CN1555708A - Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation - Google Patents
Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation Download PDFInfo
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- CN1555708A CN1555708A CNA2003101041829A CN200310104182A CN1555708A CN 1555708 A CN1555708 A CN 1555708A CN A2003101041829 A CNA2003101041829 A CN A2003101041829A CN 200310104182 A CN200310104182 A CN 200310104182A CN 1555708 A CN1555708 A CN 1555708A
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- nimbin
- ether
- matrine
- plant source
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
A composite insecticide in the form of microemulsion for killing the parasites of aquatic animals is prepared from nimbin, sophocarpidine, stemonine, dichroin, punicine, arecaline, cosolvent, emulsifier stabilizer, penetrant and antifreezing agent. Its advantages are high effect and insecticiding activity and broad spectrum.
Description
Affiliated field
The present invention relates to a kind of insecticide, relate to nimbin particularly and be mixed into microemulsion insecticide and preparation method thereof and the application in aquaculture with other plant insecticide.
Background technology
A large amount of chemical insecticides that use have brought many negative effects in the aquaculture, as cause serious pesticide resistance, and contaminated environment causes residual the exceeding standard of aquatic products medicine, and the outlet aquatic products are banned fortune repeatly.For this reason, how crossing over safe barrier, improve constantly China's aquatic product quality, is current aquaculture significant problem anxious to be solved.
Along with the raising of people's quality of life with to the concern of ecotope, non-harmful aquatic products become everybody demand, aquatic products in particular for outlet are higher to non-harmful requirement, and vegetalitas fishing medicine is the important assurance that nuisanceless aquatic products are produced, and its domestic and international market is boundless.The domestic and international market increases day by day to the demand of nuisanceless aquatic products at present, and fish production is also increasing to the demand of biological fishing medicine.Developing new fishing medicine at first is to consider and the compatibility of environment that next is only biologically active, and vegetalitas fishing medicine is a big class most important in the natural source fishing medicine, that the source is the widest, and wide potential market is arranged.Nimbin is a kind of extract from plant seal chinaberry seed, has good insecticidal activity, very fast degraded in environment, and its shortcoming is unstable, and insecticidal spectrum is narrower, and cost is higher simultaneously, be difficult to promote aborning,
Summary of the invention
Purpose of the present invention promptly is to overcome the shortcoming of prior art, provide a kind of to aquatic livestock parasite insecticidal effect ideal, overcome drug resistance in parasite, enlarge the insecticidal spectrum of existing insecticide nimbin, reduce consumption and dispenser cost, strengthen the nimbin compound plant source microemulsion insecticide of insecticidal activity.
Another object of the present invention provides the preparation method of above-mentioned nimbin compound plant source microemulsion insecticide.
A further object of the present invention provides above-mentioned nimbin compound plant source microemulsion insecticide purposes as the vegetalitas fishing medicine of killing aquatic animal parasite, treatment fish enteritis disease etc. in aquaculture.
Purpose of the present invention is achieved through the following technical solutions: nimbin compound plant source microemulsion insecticide, it comprises nimbin, it also comprises matrine, stemonine, orixine, granatenine, arecaline, cosolvent, emulsifier, stabilizing agent, bleeding agent, antifreeze, deionized water, more than the weight ratio nimbin of each composition: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.1～10: 0.1～10: 0.1～5: 0.1～10: 0.1～5: 1～50, cosolvent in the prescription is an alcohols, ketone, the ester class, in aromatic hydrocarbon and the ethers one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Emulsifier is alkyl benzene sulfonate calcium salt, C
8～C
18Sodium alkyl benzene sulfonate (zinc, barium, magnesium, aluminium) salt, C
8～C
20The alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenolic ether sulfonate, alkylphenol polyoxyethylene, the diethanolamine of fat acyl APEO, polyoxyethylene nonylphenol ether, phenethyl phenol polyethenoxy (n=15～30) ether, No. 300, homemade farming breast, homemade Nongru-700 number, the alkylphenol polyoxyethylene formaldehyde condensation products, the xenol APEO, phenethyl phenol polyethenoxy polyethenoxy ether etc. one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Stabilizing agent is one or more in 3-chloro-1,2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, epoxidised soybean oil, epoxidised linseed oil, sorb sodium alkoxide, the alkyl glycol ether, use when multiple, total usage amount can not be greater than the maximum of deal; Bleeding agent is one or more of 4-ethyl octyl group propyl group sodium sulphate, succinic acid di-secondary sodium octyl sulfate, aliphatic alcohol polyethenoxy (n=25) ether, tridecanol polyoxyethylene ether (n=6), polyoxyethylene nonylphenol ether (n=25), dimethyl sulfoxide (DMSO), use when multiple, total usage amount can not be greater than the maximum of deal; Antifreeze is one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal.Above-mentioned nimbin can be former medicine, also can be neem oil or the plant extract that contains nimbin or nimbin preparation; Matrine can be former medicine, also can be plant extract or the matrine preparation that contains matrine; Stemonine, orixine all can be that former medicine also can be a preparation; Granatenine can be former medicine or extract; Arecaline can be former medicine or preparation or betel nut extract.
