BR9917244A - Processos para polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s) e para redução da carga eletrostática gerada na polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s), filme, e, artigo - Google Patents

Processos para polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s) e para redução da carga eletrostática gerada na polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s), filme, e, artigo

Info

Publication number
BR9917244A
BR9917244A BR9917244-5A BR9917244A BR9917244A BR 9917244 A BR9917244 A BR 9917244A BR 9917244 A BR9917244 A BR 9917244A BR 9917244 A BR9917244 A BR 9917244A
Authority
BR
Brazil
Prior art keywords
olefin
polymerization
reducing
electrostatic charge
processes
Prior art date
Application number
BR9917244-5A
Other languages
English (en)
Other versions
BR9917244B1 (pt
Inventor
Randal Ray Ford
Kenneth Alan Dooley
Jeffrey James Vanderbilt
Roxanna Whitfield
Alan George Wonders
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26825148&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR9917244(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Publication of BR9917244A publication Critical patent/BR9917244A/pt
Publication of BR9917244B1 publication Critical patent/BR9917244B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

"PROCESSOS PARA POLIMERIZAçãO DE UMA OLEFINA E/OU UMA OLEFINA E PELO MENOS UMA OU MAIS OUTRA(S) OLEFINA(S) E PARA REDUçãO DA CARGA ELETROSTáTICA GERADA NA POLIMERIZAçãO DE UMA OLEFINA E/OU UMA OLEFINA E PELO MENOS UMA OU MAIS OUTRA(S) OLEFINA(S)". Novo processo para produção de homopolímeros e interpolímeros de olefinas que envolve o contato da olefina e/ou olefina e pelo menos uma ou mais outra(s) olefina(s) mediante condições de polimerização com o catalisador de polimerização de olefina e pelo menos um éter compreendendo pelo menos uma ligação carbono-oxigênio-carbono (C-O-C) da fórmula R^ 1^-O(-R^ 2^-O)~ m~-R^ 3^ em quantidades suficientes para reduzir a carga eletrostática no meio de polimerização. Também divulgado está o processo para redução de carga eletrostática no meio de polimerização da olefina.
BRPI9917244-5A 1999-03-30 1999-10-14 processos para polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra(s) olefina(s) e para redução da carga eletrostática gerada na polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra(s) olefina(s). BR9917244B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12690999P 1999-03-30 1999-03-30
US09/387,599 US6313236B1 (en) 1999-03-30 1999-08-31 Process for producing polyolefins
PCT/US1999/023899 WO2000058373A1 (en) 1999-03-30 1999-10-14 Process for producing polyolefins

Publications (2)

Publication Number Publication Date
BR9917244A true BR9917244A (pt) 2002-03-26
BR9917244B1 BR9917244B1 (pt) 2011-10-18

Family

ID=26825148

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9917244-5A BR9917244B1 (pt) 1999-03-30 1999-10-14 processos para polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra(s) olefina(s) e para redução da carga eletrostática gerada na polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra(s) olefina(s).

Country Status (9)

Country Link
US (1) US6313236B1 (pt)
EP (1) EP1169360B2 (pt)
JP (1) JP4699613B2 (pt)
CN (1) CN1159353C (pt)
BR (1) BR9917244B1 (pt)
CA (1) CA2368405A1 (pt)
DE (1) DE69934332T3 (pt)
MX (1) MXPA01009834A (pt)
WO (1) WO2000058373A1 (pt)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0027990D0 (en) * 2000-11-16 2001-01-03 Bp Chemicals Snc Polymerisation process
US6828395B1 (en) 2003-10-15 2004-12-07 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US7238756B2 (en) * 2003-10-15 2007-07-03 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
TW200613326A (en) * 2004-05-20 2006-05-01 Exxonmobil Chemical Patents Inc Polymerization process
WO2006009981A1 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Polymeriyation process and reactor system
WO2006009980A2 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Olefin polymerisation process
WO2006009944A2 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Polymerization process
RU2446175C2 (ru) * 2006-09-07 2012-03-27 Юнивейшн Текнолоджиз, Ллк Способы определения значения температуры, характеризующие липкость смолы, на основе данных мониторинга реакции полимеризации
MX2009002495A (es) * 2006-09-07 2009-05-22 Univation Tech Llc Metodos para determinacion en linea del grado de pegajosidad de resina usando un modelo para la reduccion de la temperatura de inicio de fusion.
US20100210798A1 (en) * 2007-08-29 2010-08-19 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins
CN101423573B (zh) * 2007-10-31 2011-05-18 中国石油化工股份有限公司 管材用聚乙烯树脂和制备方法及其组合物
US8087412B2 (en) 2008-05-01 2012-01-03 Ansell Healthcare Products Llc Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks
US10662269B2 (en) 2017-08-31 2020-05-26 Lifestyles Healthcare Pte. Ltd. Ziegler-Natta catalyzed polyisoprene articles

