MXPA01009834A - Proceso para producir poliolefinas. - Google Patents
Proceso para producir poliolefinas.Info
- Publication number
- MXPA01009834A MXPA01009834A MXPA01009834A MXPA01009834A MXPA01009834A MX PA01009834 A MXPA01009834 A MX PA01009834A MX PA01009834 A MXPA01009834 A MX PA01009834A MX PA01009834 A MXPA01009834 A MX PA01009834A MX PA01009834 A MXPA01009834 A MX PA01009834A
- Authority
- MX
- Mexico
- Prior art keywords
- ether
- catalysts
- olefin
- process according
- catalyst
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 67
- 230000008569 process Effects 0.000 title claims abstract description 62
- 229920000098 polyolefin Polymers 0.000 title description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 150
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 94
- 150000001336 alkenes Chemical class 0.000 claims abstract description 76
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 32
- 229920001519 homopolymer Polymers 0.000 claims abstract description 8
- LTIPUQSMGRSZOQ-UHFFFAOYSA-N [C].[C].[O] Chemical compound [C].[C].[O] LTIPUQSMGRSZOQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims description 91
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 72
- 239000010936 titanium Substances 0.000 claims description 59
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 53
- 229910052719 titanium Inorganic materials 0.000 claims description 53
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 41
- 229920000642 polymer Polymers 0.000 claims description 24
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- 230000000737 periodic effect Effects 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 125000002091 cationic group Chemical group 0.000 claims description 15
- 150000008282 halocarbons Chemical class 0.000 claims description 15
- 239000012968 metallocene catalyst Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 125000004122 cyclic group Chemical group 0.000 claims description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 9
- 125000005842 heteroatom Chemical group 0.000 claims description 9
- 125000003367 polycyclic group Chemical group 0.000 claims description 9
- 229910052726 zirconium Inorganic materials 0.000 claims description 9
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 8
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 238000009826 distribution Methods 0.000 claims description 7
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 6
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 6
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 6
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 5
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 39
- 150000001875 compounds Chemical class 0.000 description 39
- -1 polyethylene Polymers 0.000 description 39
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 35
- 239000005977 Ethylene Substances 0.000 description 34
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 30
- 239000004698 Polyethylene Substances 0.000 description 23
- 229920000573 polyethylene Polymers 0.000 description 23
- 229910052723 transition metal Inorganic materials 0.000 description 19
- 150000003624 transition metals Chemical class 0.000 description 19
- 239000002245 particle Substances 0.000 description 18
- 239000000377 silicon dioxide Substances 0.000 description 17
- 239000007789 gas Substances 0.000 description 16
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 14
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 12
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 12
- 125000002524 organometallic group Chemical group 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 11
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000005243 fluidization Methods 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 6
- 229910052796 boron Inorganic materials 0.000 description 6
- 150000001639 boron compounds Chemical group 0.000 description 6
- 239000000969 carrier Substances 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- GSNUFIFRDBKVIE-UHFFFAOYSA-N 2,5-dimethylfuran Chemical compound CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000012685 gas phase polymerization Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 5
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- ARGCQEVBJHPOGB-UHFFFAOYSA-N 2,5-dihydrofuran Chemical compound C1OCC=C1 ARGCQEVBJHPOGB-UHFFFAOYSA-N 0.000 description 4
- OXMIDRBAFOEOQT-UHFFFAOYSA-N 2,5-dimethyloxolane Chemical compound CC1CCC(C)O1 OXMIDRBAFOEOQT-UHFFFAOYSA-N 0.000 description 4
- VQKFNUFAXTZWDK-UHFFFAOYSA-N 2-Methylfuran Chemical compound CC1=CC=CO1 VQKFNUFAXTZWDK-UHFFFAOYSA-N 0.000 description 4
- HLPIHRDZBHXTFJ-UHFFFAOYSA-N 2-ethylfuran Chemical compound CCC1=CC=CO1 HLPIHRDZBHXTFJ-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 150000002902 organometallic compounds Chemical class 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000004846 x-ray emission Methods 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- DYOZNCVZPFIXLU-UHFFFAOYSA-N 1,1,2-trimethoxyethane Chemical compound COCC(OC)OC DYOZNCVZPFIXLU-UHFFFAOYSA-N 0.000 description 2
- FKZYYYDRLJCHGL-UHFFFAOYSA-N 1,1,3-trimethoxypropane Chemical compound COCCC(OC)OC FKZYYYDRLJCHGL-UHFFFAOYSA-N 0.000 description 2
- LEEANUDEDHYDTG-UHFFFAOYSA-N 1,2-dimethoxypropane Chemical compound COCC(C)OC LEEANUDEDHYDTG-UHFFFAOYSA-N 0.000 description 2
- FKASFBLJDCHBNZ-UHFFFAOYSA-N 1,3,4-oxadiazole Chemical compound C1=NN=CO1 FKASFBLJDCHBNZ-UHFFFAOYSA-N 0.000 description 2
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 2
