CN1167500C - 用于由催化剂表面除去可离子化物质以提高催化性能的方法 - Google Patents

用于由催化剂表面除去可离子化物质以提高催化性能的方法 Download PDF

Info

Publication number
CN1167500C
CN1167500C CNB998108952A CN99810895A CN1167500C CN 1167500 C CN1167500 C CN 1167500C CN B998108952 A CNB998108952 A CN B998108952A CN 99810895 A CN99810895 A CN 99810895A CN 1167500 C CN1167500 C CN 1167500C
Authority
CN
China
Prior art keywords
support
carrier
catalyst
catalysts
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB998108952A
Other languages
English (en)
Chinese (zh)
Other versions
CN1317990A (zh
Inventor
J��R���Ϳ�õ����
J·R·劳克玫伊尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CN1317990A publication Critical patent/CN1317990A/zh
Application granted granted Critical
Publication of CN1167500C publication Critical patent/CN1167500C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB998108952A 1998-09-14 1999-09-09 用于由催化剂表面除去可离子化物质以提高催化性能的方法 Expired - Lifetime CN1167500C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10019498P 1998-09-14 1998-09-14
US60/100,194 1998-09-14

Publications (2)

Publication Number Publication Date
CN1317990A CN1317990A (zh) 2001-10-17
CN1167500C true CN1167500C (zh) 2004-09-22

Family

ID=22278549

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998108952A Expired - Lifetime CN1167500C (zh) 1998-09-14 1999-09-09 用于由催化剂表面除去可离子化物质以提高催化性能的方法

Country Status (18)

Country Link
US (1) US6368998B1 (enExample)
EP (1) EP1115485A1 (enExample)
JP (1) JP4698835B2 (enExample)
KR (1) KR100572966B1 (enExample)
CN (1) CN1167500C (enExample)
AU (1) AU750895B2 (enExample)
BR (1) BR9913600A (enExample)
CA (1) CA2343783C (enExample)
GC (1) GC0000069A (enExample)
ID (1) ID28550A (enExample)
IN (1) IN218010B (enExample)
MX (1) MXPA01002590A (enExample)
MY (1) MY121089A (enExample)
RU (1) RU2232049C2 (enExample)
TR (1) TR200100748T2 (enExample)
TW (1) TWI232133B (enExample)
WO (1) WO2000015333A1 (enExample)
ZA (1) ZA200101901B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI632954B (zh) * 2013-05-16 2018-08-21 科學設計股份有限公司 改善環氧乙烷觸媒的催化效能之載體處理

