CN1241072C - 用于冲洗光致抗蚀剂的稀释剂和处理光致抗蚀剂层的方法 - Google Patents
用于冲洗光致抗蚀剂的稀释剂和处理光致抗蚀剂层的方法 Download PDFInfo
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- CN1241072C CN1241072C CNB008177112A CN00817711A CN1241072C CN 1241072 C CN1241072 C CN 1241072C CN B008177112 A CNB008177112 A CN B008177112A CN 00817711 A CN00817711 A CN 00817711A CN 1241072 C CN1241072 C CN 1241072C
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- photoresist layer
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- photoresist
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- propylene glycol
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Links
- 229920002120 photoresistant polymer Polymers 0.000 title claims abstract description 88
- 238000000034 method Methods 0.000 title claims description 30
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 63
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 40
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 13
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 13
- -1 propylene glycol alkyl ether Chemical class 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims description 48
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- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004065 semiconductor Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000011010 flushing procedure Methods 0.000 claims description 5
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- 238000013461 design Methods 0.000 claims description 2
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- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 238000004528 spin coating Methods 0.000 claims description 2
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- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
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- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 16
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 16
- 231100000111 LD50 Toxicity 0.000 description 12
- 238000001704 evaporation Methods 0.000 description 12
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 10
- 230000008020 evaporation Effects 0.000 description 9
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 9
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- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
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- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
- G03F7/168—Finishing the coated layer, e.g. drying, baking, soaking
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/38—Treatment before imagewise removal, e.g. prebaking
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/42—Stripping or agents therefor
- G03F7/422—Stripping or agents therefor using liquids only
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/42—Stripping or agents therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02043—Cleaning before device manufacture, i.e. Begin-Of-Line process
- H01L21/02052—Wet cleaning only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
- H01L21/0273—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
- H01L21/0274—Photolithographic processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31127—Etching organic layers
- H01L21/31133—Etching organic layers by chemical means
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Detergent Compositions (AREA)
Abstract
Description
溶剂 | TWA[ppm] | STEL[ppm] | 毒物信息 |
MIBK | 50 | 75 | LD50/口服/小鼠:2080mg/kgLD50/表皮/兔:20mg/kg或更多LD50/吸入/小鼠:23300mg/m3LD10/吸入/大鼠:4000ppm |