- GMDAODGCWAPRJE-UHFFFAOYSA-N 1,3-dimethoxybenzene;1,4-dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1.COC1=CC=CC(OC)=C1 GMDAODGCWAPRJE-UHFFFAOYSA-N 0.000 description 2
- FMHAUDKGLSPVPQ-UHFFFAOYSA-N 1,3-dioxane;1,4-dioxane Chemical compound C1COCOC1.C1COCCO1 FMHAUDKGLSPVPQ-UHFFFAOYSA-N 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 2
- HMCUNLUHTBHKTB-UHFFFAOYSA-N 1,4-dimethoxybutane Chemical compound COCCCCOC HMCUNLUHTBHKTB-UHFFFAOYSA-N 0.000 description 2
- GZGPRZYZKBQPBQ-UHFFFAOYSA-N 1,4-dioxaspiro[4.5]decane Chemical compound O1CCOC11CCCCC1 GZGPRZYZKBQPBQ-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- CXBDYQVECUFKRK-UHFFFAOYSA-N 1-methoxybutane Chemical compound CCCCOC CXBDYQVECUFKRK-UHFFFAOYSA-N 0.000 description 2
- ARNKHYQYAZLEEP-UHFFFAOYSA-N 1-naphthalen-1-yloxynaphthalene Chemical compound C1=CC=C2C(OC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 ARNKHYQYAZLEEP-UHFFFAOYSA-N 0.000 description 2
- DJMUYABFXCIYSC-UHFFFAOYSA-N 1H-phosphole Chemical class C=1C=CPC=1 DJMUYABFXCIYSC-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- HEWZVZIVELJPQZ-UHFFFAOYSA-N 2,2-dimethoxypropane Chemical compound COC(C)(C)OC HEWZVZIVELJPQZ-UHFFFAOYSA-N 0.000 description 2
- SIJBDWPVNAYVGY-UHFFFAOYSA-N 2,2-dimethyl-1,3-dioxolane Chemical compound CC1(C)OCCO1 SIJBDWPVNAYVGY-UHFFFAOYSA-N 0.000 description 2
- HBEDSQVIWPRPAY-UHFFFAOYSA-N 2,3-dihydrobenzofuran Chemical compound C1=CC=C2OCCC2=C1 HBEDSQVIWPRPAY-UHFFFAOYSA-N 0.000 description 2
- JKTCBAGSMQIFNL-UHFFFAOYSA-N 2,3-dihydrofuran Chemical compound C1CC=CO1 JKTCBAGSMQIFNL-UHFFFAOYSA-N 0.000 description 2
- ZSVKDSDYRMOCFH-UHFFFAOYSA-N 2-(1,2-dibromoethyl)oxirane Chemical compound BrCC(Br)C1CO1 ZSVKDSDYRMOCFH-UHFFFAOYSA-N 0.000 description 2
- MJJRDTKNLLMJDJ-UHFFFAOYSA-N 2-methoxy-1,3-thiazole Chemical compound COC1=NC=CS1 MJJRDTKNLLMJDJ-UHFFFAOYSA-N 0.000 description 2
- FVNIMHIOIXPIQT-UHFFFAOYSA-N 2-methoxybutane Chemical compound CCC(C)OC FVNIMHIOIXPIQT-UHFFFAOYSA-N 0.000 description 2
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 2
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 2
- AIUTZIYTEUMXGG-UHFFFAOYSA-N 3,6-dioxabicyclo[3.1.0]hexane Chemical compound C1OCC2OC12 AIUTZIYTEUMXGG-UHFFFAOYSA-N 0.000 description 2
- HZAFQFFHXOLHFO-UHFFFAOYSA-N 3-methoxy-1,2-thiazole Chemical compound COC=1C=CSN=1 HZAFQFFHXOLHFO-UHFFFAOYSA-N 0.000 description 2
- VMMAQHURVWNQOM-UHFFFAOYSA-N 3-methoxyfuran Chemical compound COC=1C=COC=1 VMMAQHURVWNQOM-UHFFFAOYSA-N 0.000 description 2
- LWMDPZVQAMQFOC-UHFFFAOYSA-N 4-butylpyridine Chemical compound CCCCC1=CC=NC=C1 LWMDPZVQAMQFOC-UHFFFAOYSA-N 0.000 description 2
- FSSNZZBDEOYMMZ-UHFFFAOYSA-N 4-chloro-1h-pyrrolo[2,3-b]pyridin-5-ol Chemical compound OC1=CN=C2NC=CC2=C1Cl FSSNZZBDEOYMMZ-UHFFFAOYSA-N 0.000 description 2
- GJEZBVHHZQAEDB-UHFFFAOYSA-N 6-oxabicyclo[3.1.0]hexane Chemical compound C1CCC2OC21 GJEZBVHHZQAEDB-UHFFFAOYSA-N 0.000 description 2
- AQLZCGLPNYEIDH-UHFFFAOYSA-N C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(C=1C=CC=CC=1)O[Cr](=O)(=O)O[Si](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(C=1C=CC=CC=1)O[Cr](=O)(=O)O[Si](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 AQLZCGLPNYEIDH-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- XJUZRXYOEPSWMB-UHFFFAOYSA-N Chloromethyl methyl ether Chemical compound COCCl XJUZRXYOEPSWMB-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229940061627 chloromethyl methyl ether Drugs 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 2
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- KGPPDNUWZNWPSI-UHFFFAOYSA-N flurotyl Chemical compound FC(F)(F)COCC(F)(F)F KGPPDNUWZNWPSI-UHFFFAOYSA-N 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229920006178 high molecular weight high density polyethylene Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- SKTCDJAMAYNROS-UHFFFAOYSA-N methoxycyclopentane Chemical compound COC1CCCC1 SKTCDJAMAYNROS-UHFFFAOYSA-N 0.000 description 2
- PPNQXAYCPNTVHH-UHFFFAOYSA-N methoxymethyl(trimethyl)silane Chemical compound COC[Si](C)(C)C PPNQXAYCPNTVHH-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical class [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 150000003233 pyrroles Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- HVZJRWJGKQPSFL-UHFFFAOYSA-N tert-Amyl methyl ether Chemical compound CCC(C)(C)OC HVZJRWJGKQPSFL-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraethylene glycol dimethyl ether Natural products COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- PONDNGVOQLIOBT-UHFFFAOYSA-N trimethyl(trimethylsilylmethoxymethyl)silane Chemical compound C[Si](C)(C)COC[Si](C)(C)C PONDNGVOQLIOBT-UHFFFAOYSA-N 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 2
- 229960000834 vinyl ether Drugs 0.000 description 2
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 1
- XNWOINMNVLESRM-UHFFFAOYSA-N (3-bromo-2-chloropropoxy)methylbenzene Chemical compound BrCC(Cl)COCC1=CC=CC=C1 XNWOINMNVLESRM-UHFFFAOYSA-N 0.000 description 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- HDPNBNXLBDFELL-UHFFFAOYSA-N 1,1,1-trimethoxyethane Chemical compound COC(C)(OC)OC HDPNBNXLBDFELL-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- UIOXNNAWANDJCZ-UHFFFAOYSA-N 1,1-dimethoxypropane Chemical compound CCC(OC)OC UIOXNNAWANDJCZ-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- ZXHDVRATSGZISC-UHFFFAOYSA-N 1,2-bis(ethenoxy)ethane Chemical compound C=COCCOC=C ZXHDVRATSGZISC-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- UUAMLBIYJDPGFU-UHFFFAOYSA-N 1,3-dimethoxypropane Chemical compound COCCCOC UUAMLBIYJDPGFU-UHFFFAOYSA-N 0.000 description 1
