CN115737498A - Small-molecule keratin anti-hair-breakage hair care product easy to enter hair core repair disulfide bonds and preparation method thereof - Google Patents
Small-molecule keratin anti-hair-breakage hair care product easy to enter hair core repair disulfide bonds and preparation method thereof Download PDFInfo
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- CN115737498A CN115737498A CN202211428334.XA CN202211428334A CN115737498A CN 115737498 A CN115737498 A CN 115737498A CN 202211428334 A CN202211428334 A CN 202211428334A CN 115737498 A CN115737498 A CN 115737498A
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- 102000011782 Keratins Human genes 0.000 title claims abstract description 48
- 108010076876 Keratins Proteins 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims description 30
- 150000003384 small molecules Chemical class 0.000 title claims description 16
- 206010044625 Trichorrhexis Diseases 0.000 title claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 48
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 48
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 41
- -1 hydroxypropyl Chemical group 0.000 claims abstract description 28
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 27
- 239000003607 modifier Substances 0.000 claims abstract description 24
- 235000018958 Gardenia augusta Nutrition 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 18
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 claims abstract description 10
- 239000011703 D-panthenol Substances 0.000 claims abstract description 10
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims abstract description 10
- 235000004866 D-panthenol Nutrition 0.000 claims abstract description 10
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 10
- 229960003067 cystine Drugs 0.000 claims abstract description 10
- 229960003949 dexpanthenol Drugs 0.000 claims abstract description 10
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 8
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 8
- 241000220225 Malus Species 0.000 claims abstract description 6
- 240000001972 Gardenia jasminoides Species 0.000 claims abstract 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 41
- 238000002156 mixing Methods 0.000 claims description 41
- 239000000047 product Substances 0.000 claims description 41
- 238000003756 stirring Methods 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 241000157835 Gardenia Species 0.000 claims description 27
- 239000000706 filtrate Substances 0.000 claims description 23
- 229940087559 grape seed Drugs 0.000 claims description 19
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 238000000605 extraction Methods 0.000 claims description 14
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- 239000008139 complexing agent Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- 239000001509 sodium citrate Substances 0.000 claims description 12
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 12
- 229920001661 Chitosan Polymers 0.000 claims description 9
- 239000004254 Ammonium phosphate Substances 0.000 claims description 7
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 7
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 7
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 7
- VQEHIYWBGOJJDM-UHFFFAOYSA-H lanthanum(3+);trisulfate Chemical compound [La+3].[La+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VQEHIYWBGOJJDM-UHFFFAOYSA-H 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 6
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- 239000011975 tartaric acid Substances 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 230000002265 prevention Effects 0.000 claims 1
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- 239000004973 liquid crystal related substance Substances 0.000 abstract description 2
- 102000004169 proteins and genes Human genes 0.000 abstract description 2
- 108090000623 proteins and genes Proteins 0.000 abstract description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 2
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- 239000003921 oil Substances 0.000 description 14
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- 239000002904 solvent Substances 0.000 description 5
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
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Abstract
The invention discloses a micromolecular keratin hair-breaking-prevention hair care product capable of easily entering a hair core repairing disulfide bond, which comprises the following raw materials in parts by weight: 10-15 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 5-10 parts of hydrolyzed keratin, 3-6 parts of cystine bis-PG-propyl silanetriol, 2-5 parts of nano amino silicone oil, 1-4 parts of D-panthenol, 2-5 parts of malus oil, 2-6 parts of a Gardenia jasminoides extract and 3-6 parts of a montmorillonite-loaded carbon nanotube modifier. The invention uses the liquid crystal emulsification technology to form a multilayer material body structure, enhances the stability of the material body, has the advantages of improving the release and utilization rate of components, adds the cation modified hydrolyzed keratin, can permanently combine the fat base and the quaternary ammonium salt with hair through protein connection, and simultaneously carries out synergistic combination through the Gardenia jasminoides extract and the montmorillonite loaded carbon nano tube modifier to jointly synergize.
Description
Technical Field
The invention relates to the technical field of hair care, in particular to a micromolecule keratin breakage-proof hair care product which is easy to enter a hair core to repair disulfide bonds and a preparation method thereof.