Family Cites Families (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076698A (en) 1956-03-01 1978-02-28 E. I. Du Pont De Nemours And Company Hydrocarbon interpolymer compositions
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
NO136797C (no) 1970-09-25 1977-11-09 Union Carbide Corp Fremgangsm}te for polymerisering av etylen med modifisert katalysator
US4012573A (en) 1970-10-09 1977-03-15 Basf Aktiengesellschaft Method of removing heat from polymerization reactions of monomers in the gas phase
US3709853A (en) 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4115639A (en) * 1971-06-24 1978-09-19 Union Carbide Corporation Ethylene polymerization with ether modified catalyst
US4011382A (en) 1975-03-10 1977-03-08 Union Carbide Corporation Preparation of low and medium density ethylene polymer in fluid bed reactor
US4243619A (en) * 1978-03-31 1981-01-06 Union Carbide Corporation Process for making film from low density ethylene hydrocarbon copolymer
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
JPS55106203A (en) * 1979-01-19 1980-08-14 Showa Denko Kk Preparation of ethylenic polymer
US4792592A (en) 1981-03-26 1988-12-20 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4876320A (en) 1981-03-26 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Process for reducing sheeting during polymerization of alpha-olefins
US4532311A (en) 1981-03-26 1985-07-30 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
JPS59117508A (ja) 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd エチレンの重合法
US5210161A (en) * 1983-04-26 1993-05-11 Phillips Petroleum Company Supported vanadium dihalide-ether complex catalyst
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
JPS6067508A (ja) 1983-09-22 1985-04-17 Toa Nenryo Kogyo Kk オレフインの重合方法
US4564647A (en) 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions
CA1235543A (en) 1984-09-12 1988-04-19 Norio Kashiwa Process for producing propylene block copolymer
US4701505A (en) * 1984-09-26 1987-10-20 Mitsubishi Petrochemical Company Limited Process for production of olefin polymers
DE3682928D1 (de) 1985-03-08 1992-01-30 Mitsubishi Petrochemical Co Verfahren zum polymerisieren von aethylen.
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
DE3600610A1 (de) * 1986-01-11 1987-07-16 Basf Ag Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreaktoren
US4855370A (en) 1986-10-01 1989-08-08 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US5026795A (en) 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
FR2618786B1 (fr) 1987-07-31 1989-12-01 Bp Chimie Sa Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US5780379A (en) 1987-09-25 1998-07-14 Solvay Polyolefins Europe-Belgium (Societe Anonyme) Process for the stereospecific polymerization of alpha-olefins and catalyst system which can be employed for this polymerization
US5034479A (en) 1987-10-22 1991-07-23 Union Carbide Chemicals And Plastics Technology Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4803251A (en) 1987-11-04 1989-02-07 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US4831000A (en) 1988-01-15 1989-05-16 Mobil Oil Corporatiion Catalyst composition for preparing high density or linear low density olefin polymers of controlled molecular weight distribution
FR2646426B2 (fr) 1988-09-13 1991-08-16 Bp Chemicals Sa Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite
FR2640273B1 (fr) 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
KR950006129B1 (ko) 1989-09-11 1995-06-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 캄파니 인코포레이티드 에틸렌/프로필렌/에틸리덴 노르보르넨 고무
US5106927A (en) 1989-09-11 1992-04-21 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene/propylene/ethylidene norbornene rubbers
US5227440A (en) 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2656315B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
US5726262A (en) 1990-04-13 1998-03-10 Mitsui Petrochemical Industries, Ltd. Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
DE69127220T2 (de) 1990-04-13 1998-01-02 Mitsui Petrochemical Ind Festes Titan enthaltendes Katalysatorbestandteil und Katalysator für Olefinpolymerisation, vorpolymerisierte Olefinpolymerisationskatalysator und Verfahren für Olefinpolymerisation
WO1992002563A1 (en) 1990-07-27 1992-02-20 Nippon Petrochemicals Company, Limited Process for producing polyolefin
US5162463A (en) 1990-12-10 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Method for producing sticky polymers
US5200477A (en) 1991-02-22 1993-04-06 Union Carbide Chemicals & Plastics Technology Corporation Process for producing sticky polymers
EP0509294B1 (en) 1991-03-29 1997-05-14 CHEVRON U.S.A. Inc. Cyclopentadienyl group 6b metal-alpha-olefin polymerization catalysts and process for polymerizing alpha-olefins
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
CA2068939C (en) 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
FR2680793B1 (fr) * 1991-08-30 1994-09-09 Bp Chemicals Snc Procede de fabrication d'un polymere de l'ethylene.
US5331071A (en) 1991-11-12 1994-07-19 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5229076A (en) 1992-05-08 1993-07-20 Fagher Richard H Method for reducing polymer build-up in a polymerization reactor
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5194526A (en) 1992-07-30 1993-03-16 Union Carbide Chemicals & Plastics Technology Corporation Process for producing sticky polymers
JP3202349B2 (ja) 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
JP3156213B2 (ja) 1993-02-23 2001-04-16 日石三菱株式会社 ポリオレフィンの製造方法
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
CA2126796A1 (en) 1993-06-28 1994-12-29 Robert Converse Brade, Iii Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process
FR2707651B1 (fr) 1993-07-13 1995-08-25 Bp Chemicals Snc Procédé pour augmenter l'activité d'un catalyseur de type Ziegler-Natta.
US5416175A (en) 1993-12-17 1995-05-16 Union Carbide Chemicals & Plastics Technology Corporation Method for reducing sheeting during polymerization of α-olefins
ES2165425T3 (es) 1994-06-24 2002-03-16 Exxonmobil Chem Patents Inc Sistemas cataliticos de polimerizacion, su produccion y uso.
US5625012A (en) 1994-06-29 1997-04-29 Union Carbide Chemicals & Plastics Technology Corporation Process for reducing polymer build-up in recycle lines and heat exchangers during polymerization of alpha olefins
US5468702A (en) 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5880241A (en) 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
US5731392A (en) 1996-09-20 1998-03-24 Mobil Oil Company Static control with TEOS
US5777120A (en) 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts

