CN106342796A - Application technology of paclobutrazol in insecticidal water emulsion - Google Patents
Application technology of paclobutrazol in insecticidal water emulsion Download PDFInfo
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- CN106342796A CN106342796A CN201610632442.7A CN201610632442A CN106342796A CN 106342796 A CN106342796 A CN 106342796A CN 201610632442 A CN201610632442 A CN 201610632442A CN 106342796 A CN106342796 A CN 106342796A
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- Prior art keywords
- paclobutrazol
- aqueous emulsion
- application technology
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- water
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an application technology of paclobutrazol in insecticidal water emulsion. The water emulsion is prepared from, by weight, 1%-20% of active components, 0.1%-1% of the paclobutrazol, 1%-30% of environmentally friendly solvent, 1%-20% of a surface active agent, 0-5% of an antifreezing agent, 1%-15% of stabilizer and the balance of water. The primary solvent in the water emulsion is the environmentally friendly solvent of sec-butyl acetate and the like, and environmental pollution is lowered; the production process is simple and low in energy consumption; the liquid droplet size of the water emulsion is smaller than 0.2umm, high in component dispersion, even and high in stability, high stability, long lasting period, safety in use and low environmental pollution are achieved, use effectiveness of the primary solvent and secondary solvent is improved, and preference is provided for development of the pesticide water emulsion to environmental protection solvent form.
Description
Technical field
The invention belongs to environmental-protecting chemical pesticides application production field, it is related to a kind of paclobutrazol answering in disinsection aqueous emulsion
Use technology.
Background technology
Rationally scientifically can improve prevention effect using pesticide, delay harmful organism to develop immunity to drugs or expand to use model
Enclose simultaneous control different types of harmful organism, save manpower and dosage, reduces cost, improve drug effect, reduce toxicity, it is right to strengthen
The safety of people, animal.
The equipment that various pesticide are applied has its specific purposes and performance, and during dispenser, liquid preparation sprays, powder
Dust, granule spreads fertilizer over the fields, poison bait puts into performance, the feature being both needed to consider the apparatus and equipment using, and could play it well
Due effect, makes medicament uniformly be distributed in crop or harmful organism surface thoughtfully, acquirement science, efficiently prevents and treats result.
Using controlling object must be recognized before pesticide and grasps the suitable pesticide species of selection, with reference to various places plant protection
Books that department is write, handbook, prevent from misapplying pesticide, reach the ideal effect of dispenser to the ill.
Pesticide is also the important means that the mankind prevent and treat agricultural pest and disease damage, and chemical pesticide plays to the increasing both production and income ensureing agricultural
Very important effect, but the use of pesticide, while Ensuring Food Safety produces, also bring residual, pollution etc.
Serial environment and social problem.
Pesticide is the special chemicals of a class, and it can prevent and treat agricultural pest and disease damage, also can produce harm to people and animals.Therefore,
The use of pesticide, on the one hand brings benefit to the mankind, and on the other hand also gives people class and relies the environment according to existence to bring harm, according to related report
Road, pesticide utilization rate is generally 10%, and about 90% residual in the environment, causes the pollution to environment.The pesticide scattering and disappearing in a large number
It evaporate in the air, flow in water body, sedimentation is gathered in soil, pollute farming animals fishing fruit product, and by the enrichment of food chain
Human body is transferred in effect, produces harm to human body.Therefore, develop safe efficient environmental protection, extend the lasting period, mitigate poisoning, fall
Low pesticide residual in the environment, the novel form preparation of the range of application increasing pesticide have become the development side of pesticide in future dosage form
One of to.
, as a kind of novel environment friendly dosage form, in terms of extending the pesticide lasting period, contribution is remarkable for aqueous emulsion, but its internal interpolation
Compositions, method is different, and on market, existing aqueous emulsion seldom has formula or the composition adding physics stabilizer.And the present invention mainly with
Paclobutrazol makes water and milk system more stable for physically stable agent cooperation conventional chemical stabilizer, and its property has that raw material is nontoxic, holds
The effect phase is good, physical and chemical stability is high and the advantages of good biocompatibility.
But the duration of each product of aqueous emulsion that existing market is sold is relatively short, cause the frequent medication of peasant simultaneously constantly
Improve dosing, much area all causes drug-fast generation, and the lasting period extending this medicament for this becomes urgently to be resolved hurrily
Problem.Additionally, the current Water emulsion using is still with aromatic hydrocarbon as primary solvent, due to using substantial amounts of mineral soil with have
Machine solvent, not only consumes substantial amounts of fossil resources, and environment be also result in very big pressure.Replace aromatic hydrocarbon with environmentally friendly solvent molten
After agent, its stability not only can be improved, extend the lasting period, reduce application times and amount of application, can also be mitigated it to environment
With the harmful effect of agricultural product, thus improve medication safety.
