CN117426391A - Sterilization composition containing thifluzamide - Google Patents
Sterilization composition containing thifluzamide Download PDFInfo
- Publication number
- CN117426391A CN117426391A CN202311490471.0A CN202311490471A CN117426391A CN 117426391 A CN117426391 A CN 117426391A CN 202311490471 A CN202311490471 A CN 202311490471A CN 117426391 A CN117426391 A CN 117426391A
- Authority
- CN
- China
- Prior art keywords
- thifluzamide
- pyraclostrobin
- corn
- bactericidal composition
- southern rust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 230000001954 sterilising effect Effects 0.000 title description 2
- 238000004659 sterilization and disinfection Methods 0.000 title description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 30
- 239000005869 Pyraclostrobin Substances 0.000 claims abstract description 29
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims abstract description 29
- 240000008042 Zea mays Species 0.000 claims abstract description 22
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 22
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 21
- 235000005822 corn Nutrition 0.000 claims abstract description 21
- 239000004480 active ingredient Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000003814 drug Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 6
- 201000010099 disease Diseases 0.000 claims description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 5
- 241001057636 Dracaena deremensis Species 0.000 claims description 3
- 230000000855 fungicidal effect Effects 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000013268 sustained release Methods 0.000 claims description 2
- 239000012730 sustained-release form Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 2
- 239000008194 pharmaceutical composition Substances 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 239000000575 pesticide Substances 0.000 abstract description 3
- 206010059866 Drug resistance Diseases 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 11
- 230000004763 spore germination Effects 0.000 description 9
- 230000035784 germination Effects 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 6
- 231100000419 toxicity Toxicity 0.000 description 6
- 230000001988 toxicity Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000003899 bactericide agent Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 235000017060 Arachis glabrata Nutrition 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000018262 Arachis monticola Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 241001361634 Rhizoctonia Species 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241001530056 Athelia rolfsii Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000221300 Puccinia Species 0.000 description 1
- 241001304534 Puccinia polysora Species 0.000 description 1
- 229940122840 Succinic dehydrogenase inhibitor Drugs 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002888 effect on disease Effects 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 230000006540 mitochondrial respiration Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- -1 thiazole amide Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericidal composition containing thifluzamide, and belongs to the technical field of pesticides. The active ingredients of the bactericidal composition comprise thifluzamide and pyraclostrobin, and the weight ratio of the thifluzamide to the pyraclostrobin is 20:1-1:1. The thifluzamide and the pyraclostrobin are mixed for use, so that the thifluzamide and the pyraclostrobin have remarkable synergistic effect, effectively reduce the use dosage, delay the occurrence of drug resistance and can be used for preventing and treating southern rust of corn.
Description
Technical Field
The invention relates to the technical field of pesticides, in particular to a bactericidal composition containing thifluzamide.
Background
Thifluzamide belongs to thiazole amide bactericides, has an action mechanism of succinic dehydrogenase inhibitor, and has strong systemic conductivity and long lasting effect. Thifluzamide has activity on pathogenic fungi such as rhizoctonia, puccinia, blackia, rhizoctonia, fusarium and the like, and has special effects on diseases caused by basidiomycete fungi such as banded sclerotial blight and the like. Is widely applied to various crops such as rice, wheat, potato, peanut, cotton, beet and the like, lawns and the like.
Pyraclostrobin is a bactericide of methoxy acrylic esters. The action mechanism is mitochondrial respiration inhibitor, and has the characteristics of permeability, local systemic activity, long lasting period, rain wash resistance and the like. Has strong inhibiting effect on spore germination and mycelium growth in leaves, and has protective and therapeutic activities. The compound has low toxicity, is relatively safe to non-target organisms, is environment-friendly, is listed as a candidate agent for reducing risks by EPA in the United states, and is widely used for preventing and treating various diseases on crops such as wheat, rice, peanut, grape, potato, vegetables, various fruit trees and the like.
The southern rust is a typical air-borne disease and has the characteristics of high spreading and epidemic speed, strong outbreak and damage loss of weight. Can occur in all overground tissues of corn plants, mainly in corn leaves, and can also be in the serious cases in the form of ears, bracts or even male flowers. Once the prevention and control are insufficient, more than 10% of yield loss can be caused, when the disease is heavy, the leaves are fully distributed in spore stacks, then the leaves are dried up in advance, more than 50% of yield reduction can be caused for corn yield, and part of land parcels are even dead. There is no report in the prior art on the combined use of thifluzamide and pyraclostrobin for preventing and treating southern rust in corn.
