CN1247868A - 挥发性线形硅氧烷混合物 - Google Patents
挥发性线形硅氧烷混合物 Download PDFInfo
- Publication number
- CN1247868A CN1247868A CN99111502A CN99111502A CN1247868A CN 1247868 A CN1247868 A CN 1247868A CN 99111502 A CN99111502 A CN 99111502A CN 99111502 A CN99111502 A CN 99111502A CN 1247868 A CN1247868 A CN 1247868A
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- siloxane
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- 239000000203 mixture Substances 0.000 title claims abstract description 69
- -1 siloxanes Chemical class 0.000 title description 29
- 125000005375 organosiloxane group Chemical group 0.000 claims abstract description 34
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
- 239000002537 cosmetic Substances 0.000 claims abstract description 11
- 238000009472 formulation Methods 0.000 claims abstract description 7
- 239000011737 fluorine Substances 0.000 claims abstract description 4
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000460 chlorine Chemical group 0.000 claims abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000001704 evaporation Methods 0.000 claims description 12
- 230000008020 evaporation Effects 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 claims description 3
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005051 trimethylchlorosilane Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 150000001345 alkine derivatives Chemical class 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 19
- 238000002360 preparation method Methods 0.000 description 18
- 235000013599 spices Nutrition 0.000 description 16
- 239000000975 dye Substances 0.000 description 10
- 230000035807 sensation Effects 0.000 description 8
- 210000004209 hair Anatomy 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 238000005352 clarification Methods 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 239000006210 lotion Substances 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- AXISYYRBXTVTFY-UHFFFAOYSA-N Isopropyl tetradecanoate Chemical class CCCCCCCCCCCCCC(=O)OC(C)C AXISYYRBXTVTFY-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 229940008099 dimethicone Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000001166 anti-perspirative effect Effects 0.000 description 2