- HWGXHIRIUHJDOE-UHFFFAOYSA-N 1,3-dioxolan-2-yl(trimethyl)silane Chemical compound C[Si](C)(C)C1OCCO1 HWGXHIRIUHJDOE-UHFFFAOYSA-N 0.000 description 1
- YSMVSEYPOBXSOK-UHFFFAOYSA-N 1,4,9,12-tetraoxadispiro[4.2.4^{8}.2^{5}]tetradecane Chemical compound O1CCOC11CCC2(OCCO2)CC1 YSMVSEYPOBXSOK-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- ATFWVBMLTLPOHI-UHFFFAOYSA-N 1,4-dioxaspiro[4.4]non-8-ene Chemical compound O1CCOC11C=CCC1 ATFWVBMLTLPOHI-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- GBBVHDGKDQAEOT-UHFFFAOYSA-N 1,7-dioxaspiro[5.5]undecane Chemical compound O1CCCCC11OCCCC1 GBBVHDGKDQAEOT-UHFFFAOYSA-N 0.000 description 1
- OJMVRGXLTANFRG-UHFFFAOYSA-N 1-(2-chloroethoxy)butane Chemical compound CCCCOCCCl OJMVRGXLTANFRG-UHFFFAOYSA-N 0.000 description 1
- UPVYLEZRQICNRY-UHFFFAOYSA-N 1-(bromomethoxy)-2-(chloromethoxy)ethane Chemical compound ClCOCCOCBr UPVYLEZRQICNRY-UHFFFAOYSA-N 0.000 description 1
- OSIGJGFTADMDOB-UHFFFAOYSA-N 1-Methoxy-3-methylbenzene Chemical compound COC1=CC=CC(C)=C1 OSIGJGFTADMDOB-UHFFFAOYSA-N 0.000 description 1
- HPFWUWXYBFOJAD-UHFFFAOYSA-N 1-chloro-4-(1,3-dimethoxypropan-2-yl)benzene Chemical compound COCC(COC)C1=CC=C(Cl)C=C1 HPFWUWXYBFOJAD-UHFFFAOYSA-N 0.000 description 1
- JWMKUKRBNODZFA-UHFFFAOYSA-N 1-ethoxy-2-methylbenzene Chemical compound CCOC1=CC=CC=C1C JWMKUKRBNODZFA-UHFFFAOYSA-N 0.000 description 1
- UALKQROXOHJHFG-UHFFFAOYSA-N 1-ethoxy-3-methylbenzene Chemical compound CCOC1=CC=CC(C)=C1 UALKQROXOHJHFG-UHFFFAOYSA-N 0.000 description 1
- PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 description 1
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- WZGYJLJMTYSGCS-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-3,3-dimethylbutane Chemical compound COCC(C(C)(C)C)COC WZGYJLJMTYSGCS-UHFFFAOYSA-N 0.000 description 1
- PPHMKLXXVBJEHR-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)hexane Chemical compound CCCCC(COC)COC PPHMKLXXVBJEHR-UHFFFAOYSA-N 0.000 description 1
- NQMUGNMMFTYOHK-UHFFFAOYSA-N 1-methoxynaphthalene Chemical compound C1=CC=C2C(OC)=CC=CC2=C1 NQMUGNMMFTYOHK-UHFFFAOYSA-N 0.000 description 1
- CYXMOAZSOPXQOD-UHFFFAOYSA-N 1-methyl-2-(2-methylphenoxy)benzene Chemical compound CC1=CC=CC=C1OC1=CC=CC=C1C CYXMOAZSOPXQOD-UHFFFAOYSA-N 0.000 description 1
- JEVKYCOVKKYWNL-UHFFFAOYSA-N 1-methyl-2-phenylmethoxybenzene Chemical compound CC1=CC=CC=C1OCC1=CC=CC=C1 JEVKYCOVKKYWNL-UHFFFAOYSA-N 0.000 description 1
- LQOGVESOGIHDSO-UHFFFAOYSA-N 1-methyl-2-prop-2-enoxybenzene Chemical compound CC1=CC=CC=C1OCC=C LQOGVESOGIHDSO-UHFFFAOYSA-N 0.000 description 1
- FDLFMPKQBNPIER-UHFFFAOYSA-N 1-methyl-3-(3-methylphenoxy)benzene Chemical compound CC1=CC=CC(OC=2C=C(C)C=CC=2)=C1 FDLFMPKQBNPIER-UHFFFAOYSA-N 0.000 description 1
- FRQUHSBKTAMSDF-UHFFFAOYSA-N 1-methyl-3-phenylmethoxybenzene Chemical compound CC1=CC=CC(OCC=2C=CC=CC=2)=C1 FRQUHSBKTAMSDF-UHFFFAOYSA-N 0.000 description 1
- AOPDRZXCEAKHHW-UHFFFAOYSA-N 1-pentoxypentane Chemical compound CCCCCOCCCCC AOPDRZXCEAKHHW-UHFFFAOYSA-N 0.000 description 1
- JWSWULLEVAMIJK-UHFFFAOYSA-N 1-phenylmethoxynaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1OCC1=CC=CC=C1 JWSWULLEVAMIJK-UHFFFAOYSA-N 0.000 description 1
- YNYMCUPQXZBCJN-UHFFFAOYSA-N 1-prop-2-enoxynaphthalene Chemical compound C1=CC=C2C(OCC=C)=CC=CC2=C1 YNYMCUPQXZBCJN-UHFFFAOYSA-N 0.000 description 1
- XQQZRZQVBFHBHL-UHFFFAOYSA-N 12-crown-4 Chemical compound C1COCCOCCOCCO1 XQQZRZQVBFHBHL-UHFFFAOYSA-N 0.000 description 1
- VFTFKUDGYRBSAL-UHFFFAOYSA-N 15-crown-5 Chemical compound C1COCCOCCOCCOCCO1 VFTFKUDGYRBSAL-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- FJSKXQVRKZTKSI-UHFFFAOYSA-N 2,3-dimethylfuran Chemical compound CC=1C=COC=1C FJSKXQVRKZTKSI-UHFFFAOYSA-N 0.000 description 1
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 1
- BGCSUUSPRCDKBQ-UHFFFAOYSA-N 2,4,8,10-tetraoxaspiro[5.5]undecane Chemical compound C1OCOCC21COCOC2 BGCSUUSPRCDKBQ-UHFFFAOYSA-N 0.000 description 1
- KXZIBRUIJDEWKY-UHFFFAOYSA-N 2,5-dimethoxyfuran Chemical compound COC1=CC=C(OC)O1 KXZIBRUIJDEWKY-UHFFFAOYSA-N 0.000 description 1
- UKXROSORAUTSSH-UHFFFAOYSA-N 2-(1,2-dichloroethyl)oxirane Chemical compound ClCC(Cl)C1CO1 UKXROSORAUTSSH-UHFFFAOYSA-N 0.000 description 1
- YIBYCVPCWUSPQY-UHFFFAOYSA-N 2-(1,3-dimethoxypropyl)-1,1-dimethylcyclohexane Chemical compound COCCC(OC)C1CCCCC1(C)C YIBYCVPCWUSPQY-UHFFFAOYSA-N 0.000 description 1
- NUNQKTCKURIZQX-UHFFFAOYSA-N 2-(2-ethoxyethoxy)-2-methylpropane Chemical compound CCOCCOC(C)(C)C NUNQKTCKURIZQX-UHFFFAOYSA-N 0.000 description 1
- ACQKBWRMZFJKMZ-UHFFFAOYSA-N 2-(2-ethoxyethyl)thiophene Chemical compound CCOCCC1=CC=CS1 ACQKBWRMZFJKMZ-UHFFFAOYSA-N 0.000 description 1
- FQQBAHSCHMASLR-UHFFFAOYSA-N 2-(2-methoxyethoxy)-2-methylpropane Chemical compound COCCOC(C)(C)C FQQBAHSCHMASLR-UHFFFAOYSA-N 0.000 description 1
- IKZOMJGRWIOEDP-UHFFFAOYSA-N 2-(chloromethyl)-1,3-dioxolane Chemical compound ClCC1OCCO1 IKZOMJGRWIOEDP-UHFFFAOYSA-N 0.000 description 1
- GUMOJENFFHZAFP-UHFFFAOYSA-N 2-Ethoxynaphthalene Chemical compound C1=CC=CC2=CC(OCC)=CC=C21 GUMOJENFFHZAFP-UHFFFAOYSA-N 0.000 description 1
- LUZDYPLAQQGJEA-UHFFFAOYSA-N 2-Methoxynaphthalene Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 description 1
- GBGPVUAOTCNZPT-UHFFFAOYSA-N 2-Methylcumarone Chemical compound C1=CC=C2OC(C)=CC2=C1 GBGPVUAOTCNZPT-UHFFFAOYSA-N 0.000 description 1
- OTTSGPIUFORUOT-UHFFFAOYSA-N 2-bromo-2-(chloromethyl)-1,3-dioxolane Chemical compound ClCC1(Br)OCCO1 OTTSGPIUFORUOT-UHFFFAOYSA-N 0.000 description 1
- KBMDBLCFKPRPOC-UHFFFAOYSA-N 2-bromo-3,3,3-trifluoro-2-(trifluoromethyl)propanenitrile Chemical compound FC(F)(F)C(Br)(C#N)C(F)(F)F KBMDBLCFKPRPOC-UHFFFAOYSA-N 0.000 description 1