The preparation method of nimbin compound plant source microemulsion insecticide is earlier nimbin, matrine, stemonine, orixine, granatenine, arecaline to be become original liquid with dissolution with solvents, again various auxiliary agents are mixed, add deionized water, at last original liquid is progressively joined in the auxiliary agent mixed liquor agitating heating phase inversion and become homogeneous phase translucent or transparency liquid.
The purposes of nimbin compound plant source microemulsion insecticide is to be used for aquaculture.
By top narration as can be seen, the present invention has the following advantages: compare with single nimbin, insecticidal effect significantly improves, remove external application, can also take orally, be used to drive away the inside and outside various parasites of fish body, simultaneously fish enteritis also there is result of treatment, all harmless to aquatile and water quality, its insecticidal effect obviously is better than single nimbin insecticide, and the insecticidal spectrum that has enlarged nimbin has strengthened insecticidal activity.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment: nimbin compound plant source microemulsion insecticide, it comprises nimbin, it also comprises matrine, stemonine, orixine, granatenine, arecaline, cosolvent, emulsifier, stabilizing agent, bleeding agent, antifreeze, deionized water, above-mentioned nimbin is former medicine, matrine is the plant extract that contains matrine, and stemonine is former medicine, and orixine is a preparation, granatenine is an extract, and arecaline is the betel nut extract.More than the weight ratio nimbin of each composition: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 1: 1: 1: 0.2: 0.5: 1.5: 5: 6: 2: 2: 1: 30, cosolvent in the prescription is an alcohols, and emulsifier is alkyl benzene sulfonate calcium salt, C
8～C
20The alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenolic ether sulfonate, alkylphenol polyoxyethylene, the diethanolamine of fat acyl APEO, polyoxyethylene nonylphenol ether, phenethyl phenol polyethenoxy (n=15～30) ether, No. 300, homemade farming breast, during use, total usage amount can not be greater than 6 weight portions of above proportioning, stabilizing agent is a 3-chloro-1, bleeding agent is a 4-ethyl octyl group propyl group sodium sulphate, antifreeze is an ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite, during use, total usage amount can not be greater than 1 weight portion of above proportioning, during making, earlier with nimbin, matrine, stemonine, orixine, granatenine, arecaline becomes original liquid with dissolution with solvents, again various auxiliary agents are mixed, add deionized water, at last original liquid is progressively joined in the auxiliary agent mixed liquor agitating heating phase inversion and become homogeneous phase translucent or transparency liquid.
Indoor insecticidal test result, product of the present invention 0.1ppm external application reaches more than 95% the killing rate of Trichodina, little melonworm killing rate is reached about 90%, to killing of oblique tube insect is more than 96%, is more than 90% to the killing rate of Dactylogyrus, and the rate of killing of cat head Sao is reached more than 92%.The present invention is used for fish expelling parasite experiment for oral administration, the result is, mix the bait fish of throwing something and feeding by 0.2%, throw something and feed continuously three times, its rate of killing to tapeworm reaches more than 95%, and the rate of killing of Dactylogyrus is reached 85%, and the rate of killing of anchor head Sao is reached 92%, killing rate to the gloeospore worm is about 94%, simultaneously the fish enteritis disease is also had result of treatment.
