CN115417698A - Linear interval color stripe glazed ceramic and preparation method thereof - Google Patents
Linear interval color stripe glazed ceramic and preparation method thereof Download PDFInfo
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- CN115417698A CN115417698A CN202211061066.2A CN202211061066A CN115417698A CN 115417698 A CN115417698 A CN 115417698A CN 202211061066 A CN202211061066 A CN 202211061066A CN 115417698 A CN115417698 A CN 115417698A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 238000004804 winding Methods 0.000 claims abstract description 27
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000010410 layer Substances 0.000 claims abstract description 22
- 239000011521 glass Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000012792 core layer Substances 0.000 claims abstract description 14
- 239000010453 quartz Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 7
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 4
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims description 18
- 238000010304 firing Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- 235000019738 Limestone Nutrition 0.000 claims description 12
- 239000006028 limestone Substances 0.000 claims description 12
- 239000003292 glue Substances 0.000 claims description 10
- 238000003825 pressing Methods 0.000 claims description 10
- 239000010433 feldspar Substances 0.000 claims description 8
- 239000004927 clay Substances 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 229920004933 Terylene® Polymers 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 3
- 238000010000 carbonizing Methods 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 239000010436 fluorite Substances 0.000 claims description 3
- 239000010443 kyanite Substances 0.000 claims description 3
- 229910052850 kyanite Inorganic materials 0.000 claims description 3
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 3
- 230000036961 partial effect Effects 0.000 claims description 3
- -1 polypropylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 230000001360 synchronised effect Effects 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000009987 spinning Methods 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
Abstract
The invention relates to the field of ceramic products and preparation processes thereof, in particular to a linear interval color stripe glazed ceramic and a preparation method thereof, wherein the ceramic comprises a green body and a glaze, the green body is a rotating body, the glaze comprises an annular three-dimensional stripe covered on the surface of the green body and a transparent glaze covered on the surface of the annular three-dimensional stripe, and the transparent glaze comprises the following components in parts by weight: 50-60 parts of potassium feldspar, 10-12 parts of quartz, 15-18 parts of calcite, 5-8 parts of kaolin, 4-6 parts of glass powder, 4-6 parts of lithium carbonate and 3-4 parts of zinc oxide. The stripe yarns are adhered to the surface of the blank body after wrapping the ground glaze, and because the thickness and the gap of the stripe yarns and the skin layer of the stripe yarns are locally sunken after being burnt, the annular stripe with a three-dimensional effect is formed, and the colored glaze in the core layer enables the glaze surface to be mixed with colored stripes at intervals, so that the stripe has a unique aesthetic value; three-dimensional grains are formed in a yarn winding mode, the operation is simple and convenient, and the grains are fine and smooth.
Description
Technical Field
The invention relates to the field of ceramic products and preparation processes thereof, in particular to linear spaced color stripe glazed ceramics and a preparation method thereof.
Background
The ceramic glaze is a glaze of ceramic products and mainly consists of a ceramic layer and a glaze layer. The glaze applied on the ceramic ware is prepared from quartz, feldspar and clay as raw materials by grinding, adding water, coating on the surface of a blank, roasting at a certain temperature to melt, and forming a vitreous thin layer on the surface of the ceramic ware when the temperature is reduced. It can increase the mechanical strength, thermal stability, dielectric strength and prevent the erosion of liquid and gas. The glaze also has the functions of improving the appearance of the porcelain, facilitating cleaning and being not stained by dust, and the like. In order to present three-dimensional texture on a glaze, the traditional process comprises the steps of carving corresponding textures on a blank body through tools such as a carving knife and the like, for example, carving annular textures along the blank body, sequentially forming three-dimensional textures on the blank body, then applying glaze on the blank body, and enabling the glaze to present concave-convex texture after sintering.