- 239000003213 antiperspirant Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000002884 skin cream Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- ZQCIPRGNRQXXSK-UHFFFAOYSA-N 1-octadecoxypropan-2-ol Chemical compound CCCCCCCCCCCCCCCCCCOCC(C)O ZQCIPRGNRQXXSK-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 1
- FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000002521 alkyl halide group Chemical group 0.000 description 1
- YCLAMANSVUJYPT-UHFFFAOYSA-L aluminum chloride hydroxide hydrate Chemical compound O.[OH-].[Al+3].[Cl-] YCLAMANSVUJYPT-UHFFFAOYSA-L 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- YECIFGHRMFEPJK-UHFFFAOYSA-N lidocaine hydrochloride monohydrate Chemical compound O.[Cl-].CC[NH+](CC)CC(=O)NC1=C(C)C=CC=C1C YECIFGHRMFEPJK-UHFFFAOYSA-N 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229940113124 polysorbate 60 Drugs 0.000 description 1
- 229940078491 ppg-15 stearyl ether Drugs 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
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Abstract
本发明涉及具有化学通式1之线形有机硅氧烷混合物R3SiO-(SiR2O)n-SiR3(1),其中,R可相同或不同且是具有1至18个碳原子、选择性地由氟、氯或氰基取代且不含烯型或炔型不饱和键之烃基,及n为0至20,其中R基之平均碳原子个数至多为3及依照DIN53249测量,该混合物经蒸发之程度是:30分钟之后80至95%(重量),60分钟之后90至99%(重量)及120分钟之后95至100%(重量)。该线形有机硅氧烷用于化妆用配制品。
Description
本发明涉及线形有机硅氧烷混合物、其制备方法,及化妆用配制品之制备方法。
挥发性硅氧烷化合物在许多场合之应用范围极为广泛,包含化妆品中之挥发性载体物质。因其蒸发热低,通常挥发性硅氧烷化合物蒸发时不致引起皮肤发冷或发烧之感觉。
由于蒸气压高及沸点低,挥发性硅氧烷化合物蒸发快速且不留残渣。但蒸发速率不可太高,以免来不及将含有挥发性硅氧烷混合物之配制品均匀地涂敷、分散、抹擦或渗透在皮肤或头发上。再者,经化妆过之部位不致变干,但却平滑柔软。
最常用之硅氧烷是具有4至6个硅氧烷基之环型硅氧烷(简称D4、D5、D6,其中仅含甲基),尤其其混合物更常用,这是因为硅氧烷之蒸发速率极为适当。但目前D4有毒性再现效应的嫌疑。
美国专利US-A-5,002,762及US-A-5,084,577中曾述及化妆品所用多种线形硅氧烷代用品。但并未揭示具有适当蒸发作用之硅氧烷混合物。美国专利US-A-5,002,762中之线形硅氧烷所含作为自由基的官能团,在化妆用配制品内可发生不必要(不受欢迎)且无法计算(全面掌控)之交互作用。
本发明之目的在提供若干化妆品挥发性载体物质,该载体物质不含具有4至6个硅氧烷基之环型硅氧烷,惰性非常高且与许多其他化妆品原料之相容性甚佳。
本发明提供了若干具有化学通式1之线形有机硅氧烷混合物
R3SiO-(SiR2O)n-SiR3 (1)
其中
R可相同或不同且是一种具有1至18个碳原子、选择性地由氟、氯或氰基取代且不含烯型或炔型不饱和键之烃基,及n为0至20,
其中R基之平均碳原子个数至多为3并且
依照DIN 53249测量,该混合物经蒸发之程度是:
30分钟之后80至95%(重量),
60分钟之后90至99%(重量)及,
120分钟之后95至100%(重量)。
本发明所依据的是这样的发现:即线形有机硅氧烷混合物之蒸发作用远较具有4至6个硅氧烷基之环型硅氧烷者适当。
依照DIN 53249测量蒸发速率之步骤:
1.称量一张直径150mm之圆形滤纸,
2.用吸管滴加0.3毫升试样并立即称量过滤纸及
3.于无风处,在室温(25℃)下,每间隔5分钟称量滤纸一次。
每次重量之称量均精确至0.001克。
R基之实例是:烷基,如:甲基、乙基、正丙基、正丁基、异丁基、叔丁基、正戊基、异戊基、新戊基、叔戊基、已基,如:正己基、庚基,如:正庚基,辛基,如:正辛基及异辛基,如:2,2,4-三甲基戊基,壬基,如:正壬基,癸基,如:正癸基,十二烷基,如:正十二烷基,十八烷基,如:正十八烷基;环烷基,如:环戊基、环已基、环庚基及甲基环已基;芳香基,如:苯基、萘基及蒽基及菲基;烷芳基,如:邻-、间-、对-甲苯基、二甲苯基及乙苯基;芳烷基,如:苄基、及α-及β-苯乙基。