- ZHIRCUMWABPTME-UHFFFAOYSA-N 2-ethenylbicyclo[2.2.1]hept-4-ene Chemical compound C1C(C2)C(C=C)CC2=C1 ZHIRCUMWABPTME-UHFFFAOYSA-N 0.000 description 1
- ZKNSBWFYINLEFE-UHFFFAOYSA-N 2-ethoxy-1-methylpyrrole Chemical compound CCOC1=CC=CN1C ZKNSBWFYINLEFE-UHFFFAOYSA-N 0.000 description 1
- KFRVYYGHSPLXSZ-UHFFFAOYSA-N 2-ethoxy-2-methylbutane Chemical compound CCOC(C)(C)CC KFRVYYGHSPLXSZ-UHFFFAOYSA-N 0.000 description 1
- FHUFFVIITDISHQ-UHFFFAOYSA-N 2-ethoxyfuran Chemical compound CCOC1=CC=CO1 FHUFFVIITDISHQ-UHFFFAOYSA-N 0.000 description 1
- VYDVLDNLTSOBLM-UHFFFAOYSA-N 2-ethoxythiophene Chemical compound CCOC1=CC=CS1 VYDVLDNLTSOBLM-UHFFFAOYSA-N 0.000 description 1
- VLOCZPOGYIRFGH-UHFFFAOYSA-N 2-methoxy-1,3,4-oxadiazole Chemical compound COC1=NN=CO1 VLOCZPOGYIRFGH-UHFFFAOYSA-N 0.000 description 1
- PWEOTXCDKVNAFN-UHFFFAOYSA-N 2-methoxy-1,3-oxazole Chemical compound COC1=NC=CO1 PWEOTXCDKVNAFN-UHFFFAOYSA-N 0.000 description 1
- OKVDGQVSUDTBJI-UHFFFAOYSA-N 2-methoxy-1-methylimidazole Chemical compound COC1=NC=CN1C OKVDGQVSUDTBJI-UHFFFAOYSA-N 0.000 description 1
- HMGCMGQPPOJEPY-UHFFFAOYSA-N 2-methoxyethyl dimethyl borate Chemical compound COCCOB(OC)OC HMGCMGQPPOJEPY-UHFFFAOYSA-N 0.000 description 1
- MMVPRLPUYZBHQC-UHFFFAOYSA-N 2-methoxyethyl(diphenyl)phosphane Chemical compound C=1C=CC=CC=1P(CCOC)C1=CC=CC=C1 MMVPRLPUYZBHQC-UHFFFAOYSA-N 0.000 description 1
- OXCGHDNCMSOEBZ-UHFFFAOYSA-N 2-methoxyfuran Chemical compound COC1=CC=CO1 OXCGHDNCMSOEBZ-UHFFFAOYSA-N 0.000 description 1
- XTDKZSUYCXHXJM-UHFFFAOYSA-N 2-methoxyoxane Chemical compound COC1CCCCO1 XTDKZSUYCXHXJM-UHFFFAOYSA-N 0.000 description 1
- KAEFOGMKRPTOLL-UHFFFAOYSA-N 2-methoxypyridine;3-methoxypyridine Chemical compound COC1=CC=CN=C1.COC1=CC=CC=N1 KAEFOGMKRPTOLL-UHFFFAOYSA-N 0.000 description 1
- YLZYSVYZMDJYOT-UHFFFAOYSA-N 2-methoxypyrimidine Chemical compound COC1=NC=CC=N1 YLZYSVYZMDJYOT-UHFFFAOYSA-N 0.000 description 1
- DTFKRVXLBCAIOZ-UHFFFAOYSA-N 2-methylanisole Chemical compound COC1=CC=CC=C1C DTFKRVXLBCAIOZ-UHFFFAOYSA-N 0.000 description 1
- DZRLNYVDCIYXPG-UHFFFAOYSA-N 2-naphthalen-2-yloxynaphthalene Chemical compound C1=CC=CC2=CC(OC=3C=C4C=CC=CC4=CC=3)=CC=C21 DZRLNYVDCIYXPG-UHFFFAOYSA-N 0.000 description 1
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 1
- WLTCCDHHWYAMCG-UHFFFAOYSA-N 2-phenylmethoxynaphthalene Chemical compound C=1C=C2C=CC=CC2=CC=1OCC1=CC=CC=C1 WLTCCDHHWYAMCG-UHFFFAOYSA-N 0.000 description 1
- BGQBONSBNSNYIO-UHFFFAOYSA-N 2-tert-butylfuran Chemical compound CC(C)(C)C1=CC=CO1 BGQBONSBNSNYIO-UHFFFAOYSA-N 0.000 description 1
- VOJKCZSSUHBMKS-UHFFFAOYSA-N 2-thiophen-3-yl-1,3-dioxolane Chemical compound O1CCOC1C1=CSC=C1 VOJKCZSSUHBMKS-UHFFFAOYSA-N 0.000 description 1
- MGADZUXDNSDTHW-UHFFFAOYSA-N 2H-pyran Chemical compound C1OC=CC=C1 MGADZUXDNSDTHW-UHFFFAOYSA-N 0.000 description 1
- FJZBADSJNSFVDO-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,4-dimethylpentane Chemical compound COCC(C(C)C)(C(C)C)COC FJZBADSJNSFVDO-UHFFFAOYSA-N 0.000 description 1
- SKWKIEFIPVHTHJ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)pentane Chemical compound COCC(CC)(CC)COC SKWKIEFIPVHTHJ-UHFFFAOYSA-N 0.000 description 1
- RVGLUKRYMXEQAH-UHFFFAOYSA-N 3,3-dimethyloxetane Chemical compound CC1(C)COC1 RVGLUKRYMXEQAH-UHFFFAOYSA-N 0.000 description 1
- WAHDOBRAAIQNTA-UHFFFAOYSA-N 3,5-dimethoxypentylcyclohexane Chemical compound COCCC(OC)CCC1CCCCC1 WAHDOBRAAIQNTA-UHFFFAOYSA-N 0.000 description 1
- GDBOOQVYVVYMJW-UHFFFAOYSA-N 3-(2-ethoxyethyl)thiophene Chemical compound CCOCCC=1C=CSC=1 GDBOOQVYVVYMJW-UHFFFAOYSA-N 0.000 description 1
- JLDQCXLYQKOVLK-UHFFFAOYSA-N 3-(2-methoxyethyl)thiophene Chemical compound COCCC=1C=CSC=1 JLDQCXLYQKOVLK-UHFFFAOYSA-N 0.000 description 1
- LXWLEQZDXOQZGW-UHFFFAOYSA-N 3-bromofuran Chemical compound BrC=1C=COC=1 LXWLEQZDXOQZGW-UHFFFAOYSA-N 0.000 description 1
- LILWQPNIQCTSCE-UHFFFAOYSA-N 3-methoxy-1,2,4-oxadiazole Chemical compound COC=1N=CON=1 LILWQPNIQCTSCE-UHFFFAOYSA-N 0.000 description 1
- STMNOIJVSYNGTL-UHFFFAOYSA-N 3-methoxy-1,2,4-triazine Chemical compound COC1=NC=CN=N1 STMNOIJVSYNGTL-UHFFFAOYSA-N 0.000 description 1
- HFBFCQCSROAYNJ-UHFFFAOYSA-N 3-methoxy-1,2-oxazole Chemical compound COC=1C=CON=1 HFBFCQCSROAYNJ-UHFFFAOYSA-N 0.000 description 1
- ACKDIBSCTPBCRK-UHFFFAOYSA-N 3-methoxy-1-methyl-1,2,4-triazole Chemical compound COC=1N=CN(C)N=1 ACKDIBSCTPBCRK-UHFFFAOYSA-N 0.000 description 1
- NSLWGDABVLNWBH-UHFFFAOYSA-N 3-methoxy-1-methylpyrazole Chemical compound COC=1C=CN(C)N=1 NSLWGDABVLNWBH-UHFFFAOYSA-N 0.000 description 1
- XKPJHAIHUITWTN-UHFFFAOYSA-N 3-methoxy-1-methylpyrrolidin-2-one Chemical compound COC1CCN(C)C1=O XKPJHAIHUITWTN-UHFFFAOYSA-N 0.000 description 1
- XJAMGLKODPECAO-UHFFFAOYSA-N 3-methoxy-1-phenyl-1,2,4-triazole Chemical compound N1=C(OC)N=CN1C1=CC=CC=C1 XJAMGLKODPECAO-UHFFFAOYSA-N 0.000 description 1
- UGRATGHCUZKFJX-UHFFFAOYSA-N 3-methoxy-1-phenylpyrazole Chemical compound N1=C(OC)C=CN1C1=CC=CC=C1 UGRATGHCUZKFJX-UHFFFAOYSA-N 0.000 description 1
- IMFUYFMQPRBIED-UHFFFAOYSA-N 3-methoxyoxane Chemical compound COC1CCCOC1 IMFUYFMQPRBIED-UHFFFAOYSA-N 0.000 description 1
- FASUFOTUSHAIHG-UHFFFAOYSA-N 3-methoxyprop-1-ene Chemical compound COCC=C FASUFOTUSHAIHG-UHFFFAOYSA-N 0.000 description 1
- ASFHDLDAWYTMJS-UHFFFAOYSA-N 3-methoxypyridazine Chemical compound COC1=CC=CN=N1 ASFHDLDAWYTMJS-UHFFFAOYSA-N 0.000 description 1
- RFSKGCVUDQRZSD-UHFFFAOYSA-N 3-methoxythiophene Chemical compound COC=1C=CSC=1 RFSKGCVUDQRZSD-UHFFFAOYSA-N 0.000 description 1
- RXXCIBALSKQCAE-UHFFFAOYSA-N 3-methylbutoxymethylbenzene Chemical compound CC(C)CCOCC1=CC=CC=C1 RXXCIBALSKQCAE-UHFFFAOYSA-N 0.000 description 1
