CN115747563B - 一种海洋工程用Cu-15Ni-8Sn基合金及其制备方法 - Google Patents
一种海洋工程用Cu-15Ni-8Sn基合金及其制备方法 Download PDFInfo
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- CN115747563B CN115747563B CN202211474390.7A CN202211474390A CN115747563B CN 115747563 B CN115747563 B CN 115747563B CN 202211474390 A CN202211474390 A CN 202211474390A CN 115747563 B CN115747563 B CN 115747563B
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 198
- 239000000956 alloy Substances 0.000 title claims abstract description 198
- 238000002360 preparation method Methods 0.000 title abstract description 22
- 238000012407 engineering method Methods 0.000 title description 2
- 230000007797 corrosion Effects 0.000 claims abstract description 52
- 238000005260 corrosion Methods 0.000 claims abstract description 52
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 89
- 239000010949 copper Substances 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 55
- 239000011701 zinc Substances 0.000 claims description 51
- 238000010438 heat treatment Methods 0.000 claims description 42
- 238000003723 Smelting Methods 0.000 claims description 37
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 35
- 229910052802 copper Inorganic materials 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 33
- 230000005672 electromagnetic field Effects 0.000 claims description 28
- 229910052759 nickel Inorganic materials 0.000 claims description 27
- 238000005058 metal casting Methods 0.000 claims description 25
- 238000005266 casting Methods 0.000 claims description 23
- 230000008569 process Effects 0.000 claims description 22
- 229910052710 silicon Inorganic materials 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 22
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 21
- 239000010703 silicon Substances 0.000 claims description 21
- 230000032683 aging Effects 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 20
- 238000000137 annealing Methods 0.000 claims description 20
- 238000010622 cold drawing Methods 0.000 claims description 20
- 238000001192 hot extrusion Methods 0.000 claims description 20
- 229910052698 phosphorus Inorganic materials 0.000 claims description 19
- 229910052725 zinc Inorganic materials 0.000 claims description 19
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 17
- 229910002530 Cu-Y Inorganic materials 0.000 claims description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 15
- 239000003610 charcoal Substances 0.000 claims description 15
- 239000011574 phosphorus Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910017566 Cu-Mn Inorganic materials 0.000 claims description 9
- 229910017871 Cu—Mn Inorganic materials 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 239000010439 graphite Substances 0.000 claims description 9
- 239000000155 melt Substances 0.000 claims description 9
- 239000006104 solid solution Substances 0.000 claims description 9
- 239000011573 trace mineral Substances 0.000 claims description 8
- 235000013619 trace mineral Nutrition 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 238000005204 segregation Methods 0.000 abstract description 33
- 210000001787 dendrite Anatomy 0.000 abstract description 14
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 30
- 239000011572 manganese Substances 0.000 description 30
- 238000007711 solidification Methods 0.000 description 27
- 230000008023 solidification Effects 0.000 description 27
- 238000010309 melting process Methods 0.000 description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 19