经取代之R基之实例是:氰烷基,如:β-氰乙基及卤代烃基,例如:卤烷基,如:3,3,3-三氟正丙基,2,2,2,2’2’,2’-六氟异丙基、七氟异丙基及卤代芳基,如:邻-、间-及对-氯苯基。
R基优选线形烷基,尤其是具有1至10个碳原子,特别是具有1至6个碳原子。较优选之R基是乙基,尤其是甲基。
n优选至多12,尤其是至多10。
R基之平均碳原子数优选最多2个,尤其是最多1.5个。
在R为甲基之优选实施方案中,
0.5至20%(重量)之有机硅氧烷之n值为0,
20至65%(重量)之有机硅氧烷之n值为1,
10至40%(重量)之有机硅氧烷之n值为2,
0.5至20%(重量)之有机硅氧烷之n值为3,
0至10%(重量)之有机硅氧烷之n值为4,
0至5%(重量)之有机硅氧烷之n值为5,
0至5%(重量)之有机硅氧烷之n值为6至20。
在R为甲基之特别优选的实施方案中,
6至12%(重量)之有机硅氧烷之n值为0,
45至55%(重量)之有机硅氧烷之n值为1,
22至30%(重量)之有机硅氧烷之n值为2,
6至12%(重量)之有机硅氧烷之n值为3,
1至5%(重量)之有机硅氧烷之n值为4,
0至3%(重量)之有机硅氧烷之n值为5,
0至1%(重量)之有机硅氧烷之n值为6至20。
依照DIN 53249测量,5分钟之后,该混合物经蒸发之程度优选为20至80%(重量),尤其是30至70%(重量),15分钟之后,其经蒸发之程度优选为60至90%(重量),尤其是70至85%。
依照DIN 53249测量,优选的是,30分钟之后,该混合物经蒸发之程度为85至94%(重量),60分钟之后为94至97%(重量),120分钟之后为97至99.5%(重量)。
线形有机硅氧烷混合物优选通过在盐酸中将由1份三甲基氯硅烷及2.5至6份(优选3.5至4.5份)二甲基二氯硅烷所形成之混合物进行水解而制成。
优选地,在第二步中,具有化学通式1且n值为0至2之过量有机硅氧烷,优选藉蒸馏将其分离出来。实施水解作用时,盐酸之浓度优选藉计量加入水以保持恒定不变。盐酸浓度优选为15至25%(重量)。
该线形有机硅氧烷混合物被用于制备化妆用配制品。该线形有机硅氧烷混合物适用于许多不同之化妆品,例如:护发配制品,如:喷发胶、洗发剂、泡沫发胶、发型胶、发型液、调理剂、染发剂、漂发剂等;止汗剂及除汗臭剂配制品;护肤配制品,如护体液、护手霜、润肤霜、婴儿霜等;防晒配制品,如:防晒膏、防晒乳、护唇膏等及遮盖类化妆品,如:唇膏、睫毛油、化妆底粉、粉底等。
线形有机硅氧烷混合物可协助化妆品有效成分均匀地分布在皮肤及头发上。在装饰性化妆品中,尽管其蒸发速率较快,该线形有机硅氧烷混合物仍可提供足够之处理时间,因此改善其涂抹性,减低胶粘作用并使皮肤更平滑及更柔软。用于护发场合时,挥发性硅氧烷可协助高粘度油类的均匀分布,改善湿梳性及作为烫发/造型产品内之树脂增塑剂。
许多化妆用配制品含有香料。依照DIN 53249,开始时,尤其长达30分钟时,因其蒸发速率快,该线形有机硅氧烷导致所用香料之顶香极为迅速显著。依照DIN 53249,于30分钟之后,因其蒸发速率减低,及依照DIN 53249,于长达60分钟时,蒸发速率更加大幅减低,香料之基香则保留特别长一段时间。
参照下列各实施例,将对本发明作更详细的说明。所有份数及百分数均以重量计。这些实施例均是在环境压力(亦即约0.1MPa)及室温(亦即约21℃)之情况下进行的。
实施例:
实施例1(制备)
于一圆底烧瓶内装入100克浓度20%(重量)之盐酸溶液。
在不停搅拌之情况下,将二甲基二氯硅烷及三甲基氯硅烷摩尔比为4∶1之混合物560克计量加入,历时60分钟。
同时计量加入水,使得盐酸水溶液之浓度保持恒定。
将该混合物继续搅拌60分钟。
相分离后,用水清洗有机相至中性为止。
利用蒸馏作用除去所得粗产品中由水解/缩合作用形成之六甲基二硅氧烷之绝大部分。
如此所得最终产品之组成如下,其中化学通式内:
20%(重量)之有机硅氧烷之n值为0,
43%(重量)之有机硅氧烷之n值为1,
24%(重量)之有机硅氧烷之n值为2,
8%(重量)之有机硅氧烷之n值为3,
3%(重量)之有机硅氧烷之n值为4,
1%(重量)之有机硅氧烷之n值为5,及
1%(重量)之有机硅氧烷之n值为6至10。
实施例2(蒸发速率)
下表所列的蒸发速率是依照DIN 54249测得的。
D5 | 80%(重量)D420%(重量)D5 | D4 | 水,蒸馏作用 | 实施例1 | |
时间(分钟) | |||||
5 | 3.51 | 19.58 | 28.64 | 27.12 | 47.49 |
10 | 8.05 | 36.25 | 53.15 | 48.29 | 70.43 |
15 | 13.34 | 53.13 | 72.11 | 72.43 | 78.49 |
20 | 17.76 | 69.41 | 92.85 | 89.02 | 84.85 |
25 | 23.45 | 79.23 | 99.41 | 97.26 | 87.88 |
30 | 28.49 | 86.02 | 100.00 | 98.25 | 90.67 |
45 | 45.64 | 96.18 | 98.06 | 93.33 | |
60 | 61.98 | 100.00 | 98.59 | 96.05 | |
90 | 89.77 | 98.58 | 97.38 | ||
120 | 99.01 | 97.52 | 98.46 | ||
