CN113896506A - Linear chromatography glaze ceramic and preparation method thereof - Google Patents

Linear chromatography glaze ceramic and preparation method thereof Download PDF

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Publication number
CN113896506A
CN113896506A CN202110918434.XA CN202110918434A CN113896506A CN 113896506 A CN113896506 A CN 113896506A CN 202110918434 A CN202110918434 A CN 202110918434A CN 113896506 A CN113896506 A CN 113896506A
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parts
glaze
smoke
ceramic
furnace
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CN113896506B (en
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郑泽洽
郑晟亮
郑衍彬
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Fujian Taigu Ceramics Co ltd
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Fujian Taigu Ceramics Co ltd
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Abstract

The invention relates to the field of ceramic products and preparation methods thereof, in particular to a linear chromatography glaze ceramic and a preparation method thereof. Carrying out double-layer glaze sealing before entering a kiln, and filling paraffin among the annular textures, so that the paraffin is evaporated to break through the overglaze in the process of calcining the ceramic, and brown annular textures are separated out from the glaze layer; the smoke exhaust channel is arranged at the bottom of the furnace body, smoke rises from the space between the inner material rack and the outer material rack of the inner material rack and diffuses towards two sides at the arc furnace top, one part of smoke is discharged from the smoke return channel between the inner material rack and the rotating shaft, and the other part of smoke flows back from the recovery channel between the outer material rack and the furnace wall of the smoke and is converged with the rising smoke for reuse, so that the smoke utilization rate is improved; the flue gas gets into the whirl chamber, and the whirl air-supply line passes through the air and accelerates the flue gas rotatory to with the spraying intensive mixing, reduce the flue gas and directly discharge.

Description

Linear chromatography glaze ceramic and preparation method thereof
Technical Field
The invention relates to the field of ceramic products and preparation methods thereof, in particular to linear chromatography glaze ceramic and a preparation method thereof.
Background
The ceramic is a general term of pottery and porcelain, is also an industrial art in China, and is wild and simple ancient painted pottery and black pottery in China in the age of the stone novelties. Ceramics have different textures and properties. Pottery is made of clay with high viscosity and high plasticity as main material, and has opaque, fine pores and weak hydroscopicity. The porcelain is made of clay, feldspar and quartz, is semitransparent, does not absorb water, is corrosion resistant, has hard and compact matrix, and is crisp when being knocked. Present ceramic surface line and colour are single, and in order to increase ceramic expression form, modern ceramic burns technology and has adopted traditional firewood to burn technology and process for ceramic glaze presents ancient ways, anomalous pattern, but present firewood kiln is burnt and is had some problems: the smoke discharged by the traditional firewood kiln is positioned at the top, the smoke and flame rise linearly, the ash falling is not obvious, and the effect of melting the ash falling is difficult to achieve; the resistance auxiliary heating wire is easy to drop ash and oxidize, so that the service life of the electric heating wire is greatly shortened; the position of the ceramic in the furnace is not moved in the firing process, the falling ash is easy to concentrate on the outer side, the falling ash on one side is not caused, and the firing effect is not beautiful enough; the firewood is ignited in the whole process, and the firewood needs to be increased in the high-temperature process, so that the smoke is increased, and the burden is caused to the environment; the flue gas recovery effect is not good, and therefore the scheme is generated.
Disclosure of Invention
An object of the present invention is to solve at least the above problems by a linear chromatography glaze ceramic and a method for preparing the same.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: the linear chromatography glaze ceramic comprises a blank body, a ground glaze and a cover glaze, and is characterized in that: the blank body is formed by hand pulling, the surface of the blank body is provided with annular textures, and the glaze of the overglaze comprises the following components in parts by weight: 5-6 parts of white ball clay, 10-12 parts of sodium hexametaphosphate, 5-10 parts of red iron oxide, 20-22 parts of calcined kaolin, 10-12 parts of nepheline orthoclase, 15-17 parts of spodumene, 10-12 parts of calcium carbonate, 15-18 parts of quartz and 10-12 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 5-10 parts of sodium pyroborate, 6-8 parts of soda ash, 12-15 parts of kaolin, 5-8 parts of silicon, 3-5 parts of bentonite, 5-6 parts of flint and 10-12 parts of lithium carbonate.
Preferably, the raw material components of the ceramic body comprise the following components in parts by weight: 30-35 parts of kaolin, 20-30 parts of quartz, 10-15 parts of calcium carbonate, 10-12 parts of orthoclase and 12-15 parts of aluminum-containing ball clay.
