CN115916701A - 用于从盐水中回收锂的方法 - Google Patents
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- CN115916701A CN115916701A CN202080101867.XA CN202080101867A CN115916701A CN 115916701 A CN115916701 A CN 115916701A CN 202080101867 A CN202080101867 A CN 202080101867A CN 115916701 A CN115916701 A CN 115916701A
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- lithium ion
- lithium
- ion sieve
- reactor
- sieve
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 145
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 144
- 238000000034 method Methods 0.000 title claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 69
- 150000003839 salts Chemical class 0.000 title description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 285
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 283
- 239000012267 brine Substances 0.000 claims abstract description 108
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 108
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 17
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 17
- 239000010936 titanium Substances 0.000 claims abstract description 17
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 17
- 230000002378 acidificating effect Effects 0.000 claims abstract description 9
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 5
- 239000010955 niobium Substances 0.000 claims abstract description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 72
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 54
- 239000002245 particle Substances 0.000 claims description 44
- 239000007787 solid Substances 0.000 claims description 34
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 19
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 9
- 230000004907 flux Effects 0.000 claims description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- 239000000908 ammonium hydroxide Substances 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 238000001471 micro-filtration Methods 0.000 claims description 6
- 238000000108 ultra-filtration Methods 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
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- 238000011068 loading method Methods 0.000 description 17
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 12
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- 229910052749 magnesium Inorganic materials 0.000 description 11
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
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- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
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- 229910052748 manganese Inorganic materials 0.000 description 3
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- 238000001556 precipitation Methods 0.000 description 3
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- 239000002351 wastewater Substances 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
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- GQYHUHYESMUTHG-UHFFFAOYSA-N lithium niobate Chemical compound [Li+].[O-][Nb](=O)=O GQYHUHYESMUTHG-UHFFFAOYSA-N 0.000 description 2
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- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
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- 150000002431 hydrogen Chemical class 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical group OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
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- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/895,783 US11583830B2 (en) | 2017-12-27 | 2020-06-08 | Process for recovery of lithium from brine |
| US16/895,783 | 2020-06-08 | ||
| PCT/CA2020/000069 WO2021248221A1 (fr) | 2020-06-08 | 2020-06-09 | Procédé de récupération de lithium à partir de saumure |
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| CN115916701A true CN115916701A (zh) | 2023-04-04 |
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| EP (1) | EP4161875A1 (fr) |
| JP (1) | JP2023529407A (fr) |