Disclosure of Invention
It is an object of the present invention to solve at least the above problems by a linearly spaced striped glazed ceramic and a method for its preparation.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: the linear interval color stripe glazed ceramic is characterized in that: the glaze comprises a blank body and a glaze layer, wherein the blank body is a rotating body, the glaze layer comprises an annular three-dimensional stripe covering the surface of the blank body and a transparent glaze covering the surface of the annular three-dimensional stripe, and the transparent glaze comprises the following components in parts by weight: 50-60 parts of potash feldspar, 10-12 parts of quartz, 15-18 parts of calcite, 5-8 parts of kaolin, 4-6 parts of glass powder, 4-6 parts of lithium carbonate and 3-4 parts of zinc oxide.
Preferably, the annular three-dimensional stripes are distributed on the surface of the blank body from top to bottom, and the annular three-dimensional stripes are formed by wrapping the ground glaze with stripe yarns and then firing.
Preferably, the stripe yarn is a skin-core structure, the skin-core structure comprises a skin layer and a core layer, and the skin layer is one of terylene, polypropylene or acrylic fibers.
Preferably, the core layer comprises the following raw materials in parts by weight: 10-12 parts of terylene and 10-15 parts of colored glaze.
Preferably, the raw materials of the colored glaze comprise the following components in parts by weight: 30-35 parts of color block, 5-8 parts of glass powder, 10-12 parts of quartz, 15-16 parts of feldspar, 8-10 parts of clay, 5-8 parts of zinc oxide, 4-6 parts of limestone, 8-10 parts of sodium carbonate and 6-10 parts of tin dioxide.
Preferably, the color block is one of a fluorescent material and an iridescent material, and the raw materials of the fluorescent material comprise the following components in parts by weight: 10-12 parts of glass powder, 20-22 parts of fluorite, 4-8 parts of quartz, 5-8 parts of alumina, 5-6 parts of anhydrous boric acid, 4-5 parts of lithium carbonate, 6-8 parts of kyanite, 3-4 parts of zirconium silicate and 6-8 parts of limestone; the raw materials of the iridescent material comprise the following components in parts by weight: 10-12 parts of high-lead frit, 8-10 parts of manganese oxide, 5-6 parts of copper oxide, 3-4 parts of nickel oxide, 2-3 parts of zinc oxide, 2-3 parts of titanium dioxide, 10-12 parts of glass powder, 6-8 parts of limestone and 5-8 parts of aluminum oxide.
Preferably, the base coat comprises the following raw materials in parts by weight: 5-6 parts of CMC glue, 8-10 parts of glass powder, 5-6 parts of quartz, 12-15 parts of feldspar, 8-10 parts of clay, 7-9 parts of limestone, 5-6 parts of zinc oxide and 10-12 parts of borax.
The preparation method of the linear space color stripe glaze ceramic is characterized by comprising the following steps: the method comprises the following steps:
step a, preparing a blank, and firing the blank in a kiln;
step b, winding stripe yarns stained with ground glaze on the surface of the blank;
c, applying transparent glaze on the surfaces of the striped yarns;
and d, putting the yarn into a kiln for glaze firing, carbonizing the cortex of the stripe yarn in the firing process, exposing the color of the colored glaze of the core layer, and distributing black and colored three-dimensional annular stripes alternately on the glaze surface from top to bottom.
Preferably, in step b, the body passes through yarn coiler winding stripe yarn, the yarn coiler includes initiative carousel, driven turntable, initiative motor, glaze groove, drips glaze mouth, drips glaze pipe, pump, lead screw slip table, sliding seat and wire eye, initiative carousel and driven turntable's pivot is parallel, and initiative motor drive initiative carousel is rotatory, and the initiative carousel is used for placing the body, is equipped with the centering fixture who is used for centre gripping and location body on the initiative carousel, and the carousel top is equipped with the pressure disk with initiative carousel synchronous revolution, be equipped with the winding post of storing the stripe yarn on the driven turntable, the glaze groove sets up between initiative carousel and driven turntable, and the stripe yarn on the winding post arrives the body on the initiative carousel from the top in glaze groove through, and the lead screw slip table is located between initiative carousel and the driven turntable, and lead screw slip table drive sliding seat is equipped with the wire eye along longitudinal movement on the sliding seat, the yarn stripe passes from the wire eye, drip glaze mouth is located glaze groove top and is located between wire eye and the initiative carousel, and drip glaze mouth through glaze pipe and glaze groove intercommunication, and the bottom glaze in the glaze groove by the pump sending to drip glaze mouth.
