CN117321137A - 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体 - Google Patents

单体组合物、甲基丙烯酸系树脂组合物及树脂成形体 Download PDF

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Publication number
CN117321137A
CN117321137A CN202280036126.7A CN202280036126A CN117321137A CN 117321137 A CN117321137 A CN 117321137A CN 202280036126 A CN202280036126 A CN 202280036126A CN 117321137 A CN117321137 A CN 117321137A
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CN
China
Prior art keywords
mass
methyl
composition
resin composition
methacrylic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN202280036126.7A
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English (en)
Chinese (zh)
Inventor
伊藤大晃
平野佑典
谷口一生
磯村学
兼森纮一
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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Publication of CN117321137A publication Critical patent/CN117321137A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/14—Organic medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN202280036126.7A 2021-05-20 2022-05-19 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体 Pending CN117321137A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021085291 2021-05-20
JP2021-085291 2021-05-20
PCT/JP2022/020783 WO2022244834A1 (ja) 2021-05-20 2022-05-19 単量体組成物、メタクリル系樹脂組成物及び樹脂成形体

Publications (1)

Publication Number Publication Date
CN117321137A true CN117321137A (zh) 2023-12-29

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Application Number Title Priority Date Filing Date
CN202280036126.7A Pending CN117321137A (zh) 2021-05-20 2022-05-19 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体
CN202280036147.9A Pending CN117321138A (zh) 2021-05-20 2022-05-19 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体
CN202280036146.4A Pending CN117412996A (zh) 2021-05-20 2022-05-19 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体

Family Applications After (2)

Application Number Title Priority Date Filing Date
CN202280036147.9A Pending CN117321138A (zh) 2021-05-20 2022-05-19 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体
CN202280036146.4A Pending CN117412996A (zh) 2021-05-20 2022-05-19 单体组合物、甲基丙烯酸系树脂组合物及树脂成形体

Country Status (8)

Country Link
US (3) US20240083835A1 (https=)
EP (3) EP4353775A4 (https=)
JP (6) JP7338797B2 (https=)
KR (5) KR102850983B1 (https=)
CN (3) CN117321137A (https=)
MX (3) MX2023013618A (https=)
TW (6) TWI882589B (https=)
WO (3) WO2022244835A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4353775A4 (en) * 2021-05-20 2024-12-04 Mitsubishi Chemical Corporation MONOMER COMPOSITION, METHACRYLIC RESIN COMPOSITION AND MOLDED RESIN ARTICLE
JPWO2023210564A1 (https=) * 2022-04-27 2023-11-02
EP4620985A1 (en) * 2022-11-18 2025-09-24 Mitsubishi Chemical Corporation Monomer composition, resin composition, resin composition manufacturing method, resin molded body, and resin molded body manufacturing method

Citations (5)

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JPS62123150A (ja) * 1985-11-25 1987-06-04 Mitsui Toatsu Chem Inc メタクリル酸メチルの精製法
CN1260777A (zh) * 1997-07-11 2000-07-19 帝国化学工业公司 含甲醛的混合物的处理方法
CN102798688A (zh) * 2012-08-09 2012-11-28 北京旭阳化工技术研究院有限公司 气相色谱内标法测定丙酸甲酯、甲基丙烯酸甲酯和丙酸含量的方法
CN106699560A (zh) * 2015-11-18 2017-05-24 上海浦景化工技术股份有限公司 一种含甲基丙烯酸甲酯的物流的分离设备与分离方法
CN114316122A (zh) * 2020-09-30 2022-04-12 住友化学株式会社 含有甲基丙烯酸甲酯的组合物

