CA3184777A1 - Procede de recuperation de lithium a partir de saumure - Google Patents

Procede de recuperation de lithium a partir de saumure

Info

Publication number
CA3184777A1
CA3184777A1 CA3184777A CA3184777A CA3184777A1 CA 3184777 A1 CA3184777 A1 CA 3184777A1 CA 3184777 A CA3184777 A CA 3184777A CA 3184777 A CA3184777 A CA 3184777A CA 3184777 A1 CA3184777 A1 CA 3184777A1
Authority
CA
Canada
Prior art keywords
lithium ion
ion sieve
lithium
reactor
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3184777A
Other languages
English (en)
Inventor
Craig Johnstone Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Lithium Ltd
Original Assignee
Standard Lithium Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/895,783 external-priority patent/US11583830B2/en
Application filed by Standard Lithium Ltd filed Critical Standard Lithium Ltd
Publication of CA3184777A1 publication Critical patent/CA3184777A1/fr
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/16—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to the conditioning of the fluid carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
    • B01D15/361—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/02—Loose filtering material, e.g. loose fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0221—Group 4 or 5 metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/02—Processes using inorganic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/145—Purification by solid ion-exchangers or solid chelating agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/14—Purification
    • C01D3/16—Purification by precipitation or adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/12—Addition of chemical agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/18—Details relating to membrane separation process operations and control pH control
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2315/00—Details relating to the membrane module operation
    • B01D2315/06—Submerged-type; Immersion type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Mixers With Rotating Receptacles And Mixers With Vibration Mechanisms (AREA)

Abstract

Un procédé de récupération d'ions lithium à partir d'une saumure contenant du lithium comprend les étapes consistant à mettre en contact de la saumure contenant du lithium avec un tamis d'ion lithium (LIS) (ce LIS comprenant un oxyde de titane ou de niobium) dans un premier réacteur agité pour former un complexe d'ion lithium avec le tamis d'ion lithium, et décomplexer l'ion lithium du tamis d'ion lithium dans un second réacteur agité pour former le tamis d'ion lithium et un éluat de sel de lithium acide.
CA3184777A 2020-06-08 2020-06-09 Procede de recuperation de lithium a partir de saumure Pending CA3184777A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16/895,783 US11583830B2 (en) 2017-12-27 2020-06-08 Process for recovery of lithium from brine
US16/895,783 2020-06-08
PCT/CA2020/000069 WO2021248221A1 (fr) 2020-06-08 2020-06-09 Procédé de récupération de lithium à partir de saumure

Publications (1)

Publication Number Publication Date
CA3184777A1 true CA3184777A1 (fr) 2021-12-16

Family

ID=78846864

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3184777A Pending CA3184777A1 (fr) 2020-06-08 2020-06-09 Procede de recuperation de lithium a partir de saumure

Country Status (10)

Country Link
EP (1) EP4161875A1 (fr)
JP (1) JP2023529407A (fr)
KR (1) KR20230051148A (fr)
CN (1) CN115916701A (fr)
AU (1) AU2020452303A1 (fr)
BR (1) BR112022025082A2 (fr)
CA (1) CA3184777A1 (fr)
CL (1) CL2022003448A1 (fr)
MX (1) MX2022015540A (fr)
WO (1) WO2021248221A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3087356B1 (fr) * 2018-10-18 2021-04-23 Geolith Installation et procede de separation d’au moins une espece ionique a partir d’une solution comprenant au moins ladite espece ionique et du lithium
CN115301196B (zh) * 2022-04-27 2023-06-16 南京工业大学 一种钛掺杂改性锰系锂离子筛及其制备方法
US20230373803A1 (en) * 2022-05-20 2023-11-23 Schlumberger Technology Corporation Lithium recovery from precipitated solids
CN115069209A (zh) * 2022-06-27 2022-09-20 天津科技大学 一种钛系锂离子筛无机复合吸附提锂材料及其制备方法
GB202218894D0 (en) * 2022-12-14 2023-01-25 Watercycle Tech Ltd Lithium extraction
KR102656376B1 (ko) 2023-08-18 2024-04-11 (주)유에스티21 인공위성 영상 이미지 분석을 통한 리튬 광산 모니터링 시스템 및 그 방법

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101047986B1 (ko) * 2010-11-26 2011-07-13 한국지질자원연구원 Ｃｃｄ 공정을 이용한 리튬 이온의 흡착/탈착 장치 및 그 방법
CN102774860B (zh) * 2012-08-22 2014-07-16 东莞市广华化工有限公司 一种用卤水制备碳酸锂的方法
WO2015096549A1 (fr) * 2013-12-26 2015-07-02 江苏久吾高科技股份有限公司 Procédé et appareil pour extraire du lithium de qualité pour batterie à partir de saumure
CN107921328A (zh) * 2015-08-06 2018-04-17 因尼威森有限公司 从卤水中提取锂
CN106435220A (zh) * 2016-09-06 2017-02-22 南京工业大学 一种降低盐湖卤水镁锂比的方法
KR20190072667A (ko) * 2016-11-14 2019-06-25 리락 솔루션즈, 인크. 코팅된 이온 교환 입자를 이용한 리튬 추출
MX2019009336A (es) * 2017-02-08 2020-01-30 Inneovation Pty Ltd Metodo de procesamiento combinado para soluciones que contienen litio.
US20200299805A1 (en) * 2017-06-27 2020-09-24 Purlucid Treatment Solutions (Canada) Inc. Method and apparatus for the treatment of water with the recovery of metals
US11534748B2 (en) * 2017-12-27 2022-12-27 Standard Lithium Ltd. Process for recovery of lithium from brine
US10648090B2 (en) * 2018-02-17 2020-05-12 Lilac Solutions, Inc. Integrated system for lithium extraction and conversion
MX2021007232A (es) * 2018-12-18 2021-09-23 Standard Lithium Ltd Proceso para la recuperacion de litio a partir de salmuera con adicion de alcali.

Also Published As

Publication number Publication date
AU2020452303A1 (en) 2023-01-05
CN115916701A (zh) 2023-04-04
EP4161875A1 (fr) 2023-04-12
MX2022015540A (es) 2023-01-18
BR112022025082A2 (pt) 2022-12-27
CL2022003448A1 (es) 2023-06-02
WO2021248221A1 (fr) 2021-12-16
JP2023529407A (ja) 2023-07-10
KR20230051148A (ko) 2023-04-17

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Effective date: 20240405