Background
Caring hair and protecting hair. Hair is the most messy part of the body. Hair care and cleaning are the most important, hair and skin have the same oily, neutral and dry properties, and the secretion amount of the sebum membrane depends; hair care is not only related to age, environment, physical condition, occupation, but also should be aware of seasonal characteristics. In summer, sweat glands and sebaceous glands of a human body are exuberant in secretion, and a large amount of sweat and sebum are accumulated on the head, so that the quality of hair is influenced.
The invention provides a micromolecule keratin breakage-proof hair care product which is easy to enter a hair core to repair disulfide bonds and a preparation method thereof based on the fact that the existing hair care product can not improve the flexibility of hair, can not repair the damage of scales of hair, and reduces the use efficiency of hair under the conditions of perm, dyeing and the like.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a small-molecule keratin breakage-proof hair care product which is easy to enter a hair core and repair disulfide bonds and a preparation method thereof, so as to solve the problems in the background technology.
The technical scheme adopted by the invention for solving the technical problems is as follows:
the invention provides a micromolecule keratin anti-hair-breaking hair care product capable of easily entering a hair core to repair disulfide bonds, which comprises the following raw materials in parts by weight:
10-15 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 5-10 parts of hydrolyzed keratin, 3-6 parts of cystine bis-PG-propyl silanetriol, 2-5 parts of nano amino silicone oil, 1-4 parts of D-panthenol, 2-5 parts of malus oil, 2-6 parts of a gardenia extract, 3-6 parts of a montmorillonite-loaded carbon nanotube modifier and 5-10 parts of deionized water.
Preferably, the hair care product comprises the following raw materials in parts by weight:
12.5 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 7.5 parts of hydrolyzed keratin, 4.5 parts of cystine bis-PG-propyl silanetriol, 3.5 parts of nano amino silicone oil, 2.5 parts of D-panthenol, 3.5 parts of malus oil, 4 parts of a gardenia extract, 4.5 parts of a montmorillonite-loaded carbon nanotube modifier and 7.5 parts of deionized water.
Preferably, the preparation method of the gardenia extract comprises the following steps:
s01: sending the gardenia extracted from the West region of Taixi province into a triturator to triturate, then sending the triturator into 3-6 times of water to carry out extraction with slow fire for 1-2h, and filtering after the extraction is finished to obtain a first filtrate;
s02: extracting the filter residue with 3-5 times of ethanol solvent at 45-50 deg.C for 1-2 hr, removing ethanol, filtering to obtain second filtrate, and mixing the first filtrate and the second filtrate to obtain extract of Gardenia jasminoides Ellis;
s03: adding chitosan into 2-3 times of sodium citrate solution, stirring, adding oleum Olivarum 4-8%, grape seed extractant 5-8% and Gardenia Acutissimae extractive solution 20-30%, stirring, and mixing to obtain Gardenia Acutissimae extract.
Preferably, the mass fraction of the sodium citrate solution is 5-10%.
Preferably, the grape seed extractant is prepared by the following specific steps: mixing grape seeds with 80% of ethanol in a mass fraction ratio of 1 to 15, then performing reflux extraction at 55-65 ℃ for 2-4h, and removing alcohol to obtain the grape seed extractant.
Preferably, the preparation method of the montmorillonite-loaded carbon nanotube modifier comprises the following steps:
s11: sending the carbon nano tube into an acid solution of 2-3 times of sodium alkylsulfonate, then adding 5-10% of ammonium phosphate and 1-5% of lanthanum sulfate based on the total amount of the carbon nano tube, and fully stirring and mixing to obtain a carbon nano tube complexing agent;
s12: sending 10-15 parts of montmorillonite into 20-30 parts of water, stirring and dispersing, then adding 1-4 parts of carboxymethyl cellulose and 1-3 parts of tartaric acid, fully dispersing and mixing, washing with water, and drying to obtain modified montmorillonite;
s13: and (2) reacting the modified montmorillonite and the carbon nano tube complexing agent in a reactor according to the weight ratio of 1.
Preferably, the acid solution of sodium alkylsulfonate is prepared from sodium alkylsulfonate, deionized water and glycolic acid according to the weight ratio of 3.