The defect existing for existing method for producing aqueous emulsion above and Related product, the application purpose is to develop special
In insecticide and a kind of new aqueous emulsion product of high-efficiency environment friendly of crop yield can be improved, above aqueous emulsion system both can be solved
The safety issue of standby process, can keep the exclusive feature of aqueous emulsion product again.This aqueous emulsion product is removed has prevention and control insect pest
Can be outer, also by adding synergist and plant growth regulator, significantly improve drug effect, after aqueous emulsion product of the present invention,
The drug effect lasting period is long, and yield lifting substantially, thus decreasing the persistently administration pollution to environment for the chemical pesticide, is more beneficial for reducing
Pesticide residues on crop.And the product being exclusively used in pest control is more easy to and Fertilizer combination, mixture is simple, uniformly, can substantially contract
During casual labourer, improve work efficiency, increase drug effect.
Content of the invention
Blank used in aqueous emulsion for solving current physically stable agent, it is an object of the invention to provide a kind of multiple-effect
Application technology in disinsection aqueous emulsion for the azoles.
The present invention is achieved through the following technical solutions: a kind of application technology in disinsection aqueous emulsion for paclobutrazol,
Described aqueous emulsion is grouped into by the one-tenth of following percetage by weight: effective ingredient 1-20%, paclobutrazol 0.1-1%, environmentally friendly solvent 1-
30%, surfactant 1-20%, antifreezing agent 0-5%, stabilizer 1-15%, remaining is water.
Described effective ingredient is selected from Biphenthrin, gamma cyhalothrin, avilamycin, chlopyrifos, propargite, demodicid mite of rattling away
One of spirit；
Described environmentally friendly solvent is selected from one of sec-Butyl Acetate, solvent naphtha 100#, solvent naphtha 150#, solvent naphtha 200#
Or several combinations.
Described surfactant is wooden sodium sulfonate, dodecyl sodium sulfate, sodium lauryl sulphate, lauryl alcohol polyoxy
Oxyethylene sulfate, sorbitan fatty acid ester, alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkaryl phenol
Polyoxyethylene ether phosphate, castor oil polyoxyethylene ether, alkylbenzenesulfonate, alkylphenol-polyethenoxy phosphate, maleic two
The combination of two or more in sour di-sec-octyl sodium sulfonate, polyol fatty acid ester and its ethylene oxide adduct.
Described stabilizer is one of epoxy soybean oil, bht, epoxychloropropane or two kinds of combination.
Described antifreezing agent is one of ethylene glycol, glycerol, sodium salicylate or two kinds of combination.
Described water is soft tap water or soft water or deionized water.
The preparation method of aqueous emulsion of the present invention: accurately weigh each component in proportion；By the appropriate solvent of effective ingredient
Fully dissolve completely, uniformly, add emulsifying agent, mix；Add paclobutrazol so as to mixing and emulsifying is uniform；Add stabilizer, antifreeze
Agent, deionized water simultaneously stir, with efficient cutter high speed shear 10-15 minute；Room temperature cools down, and obtains finished product
Described paclobutrazol is plant growth regulators, has and delays plant growing, suppression cane elongation, shortens section
Between, promote plant tillering, increase plant stress-resistance performance, promote plant metabolism, so that medicinal liquid can be entered in plant body, to thorn
Suction, the insect of biting mouthparts, have the insecticidal effect of strength, can improve drug effect, increase yield.
The invention provides a kind of lasting period length, low toxicity, environmentally friendly, person poultry safety, drug resistance is not likely to produce to insect pest
The aqueous emulsion of property.Said preparation stable performance, degradable, the crop pests lasting period is grown tall, environmental pollution very little.With existing
Technology is compared, there is provided the more eco-friendly pesticidal preparations of one kind, meets the non-environmental pollution control needs of agricultural pests.
Specific embodiment
Hereinafter the preferred embodiments of the present invention are illustrated it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Unless otherwise indicated, the percent employed in the present invention is percetage by weight.
Embodiment 1:2.5% Biphenthrin emulsion in water.
Preparation method:
(1) accurately weigh 2.55 grams of 98% Biphenthrin active compound, fully dissolved with 5 grams of ethylene glycol monoethyl ethers complete, uniform,
Add 2 grams of emulsifying agent castor oil polyoxyethylene ether, 1.5 grams of polyol fatty acid ester, stand-by.
(2) in the case of (1) stirring, add 0.1g paclobutrazol so as to mixing and emulsifying is uniform.
(3) in the case of (2) stirring, add stabilizer 2.5g glycerol.
(4) in the case of (3) stirring, deionized water is mended to 100g.
(5) with efficient cutter high speed shear 10-15 minute.