Preferably, the step of winding the stripe yarn in the step b by a yarn winding machine comprises the following steps: placing a blank on a driving turntable, performing center positioning on the blank through a centering fixture, pressing a pressure plate to the top of the blank to fix the blank, dipping the head of stripe yarns with partial glue, guiding the head of the stripe yarns to the surface of the blank to be close to the top for fixing, starting the driving turntable to rotate after the glue is dried, enabling the stripe yarns on a winding column to pass through the glaze groove and to pass through a guide wire eye to be wound on the blank, and driving the guide wire eye to move from top to bottom under the driving of a screw rod sliding table so as to drive the stripe yarns to cover the surface of the blank from top to bottom; in the process of yarn winding, the glaze dripping nozzle drips the ground glaze on the stripe yarns, and before the active rotary table is started, the ground glaze is manually brushed on the part between the head of the stripe yarns and the wire eye.
From the above description, the linear space color stripe glazed ceramic and the preparation method thereof provided by the invention have the following beneficial effects: the stripe yarns are adhered to the surface of the blank body after wrapping the ground glaze, and because the thickness and the gap of the stripe yarns and the skin layer of the stripe yarns are locally sunken after being burnt, the annular stripe with a three-dimensional effect is formed, and the colored glaze in the core layer enables the glaze surface to be mixed with colored stripes at intervals, so that the stripe has a unique aesthetic value; three-dimensional grains are formed in a yarn winding mode, the operation is simple and convenient, and the grains are fine and smooth.
Drawings
Fig. 1 is a schematic structural view of a yarn winding machine.
Detailed Description
The invention is further described below by means of specific embodiments.
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further explained by combining the specific embodiments.
As shown in the figure, the linear interval color stripe glazed ceramic comprises a green body and a glaze, wherein the green body is a rotating body, the glaze comprises an annular three-dimensional stripe covering the surface of the green body and a transparent glaze covering the surface of the annular three-dimensional stripe, and the transparent glaze comprises the following components in parts by weight: 50-60 parts of potassium feldspar, 10-12 parts of quartz, 15-18 parts of calcite, 5-8 parts of kaolin, 4-6 parts of glass powder, 4-6 parts of lithium carbonate and 3-4 parts of zinc oxide. The transparent glaze has a transparent effect after being fired, and covers the annular three-dimensional stripes to form transparent protective layers.
The annular three-dimensional stripes are distributed on the surface of the blank body from top to bottom and are formed by wrapping the ground glaze with stripe yarns and then firing. The stripe yarns are adhered to the surface of the blank body after being wrapped with the ground glaze, and the stripe yarns are locally sunken due to the thickness and the gaps of the stripe yarns and the burning of the skin layers of the stripe yarns, so that the annular stripe with the three-dimensional effect is formed.
The stripe yarn is of a skin-core structure, the skin-core structure comprises a skin layer and a core layer, and the skin layer is one of terylene, polypropylene or acrylic. The yarn of skin-core structure is formed by spinning, and the melting raw material of the skin layer and the melting raw material of the core layer are converged to a spinning nozzle and are sprayed by the spinning nozzle.
The core layer comprises the following raw materials in parts by weight: 10-12 parts of terylene and 10-15 parts of colored glaze.
The colored glaze comprises the following raw materials in parts by weight: 30-35 parts of color block, 5-8 parts of glass powder, 10-12 parts of quartz, 15-16 parts of feldspar, 8-10 parts of clay, 5-8 parts of zinc oxide, 4-6 parts of limestone, 8-10 parts of sodium carbonate and 6-10 parts of tin dioxide.