Preferably, the rotation speed of the reaction treatment in the reactor is 1000-1500r/min, the reaction time is 20-30min, and the reaction temperature is 55-65 ℃.
The invention also provides a preparation method of the micromolecule keratin breakage-proof hair care product easy to enter the hair core to repair the disulfide bonds, which comprises the following steps: sequentially adding the raw materials into a stirrer, stirring and mixing for 20-30min, and stirring to obtain the hair care product.
Preferably, the mixing rotating speed is 450-550r/min.
Compared with the prior art, the invention has the following beneficial effects:
the invention uses the liquid crystal emulsification technology to form a multilayer body structure, enhances the body stability, and has the advantages of improving the component release and the utilization rate, the addition of the cation modified hydrolyzed keratin can permanently combine the fat base and the quaternary ammonium salt with the hair through protein connection, and simultaneously, the Gardenia jasminoides extract and the montmorillonite loaded carbon nanotube modifier are cooperatively combined and synergized together, thereby repairing the damaged disulfide bond structure, enabling the hair to be more tenacious, repairing the hair scales and the damage and improving the hair care efficiency.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below with reference to specific embodiments, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
The micromolecule keratin hair-break-preventing and hair-protecting product capable of easily entering hair core to repair disulfide bonds comprises the following raw materials in parts by weight:
10-15 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 5-10 parts of hydrolyzed keratin, 3-6 parts of cystine bis-PG-propyl silanetriol, 2-5 parts of nano amino silicone oil, 1-4 parts of D-panthenol, 2-5 parts of malus oil, 2-6 parts of a gardenia extract, 3-6 parts of a montmorillonite-loaded carbon nanotube modifier and 5-10 parts of deionized water.
The hair care product comprises the following raw materials in parts by weight:
12.5 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 7.5 parts of hydrolyzed keratin, 4.5 parts of cystine bis-PG-propyl silanetriol, 3.5 parts of nano amino silicone oil, 2.5 parts of D-panthenol, 3.5 parts of malus oil, 4 parts of a gardenia extract, 4.5 parts of a montmorillonite-loaded carbon nanotube modifier and 7.5 parts of deionized water.
The preparation method of the gardenia extract of the embodiment comprises the following steps:
s01: sending the gardenia extracted from the West region of Taixi province into a triturator to triturate, then sending the triturator into 3-6 times of water to carry out extraction with slow fire for 1-2h, and filtering after the extraction is finished to obtain a first filtrate;
s02: extracting the filter residue with 3-5 times of ethanol solvent at 45-50 deg.C for 1-2 hr, removing ethanol, filtering to obtain second filtrate, and mixing the first filtrate and the second filtrate to obtain extract of Gardenia jasminoides Ellis;
s03: adding chitosan into 2-3 times of sodium citrate solution, stirring, adding oleum Olivarum 4-8%, grape seed extractant 5-8% and Gardenia Acutissimae extractive solution 20-30%, stirring, and mixing to obtain Gardenia Acutissimae extract.
The mass fraction of the sodium citrate solution in this example is 5-10%.
The grape seed extractant of the embodiment is prepared by the following specific steps: mixing grape seeds with 80% of ethanol in a mass fraction ratio of 1 to 15, then performing reflux extraction at 55-65 ℃ for 2-4h, and removing alcohol to obtain the grape seed extractant.
The preparation method of the montmorillonite-supported carbon nanotube modifier comprises the following steps:
s11: sending the carbon nano tube into an acid solution of 2-3 times of sodium alkylsulfonate, then adding 5-10% of ammonium phosphate and 1-5% of lanthanum sulfate based on the total amount of the carbon nano tube, and fully stirring and mixing to obtain a carbon nano tube complexing agent;
s12: sending 10-15 parts of montmorillonite into 20-30 parts of water, stirring and dispersing, then adding 1-4 parts of carboxymethyl cellulose and 1-3 parts of tartaric acid, fully dispersing and mixing, washing with water, and drying to obtain modified montmorillonite;
s13: reacting the modified montmorillonite and the carbon nano tube complexing agent in a reactor according to the weight ratio of 1.
The acid solution of sodium alkylsulfonate in this example is prepared from sodium alkylsulfonate, deionized water, and glycolic acid according to a weight ratio of 3.