(6) room temperature cooling, obtains finished product.
Stability observing: optical microphotograph Microscopic observation, obtain the 2.5% Biphenthrin water and milk that mean diameter is 0.16 μm
Agent, under conditions of irradiating 24h through cold storage (0 ± 1 DEG C) 7 days, heat storage (54 ± 2 DEG C) 14 days, room temperature ultraviolet light, Biphenthrin
Resolution ratio difference 0.06%, 0.13%, 0.19%.
Embodiment 2:2.5% gamma cyhalothrin aqueous emulsion.
Preparation method:
(1) accurately weigh 2.58 grams of 97% gamma cyhalothrin active compound, fully dissolved with 6 grams of n- methyl pyrrolidones
Entirely, uniformly, add 1.4 grams of emulsifying agent disecoctylmaleate sodium sulfonate, 2.6 grams of styryl phenol polyethenoxy ether, treat
With.
(2) in the case of (1) stirring, add 0.5g paclobutrazol so as to mixing and emulsifying is uniform.
(3) in the case of (2) stirring, add stabilizer 2.5g glycerol.
(4) in the case of (3) stirring, deionized water is mended to 100g.
(5) with efficient cutter high speed shear 10-15 minute.
(6) room temperature cooling, obtains finished product.
Stability observing: optical microphotograph Microscopic observation, obtain 2.5% gamma cyhalothrin that mean diameter is 0.13 μm
Aqueous emulsion, irradiates 1 day under the conditions of obtaining through cold storage (0 ± 1 DEG C) 7 days, heat storage (54 ± 2 DEG C) 14 days, room temperature ultraviolet light, efficient chlorine
The resolution ratio of flucythrinate is respectively 0.20%, 0.38%, 0.97%.
Embodiment 3:5% gamma cyhalothrin aqueous emulsion.
Preparation method:
(1) accurately weigh 5.15 grams of 97% gamma cyhalothrin active compound, with 12 grams of propylene glycol monomethyl ethers fully dissolve completely,
Uniformly, 2.9 grams of emulsifying agent alkylphenol polyoxyethylene, 1.6 grams of alkylphenol-polyethenoxy phosphate sodium are added, stand-by.
(2) in the case of (1) stirring, add 0.8g paclobutrazol so as to mixing and emulsifying is uniform.
(3) in the case of (2) stirring, add stabilizer 1.5g ethylene glycol.
(4) in the case of (3) stirring, deionized water is mended to 100g.
(5) with efficient cutter high speed shear 10-15 minute.
(6) room temperature cooling, obtains finished product.
Stability observing: optical microphotograph Microscopic observation, obtain the 5% gamma cyhalothrin water that mean diameter is 0.18 μm
Emulsion, under conditions of irradiating 24h through cold storage (0 ± 1 DEG C) 7 days, heat storage (54 ± 2 DEG C) 14 days, room temperature ultraviolet light, efficient chlorine fluorine
The resolution ratio of Cyano chrysanthemate is respectively 0.22%, 0.56%, 0.98%.
Embodiment 4:3% abamectin aqueous emulsion.
Preparation method:
(1) accurately weigh 3.23 grams of 93% the former medicine of AVM, fully dissolved with 7 grams of sec-Butyl Acetates complete, uniform, plus
Enter .9 gram of emulsifying agent alkaryl phenol polyethenoxy ether phosphoesterase 30,3.5 grams of alkylbenzenesulfonate sodium, stand-by.
(2) in the case of (1) stirring, add 0.55g paclobutrazol so as to mixing and emulsifying is uniform.
(3) in the case of (2) stirring, stabilizer 5.5g sodium salicylate, antifreeze glycol 2g are added.
(4) in the case of (3) stirring, deionized water is mended to 100g.
(5) with efficient cutter high speed shear 10-15 minute.
(6) room temperature cooling, obtains finished product.
Stability observing: optical microphotograph Microscopic observation, obtain 3% abamectin aqueous emulsion that mean diameter is 0.11 μm,
Through cold storage (0 ± 1 DEG C) 7 days, heat storage (54 ± 2 DEG C) 14 days, room temperature ultraviolet light irradiate 24h under conditions of, avilamycin point
Solution rate is respectively 0.20%, 0.29%, 1.46%.
Embodiment 5: field control effectiveness test.
The aqueous emulsion that example obtains is prepared compared with the existing formulations of pesticide without improve stability by above-mentioned enforcement, also prolongs
Grow the lasting period, decreased application times and amount of application, also reduced its harmful effect to environment and agricultural product, thus improved
The safety of medication.