180 | 99.91 |
与实施例1内混合物之优点相较,环型化合物之性能为:
依照DIN 53249,30分钟之后D4已蒸发,且约60分钟之后,展开之D4/D5混合物(约80/20)亦已蒸发。其蒸发情形同样是用较实施例1混合物更低之蒸发速率测定的。作为比较:120分钟之后D5之蒸发程度已达99%;但30分钟之后仅达约29%及60分钟之后达约62%,因此使用该配制品时难免有潮湿油腻的感觉。
实施例3(包括实施例1混合物之化妆用配制品)
与环型化合物(D4,D5及80/20 D4/D5混合物)相比较,在处理中并无重大明显差异。该配制品之光学外观仍保持不变。
a)止汗棒剂
附有稍软一些的擦除部分之固态棒剂
A 18.00%硬脂酸
18.00%鲸蜡醇
24.00%水合氯化铝
B 40.00%实施例1之混合物
依照需求,香料、染料
将A加以混合并热至75至80℃,将B混入A内。
比较例:以同量之D5代替实施例1之混合物。
附注:在配制品a)之情况下,在较短时间后皮肤上具有较干之感觉。
b)除臭泵喷剂
无色、澄清、低粘度
30.00%乙醇
69.00%实施例1之混合物
1.00%香料
将所有成分彻底加以混合。
比较例:以同量之D5代替实施例1之混合物
附注:配制品b)较比较例内吸收更快速;在较短时间后皮肤上具有舒适干燥的感觉。
c)沐浴油
无色、微浊、低粘度
25.00%实施例1之混合物
70.00%鳄梨油
5.00%PPG-15硬脂基醚
依照需求,防腐剂、染料、香料。
将所有成分彻底加以混合。
比较例:以同量之80/20 D4/D5混合物代替实施例1之混合物。
附注:配制品c)较比较例之相容性佳;更易吸收。
d)防晒油
无色、澄清、低粘度
A 10.00%实施例1之混合物
10.00%肉豆蔻酸异丙基酯
77.00%石蜡油
B 3.00%甲氧基肉桂酸辛基酯
依照需求,防腐剂、香料、染料。
将A加以混合,添加B,并加以混合。
比较例:以同量之80/20 D4/D5混合物代替实施例1之混合物。
附注:配制品d)较比较例吸收快速;皮肤上较早具有舒适干燥的感觉。
e)防晒油
无色、澄清、低粘度
A 40.00%实施例1之混合物
10.00%肉豆蔻酸异丙基酯
47.00%油酸油基酯(oleyl oleate)
B 3.00%甲氧基肉桂酸辛基酯
依照需求,防腐剂、香料、染料。
将A加以混合,添加B,并加以混合。
比较例:以同量之30%D5及10%六甲基二硅氧烷代替实施例1之混合物。
附注:配制品e)较比较例吸收快速;皮肤上较早具有舒适干燥的感觉。
f)化妆底粉
均匀粉末。
A 74.00%滑石
6.00%硬脂酸镁
3.00%丙烯酸酯/丙烯酸C10-30-烷基酯交错聚合物(crosspolymer)
B 12.00%实施例1之混合物
2.00%水解动物蛋白质(INCI)
C 0.20%对羟基苯甲酸甲酯
1.90%滑石
0.70%颜料
依照需求,香料、染料。
将A加以彻底混合,分批将其混入B内,添加C,将其均匀地混合于D内。
比较例:以同量之D5代替实施例1之混合物。
附注:配制品f)较比较例更细密地分布在皮肤上;不会形成结块或剥层。
g)护肤霜
白色固态膏霜,容易分散,皮肤上具有天鹅绒般柔软光滑的感觉。
A 3.85%聚山梨酸酯-60
7.69%鲸蜡醇
19.23%矿脂(INCI)
B 38.46%水
7.69%甘油
C 23.08%实施例1的混合物
依照需求,防腐剂、香料。
将A及B分别加热至70℃。将B混入A内。
h)除臭棒剂
具有轻微擦除部分之乳白色膏
1.00%蓖麻油酸锌、三乙醇胺、二丙二醇、乳酸
8.50%硬脂酸钠
5.50%甘油
4.00%实施例1之混合物
70.40%丙二醇
10.00%乙醇
0.60%羟基乙基纤维素
依照需求,香料、染料。
将所有成分加以混合及熔化。趁热时将均质溶液除去。
比较例:以同量之D5代替实施例1之混合物。
附注:配制品h)之情形中,皮肤较早具有较干燥的感觉。
i)遮盖霜(cover cream)
柔软均质霜。
A 5.50%小烛树蜡
6.70%硬脂氧基聚二甲基硅氧烷
3.00%硬脂酸
B 44.80%水
3.40%丙二醇
1.30%三乙醇胺
C 14.00%二氧化钛
D 18.30%实施例1的混合物
依照需求,防腐剂、香料、染料。
将A及B分别加热至70℃。将B混入A。将C均匀地掺入。稍事冷却,在约30℃温度下将其搅入D内。
比较例:以同量之D5代替实施例1之混合物。
附注:配制品i)较比较例容易分布且防水性较强。
k)除臭棒剂
附有轻微擦除部分之固态、淡黄色棒剂。
50.00%羊毛蜡酸
36.00%硬脂氧基聚二甲基硅氧烷(INCI)
5.00%肉豆蔻酸异丙基酯
4.00%聚二甲基硅氧烷,粘度350mm2/秒
5.00%实施例1之混合物
依照需求、香料、染料。
将所有成分熔化在一起。
比较例:以同量之D5代替实施例1之混合物。
附注:配制品k)较比较例略微不易擦除。
l)沐浴油
淡黄、澄清、低粘度
A 1.00%硬脂氧基聚二甲基硅氧烷(INCI)
69.00%霍霍巴油
B 25.00%实施例1之混合物
5.00%聚丙二醇-15硬脂基醚
依照需求,防腐剂、染料、香料。
将A加热至50℃,将B混入A内。
比较例:以同量之D5代替实施例1之混合物。
附注:配制品l)在沐浴水中具有较佳分布。
m)防晒油
淡黄色、澄清、低粘度。
60.00%实施例1之混合物
10.00%聚甲基硅氧烷醇、聚二甲基硅氧烷、粘度>10mm2/s
10.00%已二酸二异丙基酯