- 238000002844 melting Methods 0.000 description 14
- 230000008018 melting Effects 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 239000002994 raw material Substances 0.000 description 12
- 239000002893 slag Substances 0.000 description 12
- 239000012071 phase Substances 0.000 description 10
- 238000005728 strengthening Methods 0.000 description 10
- 230000009471 action Effects 0.000 description 8
- 230000009286 beneficial effect Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 229910052761 rare earth metal Inorganic materials 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 7
- 229910000881 Cu alloy Inorganic materials 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 238000005238 degreasing Methods 0.000 description 6
- 238000000265 homogenisation Methods 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 150000002910 rare earth metals Chemical class 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 238000005275 alloying Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229910052727 yttrium Inorganic materials 0.000 description 5
- 229910052684 Cerium Inorganic materials 0.000 description 4
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000002161 passivation Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000013535 sea water Substances 0.000 description 4
- 229910000906 Bronze Inorganic materials 0.000 description 3
- -1 HSn70-1 and HSn60-1 Substances 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 229910000943 NiAl Inorganic materials 0.000 description 3
- 229910005883 NiSi Inorganic materials 0.000 description 3
- 238000003483 aging Methods 0.000 description 3
- 239000010974 bronze Substances 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 229910018100 Ni-Sn Inorganic materials 0.000 description 2
- 229910018532 Ni—Sn Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- DMFGNRRURHSENX-UHFFFAOYSA-N beryllium copper Chemical compound [Be].[Cu] DMFGNRRURHSENX-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000010071 organism adhesion Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000009772 tissue formation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/02—Use of electric or magnetic effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D7/00—Casting ingots, e.g. from ferrous metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Conductive Materials (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211474390.7A CN115747563B (zh) | 2022-11-23 | 2022-11-23 | 一种海洋工程用Cu-15Ni-8Sn基合金及其制备方法 |
| PCT/CN2022/135142 WO2023061514A1 (fr) | 2022-11-23 | 2022-11-29 | Alliage à base de cu-15ni-8sn pour le génie océanique et son procédé de préparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211474390.7A CN115747563B (zh) | 2022-11-23 | 2022-11-23 | 一种海洋工程用Cu-15Ni-8Sn基合金及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115747563A CN115747563A (zh) | 2023-03-07 |
| CN115747563B true CN115747563B (zh) | 2023-12-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211474390.7A Active CN115747563B (zh) | 2022-11-23 | 2022-11-23 | 一种海洋工程用Cu-15Ni-8Sn基合金及其制备方法 |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN115747563B (fr) |
| WO (1) | WO2023061514A1 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116287857A (zh) * | 2023-04-04 | 2023-06-23 | 昆明理工大学 | 一种高弹性高强度高导电Cu-Ni-Sn合金及其制备方法 |
| CN117127058B (zh) * | 2023-05-06 | 2024-02-09 | 江西省科学院应用物理研究所 | 一种高强度高硬度铜基合金及其制备工艺 |
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|---|---|---|---|---|