Table 1, field control effectiveness test result
Field control effectiveness test shows, the present invention adds the aqueous emulsion of paclobutrazol, after medicine 15 days insect pest preventive effects all 95% with
On, do not add more than the 85% of paclobutrazol better than comparison aqueous emulsion, add the aqueous emulsion of paclobutrazol, remain within 90 days after medicine maintain insect pest
Preventive effect more than 90%, does not add more than the 80% of paclobutrazol better than comparison aqueous emulsion, and effect of increasing production is obvious.
Claims (8)
1. a kind of application technology in disinsection aqueous emulsion for paclobutrazol is it is characterised in that described aqueous emulsion is by following weight percent
The one-tenth of number is grouped into: effective ingredient 1-20%, paclobutrazol 0.1-1%, environmentally friendly solvent 1-30%, surfactant 1-20%, prevents
Freeze agent 0-5%, stabilizer 1-15%, remaining is water.
2. a kind of application technology in disinsection aqueous emulsion for the paclobutrazol according to claim 1 is it is characterised in that described
Effective ingredient is selected from one of Biphenthrin, gamma cyhalothrin, avilamycin, chlopyrifos, propargite, pyridaben.
3. a kind of application technology in disinsection aqueous emulsion for the paclobutrazol according to claim 1 is it is characterised in that described
Environmentally friendly solvent is selected from the combination of one or more of sec-Butyl Acetate, solvent naphtha 100#, solvent naphtha 150#, solvent naphtha 200#.
4. a kind of application technology in disinsection aqueous emulsion for the paclobutrazol according to claim 1 is it is characterised in that described
Surfactant is wooden sodium sulfonate, dodecyl sodium sulfate, sodium lauryl sulphate, lauryl alcohol polyethylene glycol oxide sodium sulfate, mistake
Water Span, alkylphenol polyoxyethylene, styryl phenol polyethenoxy ether, alkaryl phenol polyethenoxy ether phosphoric acid
Ester, castor oil polyoxyethylene ether, alkylbenzenesulfonate, alkylphenol-polyethenoxy phosphate, maleic acid di-sec-octyl sulfonic acid
The combination of two or more in sodium, polyol fatty acid ester and its ethylene oxide adduct.
5. a kind of application technology in disinsection aqueous emulsion for the paclobutrazol according to claim 1 is it is characterised in that described
Stabilizer is one of epoxy soybean oil, bht, epoxychloropropane or two kinds of combination.
6. a kind of application technology in disinsection aqueous emulsion for the paclobutrazol according to claim 1 is it is characterised in that described
Antifreezing agent is one of ethylene glycol, glycerol, sodium salicylate or two kinds of combination.
7. a kind of application technology in disinsection aqueous emulsion for the paclobutrazol according to claim 1 is it is characterised in that described
Water is soft tap water or soft water or deionized water.
8. the paclobutrazol described in a kind of claim 1 in disinsection aqueous emulsion it is characterised in that the preparation method of described aqueous emulsion:
Accurately weigh each component in proportion；Effective ingredient is fully dissolved with appropriate solvent complete, uniform, add emulsifying agent, mix；Plus
Enter paclobutrazol so as to mixing and emulsifying is uniform；Add stabilizer, antifreezing agent, deionized water and stir, high with efficient cutter
Speed shearing 10-15 minute；Room temperature cools down, and obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610632442.7A CN106342796A (en) | 2016-08-03 | 2016-08-03 | Application technology of paclobutrazol in insecticidal water emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610632442.7A CN106342796A (en) | 2016-08-03 | 2016-08-03 | Application technology of paclobutrazol in insecticidal water emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106342796A true CN106342796A (en) | 2017-01-25 |
Family
ID=57843582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610632442.7A Withdrawn CN106342796A (en) | 2016-08-03 | 2016-08-03 | Application technology of paclobutrazol in insecticidal water emulsion |
Country Status (1)
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| CN (1) | CN106342796A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113229282A (en) * | 2021-06-08 | 2021-08-10 | 中国水稻研究所 | Application of paclobutrazol as pesticide synergist |
| CN115104612A (en) * | 2021-08-24 | 2022-09-27 | 汝阳自强生物科技有限公司 | Granular formulation for treating melon wilt and preparation method and application thereof |
-
2016
- 2016-08-03 CN CN201610632442.7A patent/CN106342796A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113229282A (en) * | 2021-06-08 | 2021-08-10 | 中国水稻研究所 | Application of paclobutrazol as pesticide synergist |
| CN115104612A (en) * | 2021-08-24 | 2022-09-27 | 汝阳自强生物科技有限公司 | Granular formulation for treating melon wilt and preparation method and application thereof |
| CN115104612B (en) * | 2021-08-24 | 2023-10-27 | 汝阳自强生物科技有限公司 | Granule for treating melon wilt and preparation method and application thereof |
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Application publication date: 20170125 |