activity, the fuel is promoted to be fully combusted, the emission of harmful gas is reduced, and the purposes of saving energy and reducing emission are achieved.
Example 5
The formula of the fuel oil efficient activation material comprises the following components in percentage by weight: 35% of far infrared balls, 30% of tourmaline powder, 10% of magnetic balls, 15% of medical stone balls and 10% of negative ion balls, ball-milling all the raw materials to be below 200 meshes, sintering at 950 ℃, cooling to obtain the fuel efficient activation material, and processing the obtained fuel efficient activation material into balls with the diameter of 7 mm.
Wherein the model of the jet mill is QS50 type gas mill, the model of the vibration sample grinding machine is XZM100 type vibration sample grinding machine, and the model of the vacuum drying box is DGG-9070 type electric heating constant temperature air blast drying box.
The prepared spherical fuel high-efficiency activation material can break up large fuel molecular groups after contacting with fuel for 1h, and can excite fuel molecular bond energy by resonance, so that the combustion efficiency of the fuel is improved, the fuel generates good activity, the fuel is promoted to be fully combusted, the emission of harmful gas is reduced, and the purposes of saving energy and reducing emission are achieved.
Comparing the first, second, third, fourth and fifth examples to draw a conclusion;
the five embodiments can be used for preparing the fuel oil high-efficiency activation material, the diameter of the prepared fuel oil high-efficiency activation material is 3-7 mm, the activation efficiency of different diameters on fuel oil is different, but compared with the traditional activation material, the activation speed is high, the defects that the fuel oil treatment effect is poor and the emission reduction effect is not obvious due to the fact that the traditional fuel oil activation material only uses a single far infrared functional raw material are overcome, and the raw materials comprise a plurality of different composite components such as a far infrared ball, tourmaline powder, a magnetic ball, an anion ball and an additive. According to the invention, high-energy infrared rays are radiated by the far infrared balls and the tourmaline powder in a band of 2.5-22 μm and the magnetization effect of the magnetic balls, and after the far infrared balls and the tourmaline powder are contacted with fuel for a period of time, large fuel molecular groups can be scattered, fuel molecular bond energy is excited by resonance, the combustion efficiency of the fuel is improved, good activity is generated, the fuel is promoted to be fully combusted, the emission of harmful gases is reduced, and the purposes of saving energy and reducing emission are achieved. Under the background of severe haze in Jingjin Ji area of China at present, the method is suitable for large-scale application in oil refineries and finished oil sales industries.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (8)
1. A fuel oil high-efficiency activation material is characterized in that: the fuel oil high-efficiency activation material is prepared by grinding and heating a tourmaline block after crushing, and then sintering and cooling the ground tourmaline block after ball milling with a far infrared ball, a magnetic ball, a medical stone ball, an anion ball and an additive, wherein:
the method comprises the following steps: selecting tourmaline blocks, and crushing in a crusher;
step two: and putting the crushed tourmaline blocks into a vibration sample grinder to carry out vibration grinding for 3 hours for crushing, and putting the crushed tourmaline blocks into a jet mill to carry out gas grinding for 3 hours after crushing to obtain tourmaline powder with the average particle size of 1.43 mu m.
Step three: the prepared tourmaline powder is placed in a vacuum drying oven to be heated for 3 hours, and the radiation frequency of the tourmaline powder in a high wave band is improved.
Step four: the material composition according to the mass percentage is that the far infrared ball 35% -50%, the tourmaline powder 20% -30%, the magnetic ball 10% -20%, the medical stone ball 0% -25%, the negative ion ball 0% -10%, the additive 0% -5%, ball milling all the materials to below 200 mesh, and sintering at 950 ℃.
2. The fuel efficient activating material according to claim 1, wherein: the magnetic ball is a ferrimagnetic ball.
3. The fuel efficient activating material according to claim 1, wherein: the average diameter of the powder after the gas milling in the step two is 1.43 mu m.
4. The fuel efficient activating material according to claim 1, wherein: the negative ion ball is formed by mixing tourmaline and clay and grinding into particles with the diameter of 6-140 um, and accounts for 3% -98% of the total weight; the clay accounts for 97-2% of the total weight; adding water, stirring, molding, drying and sintering to obtain the small balls with the diameter of 5-50 mm.
5. The fuel efficient activating material according to claim 1, wherein: the additive is one or more of alkali metal oxide, alkaline earth metal oxide, boron oxide and titanium dioxide.
6. The fuel efficient activating material according to claim 1, wherein: the effective wave band of the far infrared ball and the tourmaline powder is 2.5-22 mu m wave band.
7. The fuel efficient activating material according to claim 1, wherein: the heating temperature in the third step is 500-1000 ℃, wherein the emissivity is 0.65-0.89.
8. The fuel efficient activating material according to claim 1, wherein: the tourmaline selected in the first step is black or purple.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910811421.5A CN110699127A (en) | 2019-08-30 | 2019-08-30 | Efficient fuel oil activating material |
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| CN201910811421.5A CN110699127A (en) | 2019-08-30 | 2019-08-30 | Efficient fuel oil activating material |
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| CN110699127A true CN110699127A (en) | 2020-01-17 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114436633A (en) * | 2020-11-03 | 2022-05-06 | 西安昊锐电子科技有限公司 | Production method of inorganic porous nano ceramic material |
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