CN1250086C - Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation - Google Patents
Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation Download PDFInfo
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- CN1250086C CN1250086C CNB2003101041829A CN200310104182A CN1250086C CN 1250086 C CN1250086 C CN 1250086C CN B2003101041829 A CNB2003101041829 A CN B2003101041829A CN 200310104182 A CN200310104182 A CN 200310104182A CN 1250086 C CN1250086 C CN 1250086C
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- nimbin
- plant source
- ether
- matrine
- micro emulsion
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The present invention discloses nimbin composite plant source micro emulsion insecticide and a manufacturing method thereof and purposes in aquatic product cultivation. Nimbin is recompounded with auxiliary agents, such as matrine, stemonine, dichroine, granatenine, arecoline, cosolvent, emulsifying agents, stabilizing agents, penetrating agents, antifreezing agents, etc., and micro emulsion is manufactured. The nimbin composite plant source micro emulsion insecticide is mainly used for killing parasites of aquatic animals. Compared with single nimbin, the disinsection effect of the nimbin composite plant source micro emulsion insecticide is obviously enhanced, and the nimbin composite plant source micro emulsion insecticide which can be used for external application and oral administration is used for expelling various parasites inside and outside fishes; the nimbin composite plant source micro emulsion insecticide has the advantages of higher killing ratio, therapeutic effect on fish enteritis simultaneously, and no harm for aquatic organisms and water quality, the disinsection effect of the nimbin composite plant source micro emulsion insecticide is obviously superior to the disinsection effect of insecticide with the single nimbin, nimbin disinsection spectra are expanded, and insecticidal activity is strengthened.
Description
Affiliated field
The present invention relates to a kind of insecticide, relate to nimbin particularly and be mixed into microemulsion insecticide and preparation method thereof and the application in aquaculture with other plant insecticide.
Background technology
A large amount of chemical insecticides that use have brought many negative effects in the aquaculture, as cause serious pesticide resistance, and contaminated environment causes residual the exceeding standard of aquatic products medicine, and the outlet aquatic products suffer misfortune repeatly.For this reason, how crossing over safe barrier, improve constantly China's aquatic product quality, is current aquaculture significant problem anxious to be solved.
Along with the raising of people's quality of life with to the concern of ecotope, non-harmful aquatic products become everybody demand, aquatic products in particular for outlet are higher to non-harmful requirement, and vegetalitas fishing medicine is the important assurance that nuisanceless aquatic products are produced, and its domestic and international market is boundless.The domestic and international market increases day by day to the demand of nuisanceless aquatic products at present, and fish production is also increasing to the demand of biological fishing medicine.Developing new fishing medicine at first is to consider and the compatibility of environment that next is only biologically active, and vegetalitas fishing medicine is a big class most important in the natural source fishing medicine, that the source is the widest, and wide potential market is arranged.In aquaculture, kill the aquatic animal parasite now and generally use nimbin, nimbin be a kind of be the extract of chinaberry seed from plant, has good insecticidal activity, very fast degraded in environment, its shortcoming is unstable, and insecticidal spectrum is narrower, and cost is higher simultaneously, be difficult to promote aborning
Summary of the invention
Purpose of the present invention promptly is to overcome the shortcoming of prior art, provide a kind of to aquatic livestock parasite insecticidal effect ideal, overcome drug resistance in parasite, enlarge the insecticidal spectrum of existing insecticide nimbin, reduce consumption and dispenser cost, strengthen the nimbin compound plant source microemulsion insecticide of insecticidal activity.
Another object of the present invention provides the preparation method of above-mentioned nimbin compound plant source microemulsion insecticide.
A further object of the present invention provides above-mentioned nimbin compound plant source microemulsion insecticide purposes as the vegetalitas fishing medicine of killing aquatic animal parasite, treatment fishing class enteritis disease etc. in aquaculture.