n-BA | 150 | 200 | LD50/口服/大鼠:14000mg/kgLD50/吸入/大鼠:2000ppm(4小时) |
PGMA | 100 | N.A. | LD50/口服/大鼠:6600mg/kgLD50/表皮/大鼠:13000mg/kgLD50/吸入/大鼠:5000ppm(7小时) |
PGMEA | 100 | N.A. | /口服/大鼠:8532mg/kgLD50/表皮:5000mg/kgLD50/吸入/大鼠:4245ppm(6小时) |
溶剂 | 蒸发速率 | 蒸发压力[mmHg]/温度[℃] | 闪点[℃] | 沸点[℃] | 燃点[℃] | 爆炸极限[%] |
MIBK | 1.57 | 16/20 | 18 | 115 | 449 | 1.4到7.5 |
n-BA | 0.98 | 7.8/20 | 22 | 126 | 425 | 1.7到15 |
PGMA | 0.66 | 6.7/20 | 32 | 120 | N.A. | 2.7到11.8 |
PGMEA | 0.34 | 3.8/20 | 42 | 146 | 354 | 1.5到7 |
实施例1 | 比较例1 | |
除去全部光致抗蚀剂的时间[秒] | 18 | 18 |
实施例2 | 比较例2 | |
32分钟后残余重量(重量%) | 6 | 0 |
实施例6 | 对比例6 | |||
观测点 | 堆积值[微米] | 渗透[微米] | 堆积值[微米] | 渗透[微米] |
1 | 3.33 | 4.02 | 3.49 | 4.20 |
2 | 1.30 | 2.48 | 1.65 | 2.54 |
3 | 2.48 | 2.68 | 1.80 | 2.98 |
4 | 1.52 | 1.98 | 2.58 | 2.20 |
平均 | 2.16 | 2.79 | 2.36 | 2.98 |
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1999/62169 | 1999-12-24 | ||
KR1019990062169A KR100594815B1 (ko) | 1999-12-24 | 1999-12-24 | 포토레지스트 린스용 씬너 및 이를 이용한 포토레지스트막의 처리 방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1413317A CN1413317A (zh) | 2003-04-23 |
CN1241072C true CN1241072C (zh) | 2006-02-08 |
Family
ID=19629723
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008177112A Expired - Lifetime CN1241072C (zh) | 1999-12-24 | 2000-12-08 | 用于冲洗光致抗蚀剂的稀释剂和处理光致抗蚀剂层的方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6645682B2 (zh) |
EP (1) | EP1240555A1 (zh) |
JP (1) | JP4326741B2 (zh) |
KR (1) | KR100594815B1 (zh) |
CN (1) | CN1241072C (zh) |
AU (1) | AU2027101A (zh) |
MY (1) | MY129830A (zh) |
TW (1) | TW500986B (zh) |
WO (1) | WO2001048555A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100459057C (zh) * | 2006-05-22 | 2009-02-04 | 中芯国际集成电路制造(上海)有限公司 | 晶圆表面的清洗方法 |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6682876B2 (en) * | 2001-12-14 | 2004-01-27 | Samsung Electronics Co., Ltd. | Thinner composition and method of stripping a photoresist using the same |
KR100503967B1 (ko) * | 2002-03-29 | 2005-07-26 | 주식회사 동진쎄미켐 | 감광성 수지 제거용 씬너 조성물 |
KR20050032719A (ko) * | 2003-10-02 | 2005-04-08 | 주식회사 동진쎄미켐 | 포토레지스트 제거용 씬너 조성물 |
KR20060017170A (ko) * | 2004-08-20 | 2006-02-23 | 동부아남반도체 주식회사 | 감광막 패턴 형성 방법 |
TW200634448A (en) * | 2005-02-09 | 2006-10-01 | Showa Denko Kk | Photosensitive composition removing liquid |
JP2006278693A (ja) * | 2005-03-29 | 2006-10-12 | Asahi Glass Co Ltd | 水パージ剤およびそれを用いたレジストパターン形成方法 |
US7709402B2 (en) * | 2006-02-16 | 2010-05-04 | Micron Technology, Inc. | Conductive layers for hafnium silicon oxynitride films |
US8852673B2 (en) * | 2011-11-01 | 2014-10-07 | Taiwan Semiconductor Manufacturing Company, Ltd. | Defect monitoring for resist layer |
KR20140101156A (ko) * | 2013-02-08 | 2014-08-19 | 주식회사 동진쎄미켐 | 신너 조성물 및 이의 용도 |
CN104779178B (zh) * | 2014-01-13 | 2018-10-16 | 中芯国际集成电路制造(上海)有限公司 | 底部防反射层形成方法 |
US10684549B2 (en) | 2016-12-31 | 2020-06-16 | Rohm And Haas Electronic Materials Llc | Pattern-formation methods |
SG11202010737UA (en) * | 2018-05-25 | 2020-12-30 | Basf Se | Use of compositions comprising a solvent mixture for avoiding pattern collapse when treating patterned materials with line-space dimensions of 50 nm or below |
CN113504714A (zh) * | 2021-06-28 | 2021-10-15 | 华虹半导体(无锡)有限公司 | 晶片去胶方法 |
KR20240047431A (ko) * | 2021-09-30 | 2024-04-12 | 후지필름 가부시키가이샤 | 감광성 조성물의 검정 방법 및 감광성 조성물의 제조 방법 |
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US4885232A (en) * | 1985-03-11 | 1989-12-05 | Hoechst Celanese Corporation | High temperature post exposure baking treatment for positive photoresist compositions |
