CN1198750A - 通过在稳定的自由基存在下进行1,3－二烯的控制的自由基聚合制备1,3－二烯的遥爪低聚物的方法 - Google Patents

通过在稳定的自由基存在下进行1,3－二烯的控制的自由基聚合制备1,3－二烯的遥爪低聚物的方法 Download PDF

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Publication number
CN1198750A
CN1198750A CN97191040A CN97191040A CN1198750A CN 1198750 A CN1198750 A CN 1198750A CN 97191040 A CN97191040 A CN 97191040A CN 97191040 A CN97191040 A CN 97191040A CN 1198750 A CN1198750 A CN 1198750A
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CN
China
Prior art keywords
diene
group
nitroxide
telechelic
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN97191040A
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English (en)
Chinese (zh)
Inventor
B·鲍特文
M·克尔夫
J·L·普拉德尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Elf Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elf Atochem SA filed Critical Elf Atochem SA
Publication of CN1198750A publication Critical patent/CN1198750A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN97191040A 1996-06-04 1997-06-03 通过在稳定的自由基存在下进行1,3－二烯的控制的自由基聚合制备1,3－二烯的遥爪低聚物的方法 Pending CN1198750A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR96/06875 1996-06-04
FR9606875 1996-06-04

Publications (1)

Publication Number Publication Date
CN1198750A true CN1198750A (zh) 1998-11-11

Family

ID=9492700

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97191040A Pending CN1198750A (zh) 1996-06-04 1997-06-03 通过在稳定的自由基存在下进行1,3－二烯的控制的自由基聚合制备1,3－二烯的遥爪低聚物的方法

Country Status (8)

Country Link
EP (1) EP0842198A1 (ko)
JP (1) JPH11511202A (ko)
KR (1) KR19990036179A (ko)
CN (1) CN1198750A (ko)
AU (1) AU3098297A (ko)
BR (1) BR9702291A (ko)
CA (1) CA2229978A1 (ko)
WO (1) WO1997046593A1 (ko)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126767C (zh) * 1999-10-21 2003-11-05 复旦大学 一种含tempo嵌段聚醚－聚苯乙烯聚合物及其制备方法
CN101386652B (zh) * 2002-08-19 2011-12-07 阿克苏诺贝尔公司 含有活性自由基的分散体
CN102351972A (zh) * 2011-07-28 2012-02-15 中山大学 一种含烷氧胺基团的热可逆自修复交联聚合物
CN106661161A (zh) * 2014-08-20 2017-05-10 维尔萨利斯股份公司 用于制备二烯聚合物或无规乙烯基芳烃‑二烯共聚物的工艺
CN110396147A (zh) * 2014-12-18 2019-11-01 阿科玛法国公司 烷氧基胺的低温自由基聚合

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970064016U (ko) 1996-05-31 1997-12-11 브이시알의 전면 패널
FR2768739B1 (fr) 1997-09-19 2004-08-06 Atochem Elf Sa Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable
FR2768738A1 (fr) * 1997-09-19 1999-03-26 Atochem Elf Sa Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable
NL1008700C2 (nl) * 1998-03-25 1999-09-28 Univ Eindhoven Tech Werkwijze ter bereiding van cyclische secundaire amineverbindingen, cyclische secundaire amineverbindingen en toepassingen hiervan.
FR2779437B1 (fr) * 1998-06-03 2004-10-15 Atochem Elf Sa Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation
WO2000011055A1 (fr) * 1998-08-21 2000-03-02 Elf Atochem S.A. Procede de fabrication de copolymers a architecture controlee et copolymeres obtenus
FR2788272B1 (fr) * 1999-01-08 2001-03-16 Atochem Elf Sa Procede de preparation de nitroxydes
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
DE50015539D1 (de) 1999-09-07 2009-03-19 Bayer Materialscience Ag Oligomere und polymere Telechelen
EP2552971B1 (en) 2010-03-30 2014-07-02 Basf Se End-functionalized polymers

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1218456A (en) * 1968-09-06 1971-01-06 Bp Chem Int Ltd Process for the stabilisation of butadiene
US5322912A (en) * 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126767C (zh) * 1999-10-21 2003-11-05 复旦大学 一种含tempo嵌段聚醚－聚苯乙烯聚合物及其制备方法
CN101386652B (zh) * 2002-08-19 2011-12-07 阿克苏诺贝尔公司 含有活性自由基的分散体
CN102351972A (zh) * 2011-07-28 2012-02-15 中山大学 一种含烷氧胺基团的热可逆自修复交联聚合物
CN102351972B (zh) * 2011-07-28 2014-04-23 中山大学 一种含烷氧胺基团的热可逆自修复交联聚合物
CN106661161A (zh) * 2014-08-20 2017-05-10 维尔萨利斯股份公司 用于制备二烯聚合物或无规乙烯基芳烃‑二烯共聚物的工艺
CN106661161B (zh) * 2014-08-20 2020-03-24 维尔萨利斯股份公司 用于制备二烯聚合物或无规乙烯基芳烃-二烯共聚物的工艺
CN110396147A (zh) * 2014-12-18 2019-11-01 阿科玛法国公司 烷氧基胺的低温自由基聚合

Also Published As

Publication number Publication date
EP0842198A1 (fr) 1998-05-20
JPH11511202A (ja) 1999-09-28
AU3098297A (en) 1998-01-05
KR19990036179A (ko) 1999-05-25
WO1997046593A1 (fr) 1997-12-11
BR9702291A (pt) 1999-07-20
CA2229978A1 (fr) 1997-12-11

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