Purpose of the present invention is achieved through the following technical solutions: nimbin compound plant source microemulsion insecticide, it comprises nimbin, it also comprises matrine, stemonine, orixine, granatenine, arecaline, cosolvent, emulsifier, stabilizing agent, bleeding agent, antifreeze, deionized water, more than the weight ratio nimbin of each composition: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.1～10: 0.1～10: 0.1～5: 0.1～10: 0.1～5: 1～50, cosolvent in the prescription is an alcohols, ketone, the ester class, in aromatic hydrocarbon and the ethers one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Emulsifier is alkyl benzene sulfonate calcium salt, C
8～C
18Sodium alkyl benzene sulfonate, C
8～C
18Alkyl benzene sulphonate zinc, C
8～C
18Alkyl benzene sulphonate barium, C
8～C
18Magnesium alkylbenzene sulfonate, C
8～C
18Alkyl benzene sulphonate aluminium, C
8～C
20The alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenolic ether sulfonate, alkylphenol polyoxyethylene, the diethanolamine of fat acyl APEO, phenethyl phenol polyethenoxy (n=15～30) ether, No. 300, farming breast, Nongru-700 number, the alkylphenol polyoxyethylene formaldehyde condensation products, the xenol APEO, phenethyl phenol polyethenoxy polyethenoxy ether etc. one or more, use when multiple, total usage amount can not be greater than the maximum of deal, and the alkylphenol polyoxyethylene in the emulsifier comprises polyoxyethylene nonylphenol ether; Stabilizing agent is one or more in 3-chloro-1,2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, epoxidised soybean oil, epoxidised linseed oil, sorb sodium alkoxide, the alkyl glycol ether, use when multiple, total usage amount can not be greater than the maximum of deal; Bleeding agent is 4-ethyl octyl group propyl group sodium sulphate, succinic acid di-secondary sodium octyl sulfate, aliphatic alcohol polyethenoxy (n=25) ether, tridecanol polyoxyethylene ether (n=6),, polyoxyethylene nonylphenol ether (n=25), methyl-sulfoxide one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Antifreeze is one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal.Above-mentioned nimbin is former medicine, or neem oil or contain the plant extract or the nimbin preparation of nimbin; Matrine is former medicine, or contains the plant extract or the matrine preparation of matrine; Stemonine, orixine all are former medicine or preparation; Granatenine is former medicine or extract; Arecaline is former medicine or preparation or betel nut extract.
The preparation method of nimbin compound plant source microemulsion insecticide is by nimbin: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.1～10: 0.1～10: 0.1～5: 0.1～10: 0.1～5: 1～50 takes by weighing each component, earlier with nimbin, matrine, stemonine, orixine, granatenine, arecaline becomes original liquid with dissolution with solvents, again various auxiliary agents are mixed, add deionized water, at last original liquid is progressively joined in the auxiliary agent mixed liquor agitating heating phase inversion and become homogeneous phase translucent or transparency liquid.
The purposes of nimbin compound plant source microemulsion insecticide is to be used for aquaculture.
By top narration as can be seen, the present invention has the following advantages: compare with single nimbin, insecticidal effect significantly improves, remove external application and can also be used for fish expelling parasite for oral administration, the killing rate of fish internal parasite is also higher, simultaneously fish enteritis is also had result of treatment, and is all harmless to aquatic organism and water quality, its insecticidal effect obviously is better than single nimbin insecticide, and the insecticidal spectrum that has enlarged nimbin has strengthened insecticidal activity.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment: nimbin compound plant source microemulsion insecticide, it comprises nimbin, it also comprises matrine, stemonine, orixine, granatenine, arecaline, cosolvent, emulsifier, stabilizing agent, bleeding agent, antifreeze, deionized water, above-mentioned nimbin is former medicine, matrine is the plant extract that contains matrine, and stemonine is former medicine, and orixine is a preparation, granatenine is an extract, and arecaline is the betel nut extract.More than the weight ratio nimbin of each composition: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 1: 1: 1: 0.2: 0.5: 1.5: 5: 6: 2: 2: 1: 30, cosolvent in the prescription is an alcohols, and emulsifier is alkyl benzene sulfonate calcium salt, C
8～C
20The alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenolic ether sulfonate, alkylphenol polyoxyethylene, the diethanolamine of fat acyl APEO, phenethyl phenol polyethenoxy (n=15～30) ether, No. 300, farming breast, during use, total usage amount can not be greater than 6 weight portions of above proportioning, stabilizing agent is a 3-chloro-1, bleeding agent is a 4-ethyl octyl group propyl group sodium sulphate, antifreeze is an ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, during use, total usage amount can not be greater than 1 weight portion of above proportioning, during making, earlier with nimbin, matrine, stemonine, orixine, granatenine, arecaline becomes original liquid with dissolution with solvents, again various auxiliary agents are mixed, add deionized water, at last original liquid is progressively joined in the auxiliary agent mixed liquor agitating heating phase inversion and become homogeneous phase translucent or transparency liquid.
Indoor insecticidal test result, product of the present invention 0.1ppm external application reaches more than 95% the killing rate of Trichodina, little melonworm killing rate is reached about 90%, to killing of oblique tube insect is more than 96%, is more than 90% to the killing rate of Dactylogyrus, and the rate of killing of cat head Sao is reached more than 92%.The present invention is used for the expelling parasite experiment for oral administration of fishing class, the result is, mix the bait fish of throwing something and feeding by 0.2%, throw something and feed continuously three times, its rate of killing to tapeworm reaches more than 95%, and the rate of killing of Dactylogyrus is reached 85%, and the rate of killing of cat head Sao is reached 92%, killing rate to the gloeospore worm is about 94%, simultaneously the fish enteritis disease is also had result of treatment.