Preferably, the glaze of the overglaze comprises the following components in parts by weight: the glaze comprises, by weight, 5 parts of white ball clay, 10 parts of sodium hexametaphosphate, 5 parts of red iron oxide, 20 parts of calcined kaolin, 10 parts of nepheline orthoclase, 15 parts of spodumene, 10 parts of calcium carbonate, 15 parts of quartz and 10 parts of zinc oxide, and the glaze of the ground glaze comprises the following components: 5 parts of sodium pyroborate, 6 parts of soda ash, 12 parts of kaolin, 5 parts of silicon, 3 parts of bentonite, 5 parts of flint and 10 parts of lithium carbonate.
Preferably, the glaze of the overglaze comprises the following components in parts by weight: 6 parts of white ball clay, 12 parts of sodium hexametaphosphate, 10 parts of red iron oxide, 22 parts of calcined kaolin, 12 parts of nepheline orthoclase, 17 parts of spodumene, 12 parts of calcium carbonate, 18 parts of quartz and 12 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 10 parts of sodium pyroborate, 8 parts of soda ash, 15 parts of kaolin, 8 parts of silicon, 5 parts of bentonite, 6 parts of flint and 12 parts of lithium carbonate.
Preferably, the glaze of the overglaze comprises the following components in parts by weight: 5.5 parts of white ball clay, 11 parts of sodium hexametaphosphate, 7 parts of red iron oxide, 21 parts of calcined kaolin, 11 parts of nepheline orthoclase, 16 parts of spodumene, 11 parts of calcium carbonate, 16 parts of quartz and 11 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 7 parts of sodium pyroborate, 7 parts of soda ash, 13 parts of kaolin, 7 parts of silicon, 4 parts of bentonite, 5.5 parts of flint and 11.5 parts of lithium carbonate.
The preparation method of the linear chromatography glaze ceramic is characterized by comprising the following steps: the method comprises the following steps: step a, preparing a ceramic blank raw material, a ground glaze material and a surface glaze material; step b, forming a ceramic blank by hand pulling; c, spraying a base glaze material on the surface of the blank body in a glaze spraying mode, and drying the base glaze material; d, applying paraffin on the base glaze, and scraping redundant paraffin on the surface of the blank by using a scraper after the paraffin is dried so that the paraffin is only filled in the annular texture on the surface of the blank; e, spraying a surface glaze material on the base glaze, and drying the surface glaze material; and f, placing the blank body in an electric and diesel integrated kiln for sintering.
Preferably, electricity firewood integration kiln includes furnace body, electric heater unit, charging device, firewood burns device and smoke abatement device, electric heater unit sets up on the oven of furnace body, charging device sets up in the furnace body inner wall, firewood burns device sets up in the furnace body side, smoke abatement device sets up in the furnace body bottom, electric heater unit includes annular floor and electric heating wire, annular floor arranges along longitudinal separation, the inside electric heating wire that is equipped with of every annular floor, firewood burns device including dress firewood passageway and inlet channel, dress firewood passageway is located inlet channel top, is equipped with the air vent between dress firewood passageway and the inlet channel, the furnace body bottom is equipped with into the cigarette passageway, dress firewood passageway and inlet channel's end and inlet channel intercommunication.
Preferably, the furnace body comprises a furnace top, a furnace wall and a furnace base, the furnace top is arc-shaped, the furnace top can be placed at the top of the furnace wall in an opening mode, the furnace body is made of refractory bricks, the top surface of the annular rib plate declines from the furnace wall to the inside of the furnace body, the corner of the air inlet channel, which is connected with the smoke inlet channel, is arc-shaped, the connecting part of the furnace wall and the furnace base is arc-shaped, two firewood burning devices are arranged and symmetrically arranged, the charging device comprises a rotating shaft, a rotating motor, a lifting support, a lifting hydraulic cylinder, an inner material rack and an outer material rack, the rotating shaft is rotatably arranged below the furnace top, the rotating motor drives the rotating shaft to rotate, the lifting support is fixedly arranged at the upper end of the furnace top, the lifting hydraulic cylinder drives the lifting support to move up and down, the inner material rack is fixedly arranged on the rotating shaft, the outer material rack is fixedly arranged outside the inner material rack, and a smoke return channel is arranged between the inner material rack and the rotating shaft, a smoke ascending channel is arranged between the inner material frame and the outer material frame, and a smoke recycling channel is arranged between the outer material frame and the furnace wall.