- UJQZTMFRMLEYQN-UHFFFAOYSA-N 3-methyloxane Chemical compound CC1CCCOC1 UJQZTMFRMLEYQN-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
- UNDXPKDBFOOQFC-UHFFFAOYSA-N 4-[2-nitro-4-(trifluoromethyl)phenyl]morpholine Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=CC=C1N1CCOCC1 UNDXPKDBFOOQFC-UHFFFAOYSA-N 0.000 description 1
- DHRSKOBIDIDMJZ-UHFFFAOYSA-N 4-chlorooxane Chemical compound ClC1CCOCC1 DHRSKOBIDIDMJZ-UHFFFAOYSA-N 0.000 description 1
- FVNGVMJVRRBIQU-UHFFFAOYSA-N 4-cyclopent-3-en-1-yloxycyclopentene Chemical compound C1C=CCC1OC1CC=CC1 FVNGVMJVRRBIQU-UHFFFAOYSA-N 0.000 description 1
- VIJVFTUOJNTXCA-UHFFFAOYSA-N 4-ethyl-1-methoxy-2-(methoxymethyl)octane Chemical compound CCCCC(CC)CC(COC)COC VIJVFTUOJNTXCA-UHFFFAOYSA-N 0.000 description 1
- VGPMYTSIYXMWIT-UHFFFAOYSA-N 4-methoxy-1,2-oxazole Chemical compound COC=1C=NOC=1 VGPMYTSIYXMWIT-UHFFFAOYSA-N 0.000 description 1
- FEQZWMASISDUHM-UHFFFAOYSA-N 4-methoxy-1,2-thiazole Chemical compound COC=1C=NSC=1 FEQZWMASISDUHM-UHFFFAOYSA-N 0.000 description 1
- GJKXGXUYBNNXIQ-UHFFFAOYSA-N 4-methoxy-1,3-oxazole Chemical compound COC1=COC=N1 GJKXGXUYBNNXIQ-UHFFFAOYSA-N 0.000 description 1
- GLCMZDPRGOZERZ-UHFFFAOYSA-N 4-methoxy-1,3-thiazole Chemical compound COC1=CSC=N1 GLCMZDPRGOZERZ-UHFFFAOYSA-N 0.000 description 1
- LPDDIVRSCAXDIN-UHFFFAOYSA-N 4-methoxy-1-methylimidazole Chemical compound COC1=CN(C)C=N1 LPDDIVRSCAXDIN-UHFFFAOYSA-N 0.000 description 1
- PMCGMKDQOXUILW-UHFFFAOYSA-N 4-methoxy-1-methylpyrazole Chemical compound COC=1C=NN(C)C=1 PMCGMKDQOXUILW-UHFFFAOYSA-N 0.000 description 1
- SAGIWDIBMDGDRV-UHFFFAOYSA-N 4-methoxy-1-phenylimidazole Chemical compound C1=NC(OC)=CN1C1=CC=CC=C1 SAGIWDIBMDGDRV-UHFFFAOYSA-N 0.000 description 1
- RMJOXJPPJVLIGN-UHFFFAOYSA-N 4-methoxy-1-phenyltriazole Chemical compound N1=NC(OC)=CN1C1=CC=CC=C1 RMJOXJPPJVLIGN-UHFFFAOYSA-N 0.000 description 1
- YOMUZHDQFPQJEO-UHFFFAOYSA-N 4-methoxy-2h-triazole Chemical compound COC1=CN=NN1 YOMUZHDQFPQJEO-UHFFFAOYSA-N 0.000 description 1
- XQABVLBGNWBWIV-UHFFFAOYSA-N 4-methoxypyridine Chemical compound COC1=CC=NC=C1 XQABVLBGNWBWIV-UHFFFAOYSA-N 0.000 description 1
- PENVYHXKYYCYML-UHFFFAOYSA-N 4-methoxypyrimidine Chemical compound COC1=CC=NC=N1 PENVYHXKYYCYML-UHFFFAOYSA-N 0.000 description 1
- 239000004915 4-vinylcyclohex-1-ene Substances 0.000 description 1
- OKWSRUUMYHQAJG-UHFFFAOYSA-N 5-methoxy-1,2,4-oxadiazole Chemical compound COC1=NC=NO1 OKWSRUUMYHQAJG-UHFFFAOYSA-N 0.000 description 1
- GGQZKDXGZUMYSS-UHFFFAOYSA-N 5-methoxy-1,2-oxazole Chemical compound COC1=CC=NO1 GGQZKDXGZUMYSS-UHFFFAOYSA-N 0.000 description 1
- HNYHDLOJKVORSF-UHFFFAOYSA-N 5-methoxy-1,3-oxazole Chemical compound COC1=CN=CO1 HNYHDLOJKVORSF-UHFFFAOYSA-N 0.000 description 1
- AKQZOFSZTDDLNF-UHFFFAOYSA-N 5-methoxy-1-methylimidazole Chemical compound COC1=CN=CN1C AKQZOFSZTDDLNF-UHFFFAOYSA-N 0.000 description 1
- HQBVPKRARNRSQY-UHFFFAOYSA-N 5-methoxy-1-methylpyrazole Chemical compound COC1=CC=NN1C HQBVPKRARNRSQY-UHFFFAOYSA-N 0.000 description 1
- MHGOXBMKKQBEFK-UHFFFAOYSA-N 5-methoxy-1-methyltriazole Chemical compound COC1=CN=NN1C MHGOXBMKKQBEFK-UHFFFAOYSA-N 0.000 description 1
- XUACVJSMJFUHDV-UHFFFAOYSA-N 5-methoxy-1-phenyl-1,2,4-triazole Chemical compound COC1=NC=NN1C1=CC=CC=C1 XUACVJSMJFUHDV-UHFFFAOYSA-N 0.000 description 1
- DHNBFWMDEOYMTP-UHFFFAOYSA-N 5-methoxy-1-phenylimidazole Chemical compound COC1=CN=CN1C1=CC=CC=C1 DHNBFWMDEOYMTP-UHFFFAOYSA-N 0.000 description 1
- GZYUMEHIMWDNCK-UHFFFAOYSA-N 5-methoxy-1-phenylpyrazole Chemical compound COC1=CC=NN1C1=CC=CC=C1 GZYUMEHIMWDNCK-UHFFFAOYSA-N 0.000 description 1
- FFZOWQYRBMFFND-UHFFFAOYSA-N 5-methoxy-1-phenyltriazole Chemical compound COC1=CN=NN1C1=CC=CC=C1 FFZOWQYRBMFFND-UHFFFAOYSA-N 0.000 description 1
- JIADELSANNMYFC-UHFFFAOYSA-N 5-methoxypyrimidine Chemical compound COC1=CN=CN=C1 JIADELSANNMYFC-UHFFFAOYSA-N 0.000 description 1
- BGCWDXXJMUHZHE-UHFFFAOYSA-N 5-methyl-2,3-dihydrofuran Chemical compound CC1=CCCO1 BGCWDXXJMUHZHE-UHFFFAOYSA-N 0.000 description 1
- ZIFWHOAXCZEGJL-UHFFFAOYSA-N 6-methoxy-1,2,4-triazine Chemical compound COC1=CN=CN=N1 ZIFWHOAXCZEGJL-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- UBRYTXBXMFSSFU-UHFFFAOYSA-N C(CCC)C1(C=C(C=C1)C)C1=C([C-](C=C1)C)C1(C=C(C=C1)C)CCCC.C[C-]1C=CC=C1.[Zr+2] Chemical compound C(CCC)C1(C=C(C=C1)C)C1=C([C-](C=C1)C)C1(C=C(C=C1)C)CCCC.C[C-]1C=CC=C1.[Zr+2] UBRYTXBXMFSSFU-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical compound FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical compound C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- WKSXRWSOSLGSTN-UHFFFAOYSA-N Methoxypyrazine Chemical compound COC1=CN=CC=N1 WKSXRWSOSLGSTN-UHFFFAOYSA-N 0.000 description 1
- QRBVCAWHUSTDOT-UHFFFAOYSA-N Methyridine Chemical compound COCCC1=CC=CC=N1 QRBVCAWHUSTDOT-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004965 Silica aerogel Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- ZVGIBQMBZHWERX-UHFFFAOYSA-N [2-(cyclohexylmethyl)-3-methoxy-2-(methoxymethyl)propyl]cyclohexane Chemical compound C1CCCCC1CC(COC)(COC)CC1CCCCC1 ZVGIBQMBZHWERX-UHFFFAOYSA-N 0.000 description 1
- GLYOPNLBKCBTMI-UHFFFAOYSA-N [2-chloro-2-(1-chloro-2-phenylethoxy)ethyl]benzene Chemical compound C=1C=CC=CC=1CC(Cl)OC(Cl)CC1=CC=CC=C1 GLYOPNLBKCBTMI-UHFFFAOYSA-N 0.000 description 1
- WVEZHRZEAFZJOI-UHFFFAOYSA-N [3-methoxy-2-(methoxymethyl)-1-phenylpropyl]benzene Chemical compound C=1C=CC=CC=1C(C(COC)COC)C1=CC=CC=C1 WVEZHRZEAFZJOI-UHFFFAOYSA-N 0.000 description 1
- JXQCBJLNEGKSCN-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)butyl]benzene Chemical compound COCC(COC)CCC1=CC=CC=C1 JXQCBJLNEGKSCN-UHFFFAOYSA-N 0.000 description 1