The color block is one of fluorescent material and iridescent material, and the raw material of the fluorescent material comprises the following components in parts by weight: 10-12 parts of glass powder, 20-22 parts of fluorite, 4-8 parts of quartz, 5-8 parts of alumina, 5-6 parts of anhydrous boric acid, 4-5 parts of lithium carbonate, 6-8 parts of kyanite, 3-4 parts of zirconium silicate and 6-8 parts of limestone; the raw materials of the rainbow material comprise the following components in parts by weight: 10-12 parts of high-lead clinker, 8-10 parts of manganese oxide, 5-6 parts of copper oxide, 3-4 parts of nickel oxide, 2-3 parts of zinc oxide, 2-3 parts of titanium dioxide, 10-12 parts of glass powder, 6-8 parts of limestone and 5-8 parts of aluminum oxide. The phosphor has a fluorescent effect after being fired, the glaze surface integrally shows the fluorescent effect of black stripes and fluorescent stripes after being fired, and the house is beautiful; the iridescent material has golden yellow iridescent effect after being fired, and the glaze surface has the mixed effect of black stripes and golden yellow iridescent stripes after being fired; the color block can also select glaze with other colors or effects according to requirements.
The ground glaze comprises the following raw materials in parts by weight: 5-6 parts of CMC glue, 8-10 parts of glass powder, 5-6 parts of quartz, 12-15 parts of feldspar, 8-10 parts of clay, 7-9 parts of limestone, 5-6 parts of zinc oxide and 10-12 parts of borax. The ground glaze with the glue added helps the stripe yarns to adhere to the surface of the blank body in the winding process.
The preparation method of the linear interval color stripe glaze ceramic comprises the following steps:
step a, preparing a blank, and firing the blank in a kiln;
step b, winding stripe yarns stained with ground glaze on the surface of the blank;
c, applying transparent glaze on the surface of the striped yarn;
and d, putting the yarn into a kiln for glaze firing, carbonizing the skin layer of the stripe yarn in the firing process, exposing the color of the colored glaze of the core layer, and distributing black and colored three-dimensional annular stripes alternately on the glaze layer from top to bottom. The skin layer and the core layer contain high molecular materials, and are carbonized in the firing process, so that the glaze surface presents black ground color, and the colored glaze in the core layer enables colored stripes to be mixed in the glaze surface at intervals. The biscuit firing temperature is 800-900 ℃, and the firing temperature of the glaze is 1100-1150 ℃.
In the step b, as shown in fig. 1, a blank body is wound with stripe yarns through a yarn winding machine, the yarn winding machine comprises a driving rotary table 1, a driven rotary table 2, a driving motor, a glaze groove 3, a glaze dripping nozzle 4, a glaze dripping pipe 5, a pump, a lead screw sliding table 6, a sliding seat 7 and a guide eye 8, rotating shafts of the driving rotary table 1 and the driven rotary table 2 are parallel, the driving motor drives the driving rotary table 1 to rotate, the driving rotary table 1 is used for placing the blank body, a centering fixture used for clamping and positioning the blank body is arranged on the driving rotary table 1, the centering fixture is a three-jaw centering fixture, a pressure plate 10 synchronously rotating with the driving rotary table 1 is arranged above the rotary table, a winding column 9 for storing the stripe yarns is arranged on the driven rotary table 2, the glaze groove 3 is arranged between the driving rotary table 1 and the driven rotary table 2, the stripe yarns on the winding column 9 pass through the blank body on the driving rotary table 1 from the upper side of the glaze groove 3 to the blank body on the driving rotary table 1, the lead screw sliding table 6 is arranged between the driving rotary table 1 and the driven rotary table 2, the sliding seat 7 longitudinally moves, the sliding seat 8 is provided with the guide eye 8 on the sliding seat, the stripe yarns passing through the glaze groove 4, the glaze groove 3 is arranged in the glaze groove 3, the glaze groove 4, the glaze groove 3 is communicated with the glaze dripping nozzle 4, and the glaze groove 3, and the glaze dripping nozzle 4, and the glaze dripping nozzle, and the dripping nozzle is communicated with the dripping nozzle 4, and the glaze groove 3, and the dripping nozzle 4, and the dripping nozzle is communicated with the glaze groove 3. The pressing plate 10 is rotatably fixed on the pressing rod 11, the pressing rod 11 is driven by a cylinder or a lead screw sliding table 6 and the like to move up and down, the pressing rod 11 is overlapped with the rotation axis of the driving turntable 1, and after a blank body is placed on the driving turntable 1 and is centrally positioned, the pressing plate 10 is pressed down to the top of the blank body, so that the blank body is fixed between the driving turntable 1 and the pressing plate 10 and rotates along with the driving turntable 1 and the pressing plate 10.