Preferably, the stove base center is equipped with smoke exhaust pipeline, smoke abatement device includes whirl chamber, whirl air-supply line, reposition of redundant personnel separation blade, trickle atomising head, drain pipe and exhaust column, the whirl chamber is wide from top to bottom narrow, whirl chamber and smoke exhaust pipeline lower extreme intercommunication, the reposition of redundant personnel separation blade is located whirl chamber middle part, corresponds with smoke exhaust pipeline lower extreme position, the trickle atomising head is provided with reposition of redundant personnel separation blade below, whirl air-supply line and whirl chamber communicate along the tangential, and the whirl air-supply line is located between reposition of redundant personnel separation blade and the trickle atomising head, and the whirl air-supply line is equipped with two, is the symmetry setting, drain pipe and whirl chamber bottom intercommunication, exhaust column and drain pipe intercommunication.
Preferably, the step f includes the following steps: dropping ash at low temperature, igniting the firewood, and firing for one hour at low temperature depending on the temperature of the firewood so that the dropped ash of the firewood falls on the surface of the ceramic; while preserving heat and reducing and burning the wood, starting the electric heating device, raising the furnace temperature to 1350 ℃, and preserving heat for 4 hours; naturally cooling, turning off a current source, naturally cooling and taking out the ceramic.
From the above description, the linear chromatography glaze ceramic and the preparation method thereof provided by the invention have the following beneficial effects: carrying out double-layer glaze sealing before entering a kiln, and filling paraffin among the annular textures, so that the paraffin is evaporated to break through the overglaze in the process of calcining the ceramic, and brown annular textures are separated out from the glaze layer; the smoke exhaust channel is arranged at the bottom of the furnace body, smoke rises from the space between the inner material rack and the outer material rack of the inner material rack, the smoke diffuses towards two sides at the arc furnace top, one part of the smoke is discharged from the smoke return channel between the inner material rack and the rotating shaft, and the other part of the smoke flows back from the recovery channel between the outer material rack of the smoke and the furnace wall and is converged with the rising smoke for reuse, so that the smoke utilization rate is improved, the inner material rack and the outer material rack rotate in the firing process, the smoke falls from two sides, and the ash falls from the ceramic surface is uniformly distributed; the electric heating wire is protected in the annular rib plate, so that the electric heating wire cannot be oxidized with falling ash, the service life of the electric heating wire is prolonged, the temperature control precision of the electric heating wire is improved, the heating area and the heating transmission efficiency of the annular rib plate are improved, and the top of the annular rib plate is an inclined surface to avoid ash deposition; in the high-temperature firing stage, the temperature is increased by the aid of electric heating wires, so that the wood consumption is reduced, and the environmental pollution is reduced; the flue gas gets into the whirl chamber, and the whirl air-supply line passes through the air and accelerates the flue gas rotatory to with the spraying intensive mixing, reduce the flue gas and directly discharge.
Drawings
Fig. 1 is a schematic structural diagram of an electric and diesel integrated kiln.
Fig. 2 is an enlarged view of a portion a of fig. 1.
Detailed Description
The invention is further described below by means of specific embodiments.
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
As shown in the figure, the linear chromatography glaze ceramic comprises a blank body, a ground glaze and a surface glaze, wherein the blank body is formed by hand pulling, the surface of the blank body is provided with annular textures, and the glaze of the surface glaze comprises the following components in parts by weight: 5-6 parts of white ball clay, 10-12 parts of sodium hexametaphosphate, 5-10 parts of red iron oxide, 20-22 parts of calcined kaolin, 10-12 parts of nepheline orthoclase, 15-17 parts of spodumene, 10-12 parts of calcium carbonate, 15-18 parts of quartz and 10-12 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 5-10 parts of sodium pyroborate, 6-8 parts of soda ash, 12-15 parts of kaolin, 5-8 parts of silicon, 3-5 parts of bentonite, 5-6 parts of flint and 10-12 parts of lithium carbonate.
The ceramic body comprises the following raw material components in parts by weight: 30-35 parts of kaolin, 20-30 parts of quartz, 10-15 parts of calcium carbonate, 10-12 parts of orthoclase and 12-15 parts of aluminum-containing ball clay.