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU757495B2 (en) * 1998-09-14 2003-02-20 Shell Internationale Research Maatschappij B.V. Process for preparing catalysts with improved catalytic properties
US7232918B2 (en) * 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
US7232786B2 (en) * 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
US7504525B2 (en) * 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
RU2225255C2 (ru) * 1998-09-14 2004-03-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Носитель катализатора эпоксидирования, его получение и применение
WO2002078843A1 (en) 2001-03-30 2002-10-10 Shell Internationale Research Maatschappij B.V. Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate
US6624109B2 (en) 2001-10-23 2003-09-23 Council Of Scientific And Industrial Research Process for the synthesis of highly active modified carbon supported palladium catalyst
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
US6987080B2 (en) * 2002-03-01 2006-01-17 Scientific Design Company, Inc. Ethylene oxide catalyst carrier preparation
JP4421201B2 (ja) 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US6750173B2 (en) * 2002-04-08 2004-06-15 Scientific Design Company, Inc. Ethylene oxide catalyst
RU2314156C2 (ru) * 2002-06-28 2008-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ улучшения селективности катализатора и способ эпоксидирования олефина
RU2005102097A (ru) * 2002-06-28 2005-08-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина
KR100985671B1 (ko) 2002-09-30 2010-10-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 은계 에폭시화 촉매를 제조하기 위한 탄산 칼슘 담체
CN1713957B (zh) 2002-10-28 2010-11-03 国际壳牌研究有限公司 制备烯烃氧化物的方法、使用所述烯烃氧化物的方法和催化剂组合物
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
RU2328491C2 (ru) * 2003-04-01 2008-07-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ эпоксидирования олефинов и катализатор для применения в способе
US7348444B2 (en) 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US6846774B2 (en) 2003-04-23 2005-01-25 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
EP1658136A1 (en) * 2003-08-22 2006-05-24 Union Carbide Chemicals & Plastics Technology Corporation Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
EP1658135A1 (en) * 2003-08-22 2006-05-24 Union Carbide Chemicals & Plastics Technology Corporation Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
JP4824569B2 (ja) * 2003-10-16 2011-11-30 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー アルキレンオキサイド製造用の増強された安定性、効率及び／又は活性を有する触媒
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
CN100572370C (zh) * 2004-06-18 2009-12-23 国际壳牌研究有限公司 生产烯烃氧化物、1,2-二醇、1,2-二醇醚或链烷醇胺的方法
CA2571179C (en) * 2004-06-18 2014-06-10 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
MX2007001684A (es) * 2004-08-12 2007-04-12 Shell Int Research Metodo para la preparacion de un catalizador formado, el catalizador, y uso del catalizador.
BRPI0514814A (pt) 2004-09-01 2008-06-24 Shell Int Research processo de epoxidação de olefina, um catalisador para uso no processo, um veìculo para uso na preparação do catalisador, e processo para preparar o veìculo
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
BRPI0515905A (pt) * 2004-09-24 2008-08-12 Shell Int Research processo para selecionar partìculas moldadas, um processo para instalar um sistema, um processo para reagir uma carga de alimentação gasosa em um tal sistema, um produto de programa de computação e um sistema de computação
KR20070106772A (ko) * 2005-02-21 2007-11-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀의 에폭시화 방법, 그 방법에 사용하기 위한 촉매,그 촉매를 제조하는데 이용하기 위한 담체, 및 그 담체의제조방법
CA2602163C (en) * 2005-03-22 2014-02-18 Shell Internationale Research Maatschappij B.V. A reactor system and process for the manufacture of ethylene oxide
EP1724824A3 (en) * 2005-05-17 2010-08-25 Apprecia Technology Inc. Equipment and method for measuring silicon concentration in phosphoric acid solution
TWI334363B (en) * 2005-06-07 2010-12-11 Saint Gobain Ceramics A catalyst carrier
KR101369619B1 (ko) 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
BRPI0614756A2 (pt) * 2005-08-11 2011-04-12 Shell Int Research método para preparar um catalisador moldado, o catalisador, e uso do catalisador
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
BE1017793A3 (fr) * 2005-12-22 2009-07-07 Shell Int Research Procede de preparation d'un oxyde d'olefine ou d'un produit chimique pouvant provenir d'un oxyde d'olefine.
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
EP1979092A2 (en) * 2006-02-03 2008-10-15 Shell Internationale Research Maatschappij B.V. A process for treating a catalyst, the catalyst, and use of the catalyst
CN101360562B (zh) * 2006-04-10 2013-02-06 三菱化学株式会社 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法
JP4978277B2 (ja) * 2006-04-10 2012-07-18 三菱化学株式会社 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
WO2007116585A1 (ja) * 2006-04-10 2007-10-18 Mitsubishi Chemical Corporation 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
US8501664B2 (en) * 2006-11-20 2013-08-06 Shell Oil Company Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
JP5507444B2 (ja) * 2007-05-09 2014-05-28 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 酸化オレフィン、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートまたはアルカノールアミンの製造方法
EP2152411B1 (en) 2007-05-09 2019-12-04 Shell International Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
WO2008141032A1 (en) 2007-05-09 2008-11-20 Shell Oil Company An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
US20090050535A1 (en) * 2007-05-18 2009-02-26 Wayne Errol Evans Reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine
RU2474470C2 (ru) 2007-05-18 2013-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Реакторная система, абсорбент и способ осуществления реакции в подаваемом материале
WO2009029578A2 (en) * 2007-08-27 2009-03-05 Shell Oil Company A carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US7763096B2 (en) * 2008-05-06 2010-07-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Recovery of rhenium
KR101629038B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
CN102056909B (zh) 2008-05-07 2014-03-05 国际壳牌研究有限公司 环氧化工艺的开车方法及环氧乙烷、1，2-二醇、1，2-二醇醚、1，2-碳酸酯或链烷醇胺的制备方法
US8193374B2 (en) * 2008-05-15 2012-06-05 Shell Oil Company Process for the preparation of alkylene carbonate and/or alkylene glycol
WO2009140318A1 (en) * 2008-05-15 2009-11-19 Shell Oil Company Process for the preparation of an alkylene carbonate and an alkylene glycol
CA2791210C (en) 2010-03-01 2019-10-29 Shell Internationale Research Maatschappij B.V. An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
RU2541471C2 (ru) * 2010-04-30 2015-02-20 Асахи Касеи Кемикалз Корпорейшн Устройство для удаления поверхностных веществ катализатора
US9018126B2 (en) 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
CN102463141B (zh) 2010-11-02 2015-05-06 中国石油化工股份有限公司 一种氧化铝载体、其制备方法、由其制成的银催化剂及其应用
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742146B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
EP2714670B2 (en) 2011-04-29 2022-03-02 Shell Internationale Research Maatschappij B.V. Process for improving the selectivity of an eo catalyst
JP5984593B2 (ja) * 2011-09-30 2016-09-06 株式会社日本触媒 エチレンオキシド製造用触媒およびそれを用いたエチレンオキシドの製造方法
TWI632138B (zh) * 2013-05-16 2018-08-11 科學設計股份有限公司 具有降低鈉含量之建基於銀之環氧乙烷觸媒
KR102316115B1 (ko) 2013-12-19 2021-10-22 사이언티픽 디자인 컴파니 인코포레이티드 에틸렌 옥사이드 촉매 제조를 위한 고농도 은 용액
CN104492247B (zh) * 2014-12-15 2016-06-08 沈阳三聚凯特催化剂有限公司 一种瓷球脱硫剂的制备方法
EP3390356B1 (en) 2015-12-15 2019-11-13 Shell International Research Maatschappij B.V. Processes and systems for removing iodide impurities from a recycle gas stream in the production of ethylene oxide
KR102667368B1 (ko) 2015-12-15 2024-05-21 쉘 인터내셔날 리써취 마트샤피지 비.브이. 에틸렌 옥사이드의 제조 시 재순환 가스 스트림으로부터 알킬 요오드화물 불순물을 제거하기 위한 방법 및 시스템
US11000819B2 (en) 2015-12-15 2021-05-11 Shell Oil Company Guard bed system and process
WO2017102701A1 (en) 2015-12-15 2017-06-22 Shell Internationale Research Maatschappij B.V. Processes and systems for removing a vinyl iodide impurity from a recycle gas stream in the production of ethylene oxide
TWI772330B (zh) 2016-10-14 2022-08-01 荷蘭商蜆殼國際研究所 用於定量分析氣態製程流之方法及設備
CA3043504A1 (en) 2016-12-02 2018-06-07 Shell Internationale Research Maatschappij B.V. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
EP3565663A4 (en) 2017-01-05 2020-09-09 Scientific Design Company, Inc. SUPPORT, CATALYST, THEIR PRODUCTION PROCESSES AND ETHYLENE OXIDE PRODUCTION PROCESS
TW202239752A (zh) 2020-12-29 2022-10-16 荷蘭商蜆殼國際研究所 用於生產環氧乙烷之製程