7.00%甲氧基肉桂酸辛基酯
3.00%二苯酮-3
10.00%苯甲酸C12-15烷基酯
依照需求,防腐剂、香料、染料。
将所有成分加以彻底混合并过滤。
比较例:以同量之D5代替实施例1之混合物。
附注:配制品m)较比较例吸收较快,于较短时间后皮肤即具有舒适干燥的感觉。
Claims (7)
1.一种具有化学通式1之线形有机硅氧烷混合物
R3SiO-(SiR2O)n-SiR3 (1)
其中
R可相同或不同且是一种具有1至18个碳原子、选择性地由氟、氯或氰基取代、并且不含烯型或炔型不饱和键之烃基,及
n为0至20,
其中R基之平均碳原子个数至多为3,并且
依照DIN53249测量,该混合物经蒸发之程度是:
30分钟之后80至95%(重量),
60分钟之后90至99%(重量),以及
120分钟之后95至100%(重量)。
2.如权利要求1所述的混合物,其中R是具有1至10个碳原子之线形烷基。
3.如权利要求1或2所述的混合物,其中n之值最大为12。
4.如权利要求1至3之一所述的混合物,其中R基之平均碳原子数优选最多为2。
5.如权利要求1至4所述的混合物,其中,依照DIN53249测量该混合物的蒸发程度:5分钟之后为20至80%(重量),15分钟之后为60至90%(重量)。
6.一种制备如权利要求1至5之一所述的混合物之方法,其中由1份三甲基氯硅烷及2.5至6份二甲基二氯硅烷所形成之混合物于盐酸中被水解。
7.一种化妆用配制品,其中包括如权利要求1至5之一的混合物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19837850.5 | 1998-08-20 | ||
DE19837850A DE19837850C1 (de) | 1998-08-20 | 1998-08-20 | Mischungen flüchtiger linearer Siloxane, Verfahren zu ihrer Herstellung sowie diese enthaltenden kosmetischen Formulierungen |
Publications (2)
Publication Number | Publication Date |
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CN1247868A true CN1247868A (zh) | 2000-03-22 |
CN1090192C CN1090192C (zh) | 2002-09-04 |
Family
ID=7878182
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Application Number | Title | Priority Date | Filing Date |
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CN99111502A Expired - Fee Related CN1090192C (zh) | 1998-08-20 | 1999-08-17 | 挥发性线形硅氧烷混合物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6350440B1 (zh) |
EP (1) | EP0980885B1 (zh) |
JP (1) | JP2000063671A (zh) |
KR (1) | KR20000017013A (zh) |
CN (1) | CN1090192C (zh) |
BR (1) | BR9903802A (zh) |
CA (1) | CA2280465C (zh) |
DE (2) | DE19837850C1 (zh) |
ES (1) | ES2245811T3 (zh) |
TW (1) | TW555565B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7374771B2 (en) | 2001-11-13 | 2008-05-20 | Ge Bayer Silicones Gmbh & Co., Kg | Use of siloxanes as vaporizable carriers |
CN101610814A (zh) * | 2006-12-29 | 2009-12-23 | 汉高两合股份公司 | 低残留止汗棒 |
CN102234596A (zh) * | 2010-05-07 | 2011-11-09 | 上海和黄白猫有限公司 | 复合去油气雾剂 |
CN106749376A (zh) * | 2016-12-28 | 2017-05-31 | 江苏美思德化学股份有限公司 | 不同挥发速率的线性聚硅氧烷组合物及制备方法 |
CN110099670A (zh) * | 2016-12-21 | 2019-08-06 | 莱雅公司 | 含有油性连续相、液体β,β-二苯基丙烯酸酯UV遮蔽剂、液体水杨酸酯UV遮蔽剂和非环状挥发性硅油的组合物 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005004828A1 (en) * | 2003-07-08 | 2005-01-20 | L'oreal | Perfume composition |
