CN115605523A - 浸渍成型体 - Google Patents
浸渍成型体 Download PDFInfo
- Publication number
- CN115605523A CN115605523A CN202180024554.3A CN202180024554A CN115605523A CN 115605523 A CN115605523 A CN 115605523A CN 202180024554 A CN202180024554 A CN 202180024554A CN 115605523 A CN115605523 A CN 115605523A
- Authority
- CN
- China
- Prior art keywords
- chloroprene
- polymerization
- polymer block
- monomer
- latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004816 latex Substances 0.000 claims abstract description 121
- 229920000126 latex Polymers 0.000 claims abstract description 121
- 239000000178 monomer Substances 0.000 claims abstract description 117
- 229920001400 block copolymer Polymers 0.000 claims abstract description 63
- 230000009477 glass transition Effects 0.000 claims abstract description 35
- 238000005470 impregnation Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 abstract description 36
- 238000004073 vulcanization Methods 0.000 abstract description 28
- 239000003795 chemical substances by application Substances 0.000 abstract description 19
- 238000003878 thermal aging Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 description 219
- 238000004458 analytical method Methods 0.000 description 74
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 72
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 52
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- LWMFAFLIWMPZSX-UHFFFAOYSA-N bis[2-(4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene Chemical compound N=1CCNC=1C(C)(C)N=NC(C)(C)C1=NCCN1 LWMFAFLIWMPZSX-UHFFFAOYSA-N 0.000 description 22
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- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 5
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- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
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- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
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- WEERVPDNCOGWJF-UHFFFAOYSA-N 1,4-bis(ethenyl)benzene Chemical compound C=CC1=CC=C(C=C)C=C1 WEERVPDNCOGWJF-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
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- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- AISZNMCRXZWVAT-UHFFFAOYSA-N 2-ethylsulfanylcarbothioylsulfanyl-2-methylpropanenitrile Chemical compound CCSC(=S)SC(C)(C)C#N AISZNMCRXZWVAT-UHFFFAOYSA-N 0.000 description 2
- PGDIJTMOHORACQ-UHFFFAOYSA-N 9-prop-2-enoyloxynonyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCCCCOC(=O)C=C PGDIJTMOHORACQ-UHFFFAOYSA-N 0.000 description 2
- CLZVZBNIOFZSDI-UHFFFAOYSA-N C(N)(S)=S.C1(=CC=CC=C1)C(C)C=1NC=CN1 Chemical compound C(N)(S)=S.C1(=CC=CC=C1)C(C)C=1NC=CN1 CLZVZBNIOFZSDI-UHFFFAOYSA-N 0.000 description 2
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- NTEOVSMTYUCTKA-UHFFFAOYSA-N benzyl 4-chlorobenzenecarbodithioate Chemical compound C1=CC(Cl)=CC=C1C(=S)SCC1=CC=CC=C1 NTEOVSMTYUCTKA-UHFFFAOYSA-N 0.000 description 2
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/05—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0058—Liquid or visquous
- B29K2105/0064—Latex, emulsion or dispersion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulding By Coating Moulds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2020-056387 | 2020-03-26 | ||
| JP2020056387 | 2020-03-26 | ||
| PCT/JP2021/011779 WO2021193562A1 (ja) | 2020-03-26 | 2021-03-22 | 浸漬成形体 |
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| CN115605523A true CN115605523A (zh) | 2023-01-13 |
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| EP (1) | EP4129609B1 (https=) |
| JP (1) | JP7503129B2 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP4130080B1 (en) | 2020-03-26 | 2025-07-30 | Denka Company Limited | Chloroprene-based block copolymer, latex, latex composition, and rubber composition |
| JP7784437B2 (ja) * | 2021-09-28 | 2025-12-11 | デンカ株式会社 | クロロプレン系ブロック共重合体、ラテックス、ラテックス組成物、及びゴム組成物 |
