CN119947999A - 乙醇的转换方法、烃的制造方法、丙烯的制造方法、芳香族化合物的制造方法及乙醇的转换装置 - Google Patents

乙醇的转换方法、烃的制造方法、丙烯的制造方法、芳香族化合物的制造方法及乙醇的转换装置 Download PDF

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CN119947999A
CN119947999A CN202380068889.4A CN202380068889A CN119947999A CN 119947999 A CN119947999 A CN 119947999A CN 202380068889 A CN202380068889 A CN 202380068889A CN 119947999 A CN119947999 A CN 119947999A
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ethanol
dehydration
reactor
raw material
catalyst
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浦山铁平
宫崎隆介
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Asahi Kasei Corp
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Asahi Kasei Corp
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/001Processes specially adapted for distillation or rectification of fermented solutions
    • B01D3/002Processes specially adapted for distillation or rectification of fermented solutions by continuous methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28Phosphorising
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/04Purification; Separation; Use of additives by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44Noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN202380068889.4A 2022-09-30 2023-07-27 乙醇的转换方法、烃的制造方法、丙烯的制造方法、芳香族化合物的制造方法及乙醇的转换装置 Pending CN119947999A (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP2022157839 2022-09-30
JP2022-157839 2022-09-30
JP2022-157843 2022-09-30
JP2022-158148 2022-09-30
JP2022157843 2022-09-30
JP2022158148 2022-09-30
PCT/JP2023/027601 WO2024070182A1 (ja) 2022-09-30 2023-07-27 エタノールの変換方法、炭化水素の製造方法、プロピレンの製造方法、芳香族化合物の製造方法、及び、エタノールの変換装置

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CN119947999A true CN119947999A (zh) 2025-05-06

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EP (1) EP4596525A1 (https=)
JP (1) JPWO2024070182A1 (https=)
KR (1) KR20250057863A (https=)
CN (1) CN119947999A (https=)
TW (1) TWI860006B (https=)
WO (1) WO2024070182A1 (https=)

Family Cites Families (18)

* Cited by examiner, † Cited by third party
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BR7705256A (pt) * 1977-08-09 1979-04-03 Petroleo Brasileiro Sa Processo e preparacao de eteno
JP5135839B2 (ja) * 2006-03-30 2013-02-06 三菱化学株式会社 プロピレンの製造方法
JP4904076B2 (ja) * 2006-04-24 2012-03-28 出光興産株式会社 含酸素化合物からのオレフィン類の製造方法
CN103274884A (zh) * 2008-02-07 2013-09-04 道达尔石油化学产品研究弗吕公司 由乙醇制造烯烃的方法
JP5426983B2 (ja) 2009-09-30 2014-02-26 旭化成ケミカルズ株式会社 Zsm−5型ゼオライトの製造方法
DE102011014892A1 (de) 2011-03-23 2012-09-27 Lurgi Gmbh Verfahren und Anlage zur Herstellung von niedermolekularen Olefinen
CN102875309B (zh) * 2011-07-12 2014-09-10 中国石油化工股份有限公司 乙醇制备丙烯的方法
CN103796975A (zh) * 2011-09-07 2014-05-14 国际壳牌研究有限公司 制备乙烯和丙烯的方法
JP6229274B2 (ja) * 2012-02-28 2017-11-15 東ソー株式会社 Mfi型ゼオライト、及び、mfi型ゼオライトを含む触媒、並びに、前記触媒を使用する低級オレフィン製造方法
JP2014025021A (ja) 2012-07-30 2014-02-06 Toyo Ink Sc Holdings Co Ltd 光硬化性着色接着剤
KR20140018593A (ko) 2012-08-02 2014-02-13 에스케이이노베이션 주식회사 중앙 서버 및 이를 이용한 사용자 요금제에 따른 전기 이동체 충전 제어 시스템
KR101653900B1 (ko) 2012-08-10 2016-09-02 아사히 가세이 케미칼즈 가부시키가이샤 올레핀 또는 알콜의 전화방법 및 프로필렌 또는 방향족 화합물의 제조 방법
JP6398448B2 (ja) 2013-08-30 2018-10-03 東ソー株式会社 ペンタシル型ゼオライト及びその製造方法
JP2015029355A (ja) 2014-10-17 2015-02-12 株式会社東芝 機器制御装置、その方法、及び、そのプログラム
CN110560155A (zh) 2019-09-17 2019-12-13 大连理工大学 一种由生物乙醇一步法直接生产丙烯的复合型催化剂的制备方法及应用
BR112022004989A2 (pt) * 2019-09-30 2022-06-21 Gevo Inc Simultâneas desidratação, dimerização, e metátese de álcoois c2-c5
CN110871107A (zh) 2019-11-06 2020-03-10 厦门大学 一种用于低碳醇和石脑油耦合催化裂解制低碳烯烃的催化剂及其制备方法与应用
EP4474371A4 (en) * 2022-01-31 2026-02-18 Asahi Chemical Ind ETHANOL CONVERSION PROCESS AND PROCESS FOR PRODUCING ANOTHER HYDROCARBON

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JPWO2024070182A1 (https=) 2024-04-04
KR20250057863A (ko) 2025-04-29
WO2024070182A1 (ja) 2024-04-04
TWI860006B (zh) 2024-10-21
EP4596525A1 (en) 2025-08-06
TW202415639A (zh) 2024-04-16

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