FR2861593B1 (fr) * | 2003-11-04 | 2006-02-24 | Oreal | Composition cosmetique photoprotectrice comprenant au moins une phase aqueuse, au moins une phase grasse volatile siliconee et au moins un filtre uv organique |
FR2854798A1 (fr) * | 2003-12-16 | 2004-11-19 | Oreal | Composition cosmetique deorante anhydre comprenant une phase grasse volatile |
WO2005117813A1 (en) | 2004-05-26 | 2005-12-15 | L'oreal | Cosmetic mousse formulations |
US20070160547A1 (en) * | 2006-01-11 | 2007-07-12 | Janet Duffy | Method of applying a composition |
DE102007059678A1 (de) * | 2006-12-29 | 2008-07-03 | Henkel Kgaa | Rückstandsarmer Antitranspirant-Stift |
HUP0900072A2 (hu) | 2009-02-06 | 2010-09-28 | Egis Gyogyszergyar Nyilvanosan | Transzdermális gyógyszerkészítmények |
HUP1000362A2 (en) | 2010-07-12 | 2012-11-28 | Egis Gyogyszergyar Nyrt | Antiseptic and disinfecting compositions having reduced iodine content |
EP3151923A4 (en) * | 2014-06-04 | 2018-01-03 | Arbonne International LLC | Clear compositions and methods for the delivery of active ingredients for skin care |
KR20210034624A (ko) * | 2018-08-16 | 2021-03-30 | 와커 헤미 아게 | 유성 조성물 |
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DE2905257A1 (de) * | 1979-02-12 | 1980-08-21 | Wella Ag | Haarbehandlungsmittel |
US4376087A (en) * | 1981-05-26 | 1983-03-08 | Rca Corporation | Processing of video discs |
DE3319764A1 (de) * | 1982-06-01 | 1983-12-22 | Dr. Riese & Co, 5340 Bad Honnef | Kosmetisches hautpflegemittel |
US5002762A (en) * | 1988-03-16 | 1991-03-26 | The Procter & Gamble Company | Volatile silicons in household and cosmetic products |
US5084577A (en) * | 1988-03-16 | 1992-01-28 | The Procter & Gamble Company | Volatile silicon compounds |
CA1336040C (en) * | 1988-09-13 | 1995-06-27 | Makoto Gocho | Apparatus for charging material to be sintered into a sintering machine |
CA2014633C (en) * | 1989-06-02 | 2000-07-18 | Andrew D. Mccrea | Stable anhydrous compositions for topical delivery of active materials |
US5075479A (en) * | 1991-05-20 | 1991-12-24 | Dow Corning Corporation | Anhydrous hydrogen chloride evolving one-step process for producing siloxanes |
US5705562A (en) * | 1995-11-20 | 1998-01-06 | Dow Corning Corporation | Spontaneously formed clear silicone microemulsions |