Claims (5)
1, nimbin compound plant source microemulsion insecticide, it comprises nimbin, it is characterized in that: it also comprises matrine, stemonine, orixine, granatenine, arecaline, cosolvent, emulsifier, stabilizing agent, bleeding agent, antifreeze, deionized water, more than the weight ratio nimbin of each composition: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.1～10: 0.1～10: 0.1～5: 0.1～10: 0.1～5: 1～50, cosolvent in the prescription is an alcohols, ketone, the ester class, in aromatic hydrocarbon and the ethers one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Emulsifier is alkyl benzene sulfonate calcium salt, C
8～C
18Sodium alkyl benzene sulfonate, C
8～C
18Alkyl benzene sulphonate zinc, C
8～C
18Alkyl benzene sulphonate barium, C
8～C
18Magnesium alkylbenzene sulfonate, C
8～C
18Alkyl benzene sulphonate aluminium, C
8～C
20Alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenolic ether sulfonate, alkylphenol polyoxyethylene, diethanolamine of fat acyl APEO, oxirane number be 15～30 phenethyl phenol polyethenoxy ether, No. 300, farming breast, Nongru-700 number, alkylphenol polyoxyethylene formaldehyde condensation products, xenol APEO, phenethyl phenol polyethenoxy polyethenoxy ether etc. one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, epoxidised soybean oil, epoxidised linseed oil, sorb sodium alkoxide, the alkyl glycol ether one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Bleeding agent is that 4-ethyl octyl group propyl group sodium sulphate, succinic acid di-secondary sodium octyl sulfate, oxirane number are that 25 fatty alcohol-polyoxyethylene ether, oxirane number are that 6 tridecanol polyoxyethylene ether, oxirane number are one or more of 25 polyoxyethylene nonylphenol ether, methyl-sulfoxide, use when multiple, total usage amount can not be greater than the maximum of deal; Antifreeze is one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal.
2, nimbin compound plant source microemulsion insecticide according to claim 1, it is characterized in that: the alkylphenol polyoxyethylene in the emulsifier comprises polyoxyethylene nonylphenol ether.
3, nimbin compound plant source microemulsion insecticide according to claim 1, it is characterized in that: described nimbin is former medicine, or neem oil or contain the plant extract or the nimbin preparation of nimbin; Matrine is former medicine, or contains the plant extract or the matrine preparation of matrine; Stemonine, orixine are former medicine or preparation; Granatenine is former medicine or extract; Arecaline is former medicine or preparation or betel nut extract.
4, the preparation method of nimbin compound plant source microemulsion insecticide according to claim 1, it is characterized in that: by nimbin: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.1～10: 0.1～10: 0.1～5: 0.1～10: 0.1～5: 1～50, weight portion take by weighing each component, earlier with nimbin, matrine, stemonine, orixine, granatenine, arecaline is dissolved into original liquid with cosolvent, again various auxiliary agents are mixed, add deionized water, at last original liquid is progressively joined in the auxiliary agent mixed liquor agitating heating phase inversion and become homogeneous phase translucent or transparency liquid.
5, the purposes of nimbin compound plant source microemulsion insecticide as claimed in claim 1 is characterized in that: it is as the used for aquiculture insecticide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101041829A CN1250086C (en) | 2003-12-30 | 2003-12-30 | Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101041829A CN1250086C (en) | 2003-12-30 | 2003-12-30 | Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1555708A CN1555708A (en) | 2004-12-22 |
| CN1250086C true CN1250086C (en) | 2006-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003101041829A Expired - Fee Related CN1250086C (en) | 2003-12-30 | 2003-12-30 | Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation |
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| CN (1) | CN1250086C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102429896A (en) * | 2011-10-26 | 2012-05-02 | 天津生机集团股份有限公司 | Method for preparing aquatic animal insecticide |
| CN102860312A (en) * | 2012-09-28 | 2013-01-09 | 江苏省绿盾植保农药实验有限公司 | Insecticide containing sophoridine and azadirachtin |
| CN102942407B (en) * | 2012-10-18 | 2015-05-06 | 合肥科友生物科技有限公司 | Specialized organic/inorganic composite biological medicine fertilizer for cotton, and preparation method thereof |
| CN103814912A (en) * | 2014-02-18 | 2014-05-28 | 陶荣芝 | Nimbin emulsion and its preparation method |
| CN109156483A (en) * | 2018-10-30 | 2019-01-08 | 大新县科学技术情报研究所 | A kind of leek special bio insecticide and preparation method thereof |
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- 2003-12-30 CN CNB2003101041829A patent/CN1250086C/en not_active Expired - Fee Related
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| CN1555708A (en) | 2004-12-22 |
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