As a preferred embodiment: the glaze of the overglaze comprises the following components in parts by weight: 5 parts of white ball clay, 10 parts of sodium hexametaphosphate, 5 parts of red iron oxide, 20 parts of calcined kaolin, 10 parts of nepheline orthoclase, 15 parts of spodumene, 10 parts of calcium carbonate, 15 parts of quartz and 10 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 5 parts of sodium pyroborate, 6 parts of soda ash, 12 parts of kaolin, 5 parts of silicon, 3 parts of bentonite, 5 parts of flint and 10 parts of lithium carbonate.
As a preferred embodiment: the glaze of the overglaze comprises the following components in parts by weight: 6 parts of white ball clay, 12 parts of sodium hexametaphosphate, 10 parts of red iron oxide, 22 parts of calcined kaolin, 12 parts of nepheline orthoclase, 17 parts of spodumene, 12 parts of calcium carbonate, 18 parts of quartz and 12 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 10 parts of sodium pyroborate, 8 parts of soda ash, 15 parts of kaolin, 8 parts of silicon, 5 parts of bentonite, 6 parts of flint and 12 parts of lithium carbonate.
As a preferred embodiment: the glaze of the overglaze comprises the following components in parts by weight: 5.5 parts of white ball clay, 11 parts of sodium hexametaphosphate, 7 parts of red iron oxide, 21 parts of calcined kaolin, 11 parts of nepheline anorthite, 16 parts of spodumene, 11 parts of calcium carbonate, 16 parts of quartz and 11 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 7 parts of sodium pyroborate, 7 parts of soda ash, 13 parts of kaolin, 7 parts of silicon, 4 parts of bentonite, 5.5 parts of flint and 11.5 parts of lithium carbonate.
The preparation method of the linear chromatography glaze ceramic comprises the following steps: step a, preparing a ceramic blank raw material, a ground glaze material and a surface glaze material; step b, forming a ceramic blank by hand pulling; c, spraying a base glaze material on the surface of the blank body in a glaze spraying mode, and drying the base glaze material; d, applying paraffin on the base glaze, and scraping redundant paraffin on the surface of the blank by using a scraper after the paraffin is dried so that the paraffin is only filled in the annular texture on the surface of the blank; e, spraying a surface glaze material on the base glaze, and drying the surface glaze material; and f, placing the blank body in an electric and diesel integrated kiln for sintering.
Referring to fig. 1 and 2, the electric-diesel integrated kiln comprises a kiln body 1, an electric heating device 2, a charging device 3, a firewood burning device 4 and a smoke removing device 5, wherein the electric heating device 2 is arranged on a kiln wall 13 of the kiln body 1, the charging device 3 is arranged on the inner wall of the kiln body 1, the firewood burning device 4 is arranged on the side surface of the kiln body 1, the smoke removing device 5 is arranged at the bottom of the kiln body 1, the electric heating device 2 comprises annular ribbed plates 21 and electric heating wires 22, the annular ribbed plates 21 are longitudinally arranged at intervals, the electric heating wires 22 are arranged inside each annular ribbed plate 21, the firewood burning device 4 comprises a firewood containing channel 41 and an air inlet channel 42, the firewood containing channel 41 is positioned above the air inlet channel 42, a vent hole 43 is arranged between the firewood containing channel 41 and the air inlet channel 42, the bottom of the kiln body 1 is provided with a smoke inlet channel 11, the tail ends of the firewood containing channel 41 and the air inlet channel 42 are communicated with the smoke inlet channel 11, ash in the firewood containing channel 41 falls into the air inlet channel 42 through the smoke inlet channel 43, and enters the smoke intake passage 11 with the intake air.