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB568978A (en) 1941-07-05 1945-04-30 Houdry Process Corp Alumina
US2424083A (en) * 1943-08-11 1947-07-15 Shell Dev Supported silver catalyst
US2901441A (en) 1953-01-28 1959-08-25 Publicker Ind Inc Preparation of an oxidation catalyst
FR2005978A1 (en) 1968-04-10 1969-12-19 Institu Cercetari Petroc Catalyst for oxidation of ethylene to ethylene oxide
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3972829A (en) 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
IT1078404B (it) * 1976-05-19 1985-05-08 Basf Ag Catalizzatore per la preparazione di ossido di etilene
US4212772A (en) 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
GB1575810A (en) 1976-10-21 1980-10-01 Shell Int Research Process for the performance of silver catalysts
DE2819595A1 (de) * 1977-05-12 1978-12-07 Basf Ag Katalysator zur herstellung von aethylenoxid
DE2740480B2 (de) 1977-09-08 1979-07-05 Hoechst Ag, 6000 Frankfurt Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren
US5387751A (en) 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
US4916243A (en) 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
HU177860B (en) 1979-05-22 1982-01-28 Mta Koezponti Hivatala Method for producing carrier metal catalyzers
DE2933950A1 (de) * 1979-08-22 1981-03-12 Basf Ag Traegerkatalysatoren fuer die herstellung von aethylenoxid.
JPS5689843A (en) * 1979-12-25 1981-07-21 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for production of ethylene oxide
JPS56105750A (en) 1980-01-24 1981-08-22 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for production of ethylene oxide
JPS56164013A (en) 1980-05-23 1981-12-16 Showa Alum Ind Kk Preparation of alumina with low content of radioactive element
US4382149A (en) * 1980-11-05 1983-05-03 Borden, Inc. Supported silver catalyst
US4379134A (en) * 1981-02-13 1983-04-05 Union Carbide Corporation Process of preparing high purity alumina bodies
US4367167A (en) 1981-07-17 1983-01-04 The Dow Chemical Company Process for preparing supported metal catalysts
US4366092A (en) 1981-07-31 1982-12-28 The Dow Chemical Company Process for making a silver-gold alloy catalyst for oxidizing ethylene to ethylene oxide
US4361504A (en) * 1981-09-04 1982-11-30 The Dow Chemical Company Process for making a silver catalyst useful in ethylene oxide production
GB8304749D0 (en) * 1983-02-21 1983-03-23 Ici Plc Catalysts
WO1985000365A1 (en) 1983-07-05 1985-01-31 Union Carbide Corporation Alkoxylation using calcium catalysts and products therefrom
US4628129A (en) * 1985-02-04 1986-12-09 Union Carbide Corporation Process for the preparation of ethylene glycol
EP0211521B1 (en) 1985-07-31 1990-03-21 Imperial Chemical Industries Plc Process of promoting catalysts for the production of alkylene oxides
GB8613818D0 (en) 1986-06-06 1986-07-09 Ici Plc Catalysts
US4994587A (en) * 1985-08-12 1991-02-19 Union Carbide Chemicals And Plastics Company, Inc. Catalytic system for epoxidation of alkenes employing low sodium catalyst supports
US4994588A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Fluorine-containing catalytic system for expoxidation of alkenes
US4994589A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic system for epoxidation of alkenes
GB8526774D0 (en) * 1985-10-30 1985-12-04 Sandoz Ltd Bacillus thuringiensis hybrids
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US5057481A (en) 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
ES2004759A6 (es) * 1987-07-17 1989-02-01 Espanola Alumina Sa Metodo de obtencion de alumina especial a partir del polvo producido en la calcinacion de alumina metalurgica
US4797220A (en) * 1988-02-03 1989-01-10 Miller Dale A Descaling and anti-oxidizing composition and process therefor
EP0383636A1 (en) 1989-02-17 1990-08-22 Nippon Shokubai Co., Ltd. Carrier for catalyst and method for production thereof
US5037794A (en) 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5112795A (en) 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
EP0563414B1 (en) * 1992-03-30 1997-02-26 Union Carbide Chemicals & Plastics Technology Corporation Process for producing a catalyst for the production of Alkenyl alkanoates
RU2046015C1 (ru) * 1992-04-08 1995-10-20 Владимир Сергеевич Соколов Способ приготовления катализатора для получения окиси этилена
US6184175B1 (en) * 1993-03-01 2001-02-06 Scientic Design Company, Inc. Process for preparing silver catalyst
DE4311608A1 (de) 1993-04-08 1994-12-15 Huels Chemische Werke Ag Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid
US5447897A (en) 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5380697A (en) 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
US5418202A (en) 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5545603A (en) 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
DE69600628T2 (de) 1995-02-01 1999-02-25 Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage Alkylenoxidkatalysator und verfahren
JP3802106B2 (ja) 1995-06-08 2006-07-26 日本ケッチェン株式会社 炭化水素油の水素化処理触媒とその製造方法およびその活性化方法
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
TW426545B (en) * 1997-12-25 2001-03-21 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
EP0937498B1 (en) 1998-02-20 2004-08-18 Nippon Shokubai Co., Ltd. Silver catalyst for production of ethylene Oxide, method for production thereof, and method for production of ethylene oxide
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI632954B (zh) * 2013-05-16 2018-08-21 科學設計股份有限公司 改善環氧乙烷觸媒的催化效能之載體處理