- OBOXTJCIIVUZEN-UHFFFAOYSA-N [C].[O] Chemical compound [C].[O] OBOXTJCIIVUZEN-UHFFFAOYSA-N 0.000 description 1
- OUOCWAGXUILNOJ-UHFFFAOYSA-L [Cl-].[Cl-].CCCCC1=CC(C)([Zr++])C=C1 Chemical compound [Cl-].[Cl-].CCCCC1=CC(C)([Zr++])C=C1 OUOCWAGXUILNOJ-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- QBQYLYUATVLBII-UHFFFAOYSA-N benzhydryloxymethylphosphane Chemical compound C=1C=CC=CC=1C(OCP)C1=CC=CC=C1 QBQYLYUATVLBII-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- LALHWYBLLSTBLQ-UHFFFAOYSA-N butoxycyclopentane Chemical compound CCCCOC1CCCC1 LALHWYBLLSTBLQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- FCYRSDMGOLYDHL-UHFFFAOYSA-N chloromethoxyethane Chemical compound CCOCCl FCYRSDMGOLYDHL-UHFFFAOYSA-N 0.000 description 1
- AFYPFACVUDMOHA-UHFFFAOYSA-N chlorotrifluoromethane Chemical compound FC(F)(F)Cl AFYPFACVUDMOHA-UHFFFAOYSA-N 0.000 description 1
- VZWXIQHBIQLMPN-UHFFFAOYSA-N chromane Chemical compound C1=CC=C2CCCOC2=C1 VZWXIQHBIQLMPN-UHFFFAOYSA-N 0.000 description 1
- TYYBBNOTQFVVKN-UHFFFAOYSA-N chromium(2+);cyclopenta-1,3-diene Chemical compound [Cr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 TYYBBNOTQFVVKN-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- NMGSDTSOSIPXTN-UHFFFAOYSA-N cyclohexa-1,2-diene Chemical compound C1CC=C=CC1 NMGSDTSOSIPXTN-UHFFFAOYSA-N 0.000 description 1
- OCDXZFSOHJRGIL-UHFFFAOYSA-N cyclohexyloxycyclohexane Chemical compound C1CCCCC1OC1CCCCC1 OCDXZFSOHJRGIL-UHFFFAOYSA-N 0.000 description 1
- IMCZVQCVSSWPCG-UHFFFAOYSA-N cyclohexyloxymethylbenzene Chemical compound C=1C=CC=CC=1COC1CCCCC1 IMCZVQCVSSWPCG-UHFFFAOYSA-N 0.000 description 1
- BOTLEXFFFSMRLQ-UHFFFAOYSA-N cyclopentyloxycyclopentane Chemical compound C1CCCC1OC1CCCC1 BOTLEXFFFSMRLQ-UHFFFAOYSA-N 0.000 description 1
- NUFBGJAEANEZKW-UHFFFAOYSA-N cyclopropyloxycyclopropane Chemical compound C1CC1OC1CC1 NUFBGJAEANEZKW-UHFFFAOYSA-N 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- KPWCAZGRCCYQMO-UHFFFAOYSA-N dimethoxy(2-methoxyethyl)borane Chemical compound COCCB(OC)OC KPWCAZGRCCYQMO-UHFFFAOYSA-N 0.000 description 1
- ZTAIFKMKUQTCRI-UHFFFAOYSA-N dioxido-(2,3,4,5,6-pentafluorophenoxy)borane;diphenylmethylbenzene Chemical compound [O-]B([O-])OC1=C(F)C(F)=C(F)C(F)=C1F.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 ZTAIFKMKUQTCRI-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000007786 electrostatic charging Methods 0.000 description 1
- 239000012156 elution solvent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- KXYFIGWXAKGWMU-UHFFFAOYSA-N ethyl 2-(4-methyl-2-sulfanylidene-3h-1,3-thiazol-5-yl)acetate Chemical compound CCOC(=O)CC=1SC(S)=NC=1C KXYFIGWXAKGWMU-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- HRWRZEKRKZRDRW-UHFFFAOYSA-N furan-2-yl(trimethyl)silane Chemical compound C[Si](C)(C)C1=CC=CO1 HRWRZEKRKZRDRW-UHFFFAOYSA-N 0.000 description 1
- UKWXFLCAYWYEBH-UHFFFAOYSA-N furan-3-yl(trimethyl)silane Chemical compound C[Si](C)(C)C=1C=COC=1 UKWXFLCAYWYEBH-UHFFFAOYSA-N 0.000 description 1
- HHULKZIJRRIEGR-UHFFFAOYSA-N furan-3-ylmethyl dimethyl borate Chemical compound COB(OC)OCC=1C=COC=1 HHULKZIJRRIEGR-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229910021480 group 4 element Inorganic materials 0.000 description 1
- 229910021476 group 6 element Inorganic materials 0.000 description 1
- 229910021472 group 8 element Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- HEBMCVBCEDMUOF-UHFFFAOYSA-N isochromane Chemical compound C1=CC=C2COCCC2=C1 HEBMCVBCEDMUOF-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 1
- KRXJIOWFEIOFOC-UHFFFAOYSA-N methoxymethyl dimethyl borate Chemical compound COCOB(OC)OC KRXJIOWFEIOFOC-UHFFFAOYSA-N 0.000 description 1
- GQKZBCPTCWJTAS-UHFFFAOYSA-N methoxymethylbenzene Chemical compound COCC1=CC=CC=C1 GQKZBCPTCWJTAS-UHFFFAOYSA-N 0.000 description 1
- JFZUABNDWZQLIJ-UHFFFAOYSA-N methyl 2-[(2-chloroacetyl)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1NC(=O)CCl JFZUABNDWZQLIJ-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 description 1
- BOTNYLSAWDQNEX-UHFFFAOYSA-N phenoxymethylbenzene Chemical compound C=1C=CC=CC=1COC1=CC=CC=C1 BOTNYLSAWDQNEX-UHFFFAOYSA-N 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 1
- HUGHWHMUUQNACD-UHFFFAOYSA-N prop-2-enoxymethylbenzene Chemical compound C=CCOCC1=CC=CC=C1 HUGHWHMUUQNACD-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- NUMQCACRALPSHD-UHFFFAOYSA-N tert-Butyl ethyl ether Natural products CCOC(C)(C)C NUMQCACRALPSHD-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 description 1
- UHLRRTRSNJHCGH-UHFFFAOYSA-N trimethyl-[2-(trimethylsilylmethoxy)ethoxymethyl]silane Chemical compound C[Si](C)(C)COCCOC[Si](C)(C)C UHLRRTRSNJHCGH-UHFFFAOYSA-N 0.000 description 1
- IYGPXXORQKFXCZ-UHFFFAOYSA-N tris(2-methoxyethyl) borate Chemical compound COCCOB(OCCOC)OCCOC IYGPXXORQKFXCZ-UHFFFAOYSA-N 0.000 description 1
- DLQYXUGCCKQSRJ-UHFFFAOYSA-N tris(furan-2-yl)phosphane Chemical compound C1=COC(P(C=2OC=CC=2)C=2OC=CC=2)=C1 DLQYXUGCCKQSRJ-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12690999P | 1999-03-30 | 1999-03-30 | |
| US09/387,599 US6313236B1 (en) | 1999-03-30 | 1999-08-31 | Process for producing polyolefins |
| PCT/US1999/023899 WO2000058373A1 (en) | 1999-03-30 | 1999-10-14 | Process for producing polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA01009834A true MXPA01009834A (es) | 2002-05-06 |
Family
ID=26825148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA01009834A MXPA01009834A (es) | 1999-03-30 | 1999-10-14 | Proceso para producir poliolefinas. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6313236B1 (enExample) |
| EP (1) | EP1169360B2 (enExample) |
| JP (1) | JP4699613B2 (enExample) |