The furnace body 1 comprises a furnace top 12, a furnace wall 13 and a furnace base 14, the furnace top 12 is arc-shaped, the furnace top 12 is placed on the top of the furnace wall 13 in an openable manner, the furnace body 1 is made of refractory bricks, the top surface of an annular rib plate 21 declines from the furnace wall 13 to the interior of the furnace body 1, the corner of a gas inlet channel 42 connected with a smoke inlet channel 11 is arc-shaped, the joint of the furnace wall 13 and the furnace base is arc-shaped, two firewood burning devices 4 are arranged and symmetrically arranged, a charging device 3 comprises a rotating shaft 31, a rotating motor 32, a lifting support 33, a lifting hydraulic cylinder (not shown), an inner material frame 34 and an outer material frame 35, the inner material frame 34 and the outer material frame 35 are respectively provided with multiple layers, the rotating shaft 31 is rotatably arranged below the furnace top 12, the rotating motor 32 drives the rotating shaft 31 to rotate, the lifting support 33 is fixedly arranged at the upper end of the furnace top 12, the lifting hydraulic cylinder drives the lifting support 33 to move up and down, the inner material frame 34 is fixedly arranged on the rotating shaft 31, the outer material frame 35 is fixedly sleeved outside the inner material frame 34, a smoke return channel 36 is arranged between the inner material frame 34 and the rotating shaft 31, the smoke return channel 36 is communicated with a cyclone air inlet pipe 52 of the smoke removing device 5, a smoke ascending channel 37 is arranged between the inner material frame 34 and the outer material frame 35, the ascending channel 37 is communicated with the smoke inlet channel 11, a smoke recovery channel 38 is arranged between the outer material frame 35 and the furnace wall 13, and the smoke recovery channel 38 is communicated with the smoke inlet channel 11. In the charging process, the furnace top 12 and the charging device 3 are lifted by the lifting hydraulic cylinder to leave the furnace wall 13, the furnace top 12 and the charging device 3 are rotated manually or electrically, and the ceramic to be fired is charged in the inner charging frame 34 and the outer charging frame 35.
The center of the furnace base 14 is provided with a smoke exhaust pipeline 15, as shown in fig. 2, the smoke abatement device 5 comprises a cyclone cavity 51, a cyclone air inlet pipe 52, a diversion baffle 53, a water spraying spray head 54, a water outlet pipe 55 and an air exhaust pipe 56, wherein the cyclone cavity 51 is wide at the top and narrow at the bottom, the cyclone cavity 51 is communicated with the lower end of the smoke exhaust pipeline 15, the diversion baffle 53 is positioned in the middle of the cyclone cavity 51 and corresponds to the lower end of the smoke exhaust pipeline 15, the water spraying spray head 54 is arranged below the diversion baffle 53, the cyclone air inlet pipe 52 is communicated with the cyclone cavity 51 along the tangential direction, the cyclone air inlet pipe 52 is positioned between the diversion baffle 53 and the water spraying spray head 54, the cyclone air inlet pipes 52 are symmetrically arranged, the water outlet pipe 55 is communicated with the bottom of the cyclone cavity 51, the air exhaust pipe 56 is communicated with the water outlet pipe 55, and the air exhaust pipe 56 is connected with an air pump, so that vacuum is formed in the smoke abatement device 5, and smoke in the furnace body is driven to be exhausted.
The step f comprises the following steps: dropping ash at low temperature, igniting the firewood, and firing for one hour at low temperature depending on the temperature of the firewood so that the dropped ash of the firewood falls on the surface of the ceramic; while the heat preservation reduction and the wood combustion are carried out, the electric heating device 2 is started to raise the furnace temperature to 1350 ℃, the wood consumption and the smoke emission can be reduced by raising the temperature through electric heating, and the heat preservation is carried out for 4 hours; naturally cooling, turning off a current source, naturally cooling and taking out the ceramic.
Double-layer glaze sealing is carried out before the ceramic is placed in a kiln, and paraffin is filled between the annular textures, so that during the calcining process of the ceramic, the paraffin is evaporated to break through the overglaze, brown annular textures are separated out from the glaze layer, and falling ash falls onto the ceramic glaze to form natural ash glaze, thus the ceramic is rich in layers; the smoke exhaust channel is arranged at the bottom of the furnace body 1, smoke rises from the position between the inner material rack 34 and the outer material rack 35 in the inner material rack 34 and diffuses towards two sides at the arc furnace top 12, one part of smoke is exhausted from the smoke return channel 36 between the inner material rack 34 and the rotating shaft 31, and the other part of smoke flows back from the recovery channel between the smoke outer material rack 35 and the furnace wall 13 and is converged with the rising smoke for reuse, so that the smoke utilization rate is improved, the inner material rack 34 and the outer material rack 35 rotate in the firing process, the smoke falls from two sides, and the ceramic surface falls uniformly; the electric heating wire 22 is protected in the annular rib plate 21, so that the electric heating wire 22 cannot be oxidized with falling ash, the service life and the temperature control precision of the electric heating wire 22 are improved, the heating area and the heating transmission efficiency of the annular rib plate 21 are improved, and the top of the annular rib plate 21 is an inclined surface to avoid ash deposition; in the high-temperature firing stage, the temperature is increased by the aid of the electric heating wires 22, so that the wood consumption is reduced, and the environmental pollution is reduced; the flue gas enters the cyclone chamber 51, and the cyclone air inlet pipe 52 accelerates the rotation of the flue gas through air and fully mixes with the spray, so that the direct discharge of flue gas dust is reduced.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "front", "rear", "left", "right", "top", "bottom", "inner", "outer", and the like, which indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, are used only for convenience in describing the present invention and for simplicity in description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be constructed in a specific orientation, and be operated, and therefore, should not be construed as limiting the present invention, and what is not described in detail in the present specification is prior art and is known to those skilled in the art.