The rotating speed of the reaction treatment in the reactor of the embodiment is 1000-1500r/min, the reaction time is 20-30min, and the reaction temperature is 55-65 ℃.
The preparation method of the small molecule keratin breakage-proof hair care product easy to enter the hair core repair disulfide bond comprises the following steps: sequentially adding the raw materials into a stirrer, stirring and mixing for 20-30min, and finishing stirring to obtain the hair care product.
The mixing speed of the present embodiment is 450-550r/min.
Example 1.
The micromolecule keratin hair-break-preventing and hair-protecting product capable of easily entering hair core to repair disulfide bonds comprises the following raw materials in parts by weight:
10 parts of coconut oil diammonium hydroxypropyl hydrolyzed keratin, 5 parts of hydrolyzed keratin, 3 parts of cystine bis-PG-propyl silanetriol, 2 parts of nano amino silicone oil, 1 part of D-panthenol, 2 parts of maltula oil, 2 parts of a gardenia extract, 3 parts of a montmorillonite-loaded carbon nanotube modifier and 5 parts of deionized water.
The preparation method of the gardenia extract of the embodiment comprises the following steps:
s01: sending the gardenia extracted from the West region into a pounding machine for pounding, then sending into 3 times of water for extracting with slow fire for 1 hour, and filtering after the extraction is finished to obtain a first filtrate;
s02: feeding the filter residue into 3 times of ethanol solvent, extracting for 1h at 45 deg.C, removing ethanol, filtering to obtain a second filtrate, and mixing the first filtrate and the second filtrate to obtain a Gardenia jasminoides Ellis extract;
s03: adding chitosan into 2 times of sodium citrate solution, stirring, adding 4% olive oil, 5% grape seed extractant and 20% Gardenia jasminoides Ellis extract, and stirring to obtain Gardenia jasminoides Ellis extract.
The sodium citrate solution of this example was 5% by mass.
The grape seed extractant of the embodiment is prepared by the following specific steps: mixing grape seeds with 80% of ethanol in a mass fraction ratio of 1 to 15, then performing reflux extraction at 55 ℃ for 2 hours, and removing alcohol to obtain the grape seed extractant.
The preparation method of the montmorillonite-supported carbon nanotube modifier comprises the following steps:
s11: sending the carbon nano tube into an acid solution of 2 times of sodium alkylsulfonate, then adding 5 percent of ammonium phosphate and 1 percent of lanthanum sulfate of the total amount of the carbon nano tube, and fully stirring and mixing to obtain a carbon nano tube complexing agent;
s12: sending 10 parts of montmorillonite into 20 parts of water, stirring and dispersing, then adding 1 part of carboxymethyl cellulose and 1 part of tartaric acid, fully dispersing and mixing, washing with water, and drying to obtain modified montmorillonite;
s13: reacting the modified montmorillonite and the carbon nano tube complexing agent in a reactor according to the weight ratio of 1.
The acid solution of sodium alkylsulfonate of this embodiment is prepared from sodium alkylsulfonate, deionized water, and glycolic acid according to a weight ratio of 3.
The rotation speed of the reaction treatment in the reactor of this example was 1000r/min, the reaction time was 20min, and the reaction temperature was 55 ℃.
The preparation method of the small molecule keratin breakage-proof hair care product with the easy entry of the hair core repair disulfide bonds comprises the following steps: sequentially adding the raw materials into a stirrer, stirring and mixing for 20min, and finishing stirring to obtain the hair care product.
The mixing speed in this example was 450r/min.
Example 2.
The micromolecule keratin hair-break-preventing and hair-protecting product capable of easily entering hair core to repair disulfide bonds comprises the following raw materials in parts by weight:
15 parts of coconut oil diammonium hydroxypropyl hydrolyzed keratin, 10 parts of hydrolyzed keratin, 6 parts of cystine bis-PG-propyl silanetriol, 5 parts of nano amino silicone oil, 4 parts of D-panthenol, 5 parts of maltula oil, 6 parts of a gardenia extract, 6 parts of a montmorillonite-loaded carbon nanotube modifier and 10 parts of deionized water.