The step b of winding the stripe yarn by a yarn winding machine comprises the following steps: placing a blank body on an active rotary table 1, performing center positioning on the blank body through a centering fixture, pressing a pressure plate 10 downwards to the top of the blank body, fixing the blank body, dipping the head of stripe yarns with partial glue, guiding the head of the stripe yarns to the surface of the blank body to be close to the top for fixing, starting the active rotary table 1 to rotate after the glue is dried, enabling the stripe yarns on a winding column 9 to pass through the glaze groove 3 and pass through a guide wire eye 8 to be wound on the blank body, and driving the guide wire eye 8 to move from top to bottom under the driving of a lead screw sliding table 6 so as to drive the stripe yarns to spirally cover the surface of the blank body from top to bottom; in the process of yarn winding, the glaze dripping nozzle 4 drips the ground glaze on the stripe yarns, and before the active turntable 1 is started, the ground glaze is manually brushed on the part between the head of the stripe yarns and the wire eye 8.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "front", "rear", "left", "right", "top", "bottom", "inner", "outer", and the like, which indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, are used only for convenience in describing the present invention and for simplicity in description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be constructed in a specific orientation, and be operated, and therefore, should not be construed as limiting the present invention, and what is not described in detail in the present specification is prior art and is known to those skilled in the art.
In the description of the present invention, it should be noted that unless otherwise explicitly stated or limited, the terms "mounted," "connected" and "disposed" are to be construed broadly and can be, for example, fixedly connected, disposed, detachably connected, disposed or integrally connected and disposed; the type of the electrical appliance provided by the invention is only used for reference. For those skilled in the art, different types of electrical appliances with the same function can be replaced according to actual use conditions, and for those skilled in the art, specific meanings of the above terms in the present invention can be understood in specific situations.
The above description is only a few specific embodiments of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by the design concept should fall within the scope of the present invention.
Claims (10)
1. The linear interval color stripe glazed ceramic is characterized in that: the glaze comprises a blank body and a glaze layer, wherein the blank body is a rotating body, the glaze layer comprises an annular three-dimensional stripe covering the surface of the blank body and a transparent glaze covering the surface of the annular three-dimensional stripe, and the transparent glaze comprises the following components in parts by weight: 50-60 parts of potassium feldspar, 10-12 parts of quartz, 15-18 parts of calcite, 5-8 parts of kaolin, 4-6 parts of glass powder, 4-6 parts of lithium carbonate and 3-4 parts of zinc oxide.
2. The linearly spaced striped glazed ceramic of claim 1, wherein: the annular three-dimensional stripes are distributed on the surface of the blank from top to bottom, and the annular three-dimensional stripes are formed by wrapping the ground glaze with stripe yarns and then firing.
3. The linearly spaced, striped, glazed ceramic of claim 1, wherein: the stripe yarn is of a skin-core structure, the skin-core structure comprises a skin layer and a core layer, and the skin layer is one of terylene, polypropylene or acrylic.
4. The linearly spaced, striped, glazed ceramic of claim 1, wherein: the core layer comprises the following raw materials in parts by weight: 10-12 parts of terylene and 10-15 parts of colored glaze.
5. The linearly spaced, striped, glazed ceramic of claim 1, wherein: the colored glaze comprises the following raw materials in parts by weight: 30-35 parts of color block, 5-8 parts of glass powder, 10-12 parts of quartz, 15-16 parts of feldspar, 8-10 parts of clay, 5-8 parts of zinc oxide, 4-6 parts of limestone, 8-10 parts of soda ash and 6-10 parts of tin dioxide.