US5925338A (en) * | 1997-01-29 | 1999-07-20 | The Gillette Company | Clear antiperspirant or deodorant gel composition with volatile linear silicone to reduce staining |
FR2771003B1 (fr) * | 1997-11-19 | 2000-03-03 | Rhodia Chimie Sa | Melanges de silicones volatils non cycliques et compositions cosmetiques a base desdits melanges |
-
1998
- 1998-08-20 DE DE19837850A patent/DE19837850C1/de not_active Expired - Fee Related
-
1999
- 1999-06-29 EP EP99111997A patent/EP0980885B1/de not_active Expired - Lifetime
- 1999-06-29 DE DE59912454T patent/DE59912454D1/de not_active Expired - Lifetime
- 1999-06-29 ES ES99111997T patent/ES2245811T3/es not_active Expired - Lifetime
- 1999-08-02 KR KR1019990031724A patent/KR20000017013A/ko not_active Application Discontinuation
- 1999-08-13 US US09/374,179 patent/US6350440B1/en not_active Expired - Fee Related
- 1999-08-13 TW TW088113912A patent/TW555565B/zh not_active IP Right Cessation
- 1999-08-17 CN CN99111502A patent/CN1090192C/zh not_active Expired - Fee Related
- 1999-08-17 CA CA002280465A patent/CA2280465C/en not_active Expired - Fee Related
- 1999-08-18 JP JP11231635A patent/JP2000063671A/ja active Pending
- 1999-08-19 BR BR9903802-1A patent/BR9903802A/pt not_active Application Discontinuation
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7374771B2 (en) | 2001-11-13 | 2008-05-20 | Ge Bayer Silicones Gmbh & Co., Kg | Use of siloxanes as vaporizable carriers |
CN100413871C (zh) * | 2001-11-13 | 2008-08-27 | Ge拜尔硅股份有限公司 | 硅氧烷作为可汽化载体的应用 |
CN101610814A (zh) * | 2006-12-29 | 2009-12-23 | 汉高两合股份公司 | 低残留止汗棒 |
CN102234596A (zh) * | 2010-05-07 | 2011-11-09 | 上海和黄白猫有限公司 | 复合去油气雾剂 |
CN110099670A (zh) * | 2016-12-21 | 2019-08-06 | 莱雅公司 | 含有油性连续相、液体β,β-二苯基丙烯酸酯UV遮蔽剂、液体水杨酸酯UV遮蔽剂和非环状挥发性硅油的组合物 |
CN106749376A (zh) * | 2016-12-28 | 2017-05-31 | 江苏美思德化学股份有限公司 | 不同挥发速率的线性聚硅氧烷组合物及制备方法 |
Also Published As
Publication number | Publication date |
---|---|
DE19837850C1 (de) | 2000-01-05 |
DE59912454D1 (de) | 2005-09-29 |
ES2245811T3 (es) | 2006-01-16 |
US6350440B1 (en) | 2002-02-26 |
JP2000063671A (ja) | 2000-02-29 |
KR20000017013A (ko) | 2000-03-25 |
CA2280465C (en) | 2003-11-04 |
EP0980885B1 (de) | 2005-08-24 |
BR9903802A (pt) | 2000-10-31 |
TW555565B (en) | 2003-10-01 |
CA2280465A1 (en) | 2000-02-20 |
CN1090192C (zh) | 2002-09-04 |
EP0980885A1 (de) | 2000-02-23 |
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