Also Published As

Publication number Publication date
BR9917244B1 (pt) 2011-10-18
JP2002540264A (ja) 2002-11-26
DE69934332T3 (de) 2013-08-29
DE69934332D1 (de) 2007-01-18
DE69934332T2 (de) 2007-03-15
CN1159353C (zh) 2004-07-28
CA2368405A1 (en) 2000-10-05
WO2000058373A1 (en) 2000-10-05
EP1169360B1 (en) 2006-12-06
WO2000058373A8 (en) 2007-08-23
EP1169360B2 (en) 2013-06-12
US6313236B1 (en) 2001-11-06
CN1350553A (zh) 2002-05-22
MXPA01009834A (es) 2002-05-06
EP1169360A1 (en) 2002-01-09
JP4699613B2 (ja) 2011-06-15

Similar Documents

Publication Publication Date Title
BR9917244A (pt) Processos para polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s) e para redução da carga eletrostática gerada na polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s), filme, e, artigo
BR9917247A (pt) Processos para a polimerização de uma olefinae/ou uma olefina e pelo menos uma ou mais outra(s) olefina (s), e para reduzir a carga eletrostáticagerada na polimerização de uma olefina e/ou umaolefina e pelo menos uma ou mais outra (s) olefina(s), pelìcula, e, artigo
BR9106842A (pt) Processo para a producao de poli-alfa-olifenas cristalinas com um sistema catalisador de monociclopentadienila-metal de transicao
DE59410075D1 (de) Sonnennachführung
CO4560475A1 (es) Un producto de carbon modificado
MXPA00006908A (es) Pelicula de poliester orientada biaxialmente, blanca, con copolimero de cicloolefina (coc), procedimiento para producir la pelicula y su uso.
BR9912258A (pt) Processo de formação de um microgel
AU584227B2 (en) Modified disulfide polymer composition and method for making same
BR9706068A (pt) Novos foto iniciadores de alfa-aminoacetofenona
CA2162609A1 (en) Method for recognizing handwritten input
HK1060428A1 (en) Method for converting a music signal into a note-based description and for referencing a music signal in a data bank.
MXPA02006664A (es) Laminado de un substrato y una capa extruida de polietileno de alta densidad.
BR9917353A (pt) Processos para a polimerização de etileno e pelo menos uma ou mais olefina (s) para produzir um interpolìmero de etileno/olefina, e para reduzir a temperatura de pico de fusão de um interpolìmero etileno/olefina, produto de interpolìmero etileno/olefina, filme, e, artigo
BR9917242A (pt) Processos para polimerização de olefina e/ouolefina e pelo menos uma ou mais outra (s) olefina(s), e para redução da carga eletrostática geradana polimerização de olefina e/ou olefina e pelomenos uma ou mais outra (s) olefina (s), filme, e,artigo
BRPI0410508A (pt) processos de contato de 1,3-propanodiol e de um 1,3-propanodiol derivado bioquimicamente com um catalisador de polimerização, composição que compreende: 1,3-propanodiol e politrimetileno éter glicol
KR920009923A (ko) 폴리에스테르 필름
BR0017020A (pt) Processo de polimerização
BR0115982A (pt) Método de suporte catalisador e polimerização com catalisadores suportados
BR9917239A (pt) Processos para polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s) e para redução da carga eletrostática gerada na polimerização de uma olefina e/ou uma olefina e pelo menos uma ou mais outra (s) olefina (s)
ES2088633T3 (es) Estabilizantes polisiloxanicos que contienen grupos fenol y grupos oxamidicos estericamente impedidos.
KR920007956A (ko) 선형 α-올레핀의 제조방법
BR9917467A (pt) Processos para a polimerização e para reduzir a carga eletrostática na polimerização de uma olefina e/ ou uma olefina e pelo menos uma ou mais outra(s) olefina(s), filme, e, artigo
BR9915952A (pt) Processo para produzir aglomerados com uma estrutura núcleo/casca, e, aglomerado com uma estreutura núcleo/casca
BR9807921A (pt) Sistema de catalisador para sìntese de alto rendimento de poliolefinas.
ES2061474T3 (es) Fibras de elastano altamente dilatables con propiedades mejoradas.

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 18/10/2011, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved
B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 18.10.2021