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US4983490A (en) * | 1985-10-28 | 1991-01-08 | Hoechst Celanese Corporation | Photoresist treating composition consisting of a mixture of propylene glycol alkyl ether and propylene glycol alkyl ether acetate |
US5023164A (en) * | 1989-10-23 | 1991-06-11 | International Business Machines Corporation | Highly sensitive dry developable deep UV photoresist |
US5370817A (en) * | 1990-11-15 | 1994-12-06 | Lockheed Corporation | Low odor cleaning formulation comprising propylene glycol methyl ether and propylene glycol methyl ether acetate |
DE4126836A1 (de) * | 1991-08-14 | 1993-02-18 | Hoechst Ag | Strahlungsempfindliches aufzeichnungsmaterial aus schichttraeger und positiv arbeitender, strahlungsempfindlicher schicht mit rauher oberflaeche |
JPH05273757A (ja) * | 1991-08-20 | 1993-10-22 | Hoechst Celanese Corp | 高いガラス転位点と高い光感度を有するフォトレジスト用ノボラック樹脂組成物 |
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JPH0798502A (ja) * | 1993-09-29 | 1995-04-11 | Tosoh Corp | ポジ型熱硬化感光材料 |
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US5561194A (en) * | 1995-03-29 | 1996-10-01 | International Business Machines Corporation | Photoresist composition including polyalkylmethacrylate co-polymer of polyhydroxystyrene |
US5693749A (en) * | 1995-09-20 | 1997-12-02 | Hoechst Celanese Corporation | Fractionation of phenol formaldehyde condensate and photoresist compositions produced therefrom |
US5853947A (en) * | 1995-12-21 | 1998-12-29 | Clariant Finance (Bvi) Limited | Quinonediazide positive photoresist utilizing mixed solvent consisting essentially of 3-methyl-3-methoxy butanol and propylene glycol alkyl ether acetate |
JP3756991B2 (ja) * | 1996-07-01 | 2006-03-22 | 昭和電工株式会社 | 未硬化エポキシ樹脂の剥離剤組成物 |
US5763135A (en) * | 1996-09-30 | 1998-06-09 | Clariant Finance (Bvi) Limited | Light sensitive composition containing an arylhydrazo dye |
JPH10186680A (ja) * | 1996-12-26 | 1998-07-14 | Clariant Internatl Ltd | リンス液 |
JP3978255B2 (ja) * | 1997-06-24 | 2007-09-19 | Azエレクトロニックマテリアルズ株式会社 | リソグラフィー用洗浄剤 |
-
1999
- 1999-12-24 KR KR1019990062169A patent/KR100594815B1/ko active IP Right Grant
-
2000
- 2000-12-08 AU AU20271/01A patent/AU2027101A/en not_active Abandoned
- 2000-12-08 JP JP2001549146A patent/JP4326741B2/ja not_active Expired - Fee Related
- 2000-12-08 CN CNB008177112A patent/CN1241072C/zh not_active Expired - Lifetime
- 2000-12-08 EP EP00983526A patent/EP1240555A1/en not_active Withdrawn
- 2000-12-08 WO PCT/KR2000/001429 patent/WO2001048555A1/en active Application Filing
- 2000-12-08 US US10/169,033 patent/US6645682B2/en not_active Expired - Fee Related
- 2000-12-18 TW TW089127297A patent/TW500986B/zh not_active IP Right Cessation
- 2000-12-19 MY MYPI20005950A patent/MY129830A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100459057C (zh) * | 2006-05-22 | 2009-02-04 | 中芯国际集成电路制造(上海)有限公司 | 晶圆表面的清洗方法 |
Also Published As
Publication number | Publication date |
---|---|
JP4326741B2 (ja) | 2009-09-09 |
US20030091942A1 (en) | 2003-05-15 |
WO2001048555A1 (en) | 2001-07-05 |
JP2003518657A (ja) | 2003-06-10 |
CN1413317A (zh) | 2003-04-23 |
MY129830A (en) | 2007-05-31 |
US6645682B2 (en) | 2003-11-11 |
EP1240555A1 (en) | 2002-09-18 |
KR20010064052A (ko) | 2001-07-09 |
AU2027101A (en) | 2001-07-09 |
KR100594815B1 (ko) | 2006-07-03 |
TW500986B (en) | 2002-09-01 |
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