CN1253416C - 分子筛用于使含氧化合物转化成烯烃的用途 - Google Patents

分子筛用于使含氧化合物转化成烯烃的用途 Download PDF

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Publication number
CN1253416C
CN1253416C CNB028238907A CN02823890A CN1253416C CN 1253416 C CN1253416 C CN 1253416C CN B028238907 A CNB028238907 A CN B028238907A CN 02823890 A CN02823890 A CN 02823890A CN 1253416 C CN1253416 C CN 1253416C
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CN
China
Prior art keywords
molecular sieve
sapo
value
crystal
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB028238907A
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English (en)
Chinese (zh)
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CN1596235A (zh
Inventor
S·H·布朗
R·B·霍尔
K·G·斯托梅尔
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication date
Priority claimed from US09/997,778 external-priority patent/US6773688B2/en
Priority claimed from US09/997,779 external-priority patent/US6696032B2/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN1596235A publication Critical patent/CN1596235A/zh
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Publication of CN1253416C publication Critical patent/CN1253416C/zh
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62—Catalyst regeneration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Gas Separation By Absorption (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CNB028238907A 2001-11-29 2002-10-29 分子筛用于使含氧化合物转化成烯烃的用途 Expired - Fee Related CN1253416C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/997,778 US6773688B2 (en) 2001-11-29 2001-11-29 Process for manufacture of molecular sieves
US09/997,778 2001-11-29
US09/997,779 2001-11-29
US09/997,779 US6696032B2 (en) 2001-11-29 2001-11-29 Process for manufacturing a silicoaluminophosphate molecular sieve

Publications (2)

Publication Number Publication Date
CN1596235A CN1596235A (zh) 2005-03-16
CN1253416C true CN1253416C (zh) 2006-04-26

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Family Applications (1)

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CNB028238907A Expired - Fee Related CN1253416C (zh) 2001-11-29 2002-10-29 分子筛用于使含氧化合物转化成烯烃的用途

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Country Link
EP (1) EP1451131B1 (enExample)
JP (1) JP2005511669A (enExample)
CN (1) CN1253416C (enExample)
AT (1) ATE334954T1 (enExample)
AU (1) AU2002360321A1 (enExample)
DE (1) DE60213649D1 (enExample)
WO (1) WO2003048084A2 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7371915B1 (en) * 2004-06-25 2008-05-13 Uop Llc Conversion of oxygenate to propylene using moving bed technology
US7528201B2 (en) 2004-12-22 2009-05-05 Exxonmobil Chemical Patents Inc. Synthesis of silicoaluminophosphate molecular sieves
WO2007100418A1 (en) * 2006-02-27 2007-09-07 Exxonmobil Chemical Patents Inc. Method of making and process for using molecular sieve catalyst
CN101284246B (zh) * 2008-04-24 2011-05-18 中国石油化工股份有限公司 含氧化合物转化为低碳烯烃的催化剂
CN102099117B (zh) * 2008-07-25 2013-03-27 埃克森美孚化学专利公司 含菱沸石的分子筛的合成和它们在含氧物至烯烃的转化中的应用
US9492818B2 (en) 2009-06-12 2016-11-15 Albemarle Europe Sprl SAPO molecular sieve catalysts and their preparation and uses
JP5772387B2 (ja) 2011-08-23 2015-09-02 トヨタ自動車株式会社 マグネシウムを有するシリコアルミノリン酸塩モレキュラーシーブ及びその製造方法
US20140171713A1 (en) * 2012-12-14 2014-06-19 Uop Llc Nano sapo-35 and method of making
JP6703772B2 (ja) * 2015-10-09 2020-06-03 国立大学法人大阪大学 ゼオライト触媒の製造方法、ゼオライト触媒及びシリコアルミノホスフェート型ゼオライト
JP2019166418A (ja) 2016-08-08 2019-10-03 富士フイルム株式会社 ガス分離膜、ガス分離膜モジュールおよびガス分離装置
CN116002711B (zh) * 2021-10-22 2025-05-30 中国石油化工股份有限公司 Sapo-35/sapo-34共生分子筛及其制备方法和应用以及分子筛组合物及其应用
CN116002710B (zh) * 2021-10-22 2025-05-30 中国石油化工股份有限公司 一种sapo-35/sapo-5共生分子筛及其制备方法和应用以及分子筛组合物及其应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6534692B1 (en) * 1997-12-09 2003-03-18 Uop Llc Methanol to olefin process with increased selectivity to ethylene and propylene
US5912393A (en) * 1997-12-09 1999-06-15 Uop Llc Metallo aluminophosphate molecular sieve with novel crystal morphology and methanol to olefin process using the sieve
JP4168214B2 (ja) * 1998-10-15 2008-10-22 三菱瓦斯化学株式会社 メチルアミン製造触媒及び該触媒の製造方法

Also Published As

Publication number Publication date
WO2003048084A3 (en) 2003-10-16
ATE334954T1 (de) 2006-08-15
WO2003048084A2 (en) 2003-06-12
EP1451131A2 (en) 2004-09-01
DE60213649D1 (de) 2006-09-14
EP1451131B1 (en) 2006-08-02
CN1596235A (zh) 2005-03-16
AU2002360321A1 (en) 2003-06-17
JP2005511669A (ja) 2005-04-28

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