| CN (1) | CN1159353C (enExample) |
| BR (1) | BR9917244B1 (enExample) |
| CA (1) | CA2368405A1 (enExample) |
| DE (1) | DE69934332T3 (enExample) |
| MX (1) | MXPA01009834A (enExample) |
| WO (1) | WO2000058373A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0027990D0 (en) | 2000-11-16 | 2001-01-03 | Bp Chemicals Snc | Polymerisation process |
| US6828395B1 (en) | 2003-10-15 | 2004-12-07 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
| US7238756B2 (en) * | 2003-10-15 | 2007-07-03 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
| WO2005113615A2 (en) * | 2004-05-20 | 2005-12-01 | Univation Technologies, Llc | Gas olefin polymerization process |
| US7683140B2 (en) * | 2004-05-20 | 2010-03-23 | Univation Technologies, Llc | Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring |
| US7754830B2 (en) | 2004-05-20 | 2010-07-13 | Univation Technologies, Llc | Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events |
| WO2006009980A2 (en) * | 2004-06-21 | 2006-01-26 | Exxonmobil Chemical Patents Inc. | Olefin polymerisation process |
| US7491776B2 (en) * | 2004-06-21 | 2009-02-17 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2006009981A1 (en) * | 2004-06-21 | 2006-01-26 | Exxonmobil Chemical Patents Inc. | Polymeriyation process and reactor system |
| CN101511877B (zh) * | 2006-09-07 | 2012-09-05 | 尤尼威蒂恩技术有限责任公司 | 由聚合反应监测产生的数据确定指示树脂粘附的温度值的方法 |
| CN101511882B (zh) * | 2006-09-07 | 2011-09-21 | 尤尼威蒂恩技术有限责任公司 | 使用降低熔融起始温度的模型在线测定树脂粘着性程度的方法 |
| EP2183290A1 (en) * | 2007-08-29 | 2010-05-12 | Basell Poliolefine Italia S.R.L. | Catalyst for the polymerization of olefins |
| CN101423573B (zh) * | 2007-10-31 | 2011-05-18 | 中国石油化工股份有限公司 | 管材用聚乙烯树脂和制备方法及其组合物 |
| US8087412B2 (en) | 2008-05-01 | 2012-01-03 | Ansell Healthcare Products Llc | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
| US10662269B2 (en) | 2017-08-31 | 2020-05-26 | Lifestyles Healthcare Pte. Ltd. | Ziegler-Natta catalyzed polyisoprene articles |
Family Cites Families (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| NO136797C (no) | 1970-09-25 | 1977-11-09 | Union Carbide Corp | Fremgangsm}te for polymerisering av etylen med modifisert katalysator |
| US4012573A (en) | 1970-10-09 | 1977-03-15 | Basf Aktiengesellschaft | Method of removing heat from polymerization reactions of monomers in the gas phase |
| US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| US4115639A (en) * | 1971-06-24 | 1978-09-19 | Union Carbide Corporation | Ethylene polymerization with ether modified catalyst |
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| US4243619A (en) * | 1978-03-31 | 1981-01-06 | Union Carbide Corporation | Process for making film from low density ethylene hydrocarbon copolymer |
| JPS55106203A (en) * | 1979-01-19 | 1980-08-14 | Showa Denko Kk | Preparation of ethylenic polymer |
| US4792592A (en) | 1981-03-26 | 1988-12-20 | Union Carbide Corporation | Process for reducing sheeting during polymerization of alpha-olefins |
| US4876320A (en) | 1981-03-26 | 1989-10-24 | Union Carbide Chemicals And Plastics Company Inc. | Process for reducing sheeting during polymerization of alpha-olefins |
| US4532311A (en) | 1981-03-26 | 1985-07-30 | Union Carbide Corporation | Process for reducing sheeting during polymerization of alpha-olefins |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| JPS59117508A (ja) | 1982-12-24 | 1984-07-06 | Mitsui Petrochem Ind Ltd | エチレンの重合法 |
| US5210161A (en) * | 1983-04-26 | 1993-05-11 | Phillips Petroleum Company | Supported vanadium dihalide-ether complex catalyst |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| JPS6067508A (ja) | 1983-09-22 | 1985-04-17 | Toa Nenryo Kogyo Kk | オレフインの重合方法 |
| US4564647A (en) | 1983-11-14 | 1986-01-14 | Idemitsu Kosan Company Limited | Process for the production of polyethylene compositions |
| CA1235543A (en) | 1984-09-12 | 1988-04-19 | Norio Kashiwa | Process for producing propylene block copolymer |
| US4701505A (en) * | 1984-09-26 | 1987-10-20 | Mitsubishi Petrochemical Company Limited | Process for production of olefin polymers |
| EP0197311B1 (en) | 1985-03-08 | 1991-12-18 | Mitsubishi Petrochemical Co., Ltd. | Process for polymerizing ethylene |
| US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| DE3600610A1 (de) * | 1986-01-11 | 1987-07-16 | Basf Ag | Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreaktoren |
| US4855370A (en) | 1986-10-01 | 1989-08-08 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US5026795A (en) | 1987-02-24 | 1991-06-25 | Phillips Petroleum Co | Process for preventing fouling in a gas phase polymerization reactor |
| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5780379A (en) | 1987-09-25 | 1998-07-14 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Process for the stereospecific polymerization of alpha-olefins and catalyst system which can be employed for this polymerization |
| US5034479A (en) | 1987-10-22 | 1991-07-23 | Union Carbide Chemicals And Plastics Technology Corporation | Process for reducing sheeting during polymerization of alpha-olefins |
| US4803251A (en) | 1987-11-04 | 1989-02-07 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US4831000A (en) | 1988-01-15 | 1989-05-16 | Mobil Oil Corporatiion | Catalyst composition for preparing high density or linear low density olefin polymers of controlled molecular weight distribution |
| FR2646426B2 (fr) | 1988-09-13 | 1991-08-16 | Bp Chemicals Sa | Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite |
| FR2640273B1 (fr) * | 1988-12-14 | 1992-09-04 | Atochem | Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire |
| DE69022937T2 (de) | 1989-09-11 | 1996-05-23 | Union Carbide Chem Plastic | Ethylen/Propylen/Ethylidennorbornenkautschuke. |
| US5106927A (en) | 1989-09-11 | 1992-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing ethylene/propylene/ethylidene norbornene rubbers |
| US5227440A (en) | 1989-09-13 | 1993-07-13 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
| FR2656315B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
| FR2660926B1 (fr) * | 1990-04-11 | 1992-07-31 | Bp Chemicals Snc | Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere. |
| DE69127220T2 (de) | 1990-04-13 | 1998-01-02 | Mitsui Petrochemical Ind | Festes Titan enthaltendes Katalysatorbestandteil und Katalysator für Olefinpolymerisation, vorpolymerisierte Olefinpolymerisationskatalysator und Verfahren für Olefinpolymerisation |
| US5726262A (en) | 1990-04-13 | 1998-03-10 | Mitsui Petrochemical Industries, Ltd. | Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization |
| AU643057B2 (en) | 1990-07-27 | 1993-11-04 | Nippon Petrochemicals Company Limited | Process for producing polyolefin |
| US5162463A (en) | 1990-12-10 | 1992-11-10 | Union Carbide Chemicals & Plastics Technology Corporation | Method for producing sticky polymers |
| US5200477A (en) | 1991-02-22 | 1993-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing sticky polymers |
| JP2759016B2 (ja) | 1991-03-29 | 1998-05-28 | シェブロン リサーチ アンド テクノロジー カンパニー | α−オレフィンを重合する触媒系および重合方法 |
| US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| CA2068939C (en) | 1991-05-20 | 1996-04-09 | Takashi Ueda | Olefin polymerization catalyst and olefin polymerization |
| FR2680793B1 (fr) * | 1991-08-30 | 1994-09-09 | Bp Chemicals Snc | Procede de fabrication d'un polymere de l'ethylene. |
| CA2082678C (en) | 1991-11-12 | 1996-07-30 | Naoki Kataoka | Catalyst components for polymerization of olefins |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5229076A (en) | 1992-05-08 | 1993-07-20 | Fagher Richard H | Method for reducing polymer build-up in a polymerization reactor |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5194526A (en) | 1992-07-30 | 1993-03-16 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing sticky polymers |
| JP3202349B2 (ja) | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| US5420220A (en) * | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
| JP3156213B2 (ja) | 1993-02-23 | 2001-04-16 | 日石三菱株式会社 | ポリオレフィンの製造方法 |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| CA2126796A1 (en) | 1993-06-28 | 1994-12-29 | Robert Converse Brade, Iii | Use of lewis bases for activity reduction in metallocene catalyzed olefin polymerization process |
| FR2707651B1 (fr) | 1993-07-13 | 1995-08-25 | Bp Chemicals Snc | Procédé pour augmenter l'activité d'un catalyseur de type Ziegler-Natta. |
| US5416175A (en) | 1993-12-17 | 1995-05-16 | Union Carbide Chemicals & Plastics Technology Corporation | Method for reducing sheeting during polymerization of α-olefins |
| CA2193410C (en) | 1994-06-24 | 2005-06-07 | George Allen Vaughn | Polymerization catalyst systems, their production and use |
| US5625012A (en) | 1994-06-29 | 1997-04-29 | Union Carbide Chemicals & Plastics Technology Corporation | Process for reducing polymer build-up in recycle lines and heat exchangers during polymerization of alpha olefins |
| US5468702A (en) | 1994-07-07 | 1995-11-21 | Exxon Chemical Patents Inc. | Method for making a catalyst system |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| DE19615953A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums |
| US5731392A (en) | 1996-09-20 | 1998-03-24 | Mobil Oil Company | Static control with TEOS |
| US5777120A (en) | 1997-03-14 | 1998-07-07 | University Of Iowa Research Foundation | Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts |
-
1999
- 1999-08-31 US US09/387,599 patent/US6313236B1/en not_active Expired - Lifetime
- 1999-10-14 EP EP99973800.8A patent/EP1169360B2/en not_active Expired - Lifetime
- 1999-10-14 BR BRPI9917244-5A patent/BR9917244B1/pt not_active IP Right Cessation
- 1999-10-14 MX MXPA01009834A patent/MXPA01009834A/es unknown
- 1999-10-14 DE DE69934332T patent/DE69934332T3/de not_active Expired - Lifetime
- 1999-10-14 JP JP2000608665A patent/JP4699613B2/ja not_active Expired - Lifetime
- 1999-10-14 CA CA002368405A patent/CA2368405A1/en not_active Abandoned
- 1999-10-14 WO PCT/US1999/023899 patent/WO2000058373A1/en not_active Ceased
- 1999-10-14 CN CNB998166731A patent/CN1159353C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69934332T2 (de) | 2007-03-15 |
| BR9917244B1 (pt) | 2011-10-18 |
| CA2368405A1 (en) | 2000-10-05 |
| DE69934332T3 (de) | 2013-08-29 |
| WO2000058373A1 (en) | 2000-10-05 |
| BR9917244A (pt) | 2002-03-26 |
| EP1169360A1 (en) | 2002-01-09 |
| DE69934332D1 (de) | 2007-01-18 |
| CN1159353C (zh) | 2004-07-28 |
| US6313236B1 (en) | 2001-11-06 |
| WO2000058373A8 (en) | 2007-08-23 |
| EP1169360B1 (en) | 2006-12-06 |
| JP4699613B2 (ja) | 2011-06-15 |
| JP2002540264A (ja) | 2002-11-26 |
| CN1350553A (zh) | 2002-05-22 |
| EP1169360B2 (en) | 2013-06-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MXPA01009834A (es) | Proceso para producir poliolefinas. | |
| US6417296B2 (en) | Process for producing polyolefins | |
| US6300432B1 (en) | Process for producing polyolefins | |
| JP5823678B2 (ja) | ポリオレフィンの製造方法 | |
| US6228957B1 (en) | Process for producing polyethlene | |
| EP1208122B1 (en) | Process for producing polyolefins | |
| EP1159316B1 (en) | Process for producing polyethylene | |
| US6635726B2 (en) | Process for the polymerization of ethylene and interpolymers thereof |