Also Published As

Publication number Publication date
ZA200101901B (en) 2002-08-19
MY121089A (en) 2005-12-30
GC0000069A (en) 2004-06-30
BR9913600A (pt) 2001-05-22
ID28550A (id) 2001-05-31
WO2000015333A1 (en) 2000-03-23
TWI232133B (en) 2005-05-11
CA2343783A1 (en) 2000-03-23
KR100572966B1 (ko) 2006-04-24
EP1115485A1 (en) 2001-07-18
AU750895B2 (en) 2002-08-01
MXPA01002590A (es) 2001-08-01
KR20010079796A (ko) 2001-08-22
AU5746999A (en) 2000-04-03
CN1317990A (zh) 2001-10-17
US6368998B1 (en) 2002-04-09
IN218010B (enExample) 2008-06-13
TR200100748T2 (tr) 2001-08-21
CA2343783C (en) 2008-02-12
JP2002524245A (ja) 2002-08-06
RU2232049C2 (ru) 2004-07-10
IN2001DE00171A (enExample) 2007-09-28
JP4698835B2 (ja) 2011-06-08

Similar Documents

Publication Publication Date Title
CN1167500C (zh) 用于由催化剂表面除去可离子化物质以提高催化性能的方法
CN1154538C (zh) 环氧化催化剂载体、其制备和用途
CN1145526C (zh) 制备具有改进催化性能的催化剂的方法
CN1087191C (zh) 环氧化催化剂和方法
US7507689B2 (en) Catalyst composition
US7741499B2 (en) Catalyst composition
US7504525B2 (en) Catalyst composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term

Granted publication date: 20040922

CX01 Expiry of patent term