The preparation method of the extract of the gardenia jasminoides ellis in the embodiment comprises the following steps:
s01: sending the gardenia extracted from the West region into a pounding machine for pounding, then sending the pounding machine into 6 times of water for carrying out slow fire extraction for 2 hours, and filtering after the extraction is finished to obtain a first filtrate;
s02: extracting the filter residue with 5 times of ethanol solvent at 50 deg.C for 2 hr, removing ethanol, filtering to obtain second filtrate, and mixing the first filtrate and the second filtrate to obtain extract of Gardenia jasminoides Ellis;
s03: adding chitosan into 3 times of sodium citrate solution, stirring, adding oleum Olivarum 8%, grape seed extractant 8% and Gardenia jasminoides Ellis extractive solution 30%, stirring, and mixing to obtain Gardenia jasminoides Ellis extract.
The sodium citrate solution of this example was 10% by mass.
The grape seed extractant of the embodiment is prepared by the following specific steps: mixing grape seeds with 80% of ethanol according to a material-liquid ratio of 1.
The preparation method of the montmorillonite-supported carbon nanotube modifier comprises the following steps:
s11: sending the carbon nano tube into an acid solution of 3 times of sodium alkylsulfonate, then adding 10 percent of ammonium phosphate and 5 percent of lanthanum sulfate of the total amount of the carbon nano tube, and fully stirring and mixing to obtain a carbon nano tube complexing agent;
s12: sending 15 parts of montmorillonite into 30 parts of water, stirring and dispersing, then adding 4 parts of carboxymethyl cellulose and 3 parts of tartaric acid, fully dispersing and mixing, washing with water, and drying to obtain modified montmorillonite;
s13: reacting the modified montmorillonite and the carbon nano tube complexing agent in a reactor according to the weight ratio of 1.
The acid solution of sodium alkylsulfonate in this example is prepared from sodium alkylsulfonate, deionized water, and glycolic acid according to a weight ratio of 3.
The rotation speed of the reaction treatment in the reactor of this example was 1500r/min, the reaction time was 30min, and the reaction temperature was 65 ℃.
The preparation method of the small molecule keratin breakage-proof hair care product easy to enter the hair core repair disulfide bond comprises the following steps: sequentially adding the raw materials into a stirrer, stirring and mixing for 30min, and finishing stirring to obtain the hair care product.
The mixing speed of the present embodiment is 550r/min.
Example 3.
The micromolecular keratin hair-breaking-prevention hair care product easy to enter a hair core repairing disulfide bond comprises the following raw materials in parts by weight:
12.5 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 7.5 parts of hydrolyzed keratin, 4.5 parts of cystine bis-PG-propyl silanetriol, 3.5 parts of nano amino silicone oil, 2.5 parts of D-panthenol, 3.5 parts of maltula oil, 4 parts of a gardenia extract, 4.5 parts of a montmorillonite-loaded carbon nanotube modifier and 7.5 parts of deionized water.
The preparation method of the gardenia extract of the embodiment comprises the following steps:
s01: sending the gardenia extracted from the West region into a pounding machine for pounding, then sending into 4.5 times of water for extracting with slow fire for 1.5h, and filtering after the extraction is finished to obtain a first filtrate;
s02: feeding the filter residue into 4 times of ethanol solvent, extracting for 1.5h at 47.5 deg.C, removing ethanol, filtering to obtain a second filtrate, and mixing the first filtrate and the second filtrate to obtain extractive solution of Gardenia jasminoides;
s03: adding chitosan into 2.5 times of sodium citrate solution, stirring, adding oleum Olivarum 6%, grape seed extractant 6.5% and Gardenia jasminoides Ellis extractive solution 25%, stirring, and mixing to obtain Gardenia jasminoides Ellis extract.
The mass fraction of the sodium citrate solution of this example was 7.5%.
The grape seed extractant of the embodiment is prepared by the following specific steps: mixing grape seeds with 80% of ethanol in a mass fraction ratio of 1 to 15, then performing reflux extraction at 60 ℃ for 3 hours, and removing alcohol to obtain the grape seed extractant.