In the description of the present invention, it should be noted that unless otherwise explicitly stated or limited, the terms "mounted," "connected," and "disposed" are to be construed broadly, e.g., as meaning fixedly connected, disposed, detachably connected, disposed, or integrally connected and disposed; the type of the electrical appliance provided by the invention is only used for reference. For those skilled in the art, different types of electrical appliances with the same function can be replaced according to actual use conditions, and for those skilled in the art, the specific meaning of the above terms in the present invention can be understood in specific situations.
The above description is only a few specific embodiments of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by the design concept should fall within the scope of the present invention.

Claims (10)

1. The linear chromatography glaze ceramic comprises a blank body, a ground glaze and a cover glaze, and is characterized in that: the blank body is formed by hand pulling, the surface of the blank body is provided with annular textures, and the glaze of the overglaze comprises the following components in parts by weight: 5-6 parts of white ball clay, 10-12 parts of sodium hexametaphosphate, 5-10 parts of red iron oxide, 20-22 parts of calcined kaolin, 10-12 parts of nepheline orthoclase, 15-17 parts of spodumene, 10-12 parts of calcium carbonate, 15-18 parts of quartz and 10-12 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 5-10 parts of sodium pyroborate, 6-8 parts of soda ash, 12-15 parts of kaolin, 5-8 parts of silicon, 3-5 parts of bentonite, 5-6 parts of flint and 10-12 parts of lithium carbonate.
2. The linear chromatography glaze ceramic of claim 1, wherein: the ceramic body comprises the following raw material components in parts by weight: 30-35 parts of kaolin, 20-30 parts of quartz, 10-15 parts of calcium carbonate, 10-12 parts of orthoclase and 12-15 parts of aluminum-containing ball clay.
3. The linear chromatography glaze ceramic of claim 1, wherein: the glaze of the overglaze comprises the following components in parts by weight: the glaze comprises, by weight, 5 parts of white ball clay, 10 parts of sodium hexametaphosphate, 5 parts of red iron oxide, 20 parts of calcined kaolin, 10 parts of nepheline orthoclase, 15 parts of spodumene, 10 parts of calcium carbonate, 15 parts of quartz and 10 parts of zinc oxide, and the glaze of the ground glaze comprises the following components: 5 parts of sodium pyroborate, 6 parts of soda ash, 12 parts of kaolin, 5 parts of silicon, 3 parts of bentonite, 5 parts of flint and 10 parts of lithium carbonate.
4. The linear chromatography glaze ceramic of claim 1, wherein: the glaze of the overglaze comprises the following components in parts by weight: 6 parts of white ball clay, 12 parts of sodium hexametaphosphate, 10 parts of red iron oxide, 22 parts of calcined kaolin, 12 parts of nepheline orthoclase, 17 parts of spodumene, 12 parts of calcium carbonate, 18 parts of quartz and 12 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 10 parts of sodium pyroborate, 8 parts of soda ash, 15 parts of kaolin, 8 parts of silicon, 5 parts of bentonite, 6 parts of flint and 12 parts of lithium carbonate.
5. The linear chromatography glaze ceramic of claim 1, wherein: the glaze of the overglaze comprises the following components in parts by weight: 5.5 parts of white ball clay, 11 parts of sodium hexametaphosphate, 7 parts of red iron oxide, 21 parts of calcined kaolin, 11 parts of nepheline orthoclase, 16 parts of spodumene, 11 parts of calcium carbonate, 16 parts of quartz and 11 parts of zinc oxide, wherein the glaze of the ground glaze comprises the following components in parts by weight: 7 parts of sodium pyroborate, 7 parts of soda ash, 13 parts of kaolin, 7 parts of silicon, 4 parts of bentonite, 5.5 parts of flint and 11.5 parts of lithium carbonate.
