CN1159353C - 生产聚烯烃的方法 - Google Patents

生产聚烯烃的方法 Download PDF

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Publication number
CN1159353C
CN1159353C CNB998166731A CN99816673A CN1159353C CN 1159353 C CN1159353 C CN 1159353C CN B998166731 A CNB998166731 A CN B998166731A CN 99816673 A CN99816673 A CN 99816673A CN 1159353 C CN1159353 C CN 1159353C
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CN
China
Prior art keywords
ether
catalyst
olefin polymerization
polymerization catalysis
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB998166731A
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English (en)
Chinese (zh)
Other versions
CN1350553A (zh
Inventor
R・R・福特
R·R·福特
杜利
K·A·杜利
范德比尔
J·J·范德比尔
胤贫德
R·惠特菲尔德
旺德斯
A·G·旺德斯
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Westlake Longview Corp
Original Assignee
Eastman Chemical Co
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Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Publication of CN1350553A publication Critical patent/CN1350553A/zh
Application granted granted Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture And Refinement Of Metals (AREA)
CNB998166731A 1999-03-30 1999-10-14 生产聚烯烃的方法 Expired - Lifetime CN1159353C (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US12690999P 1999-03-30 1999-03-30
US60/126,909 1999-03-30
US60/126909 1999-03-30
US09/387599 1999-08-31
US09/387,599 US6313236B1 (en) 1999-03-30 1999-08-31 Process for producing polyolefins
US09/387,599 1999-08-31

Publications (2)

Publication Number Publication Date
CN1350553A CN1350553A (zh) 2002-05-22
CN1159353C true CN1159353C (zh) 2004-07-28

Family

ID=26825148

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998166731A Expired - Lifetime CN1159353C (zh) 1999-03-30 1999-10-14 生产聚烯烃的方法

Country Status (9)

Country Link
US (1) US6313236B1 (enExample)
EP (1) EP1169360B2 (enExample)
JP (1) JP4699613B2 (enExample)
CN (1) CN1159353C (enExample)
BR (1) BR9917244B1 (enExample)
CA (1) CA2368405A1 (enExample)
DE (1) DE69934332T3 (enExample)
MX (1) MXPA01009834A (enExample)
WO (1) WO2000058373A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423573B (zh) * 2007-10-31 2011-05-18 中国石油化工股份有限公司 管材用聚乙烯树脂和制备方法及其组合物

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US6828395B1 (en) 2003-10-15 2004-12-07 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US7238756B2 (en) * 2003-10-15 2007-07-03 Univation Technologies, Llc Polymerization process and control of polymer composition properties
WO2005113615A2 (en) * 2004-05-20 2005-12-01 Univation Technologies, Llc Gas olefin polymerization process
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
WO2006009980A2 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Olefin polymerisation process
US7491776B2 (en) * 2004-06-21 2009-02-17 Exxonmobil Chemical Patents Inc. Polymerization process
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CN101511877B (zh) * 2006-09-07 2012-09-05 尤尼威蒂恩技术有限责任公司 由聚合反应监测产生的数据确定指示树脂粘附的温度值的方法
CN101511882B (zh) * 2006-09-07 2011-09-21 尤尼威蒂恩技术有限责任公司 使用降低熔融起始温度的模型在线测定树脂粘着性程度的方法
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US8087412B2 (en) 2008-05-01 2012-01-03 Ansell Healthcare Products Llc Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks
US10662269B2 (en) 2017-08-31 2020-05-26 Lifestyles Healthcare Pte. Ltd. Ziegler-Natta catalyzed polyisoprene articles

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423573B (zh) * 2007-10-31 2011-05-18 中国石油化工股份有限公司 管材用聚乙烯树脂和制备方法及其组合物

Also Published As

Publication number Publication date
DE69934332T2 (de) 2007-03-15
BR9917244B1 (pt) 2011-10-18
CA2368405A1 (en) 2000-10-05
DE69934332T3 (de) 2013-08-29
MXPA01009834A (es) 2002-05-06
WO2000058373A1 (en) 2000-10-05
BR9917244A (pt) 2002-03-26
EP1169360A1 (en) 2002-01-09
DE69934332D1 (de) 2007-01-18
US6313236B1 (en) 2001-11-06
WO2000058373A8 (en) 2007-08-23
EP1169360B1 (en) 2006-12-06
JP4699613B2 (ja) 2011-06-15
JP2002540264A (ja) 2002-11-26
CN1350553A (zh) 2002-05-22
EP1169360B2 (en) 2013-06-12

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