| KR (1) | KR20230051148A (fr) |
| CN (1) | CN115916701A (fr) |
| AU (1) | AU2020452303A1 (fr) |
| BR (1) | BR112022025082A2 (fr) |
| CA (1) | CA3184777A1 (fr) |
| CL (1) | CL2022003448A1 (fr) |
| MX (1) | MX2022015540A (fr) |
| WO (1) | WO2021248221A1 (fr) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3087356B1 (fr) * | 2018-10-18 | 2021-04-23 | Geolith | Installation et procede de separation d’au moins une espece ionique a partir d’une solution comprenant au moins ladite espece ionique et du lithium |
| CN115301196B (zh) * | 2022-04-27 | 2023-06-16 | 南京工业大学 | 一种钛掺杂改性锰系锂离子筛及其制备方法 |
| WO2023225245A1 (fr) * | 2022-05-20 | 2023-11-23 | Schlumberger Technology Corporation | Récupération de lithium à partir de solides précipités |
| CN115069209A (zh) * | 2022-06-27 | 2022-09-20 | 天津科技大学 | 一种钛系锂离子筛无机复合吸附提锂材料及其制备方法 |
| KR102656376B1 (ko) | 2023-08-18 | 2024-04-11 | (주)유에스티21 | 인공위성 영상 이미지 분석을 통한 리튬 광산 모니터링 시스템 및 그 방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130001168A1 (en) * | 2010-11-26 | 2013-01-03 | Korea Institute Of Geoscience And Mineral Resources | Apparatus and method for adsorbing and desorbing lithium ions using a ccd process |
| CN106435220A (zh) * | 2016-09-06 | 2017-02-22 | 南京工业大学 | 一种降低盐湖卤水镁锂比的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102774860B (zh) * | 2012-08-22 | 2014-07-16 | 东莞市广华化工有限公司 | 一种用卤水制备碳酸锂的方法 |
| WO2015096549A1 (fr) * | 2013-12-26 | 2015-07-02 | 江苏久吾高科技股份有限公司 | Procédé et appareil pour extraire du lithium de qualité pour batterie à partir de saumure |
| CN107921328A (zh) * | 2015-08-06 | 2018-04-17 | 因尼威森有限公司 | 从卤水中提取锂 |
| KR20190072667A (ko) * | 2016-11-14 | 2019-06-25 | 리락 솔루션즈, 인크. | 코팅된 이온 교환 입자를 이용한 리튬 추출 |
| CN110506028A (zh) * | 2017-02-08 | 2019-11-26 | 因尼威森有限公司 | 含锂溶液的组合处理方法 |
| WO2019000095A1 (fr) * | 2017-06-27 | 2019-01-03 | Purlucid Treatment Solutions (Canada) Inc. | Méthode et appareil pour le traitement de l'eau avec récupération de métaux |
| US11534748B2 (en) * | 2017-12-27 | 2022-12-27 | Standard Lithium Ltd. | Process for recovery of lithium from brine |
| US10648090B2 (en) * | 2018-02-17 | 2020-05-12 | Lilac Solutions, Inc. | Integrated system for lithium extraction and conversion |
| CA3123943A1 (fr) * | 2018-12-18 | 2020-06-25 | Craig Johnstone Brown | Procede de recuperation de lithium a partir de saumure avec ajout d'alcali |
-
2020
- 2020-06-09 CN CN202080101867.XA patent/CN115916701A/zh active Pending
- 2020-06-09 EP EP20940367.4A patent/EP4161875A1/fr active Pending
- 2020-06-09 KR KR1020237000740A patent/KR20230051148A/ko unknown
- 2020-06-09 MX MX2022015540A patent/MX2022015540A/es unknown
- 2020-06-09 CA CA3184777A patent/CA3184777A1/fr active Pending
- 2020-06-09 BR BR112022025082A patent/BR112022025082A2/pt not_active Application Discontinuation
- 2020-06-09 AU AU2020452303A patent/AU2020452303A1/en active Pending
- 2020-06-09 WO PCT/CA2020/000069 patent/WO2021248221A1/fr active Application Filing
- 2020-06-09 JP JP2022575325A patent/JP2023529407A/ja active Pending
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2022
- 2022-12-06 CL CL2022003448A patent/CL2022003448A1/es unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130001168A1 (en) * | 2010-11-26 | 2013-01-03 | Korea Institute Of Geoscience And Mineral Resources | Apparatus and method for adsorbing and desorbing lithium ions using a ccd process |
| CN106435220A (zh) * | 2016-09-06 | 2017-02-22 | 南京工业大学 | 一种降低盐湖卤水镁锂比的方法 |
Non-Patent Citations (1)
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| 大井健太: "《无机粒子交换材料-选择性分离性能的解析和应用》", vol. 1, 30 June 2015, 上海科技技术出版社, pages: 97 - 98 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20230051148A (ko) | 2023-04-17 |
| AU2020452303A1 (en) | 2023-01-05 |
| CA3184777A1 (fr) | 2021-12-16 |
| WO2021248221A1 (fr) | 2021-12-16 |
| CL2022003448A1 (es) | 2023-06-02 |
| BR112022025082A2 (pt) | 2022-12-27 |
| JP2023529407A (ja) | 2023-07-10 |
| EP4161875A1 (fr) | 2023-04-12 |
| MX2022015540A (es) | 2023-01-18 |
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