The preparation method of the montmorillonite-supported carbon nanotube modifier comprises the following steps:
s11: sending the carbon nano tube into an acid solution of 2.5 times of sodium alkylsulfonate, then adding ammonium phosphate and lanthanum sulfate, wherein the total amount of the ammonium phosphate and the lanthanum sulfate is 7.5 percent and 3 percent of the total amount of the carbon nano tube, and fully stirring and mixing to obtain a carbon nano tube complexing agent;
s12: sending 12.5 parts of montmorillonite into 25 parts of water, stirring and dispersing, then adding 2.5 parts of carboxymethyl cellulose and 2 parts of tartaric acid, fully dispersing and mixing, washing with water, and drying to obtain modified montmorillonite;
s13: and (2) reacting the modified montmorillonite and the carbon nano tube complexing agent in a reactor according to the weight ratio of 1.
The acid solution of sodium alkylsulfonate in this example is prepared from sodium alkylsulfonate, deionized water, and glycolic acid according to a weight ratio of 3.
The rotational speed of the reaction treatment in the reactor of this example was 1250r/min, the reaction time was 25min, and the reaction temperature was 60 ℃.
The preparation method of the small molecule keratin breakage-proof hair care product easy to enter the hair core repair disulfide bond comprises the following steps: sequentially adding the raw materials into a stirrer, stirring and mixing for 25min, and finishing stirring to obtain the hair care product.
The mixing speed in this example was 500r/min.
Comparative example 1.
In contrast to example 3, no extract of Gardenia jasminoides was added.
Comparative example 2.
Different from the embodiment 3, the preparation of the gardenia extract is not added with a grape seed extracting agent.
Comparative example 3.
Different from example 3, chitosan was not added in the preparation of the extract of Gardenia jasminoides Ellis.
Comparative example 4.
Different from example 3, the extract of Gardenia jasminoides was prepared without adding olive oil.
Comparative example 5.
The difference from the embodiment 3 is that no montmorillonite-loaded carbon nanotube modifier is added in the preparation of the chitosan solution.
Comparative example 6.
Different from the embodiment 3, the montmorillonite raw material is not added in the preparation of the montmorillonite-loaded carbon nanotube modifier.
Comparative example 7.
Different from the embodiment 3, the modified montmorillonite is replaced by montmorillonite in the preparation of the montmorillonite-loaded carbon nanotube modifier.
Washing hair with the shampoo of the product 1 time per night for 7 days, and measuring the repair rate of hair scales;
testing the repair rate of the product to hair scales
Repair rate = total number of repaired hair scale cells/total number of damaged hair scale cells × 100%
The performance of the products of examples 1-3 and comparative examples 1-7 was tested as follows:
as can be seen from comparative examples 1 to 7 and examples 1 to 3;
the product of the invention is not added with the gardenia extract and the montmorillonite-loaded carbon nanotube modifier, the repair rate and the hair elasticity rate of the hair scales of the product are obviously reduced, and meanwhile, chitosan, olive oil and grape seed extracting agent are not added in the preparation of the gardenia extract, so that the repair rate and the elasticity rate of the product are both deteriorated;
in addition, no montmorillonite raw material is added in the preparation of the montmorillonite-supported carbon nanotube modifier, the modified montmorillonite is replaced by montmorillonite, the performance of the product is poor, and the effect of improving the product is most obvious only by adopting the montmorillonite-supported carbon nanotube modifier prepared by the method disclosed by the invention.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present specification describes embodiments, not every embodiment includes only a single embodiment, and such description is for clarity purposes only, and it is to be understood that all embodiments may be combined as appropriate by one of ordinary skill in the art to form other embodiments as will be apparent to those of skill in the art from the description herein.
Claims (10)
1. The micromolecule keratin hair-breaking-prevention hair care product easy to enter a hair core repairing disulfide bond is characterized by comprising the following raw materials in parts by weight:
10-15 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 5-10 parts of hydrolyzed keratin, 3-6 parts of cystine bis-PG-propyl silanetriol, 2-5 parts of nano amino silicone oil, 1-4 parts of D-panthenol, 2-5 parts of malus oil, 2-6 parts of a gardenia extract, 3-6 parts of a montmorillonite-loaded carbon nanotube modifier and 5-10 parts of deionized water.