6. The method for preparing a linear chromatography glaze ceramic according to any one of claims 1 to 5, wherein: the method comprises the following steps: step a, preparing a ceramic blank raw material, a ground glaze material and a surface glaze material; step b, forming a ceramic blank by hand pulling; c, spraying a base glaze material on the surface of the blank body in a glaze spraying mode, and drying the base glaze material; d, applying paraffin on the base glaze, and scraping redundant paraffin on the surface of the blank by using a scraper after the paraffin is dried so that the paraffin is only filled in the annular texture on the surface of the blank; e, spraying a surface glaze material on the base glaze, and drying the surface glaze material; and f, placing the blank body in an electric and diesel integrated kiln for sintering.
7. The preparation method of the linear chromatography glaze ceramic of claim 6, which is characterized in that: the electric firewood integrated kiln comprises a kiln body, an electric heating device, a charging device, a firewood burning device and a smoke removing device, wherein the electric heating device is arranged on the kiln wall of the kiln body, the charging device is arranged on the inner wall of the kiln body, the firewood burning device is arranged on the side surface of the kiln body, the smoke removing device is arranged at the bottom of the kiln body, the electric heating device comprises annular rib plates and electric heating wires, the annular rib plates are arranged along the longitudinal interval, the electric heating wires are arranged inside each annular rib plate, the firewood burning device comprises a firewood loading channel and an air inlet channel, the firewood loading channel is positioned above the air inlet channel, air vents are arranged between the firewood loading channel and the air inlet channel, a smoke inlet channel is arranged at the bottom of the kiln body, and the tail ends of the firewood loading channel and the air inlet channel are communicated with the smoke inlet channel.
8. The preparation method of the linear chromatography glaze ceramic of claim 6, which is characterized in that: the furnace body comprises a furnace top, a furnace wall and a furnace base, the furnace top is arc-shaped, the furnace top can be placed at the top of the furnace wall in an opening mode, the furnace body is made of refractory bricks, the top surface of the annular rib plate declines from the furnace wall to the inside of the furnace body, the corner of the air inlet channel, which is connected with the smoke inlet channel, is arc-shaped, the joint of the furnace wall and the furnace base is arc-shaped, two firewood burning devices are arranged symmetrically, each material charging device comprises a rotating shaft, a rotating motor, a lifting support, a lifting hydraulic cylinder, an inner material frame and an outer material frame, the rotating shaft is rotatably arranged below the furnace top, the rotating motor drives the rotating shaft to rotate, the lifting support is fixedly arranged at the upper end of the furnace top, the lifting hydraulic cylinder drives the lifting support to move up and down, the inner material frame is fixedly arranged on the rotating shaft, the outer material frame is fixedly arranged outside the inner material frame, and a smoke return channel is arranged between the inner material frame and the rotating shaft, a smoke ascending channel is arranged between the inner material frame and the outer material frame, and a smoke recycling channel is arranged between the outer material frame and the furnace wall.
9. The preparation method of the linear chromatography glaze ceramic of claim 6, which is characterized in that: the stove base center is equipped with smoke extraction pipeline, smoke abatement device includes whirl chamber, whirl air-supply line, reposition of redundant personnel separation blade, trickle atomising head, drain pipe and exhaust column, the whirl chamber is wide from top to bottom narrow, whirl chamber and smoke extraction pipeline lower extreme intercommunication, the reposition of redundant personnel separation blade is located whirl chamber middle part, corresponds with smoke extraction pipeline lower extreme position, the trickle atomising head is provided with reposition of redundant personnel separation blade below, whirl air-supply line and whirl chamber communicate along the tangential, and the whirl air-supply line is located between reposition of redundant personnel separation blade and the trickle atomising head, and the whirl air-supply line is equipped with two, is the symmetry setting, drain pipe and whirl chamber bottom intercommunication, exhaust column and drain pipe intercommunication.
10. The preparation method of the linear chromatography glaze ceramic of claim 6, which is characterized in that: the step f comprises the following steps: dropping ash at low temperature, igniting the firewood, and firing for one hour at low temperature depending on the temperature of the firewood so that the dropped ash of the firewood falls on the surface of the ceramic; while preserving heat and reducing and burning the wood, starting the electric heating device, raising the furnace temperature to 1350 ℃, and preserving heat for 4 hours; naturally cooling, turning off a current source, naturally cooling and taking out the ceramic.
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