Disclosure of Invention
The present invention has been made in view of the above-mentioned prior art, and an object of the present invention is to provide a bactericidal composition containing thifluzamide. The thifluzamide and the pyraclostrobin are mixed for use, so that the thifluzamide and the pyraclostrobin have remarkable synergistic effect, effectively reduce the use dosage, delay the occurrence of drug resistance and can be used for preventing and treating southern rust of corn.
In order to achieve the above purpose, the invention adopts the following technical scheme:
according to the first aspect of the invention, a bactericidal composition containing thifluzamide is provided, and the active ingredients of the bactericidal composition comprise thifluzamide and pyraclostrobin, wherein the weight ratio of the thifluzamide to the pyraclostrobin is 20:1-1:1.
Preferably, the weight ratio of thifluzamide to pyraclostrobin is 5:1.
In a second aspect of the present invention, there is provided the use of the above-described fungicidal composition in (1) or (2) as follows:
(1) Preventing and treating southern rust of corn;
(2) And preparing a product for preventing and treating southern rust of corn.
In a third aspect of the present invention, there is provided a medicament for controlling southern rust in corn, the medicament comprising an effective amount of the bactericidal composition described above.
Preferably, in the medicament, the weight percentage of the bactericidal composition is 10-60%.
Preferably, the dosage form of the medicament can be granules, powder, suspending agents, water agents, aqueous emulsion, sustained release agents, tablets and the like.
In a fourth aspect, the invention provides application of the medicament in preventing and treating southern rust of corn.
In a fifth aspect of the present invention, there is provided a method for controlling southern rust in corn, comprising the steps of:
before or during the onset of southern rust disease of corn, the medicament is sprayed on the aerial parts of corn plants.
The invention has the beneficial effects that:
the invention discovers that thifluzamide and pyraclostrobin are mixed, the synergistic effect of the thifluzamide and pyraclostrobin is obvious within the range of 20:1-1:1, wherein 5:1 is the optimal ratio. Can reduce the dosage of the medicament, improve the control effect, reduce the use cost, delay the medicament resistance and improve the safety to crops and environment.
The specific embodiment is as follows:
it should be noted that the following detailed description is illustrative and is intended to provide further explanation of the present application. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.
In order to enable those skilled in the art to more clearly understand the technical solutions of the present application, the technical solutions of the present application will be described in detail below with reference to specific embodiments. If experimental details are not specified in the examples, the conditions are generally conventional or recommended by the reagent company; reagents, consumables, etc. used in the following examples and comparative examples are commercially available unless otherwise specified.
Example 1: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to the weight ratio of 1:1 to be used as the bactericidal composition containing the thifluzamide.
Example 2: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to a weight ratio of 5:1 to obtain the bactericidal composition containing the thifluzamide.
Example 3: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to the weight ratio of 10:1 to be used as the bactericidal composition containing the thifluzamide.
Example 4: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to the weight ratio of 15:1 to be used as the bactericidal composition containing the thifluzamide.
Example 5: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to the weight ratio of 20:1 to be used as the bactericidal composition containing the thifluzamide.
Example 6: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to the weight ratio of 30:1 to be used as the bactericidal composition containing the thifluzamide.
Example 4: preparation of bactericidal composition containing thifluzamide
The thifluzamide and the pyraclostrobin are mixed according to the weight ratio of 1:5 to obtain the bactericidal composition containing the thifluzamide.
Application example: indoor toxicity determination test of thifluzamide and pyraclostrobin on southern corn rust
1. Testing for pathogenic bacteria: southern rust (Puccinia polysora Underw) of maize. And (5) field collection, and separating and identifying the obtained product to be used for indoor toxicity measurement.
2. The test method comprises the following steps:
reference is made to the combined action assay of spore germination concave slide method (NY/T1156.1-2006) and bactericide compounding (NY/T1156.6-2006) of the pesticide indoor biological assay criterion bactericide. Sequentially sucking 1mL from low concentration to high concentration by a pipette or a pipette, respectively adding into small test tubes, and then sucking 1mL of prepared spore suspension, so that the liquid medicine and the spore suspension are equal in quantity and uniformly mixed.
The mixed liquid is sucked by a microsampler and is put on a concave slide, then the concave slide is put in a culture dish with shallow water, and the concave slide is covered and cultured in an incubator with proper temperature. No less than 4 replicates per treatment and no drug containing treatment was used as a blank. And (3) culturing for 5h in an illumination biochemical incubator at 28 ℃ with the relative humidity of 90%.
When the germination rate of the blank control spores reaches more than 90%, the germination condition of each treated spore is checked. Since the germination rate of spores of southern rust of corn is relatively low, the germination of spores of each treatment is checked when the germination rate of spores of the blank control reaches more than 85% in the test process.