2. The small molecule keratin broken-proof hair care product easy to enter a hair core to repair disulfide bonds according to claim 1, which is characterized by comprising the following raw materials in parts by weight:
12.5 parts of coconut diammonium hydroxypropyl hydrolyzed keratin, 7.5 parts of hydrolyzed keratin, 4.5 parts of cystine bis-PG-propyl silanetriol, 3.5 parts of nano amino silicone oil, 2.5 parts of D-panthenol, 3.5 parts of maltula oil, 4 parts of a gardenia extract, 4.5 parts of a montmorillonite-loaded carbon nanotube modifier and 7.5 parts of deionized water.
3. The small molecule keratin breakage-proof hair care product easy to enter the hair core for repairing disulfide bonds, as claimed in claim 1, wherein the preparation method of the gardenia extract comprises the following steps:
s01: sending the gardenia extracted from the West region into a pounding machine for pounding, then sending into 3-6 times of water for extracting with slow fire for 1-2h, and filtering after the extraction is finished to obtain a first filtrate;
s02: extracting the residue with 3-5 times of ethanol at 45-50 deg.C for 1-2 hr, removing ethanol, filtering to obtain a second filtrate, and mixing the first and second filtrates to obtain extractive solution of Gardenia jasminoides Ellis;
s03: adding chitosan into 2-3 times of sodium citrate solution, stirring, adding oleum Olivarum 4-8%, grape seed extractant 5-8% and Gardenia jasminoides Ellis extractive solution 20-30%, stirring, and mixing to obtain Gardenia jasminoides Ellis extract.
4. The small molecule keratin breakage-proof hair care product easy to enter the hair core repair disulfide bonds of claim 3, wherein the mass fraction of the sodium citrate solution is 5-10%.
5. The small molecule keratin broken hair-prevention and hair-care product easy to enter the hair core to repair disulfide bonds of claim 3, wherein the grape seed extractant is prepared by the following specific steps: mixing grape seeds with 80% of ethanol in a mass fraction ratio of 1 to 15, then performing reflux extraction at 55-65 ℃ for 2-4h, and removing alcohol to obtain the grape seed extractant.
6. The small-molecule keratin hair breakage prevention and care product easy to enter the hair core repairing disulfide bonds according to claim 5, characterized in that the preparation method of the montmorillonite-supported carbon nanotube modifier comprises the following steps:
s11: sending the carbon nano tube into an acid solution of 2-3 times of sodium alkylsulfonate, then adding 5-10% of ammonium phosphate and 1-5% of lanthanum sulfate based on the total amount of the carbon nano tube, and fully stirring and mixing to obtain a carbon nano tube complexing agent;
s12: sending 10-15 parts of montmorillonite into 20-30 parts of water, stirring and dispersing, then adding 1-4 parts of carboxymethyl cellulose and 1-3 parts of tartaric acid, fully dispersing and mixing, washing with water, and drying to obtain modified montmorillonite;
s13: reacting the modified montmorillonite and the carbon nano tube complexing agent in a reactor according to the weight ratio of 1.
7. The small molecule keratin breakage-proof hair care product with easy access to the core repair disulfide bonds of claim 6, wherein the acid solution of sodium alkyl sulfonate is prepared from sodium alkyl sulfonate, deionized water and glycolic acid according to a weight ratio of 3.
8. The small molecule keratin breakage-proof hair care product easy to enter the hair core repair disulfide bonds of claim 6, wherein the rotation speed of the reaction treatment in the reactor is 1000-1500r/min, the reaction time is 20-30min, and the reaction temperature is 55-65 ℃.
9. A process for the preparation of a small molecule keratin breakage-preventing hair care product with easy access to the core repair disulfide bonds according to any one of claims 1 to 8 comprising the steps of: sequentially adding the raw materials into a stirrer, stirring and mixing for 20-30min, and stirring to obtain the hair care product.
10. The method for preparing the small molecule keratin breakage-proof hair care product with easy access to the hair core repair disulfide bonds according to claim 9, wherein the mixing rotating speed is 450-550r/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116115514A (en) * | 2023-04-04 | 2023-05-16 | 广州美思生物技术有限公司 | Hair-care plant protein composition and preparation method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116115514A (en) * | 2023-04-04 | 2023-05-16 | 广州美思生物技术有限公司 | Hair-care plant protein composition and preparation method and application thereof |
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