Claims (4)
1, nimbin compound plant source microemulsion insecticide, it comprises nimbin, it is characterized in that: it also comprises matrine, stemonine, orixine, granatenine, arecaline, cosolvent, emulsifier, stabilizing agent, bleeding agent, antifreeze, deionized water, more than the weight ratio nimbin of each composition: matrine: stemonine: orixine: granatenine: arecaline: cosolvent: emulsifier: stabilizing agent: bleeding agent: antifreeze: deionized water is 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.01～5: 0.1～10: 0.1～10: 0.1～5: 0.1～10: 0.1～5: 1～50, cosolvent in the prescription is an alcohols, ketone, the ester class, in aromatic hydrocarbon and the ethers one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Emulsifier is alkyl benzene sulfonate calcium salt, C
8～C
18Sodium alkyl benzene sulfonate (zinc, barium, magnesium, aluminium) salt, C
8～C
20The alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenolic ether sulfonate, alkylphenol polyoxyethylene, the diethanolamine of fat acyl APEO, polyoxyethylene nonylphenol ether, phenethyl phenol polyethenoxy (n=15～30) ether, No. 300, homemade farming breast, homemade Nongru-700 number, the alkylphenol polyoxyethylene formaldehyde condensation products, the xenol APEO, phenethyl phenol polyethenoxy polyethenoxy ether etc. one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Stabilizing agent is a 3-chloro-1, in 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, epoxidised soybean oil, epoxidised linseed oil, sorb sodium alkoxide, the alkyl glycol ether one or more, use when multiple, total usage amount can not be greater than the maximum of deal; Bleeding agent is one or more of 4-ethyl octyl group propyl group sodium sulphate, succinic acid di-secondary sodium octyl sulfate, aliphatic alcohol polyethenoxy (n=25) ether, tridecanol polyoxyethylene ether (n=6), polyoxyethylene nonylphenol ether (n=25), dimethyl sulfoxide (DMSO), use when multiple, total usage amount can not be greater than the maximum of deal; Antifreeze is one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite, uses when multiple, and total usage amount can not be greater than the maximum of deal.
2, nimbin compound plant source microemulsion insecticide according to claim 1, it is characterized in that: described nimbin can be former medicine, also can be neem oil or the plant extract that contains nimbin or nimbin preparation; Matrine can be former medicine, also can be plant extract or the matrine preparation that contains matrine; Stemonine, orixine all can be that former medicine also can be a preparation; Granatenine can be former medicine or extract; Arecaline can be former medicine or preparation or betel nut extract.
3, the preparation method of nimbin compound plant source microemulsion insecticide, it is characterized in that: earlier nimbin, matrine, stemonine, orixine, granatenine, arecaline are become original liquid with dissolution with solvents, again various auxiliary agents are mixed, add deionized water, at last original liquid is progressively joined in the auxiliary agent mixed liquor agitating heating phase inversion and become homogeneous phase translucent or transparency liquid.
4, the purposes of nimbin compound plant source microemulsion insecticide is characterized in that: it is as used for aquiculture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101041829A CN1250086C (en) | 2003-12-30 | 2003-12-30 | Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101041829A CN1250086C (en) | 2003-12-30 | 2003-12-30 | Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1555708A true CN1555708A (en) | 2004-12-22 |
| CN1250086C CN1250086C (en) | 2006-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003101041829A Expired - Fee Related CN1250086C (en) | 2003-12-30 | 2003-12-30 | Nimbin composite plant source micro emulsion pesticide and its manufacturing method and use in aquatic product cultivation |
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| CN (1) | CN1250086C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102429896A (en) * | 2011-10-26 | 2012-05-02 | 天津生机集团股份有限公司 | Method for preparing aquatic animal insecticide |
| CN102860312A (en) * | 2012-09-28 | 2013-01-09 | 江苏省绿盾植保农药实验有限公司 | Insecticide containing sophoridine and azadirachtin |
| CN102942407A (en) * | 2012-10-18 | 2013-02-27 | 合肥科友生物科技有限公司 | Specialized organic/inorganic composite biological medicine fertilizer for cotton, and preparation method thereof |
| CN103814912A (en) * | 2014-02-18 | 2014-05-28 | 陶荣芝 | Nimbin emulsion and its preparation method |
| CN109156483A (en) * | 2018-10-30 | 2019-01-08 | 大新县科学技术情报研究所 | A kind of leek special bio insecticide and preparation method thereof |
-
2003
- 2003-12-30 CN CNB2003101041829A patent/CN1250086C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102429896A (en) * | 2011-10-26 | 2012-05-02 | 天津生机集团股份有限公司 | Method for preparing aquatic animal insecticide |
| CN102860312A (en) * | 2012-09-28 | 2013-01-09 | 江苏省绿盾植保农药实验有限公司 | Insecticide containing sophoridine and azadirachtin |
| CN102942407A (en) * | 2012-10-18 | 2013-02-27 | 合肥科友生物科技有限公司 | Specialized organic/inorganic composite biological medicine fertilizer for cotton, and preparation method thereof |
| CN102942407B (en) * | 2012-10-18 | 2015-05-06 | 合肥科友生物科技有限公司 | Specialized organic/inorganic composite biological medicine fertilizer for cotton, and preparation method thereof |
| CN103814912A (en) * | 2014-02-18 | 2014-05-28 | 陶荣芝 | Nimbin emulsion and its preparation method |
| CN109156483A (en) * | 2018-10-30 | 2019-01-08 | 大新县科学技术情报研究所 | A kind of leek special bio insecticide and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN1250086C (en) | 2006-04-12 |
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