| JPH07126779A (ja) * | 1993-11-05 | 1995-05-16 | Dowa Mining Co Ltd | 銅基合金およびその製造法 |
| JPH08283889A (ja) * | 1995-04-14 | 1996-10-29 | Chuetsu Gokin Chuko Kk | 高強度・高硬度銅合金 |
| CN1587427A (zh) * | 2004-07-22 | 2005-03-02 | 同济大学 | 一种新型弹性导电合金及其制备方法 |
| JP2006328542A (ja) * | 2006-05-29 | 2006-12-07 | Dowa Holdings Co Ltd | 銅基合金材およびその製造法 |
| CN105256171A (zh) * | 2015-10-30 | 2016-01-20 | 中南大学 | 一种铜镍锡合金棒材及其制备方法 |
| CN105886807A (zh) * | 2016-06-01 | 2016-08-24 | 金川集团股份有限公司 | 一种高强度耐磨合金Cu-15Ni-8Sn的制备方法 |
| CN106834795A (zh) * | 2017-02-21 | 2017-06-13 | 江阴华瑞电工科技股份有限公司 | 一种高弹性、耐腐蚀、耐磨Cu‑Ni‑Sn合金制备方法 |
| CN108060326A (zh) * | 2017-12-15 | 2018-05-22 | 中南大学 | 一种超高强、低反偏析CuNiSn系弹性铜合金及其制备方法 |
| CN108188362A (zh) * | 2017-12-15 | 2018-06-22 | 中南大学 | CuNiSn系合金及带坯组合外场水平连铸制备方法及装置 |
| CN108677059A (zh) * | 2018-05-28 | 2018-10-19 | 中色奥博特铜铝业有限公司 | Cu-15Ni-8Sn铜合金、铜合金棒及其制备方法 |
| CN110629070A (zh) * | 2019-10-30 | 2019-12-31 | 江阴华瑞电工科技股份有限公司 | 一种高弹性、耐腐蚀、耐磨Cu-Ni-Sn合金制备方法 |
| CN113278846A (zh) * | 2021-04-06 | 2021-08-20 | 中铝材料应用研究院有限公司 | 一种耐磨铜镍锡合金及其制备方法 |
| CN113789459A (zh) * | 2021-09-02 | 2021-12-14 | 宁波博威合金材料股份有限公司 | 一种铜镍锡合金及其制备方法和应用 |
| CN113913646A (zh) * | 2021-10-29 | 2022-01-11 | 宁波金田铜业(集团)股份有限公司 | 一种铜镍锡合金铸锭的制备方法 |
| CN114086027A (zh) * | 2021-11-25 | 2022-02-25 | 江西理工大学 | 一种抗高温软化的Cu-Ni-Sn系高强高弹铜合金及其制备方法 |
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| CN103243232B (zh) * | 2013-06-05 | 2016-02-24 | 中南大学 | 一种高抗变色金色耐蚀铜合金及其板材制备方法 |
| CN105714148B (zh) * | 2016-04-29 | 2017-10-20 | 华南理工大学 | 一种调幅分解型高强铜镍锡合金 |
| CN107475562B (zh) * | 2017-08-29 | 2019-06-21 | 河南科技大学 | 一种耐海水冲蚀用加工铜合金及其制备方法 |
| CN107447127B (zh) * | 2017-08-29 | 2019-05-21 | 河南科技大学 | 一种海洋工况用耐冲蚀铜合金及其制备方法 |
| CN109266901B (zh) * | 2018-09-28 | 2020-11-17 | 兰州理工大学 | 一种Cu15Ni8Sn高强耐磨合金杆/丝的制备方法 |
| CN110066942B (zh) * | 2019-04-28 | 2020-12-29 | 中南大学 | 一种超高强高韧高导电铜镍锡合金及其制备方法 |
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2022
- 2022-11-23 CN CN202211474390.7A patent/CN115747563B/zh active Active
- 2022-11-29 WO PCT/CN2022/135142 patent/WO2023061514A1/fr unknown
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07126779A (ja) * | 1993-11-05 | 1995-05-16 | Dowa Mining Co Ltd | 銅基合金およびその製造法 |
| JPH08283889A (ja) * | 1995-04-14 | 1996-10-29 | Chuetsu Gokin Chuko Kk | 高強度・高硬度銅合金 |
| CN1587427A (zh) * | 2004-07-22 | 2005-03-02 | 同济大学 | 一种新型弹性导电合金及其制备方法 |
| JP2006328542A (ja) * | 2006-05-29 | 2006-12-07 | Dowa Holdings Co Ltd | 銅基合金材およびその製造法 |
| CN105256171A (zh) * | 2015-10-30 | 2016-01-20 | 中南大学 | 一种铜镍锡合金棒材及其制备方法 |
| CN105886807A (zh) * | 2016-06-01 | 2016-08-24 | 金川集团股份有限公司 | 一种高强度耐磨合金Cu-15Ni-8Sn的制备方法 |
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| CN108060326A (zh) * | 2017-12-15 | 2018-05-22 | 中南大学 | 一种超高强、低反偏析CuNiSn系弹性铜合金及其制备方法 |
| CN108188362A (zh) * | 2017-12-15 | 2018-06-22 | 中南大学 | CuNiSn系合金及带坯组合外场水平连铸制备方法及装置 |
| CN108677059A (zh) * | 2018-05-28 | 2018-10-19 | 中色奥博特铜铝业有限公司 | Cu-15Ni-8Sn铜合金、铜合金棒及其制备方法 |
| CN110629070A (zh) * | 2019-10-30 | 2019-12-31 | 江阴华瑞电工科技股份有限公司 | 一种高弹性、耐腐蚀、耐磨Cu-Ni-Sn合金制备方法 |
| CN113278846A (zh) * | 2021-04-06 | 2021-08-20 | 中铝材料应用研究院有限公司 | 一种耐磨铜镍锡合金及其制备方法 |
| CN113789459A (zh) * | 2021-09-02 | 2021-12-14 | 宁波博威合金材料股份有限公司 | 一种铜镍锡合金及其制备方法和应用 |
| CN113913646A (zh) * | 2021-10-29 | 2022-01-11 | 宁波金田铜业(集团)股份有限公司 | 一种铜镍锡合金铸锭的制备方法 |
| CN114086027A (zh) * | 2021-11-25 | 2022-02-25 | 江西理工大学 | 一种抗高温软化的Cu-Ni-Sn系高强高弹铜合金及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115747563A (zh) | 2023-03-07 |
| WO2023061514A1 (fr) | 2023-04-20 |
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