TWI860006B - 乙醇之轉換方法、烴之製造方法、丙烯之製造方法、芳香族化合物之製造方法、及乙醇之轉換裝置 - Google Patents

乙醇之轉換方法、烴之製造方法、丙烯之製造方法、芳香族化合物之製造方法、及乙醇之轉換裝置 Download PDF

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TWI860006B
TWI860006B TW112128324A TW112128324A TWI860006B TW I860006 B TWI860006 B TW I860006B TW 112128324 A TW112128324 A TW 112128324A TW 112128324 A TW112128324 A TW 112128324A TW I860006 B TWI860006 B TW I860006B
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ethanol
dehydration
reactor
raw material
catalyst
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TW112128324A
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Chinese (zh)
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TW202415639A (zh
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浦山鉄平
宮崎隆介
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日商旭化成股份有限公司
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/001—Processes specially adapted for distillation or rectification of fermented solutions
    • B01D3/002—Processes specially adapted for distillation or rectification of fermented solutions by continuous methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
TW112128324A 2022-09-30 2023-07-28 乙醇之轉換方法、烴之製造方法、丙烯之製造方法、芳香族化合物之製造方法、及乙醇之轉換裝置 TWI860006B (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2022157839 2022-09-30
JP2022-157839 2022-09-30
JP2022-157843 2022-09-30
JP2022-158148 2022-09-30
JP2022157843 2022-09-30
JP2022158148 2022-09-30

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TW202415639A TW202415639A (zh) 2024-04-16
TWI860006B true TWI860006B (zh) 2024-10-21

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EP (1) EP4596525A1 (https=)
JP (1) JPWO2024070182A1 (https=)
KR (1) KR20250057863A (https=)
CN (1) CN119947999A (https=)
TW (1) TWI860006B (https=)
WO (1) WO2024070182A1 (https=)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4232179A (en) * 1977-08-09 1980-11-04 Petroleo Brasileiro S.A.-Petrobras Process for preparing ethene
CN102875309A (zh) * 2011-07-12 2013-01-16 中国石油化工股份有限公司 乙醇制备丙烯的方法

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JP5135839B2 (ja) * 2006-03-30 2013-02-06 三菱化学株式会社 プロピレンの製造方法
JP4904076B2 (ja) * 2006-04-24 2012-03-28 出光興産株式会社 含酸素化合物からのオレフィン類の製造方法
CN103274884A (zh) * 2008-02-07 2013-09-04 道达尔石油化学产品研究弗吕公司 由乙醇制造烯烃的方法
JP5426983B2 (ja) 2009-09-30 2014-02-26 旭化成ケミカルズ株式会社 Ｚｓｍ−５型ゼオライトの製造方法
DE102011014892A1 (de) 2011-03-23 2012-09-27 Lurgi Gmbh Verfahren und Anlage zur Herstellung von niedermolekularen Olefinen
CN103796975A (zh) * 2011-09-07 2014-05-14 国际壳牌研究有限公司 制备乙烯和丙烯的方法
JP6229274B2 (ja) * 2012-02-28 2017-11-15 東ソー株式会社 Ｍｆｉ型ゼオライト、及び、ｍｆｉ型ゼオライトを含む触媒、並びに、前記触媒を使用する低級オレフィン製造方法
JP2014025021A (ja) 2012-07-30 2014-02-06 Toyo Ink Sc Holdings Co Ltd 光硬化性着色接着剤
KR20140018593A (ko) 2012-08-02 2014-02-13 에스케이이노베이션 주식회사 중앙 서버 및 이를 이용한 사용자 요금제에 따른 전기 이동체 충전 제어 시스템
KR101653900B1 (ko) 2012-08-10 2016-09-02 아사히 가세이 케미칼즈 가부시키가이샤 올레핀 또는 알콜의 전화방법 및 프로필렌 또는 방향족 화합물의 제조 방법
JP6398448B2 (ja) 2013-08-30 2018-10-03 東ソー株式会社 ペンタシル型ゼオライト及びその製造方法
JP2015029355A (ja) 2014-10-17 2015-02-12 株式会社東芝 機器制御装置、その方法、及び、そのプログラム
CN110560155A (zh) 2019-09-17 2019-12-13 大连理工大学 一种由生物乙醇一步法直接生产丙烯的复合型催化剂的制备方法及应用
BR112022004989A2 (pt) * 2019-09-30 2022-06-21 Gevo Inc Simultâneas desidratação, dimerização, e metátese de álcoois c2-c5
CN110871107A (zh) 2019-11-06 2020-03-10 厦门大学 一种用于低碳醇和石脑油耦合催化裂解制低碳烯烃的催化剂及其制备方法与应用
EP4474371A4 (en) * 2022-01-31 2026-02-18 Asahi Chemical Ind ETHANOL CONVERSION PROCESS AND PROCESS FOR PRODUCING ANOTHER HYDROCARBON

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4232179A (en) * 1977-08-09 1980-11-04 Petroleo Brasileiro S.A.-Petrobras Process for preparing ethene
US4232179B1 (https=) * 1977-08-09 1987-12-08
CN102875309A (zh) * 2011-07-12 2013-01-16 中国石油化工股份有限公司 乙醇制备丙烯的方法

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CN119947999A (zh) 2025-05-06
JPWO2024070182A1 (https=) 2024-04-04
KR20250057863A (ko) 2025-04-29
WO2024070182A1 (ja) 2024-04-04
EP4596525A1 (en) 2025-08-06
TW202415639A (zh) 2024-04-16

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