Three or more fields were randomly observed for each treatment, the total number of spores was not less than 200, and the germination number and total number of spores were recorded, respectively. The short radius of the spore bud tube length greater than the spores is considered germination.
The blank control spore germination inhibition rate is less than 5% without correction; the blank control spore germination inhibition rate is 5% -20%, and the correction inhibition rate of each treatment is calculated by using an Abott formula; the blank control spore germination inhibition rate is more than 20%, and then the test is required to be reworked.
According to investigation data, calculating the relative inhibition rate of spore germination of each treatment, wherein the unit is percentage (%), the control effect of each treatment concentration is calculated according to a formula, then adopting DPS data processing software to calculate test results, respectively solving virulence regression equations, EC50 and EC90 and 95% confidence limits of single-dose and mixed agents with different proportions of the test agents, solving co-toxicity coefficients (CTC) of the two agents with different proportions, and screening out the optimal proportion of the test agents. And records each process all the repeated raw data.
Correction inhibition (%) = (control spore germination rate-treated spore germination rate)/control spore germination rate x 100
And calculating the co-toxicity coefficient (CTC) of the compound medicament mixture according to the grand cloud Pei method. The co-toxicity coefficient (CTC) is calculated as follows:
measured virulence index (ATI) = (EC 50 of standard agent/EC 50 of test agent) ×100
Theoretical Toxicity Index (TTI) =toxicity index of agent a x percent of agent a in the mix + toxicity index of agent B x percent of agent B in the mix
Co-toxicity coefficient (CTC) = (ATI/TTI) ×100
According to the division standard of co-toxicity coefficient (CTC), CTC is less than or equal to 80 and is antagonism, CTC 80 is additive, CTC is greater than or equal to 120 and is synergistic.
3. Test results:
the test results are shown in Table 1.
Table 1: indoor combined toxicity measurement result of thifluzamide and pyraclostrobin on southern corn rust pathogen
As can be seen from the results in Table 1, the thifluzamide and the pyraclostrobin are mixed, the co-toxicity coefficient (CTC) of the thifluzamide and the pyraclostrobin is greater than 120 in the range of 20:1-1:1, the synergistic effect is obvious, and the thifluzamide and the pyraclostrobin show very high activity on southern rust bacteria, wherein the ratio of 5:1 is the optimal ratio.
In conclusion, the bactericidal composition thifluzamide and pyraclostrobin are compounded, the synergistic effect is obvious, the dosage of the medicament can be reduced, the effect of preventing and treating southern rust of corn is improved, the use cost is reduced, the medicament resistance is delayed, and the safety to crops and the environment is improved.
The foregoing description is only of the preferred embodiments of the present application and is not intended to limit the same, but rather, various modifications and variations may be made by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principles of the present application should be included in the protection scope of the present application.
Claims (7)
1. The bactericidal composition containing the thifluzamide is characterized in that the active ingredients of the bactericidal composition contain the thifluzamide and the pyraclostrobin, and the weight ratio of the thifluzamide to the pyraclostrobin is 20:1-1:1.
2. The bactericidal composition of claim 1, wherein the weight ratio of thifluzamide to pyraclostrobin is 5:1.
3. Use of the fungicidal composition as claimed in claim 1 or 2 in (1) or (2) as follows:
(1) Preventing and treating southern rust of corn;
(2) And preparing a product for preventing and treating southern rust of corn.
4. A medicament for controlling southern rust in corn, comprising an effective amount of the fungicidal composition of claim 1 or 2.
5. The pharmaceutical formulation of claim 4, wherein the formulation of the pharmaceutical formulation is a granule, powder, suspension, aqueous solution, emulsion in water, sustained release formulation, or tablet.
6. Use of the agent according to claim 4 or 5 for controlling southern rust in corn.
7. A method for controlling southern rust in corn, comprising the steps of:
the agent of claim 4 or 5 is sprayed on the aerial parts of corn plants before or at the time of onset of southern rust disease of corn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311490471.0A CN117426391A (en) | 2023-11-10 | 2023-11-10 | Sterilization composition containing thifluzamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311490471.0A CN117426391A (en) | 2023-11-10 | 2023-11-10 | Sterilization composition containing thifluzamide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117426391A true CN117426391A (en) | 2024-01-23 |
Family
ID=89547909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311490471.0A Pending CN117426391A (en) | 2023-11-10 | 2023-11-10 | Sterilization composition containing thifluzamide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN117426391A (en) |
-
2023
- 2023-11-10 CN CN202311490471.0A patent/CN117426391A/en active Pending
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