6. The linearly spaced, striped, glazed ceramic of claim 1, wherein: the color block is one of a fluorescent material and an iridescent material, and the raw materials of the fluorescent material comprise the following components in parts by weight: 10-12 parts of glass powder, 20-22 parts of fluorite, 4-8 parts of quartz, 5-8 parts of alumina, 5-6 parts of anhydrous boric acid, 4-5 parts of lithium carbonate, 6-8 parts of kyanite, 3-4 parts of zirconium silicate and 6-8 parts of limestone; the raw materials of the iridescent material comprise the following components in parts by weight: 10-12 parts of high-lead clinker, 8-10 parts of manganese oxide, 5-6 parts of copper oxide, 3-4 parts of nickel oxide, 2-3 parts of zinc oxide, 2-3 parts of titanium dioxide, 10-12 parts of glass powder, 6-8 parts of limestone and 5-8 parts of aluminum oxide.
7. The linearly spaced, striped, glazed ceramic of claim 1, wherein: the ground glaze comprises the following raw materials in parts by weight: 5-6 parts of CMC glue, 8-10 parts of glass powder, 5-6 parts of quartz, 12-15 parts of feldspar, 8-10 parts of clay, 7-9 parts of limestone, 5-6 parts of zinc oxide and 10-12 parts of borax.
8. The method for preparing a linear space color stripe glazed ceramic as claimed in any one of claims 1-7, wherein: the method comprises the following steps:
step a, preparing a blank, and firing the blank in a kiln;
step b, winding stripe yarns stained with ground glaze on the surface of the blank;
c, applying transparent glaze on the surface of the striped yarn;
and d, putting the yarn into a kiln for glaze firing, carbonizing the skin layer of the stripe yarn in the firing process, exposing the color of the colored glaze of the core layer, and distributing black and colored three-dimensional annular stripes alternately on the glaze layer from top to bottom.
9. The method for preparing a linear space color stripe glazed ceramic as claimed in claim 8, wherein: in step b, the body passes through yarn coiler winding stripe yarn, the yarn coiler includes initiative carousel, driven turntable, initiative motor, glaze groove, drips glaze mouth, drips glaze pipe, pump, lead screw slip table, sliding seat and wire eye, the pivot of initiative carousel and driven turntable is parallel, and initiative motor drive initiative carousel is rotatory, and the initiative carousel is used for placing the body, is equipped with the centering fixture who is used for centre gripping and location body on the initiative carousel, is equipped with the pressure disk with initiative carousel synchronous revolution above the carousel, be equipped with the spiral post of storing the stripe yarn on the driven turntable, the glaze groove sets up between initiative carousel and driven turntable, and the stripe yarn on the spiral post arrives the body on the initiative carousel from the top in glaze groove, and the lead screw slip table is located between initiative carousel and the driven turntable, and lead screw slip table drive sliding seat is equipped with the wire eye along longitudinal movement on the sliding seat, the stripe yarn passes from the wire eye, drip glaze mouth be located glaze groove top and be located the wire eye and initiative between, drip glaze mouth through dripping glaze pipe and glaze groove intercommunication, and the glaze inslot's ground glaze is by the pump sending to dripping glaze mouth.
10. The method for preparing a linear space color stripe glazed ceramic as claimed in claim 8, wherein: and the step b of winding the stripe yarns by a yarn winding machine comprises the following steps: placing a blank on a driving turntable, performing center positioning on the blank through a centering fixture, pressing a pressure plate to the top of the blank to fix the blank, dipping the head of stripe yarns with partial glue, guiding the head of the stripe yarns to the surface of the blank to be close to the top for fixing, starting the driving turntable to rotate after the glue is dried, enabling the stripe yarns on a winding column to pass through the glaze groove and to pass through a guide wire eye to be wound on the blank, and driving the guide wire eye to move from top to bottom under the driving of a screw rod sliding table so as to drive the stripe yarns to cover the surface of the blank from top to bottom; in the process of yarn winding, the glaze dripping nozzle drips the ground glaze on the stripe yarns, and before the active turntable is started, the ground glaze is manually brushed on the part between the head of the stripe yarns and the wire eye.
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| CN115417698B (en) | 2023-11-10 |
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