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DE3004467A1 (de) * 1980-02-07 1981-08-13 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von methylmethacrylat durch umsetzung von methylpropionat und methanol
JPS579739A (en) * 1980-06-20 1982-01-19 Asahi Chem Ind Co Ltd Purification of methyl methacrylate
US4410723A (en) * 1982-08-09 1983-10-18 Ashland Oil, Inc. Oxydehydrogenation process
JPH0794506B2 (ja) * 1989-01-18 1995-10-11 株式会社クラレ 透明性に優れたメタクリル系樹脂、その樹脂組成物およびそれらの製造方法
CA2012935A1 (en) * 1989-03-31 1990-09-30 Hirozo Segawa Purification and preparation processes for methyl methacrylate
JP2859682B2 (ja) * 1989-03-31 1999-02-17 三井化学株式会社 メタクリル酸メチルの精製方法及び製造方法
FR2651236B1 (fr) * 1989-08-23 1993-06-25 Acome Procede de polymerisation du methacrylate de methyle.
JPH11171833A (ja) * 1997-12-11 1999-06-29 Mitsubishi Rayon Co Ltd β−ヒドロキシイソ酪酸エステルの製造方法
SG83788A1 (en) * 1999-04-13 2001-10-16 Mitsui Chemicals Inc Method for preparing polymer
JP3672818B2 (ja) * 2000-12-26 2005-07-20 三菱レイヨン株式会社 （メタ）アクリル酸エステルの精製方法
US7407998B2 (en) * 2004-09-28 2008-08-05 Arkema France Stabilized UV transparent acrylic composition
EP1702934B1 (en) * 2005-03-14 2015-05-06 Mitsubishi Gas Chemical Company, Inc. Method of producing hydrogenated polymers
GB0905257D0 (en) 2009-03-27 2009-05-13 Lucite Int Uk Ltd Process for the treatment of an ion exchange resin
EP3450422A1 (de) 2017-08-29 2019-03-06 Evonik Röhm GmbH Verfahren zur herstellung optischer formmassen
EP3798202A1 (de) * 2019-09-25 2021-03-31 Röhm GmbH Verfahren zur aufreinigung von methylmethacrylat von leichtsiedenden komponenten
JP7359667B2 (ja) 2019-11-29 2023-10-11 三和シヤッター工業株式会社 開閉体
KR20230175256A (ko) * 2021-04-28 2023-12-29 미쯔비시 케미컬 주식회사 메타크릴산 메틸 함유 조성물 및 메타크릴산 메틸 중합체의 제조 방법
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EP4353775A4 (en) * 2021-05-20 2024-12-04 Mitsubishi Chemical Corporation MONOMER COMPOSITION, METHACRYLIC RESIN COMPOSITION AND MOLDED RESIN ARTICLE
WO2023100867A1 (ja) * 2021-11-30 2023-06-08 三菱ケミカル株式会社 メタクリル酸メチル含有組成物、メタクリル酸メチル含有組成物の保存方法及びメタクリル酸メチル重合体の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62123150A (ja) * 1985-11-25 1987-06-04 Mitsui Toatsu Chem Inc メタクリル酸メチルの精製法
CN1260777A (zh) * 1997-07-11 2000-07-19 帝国化学工业公司 含甲醛的混合物的处理方法
CN102798688A (zh) * 2012-08-09 2012-11-28 北京旭阳化工技术研究院有限公司 气相色谱内标法测定丙酸甲酯、甲基丙烯酸甲酯和丙酸含量的方法
CN106699560A (zh) * 2015-11-18 2017-05-24 上海浦景化工技术股份有限公司 一种含甲基丙烯酸甲酯的物流的分离设备与分离方法
CN114316122A (zh) * 2020-09-30 2022-04-12 住友化学株式会社 含有甲基丙烯酸甲酯的组合物

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CN117412996A (zh) 2024-01-16
JP2023084157A (ja) 2023-06-16
JP7318828B2 (ja) 2023-08-01
TWI845944B (zh) 2024-06-21
KR20240008349A (ko) 2024-01-18
KR20240033122A (ko) 2024-03-12
US20240083835A1 (en) 2024-03-14
TW202302518A (zh) 2023-01-16
EP4353775A1 (en) 2024-04-17
JP2023096058A (ja) 2023-07-06
TWI882591B (zh) 2025-05-01
EP4353779A4 (en) 2024-10-16
KR102749709B1 (ko) 2025-01-07
TWI882589B (zh) 2025-05-01
EP4353779A1 (en) 2024-04-17
MX2023013613A (es) 2023-11-30
TW202421681A (zh) 2024-06-01
TW202302517A (zh) 2023-01-16
KR102828115B1 (ko) 2025-07-03
KR102733199B1 (ko) 2024-11-25
JPWO2022244833A1 (https=) 2022-11-24
US20240158552A1 (en) 2024-05-16
EP4353754A4 (en) 2024-12-04
WO2022244835A1 (ja) 2022-11-24
TW202417409A (zh) 2024-05-01
WO2022244834A1 (ja) 2022-11-24
MX2023013618A (es) 2023-11-30
JP7272512B2 (ja) 2023-05-12
TWI845945B (zh) 2024-06-21
MX2023013617A (es) 2023-11-30
EP4353775A4 (en) 2024-12-04
TW202302519A (zh) 2023-01-16
KR20240007271A (ko) 2024-01-16
WO2022244833A1 (ja) 2022-11-24
KR20240007270A (ko) 2024-01-16
TWI845943B (zh) 2024-06-21
JPWO2022244834A1 (https=) 2022-11-24
KR102647117B1 (ko) 2024-03-14
TW202421680A (zh) 2024-06-01
JP7338797B2 (ja) 2023-09-05
JPWO2022244835A1 (https=) 2022-11-24
EP4353754A1 (en) 2024-04-17
KR20240033105A (ko) 2024-03-12
US20240084055A1 (en) 2024-03-14
KR102850983B1 (ko) 2025-08-27
TWI882590B (zh) 2025-05-01
JP2023089218A (ja) 2023-06-27
CN117321138A (zh) 2023-12-29

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