CN115605449A - 含氧化合物生产低碳烯烃的方法 - Google Patents
含氧化合物生产低碳烯烃的方法 Download PDFInfo
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- CN115605449A CN115605449A CN202180020813.5A CN202180020813A CN115605449A CN 115605449 A CN115605449 A CN 115605449A CN 202180020813 A CN202180020813 A CN 202180020813A CN 115605449 A CN115605449 A CN 115605449A
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- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 120
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title description 6
- 150000001875 compounds Chemical class 0.000 title description 6
- 238000004519 manufacturing process Methods 0.000 title description 6
- 229910052760 oxygen Inorganic materials 0.000 title description 6
- 239000001301 oxygen Substances 0.000 title description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 330
- 238000006243 chemical reaction Methods 0.000 claims abstract description 247
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 96
- 238000000034 method Methods 0.000 claims abstract description 64
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000005977 Ethylene Substances 0.000 claims abstract description 41
- 239000002808 molecular sieve Substances 0.000 claims abstract description 39
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 39
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 36
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 36
- 150000001336 alkenes Chemical class 0.000 claims abstract description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 213
- 238000009826 distribution Methods 0.000 claims description 61
- 230000008021 deposition Effects 0.000 claims description 37
- 238000000926 separation method Methods 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 26
- 230000008929 regeneration Effects 0.000 claims description 24
- 238000011069 regeneration method Methods 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 16
- 239000000571 coke Substances 0.000 claims description 12
- 239000007789 gas Substances 0.000 description 30
- 239000000047 product Substances 0.000 description 24
- 238000004458 analytical method Methods 0.000 description 18
- 238000005070 sampling Methods 0.000 description 18
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- JGNPSJMNGPUQIW-UHFFFAOYSA-N [C].CC=C Chemical group [C].CC=C JGNPSJMNGPUQIW-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- -1 steam) Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000269350 Anura Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000012492 regenerant Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
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- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
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- B01D45/16—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream, the centrifugal forces being generated solely or partly by mechanical means, e.g. fixed swirl vanes
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- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
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- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C2529/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
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Abstract
由含氧化合物生产低碳烯烃的方法,包括使包含含氧化合物的原料在流化床反应区与分子筛催化剂接触,在有效条件下生成含乙烯和/或丙烯产品的步骤;所述有效条件包括所述流化床反应区内,以催化剂中分子筛质量计,控制各种积炭量的催化剂质量占所述流化床反应区内全部催化剂质量的比例如下:积炭量小于3重量%的催化剂质量占所述流化床反应区内全部催化剂质量的比例。
Description
PCT国内申请,说明书已公开。
Claims (16)
- PCT国内申请,权利要求书已公开。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010173926.6A CN113387763B (zh) | 2020-03-13 | 2020-03-13 | 含氧化合物生产低碳烯烃的方法 |
CN2020101739393 | 2020-03-13 | ||
CN202010173939.3A CN113387765B (zh) | 2020-03-13 | 2020-03-13 | 以甲醇为原料制备烯烃的方法 |
CN2020101739266 | 2020-03-13 | ||
PCT/CN2021/080114 WO2021180150A1 (zh) | 2020-03-13 | 2021-03-11 | 含氧化合物生产低碳烯烃的方法 |
Publications (1)
Publication Number | Publication Date |
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CN115605449A true CN115605449A (zh) | 2023-01-13 |
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CN202180020813.5A Pending CN115605449A (zh) | 2020-03-13 | 2021-03-11 | 含氧化合物生产低碳烯烃的方法 |
Country Status (6)
Country | Link |
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US (1) | US20230118436A1 (zh) |
CN (1) | CN115605449A (zh) |
AU (1) | AU2021233959A1 (zh) |
BR (1) | BR112022018248A2 (zh) |
WO (1) | WO2021180150A1 (zh) |
ZA (1) | ZA202211242B (zh) |
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BE1027227B1 (nl) * | 2019-04-25 | 2020-11-23 | Atlas Copco Airpower Nv | Inrichting en werkwijze voor het afscheiden van vloeistof uit een gas en compressorinrichting voorzien van zulke inrichting |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101293803B (zh) * | 2008-04-11 | 2011-08-17 | 中国石油化工股份有限公司 | 含氧化合物转化为低碳烯烃的方法 |
CN101260013B (zh) * | 2008-04-24 | 2011-07-20 | 中国石油化工股份有限公司 | 含氧化合物制备低碳烯烃的方法 |
CN101318870B (zh) * | 2008-06-12 | 2011-07-20 | 中国石油化工股份有限公司 | 提高乙烯和丙烯收率的方法 |
-
2021
- 2021-03-11 WO PCT/CN2021/080114 patent/WO2021180150A1/zh active Application Filing
- 2021-03-11 AU AU2021233959A patent/AU2021233959A1/en active Pending
- 2021-03-11 CN CN202180020813.5A patent/CN115605449A/zh active Pending
- 2021-03-11 US US17/906,230 patent/US20230118436A1/en active Pending
- 2021-03-11 BR BR112022018248A patent/BR112022018248A2/pt unknown
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2022
- 2022-10-13 ZA ZA2022/11242A patent/ZA202211242B/en unknown
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Publication number | Publication date |
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BR112022018248A2 (pt) | 2022-10-25 |
AU2021233959A1 (en) | 2022-10-06 |
US20230118436A1 (en) | 2023-04-20 |
WO2021180150A1 (zh) | 2021-09-16 |
ZA202211242B (en) | 2024-04-24 |
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