| JP2026059811A (ja) * | 2023-02-27 | 2026-04-08 | デンカ株式会社 | クロロプレン系ブロック共重合体、クロロプレン系ブロック共重合体ラテックス、クロロプレン系ブロック共重合体ラテックス組成物、浸漬成形体、ゴム組成物、及び成形体 |
| JP2026059810A (ja) * | 2023-02-27 | 2026-04-08 | デンカ株式会社 | クロロプレン系ブロック共重合体、クロロプレン系ブロック共重合体ラテックス、クロロプレン系ブロック共重合体ラテックス組成物、ゴム組成物、及び浸漬成形体 |
| WO2025164576A1 (ja) * | 2024-01-31 | 2025-08-07 | デンカ株式会社 | クロロプレン系重合体、クロロプレン系重合体ラテックス、クロロプレン系重合体ラテックス組成物、浸漬成形体、ゴム組成物、及び成形体 |
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| US4443582A (en) * | 1981-05-26 | 1984-04-17 | Bayer Aktiengesellschaft | Mixtures of chloroprene polymers and the production thereof |
| CN101263170A (zh) * | 2005-07-08 | 2008-09-10 | 东曹株式会社 | 氯丁二烯类嵌段共聚物和无皂聚氯丁二烯类胶乳、以及它们的制造方法 |
| JP2011122141A (ja) * | 2009-11-10 | 2011-06-23 | Showa Denko Kk | クロロプレン系重合体ラテックス及びその製造方法 |
| CN110167982A (zh) * | 2017-03-30 | 2019-08-23 | 电化株式会社 | 嵌段共聚物及嵌段共聚物的制造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2844785B2 (ja) | 1990-01-18 | 1999-01-06 | 東ソー株式会社 | クロロプレンブロック共重合体 |
| JP2850432B2 (ja) | 1990-01-11 | 1999-01-27 | 東ソー株式会社 | 共重合体及びその製造方法 |
| DE112006001808T5 (de) * | 2005-07-08 | 2008-06-19 | Tosoh Corporation | Blockcopolymer auf Chloroprenbasis, seifenfreier Latex auf Polychloroprenbasis und Verfahren zur Herstellung derselbigen |
| JP2007297502A (ja) | 2006-04-28 | 2007-11-15 | Tosoh Corp | ソープレスポリクロロプレン系ラテックス及びその製造法 |
| JP2010001458A (ja) * | 2008-05-23 | 2010-01-07 | Tosoh Corp | ポリクロロプレンラテックス及びその製造法 |
| FR2935979B1 (fr) | 2008-09-18 | 2011-04-08 | Arkema France | Nouveau materiau elastomere et son procede d'obtention |
| KR101715213B1 (ko) * | 2010-06-25 | 2017-03-10 | 얼리젼스 코포레이션 | 알레르기 유발 가능성이 감소된 가황 조성물 |
| JP5918767B2 (ja) | 2011-07-25 | 2016-05-18 | デンカ株式会社 | ポリクロロプレンラテックス組成物及び浸漬成形品 |
| NL2007262C2 (en) * | 2011-08-12 | 2013-02-13 | Kraton Polymers Us Llc | A process for preparing articles from a latex comprising water and a styrenic block copolymer and such a latex. |
| JP6041650B2 (ja) * | 2012-12-07 | 2016-12-14 | デンカ株式会社 | ポリクロロプレンラテックス、ポリクロロプレンラテックス組成物及び浸漬成形製品 |
| KR101797883B1 (ko) * | 2013-10-11 | 2017-11-15 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | 올레핀계 불포화 방사형 스티렌계 블록 공중합체 및 개량된 가황제 무함유 라텍스 |
| CN107429001B (zh) | 2015-04-16 | 2021-05-28 | 昭和电工株式会社 | 橡胶用组合物及其用途 |
| BR112018015004A2 (pt) * | 2016-01-27 | 2018-12-18 | Zeon Corporation | ?composição de látex, película moldada, e, método para produção de um produto moldado por imersão? |
| EP3431510A4 (en) * | 2016-03-15 | 2019-10-23 | Zeon Corporation | PROCESS FOR PRODUCING POLYMER LATEX |
| MY192063A (en) | 2017-07-04 | 2022-07-25 | Denka Company Ltd | Mercaptane-modified polychloroprene latex and production method therefor |
| CN110959019B (zh) * | 2017-07-31 | 2022-10-14 | 电化株式会社 | 嵌段共聚物和嵌段共聚物的制造方法 |
| US10759913B2 (en) * | 2017-12-13 | 2020-09-01 | Allegiance Corporation | Vulcanization composition for reducing allergenic potential and elastomeric articles formed therewith |
-
2021
- 2021-03-22 US US17/788,782 patent/US20230025987A1/en active Pending
- 2021-03-22 EP EP21776541.1A patent/EP4129609B1/en active Active
- 2021-03-22 JP JP2022510498A patent/JP7503129B2/ja active Active
- 2021-03-22 CN CN202180024554.3A patent/CN115605523A/zh active Pending
- 2021-03-22 WO PCT/JP2021/011779 patent/WO2021193562A1/ja not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4443582A (en) * | 1981-05-26 | 1984-04-17 | Bayer Aktiengesellschaft | Mixtures of chloroprene polymers and the production thereof |
| CN101263170A (zh) * | 2005-07-08 | 2008-09-10 | 东曹株式会社 | 氯丁二烯类嵌段共聚物和无皂聚氯丁二烯类胶乳、以及它们的制造方法 |
| JP2011122141A (ja) * | 2009-11-10 | 2011-06-23 | Showa Denko Kk | クロロプレン系重合体ラテックス及びその製造方法 |
| CN110167982A (zh) * | 2017-03-30 | 2019-08-23 | 电化株式会社 | 嵌段共聚物及嵌段共聚物的制造方法 |
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| JP7503129B2 (ja) | 2024-06-19 |
| US20230025987A1 (en) | 2023-01-26 |
| EP4129609B1 (en) | 2024-11-27 |
| EP4129609A1 (en) | 2023-02-08 |
| JPWO2021193562A1 (https=) | 2021-09-30 |
| WO2021193562A1 (ja) | 2021-09-30 |
| EP4129609A4 (en) | 2023-10-11 |
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