CN116495736B - 一种闪速冷冻-微波高效制备MXenes复合材料的方法 - Google Patents
一种闪速冷冻-微波高效制备MXenes复合材料的方法 Download PDFInfo
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- CN116495736B CN116495736B CN202310692823.4A CN202310692823A CN116495736B CN 116495736 B CN116495736 B CN 116495736B CN 202310692823 A CN202310692823 A CN 202310692823A CN 116495736 B CN116495736 B CN 116495736B
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- 239000002131 composite material Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 28
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- 239000000463 material Substances 0.000 claims abstract description 74
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
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- 238000006243 chemical reaction Methods 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 16
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 10
- 239000012265 solid product Substances 0.000 claims description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 9
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000004321 preservation Methods 0.000 claims description 8
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- 238000005303 weighing Methods 0.000 claims description 6
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- 238000002360 preparation method Methods 0.000 abstract description 16
- 150000002736 metal compounds Chemical class 0.000 abstract description 11
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- 230000015572 biosynthetic process Effects 0.000 abstract description 7
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- 238000003786 synthesis reaction Methods 0.000 abstract description 7
- 238000011065 in-situ storage Methods 0.000 abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- -1 polytetrafluoroethylene Polymers 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
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- 238000001228 spectrum Methods 0.000 description 5
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- 230000000877 morphologic effect Effects 0.000 description 4
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000002070 nanowire Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
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- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004108 freeze drying Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910005913 NiTe Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
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- 238000002715 modification method Methods 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
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- 238000010257 thawing Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105084360A (zh) * | 2015-09-14 | 2015-11-25 | 哈尔滨工业大学 | 一种微波加热辅助超声剥离二维纳米Ti3C2片层的方法 |
CN111675221A (zh) * | 2020-06-18 | 2020-09-18 | 济南大学 | 一种碳化钛空心球的制备方法 |
CN113371765A (zh) * | 2021-07-22 | 2021-09-10 | 重庆邮电大学 | 一种基于NiFe层状双金属氧化物修饰MXene的电磁吸波材料的制备方法及其产品 |
WO2022032743A1 (zh) * | 2020-08-12 | 2022-02-17 | 五邑大学 | 一种CoTe2/MXene复合材料及其制备方法 |
CN114196988A (zh) * | 2021-12-14 | 2022-03-18 | 黑龙江大学 | 一种用于电解水析氧的双金属硫化物/MXene复合体的制备方法 |
CN115064663A (zh) * | 2022-08-18 | 2022-09-16 | 昆明理工大学 | 一种MXene基凝胶态正极的制备方法及其应用 |
CN115246640A (zh) * | 2022-03-04 | 2022-10-28 | 成都大学 | 一种三维HCNTs@Ti3C2Tx MXene杂化气凝胶微球及其制备方法和应用 |
CN115528227A (zh) * | 2022-09-27 | 2022-12-27 | 南通大学 | 一种双金属CoZn-Se@MXene电极的制备方法 |
CN115863581A (zh) * | 2022-12-12 | 2023-03-28 | 赣南科技学院 | CoNiP-C/MXene复合负极材料的制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20200399771A1 (en) * | 2019-06-24 | 2020-12-24 | The Hong Kong Polytechnic University | Method for hf-free facile and rapid synthesis of mxenes related compounds |
US11866597B2 (en) * | 2020-02-13 | 2024-01-09 | Korea Institute Of Science And Technology | 2-dimensional MXene surface-modified with catechol derivative, method for preparing the same, and MXene organic ink including the same |
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- 2023-06-13 CN CN202310692823.4A patent/CN116495736B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105084360A (zh) * | 2015-09-14 | 2015-11-25 | 哈尔滨工业大学 | 一种微波加热辅助超声剥离二维纳米Ti3C2片层的方法 |
CN111675221A (zh) * | 2020-06-18 | 2020-09-18 | 济南大学 | 一种碳化钛空心球的制备方法 |
WO2022032743A1 (zh) * | 2020-08-12 | 2022-02-17 | 五邑大学 | 一种CoTe2/MXene复合材料及其制备方法 |
CN113371765A (zh) * | 2021-07-22 | 2021-09-10 | 重庆邮电大学 | 一种基于NiFe层状双金属氧化物修饰MXene的电磁吸波材料的制备方法及其产品 |
CN114196988A (zh) * | 2021-12-14 | 2022-03-18 | 黑龙江大学 | 一种用于电解水析氧的双金属硫化物/MXene复合体的制备方法 |
CN115246640A (zh) * | 2022-03-04 | 2022-10-28 | 成都大学 | 一种三维HCNTs@Ti3C2Tx MXene杂化气凝胶微球及其制备方法和应用 |
CN115064663A (zh) * | 2022-08-18 | 2022-09-16 | 昆明理工大学 | 一种MXene基凝胶态正极的制备方法及其应用 |
CN115528227A (zh) * | 2022-09-27 | 2022-12-27 | 南通大学 | 一种双金属CoZn-Se@MXene电极的制备方法 |
CN115863581A (zh) * | 2022-12-12 | 2023-03-28 | 赣南科技学院 | CoNiP-C/MXene复合负极材料的制备方法 |
Non-Patent Citations (1)
Title |
---|
二维多层状Ti_3C_2T_x-MXene/聚吡咯纳米线复合材料的制备及电容性能研究;陈露;简选;何敏;张咪咪;陈晓蝶;高楼军;梁镇海;;电化学(02);全文 * |
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